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高効率・高安定ナノ結晶シリコン発光素子の開発と光増幅への展開

Research Project

Project/Area Number 18760248
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeSingle-year Grants
Research Field Electron device/Electronic equipment
Research InstitutionTokyo University of Agriculture and Technology

Principal Investigator

BERNARD Gelloz (GELLOZ Bernard)  Tokyo University of Agriculture and Technology, 大学院・共生科学技術研究院, 教務職員 (40343157)

Project Period (FY) 2006 – 2007
Project Status Completed (Fiscal Year 2007)
Budget Amount *help
¥3,600,000 (Direct Cost: ¥3,600,000)
Fiscal Year 2007: ¥900,000 (Direct Cost: ¥900,000)
Fiscal Year 2006: ¥2,700,000 (Direct Cost: ¥2,700,000)
Keywordsエレクトロルミネッセンス / シリコンナノ結晶 / 発光効率 / 偏光メモリ / 表面パッシベーション / 青色発光 / ホットエレクトロン / 不揮発メモリ / 動作安定化
Research Abstract

量子サイズナノ結晶シリコン(nc-Si)の可視発光効果を本質的に解明し、素子化へ発展させるための学術課題に取り組んだ。前年度の結果をふまえ、nc-Si素子の可視発光特性を輝度・安定性の両面で飛躍的に向上させるプロセス技術を検討し、光励起一緩和過程の解析を行った。また発光の短波長化、光増幅性の検証に向けた基礎的知見を得た。主な成果を以下に示す
(1)可視域フォトルミネセンス(PL)の高効率化と安定化に対して有効な高圧水蒸気アニール(HWA)を最適化することで、安定な青色発光が得られることを見いだした。発光強度・スペクトルの温度依存性、励起強度依存性、励起光の偏光メモリ、発光寿命特性などにより、青色発光を従来の赤色発光と比較して詳細に解析した。その結果、ナノドット内の励起子に起因する赤色発光とは異なり、青色発光が表面酸化膜における特異な再結合機構に由来することをつきとめた。
(2)HWAにより発光効率を高めた試料にレーザー色素を含浸させたナノコンポジットを作製してPLの偏光メモリ効果の解析を行い、ナノドットにおけるエネルギー伝達過程の存在を実証した。またHWAをシリコンナノワイヤの安定化プロセスにも適用し、発光増強の効果を確認した。さらに、HWAがエレクトロルミネセンス(EL)の長期安定性にも大きく寄与することを示した。
(3)HWA処理によるnc-Si界面トラップの低減が多重トンネルによるホットエレクトロンの生成を効率化することに着目し、電子励起機能を内蔵した発光素子を作製した。無機蛍光体薄膜を金属薄膜ミラーで挟んだ共振器を装荷した素子において、駆動電圧の低減と発光スペクトルの狭帯化を確認した。また、nc-Si励起不揮発メモリにおいてもHWAは有効で、情報保持特性を著しく向上させることがわかった。

Report

(2 results)
  • 2007 Annual Research Report
  • 2006 Annual Research Report
  • Research Products

    (25 results)

All 2008 2007 2006 Other

All Journal Article (14 results) (of which Peer Reviewed: 7 results) Presentation (10 results) Remarks (1 results)

  • [Journal Article] Characteristics of nanocrystalline ballistic cold cathode in liquids as anactive electrode2008

    • Author(s)
      T. Ohta, B. Gelloz and N. Koshida
    • Journal Title

      Journal of Vacuum Science & Technology B 26

      Pages: 716-719

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] 溶液中でも動作する電子源電極の開発と水素発生2008

    • Author(s)
      越田信義、太田敢行、B. Gelloz
    • Journal Title

      燃料電池 7

      Pages: 88-92

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Energy transfer in porous silicon / laser dye composite evidenced by polarization memory of photoluminescence2007

    • Author(s)
      A. Chouket, H. Elhouichet, M.Oueslati, H. Koyama, B. Gelloz and N. Koshida
    • Journal Title

      Appl. Phys. Lett. 91

      Pages: 2119021-3

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Operation of Nanosilicon Ballistic Electron Emitter in Liquid Water and Hydrogen Generation Effect2007

    • Author(s)
      N. Koshida、T. Ohta, and B. Gelloz
    • Journal Title

      Appl. Phys. Lett. 90

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Highly Efficient and Stable Photoluminescence of Nanocrystalline Porous Silicon by Combination of Chemical Modification and Oxidation under High-Pressure2007

    • Author(s)
      B. Gelloz and N. Koshida
    • Journal Title

      Jpn J. Appl. Phys. 46

      Pages: 3462-3465

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Stabilization of nano-crystalline porous silicon electroluminescence by high pressure water vapor annealing2007

    • Author(s)
      B. Gelloz, T. Shibata and N. Koshida
    • Journal Title

      Physica Status Solidi (c) 4

      Pages: 2141-2144

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis and photoluminescence properties of silicon nanowires treated by high-pressure water vapor annealing2007

    • Author(s)
      B. Salhi, B. Gelloz, N. Koshida and R. Boukherroub
    • Journal Title

      Physica Status Solidi (a) 204

      Pages: 1302-1306

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Stabilization of nano-crystalline porous silicon electroluminescence by high pressure water vapor annealing2007

    • Author(s)
      B.Gelloz
    • Journal Title

      Physica Status Solidi (c) (in press)

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Synthesis and photoluminescence properties of silicon nanowires treated by high-pressure water vapor annealing2007

    • Author(s)
      B.Salhi, B.Gelloz
    • Journal Title

      Physica Status Solidi (c) (in press)

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Highly Efficient and Stable Photoluminescence of Nanocrystalline Porous Silicon by Combination of Chemical Modification and Oxidation under High Pressure2007

    • Author(s)
      B.Gelloz
    • Journal Title

      Japanese Journal of Applied Physics 46(In press)

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Synthesis and optical properties of silicon oxide nanowires2007

    • Author(s)
      B.Gelloz
    • Journal Title

      Material Research Society Symposium Proceedings, Group IV Semiconductor Nanostructures 958

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Pronounced Photonic Effects of High-Pressure Water Vapor Annealing on Nanocrystalline Porous Silicon2007

    • Author(s)
      B.Gelloz
    • Journal Title

      Material Research Society Symposium Proceedings, Group IV Semiconductor Nanostructures 958

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Stable electroluminescence of nanocrystalline silicon device activated by high-pressure water vapor annealing2006

    • Author(s)
      B.Gelloz
    • Journal Title

      Applied Physics Letters 89

      Pages: 191103-191103

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Highly Enhanced Efficiency and Stability of Photo- and Electro- Luminescence of Nano-Crystalline Porous Silicon by High-Pressure Water Vapor Annealing2006

    • Author(s)
      B.Gelloz
    • Journal Title

      Japanese Journal of Applied Physics 45

      Pages: 3462-3462

    • Related Report
      2006 Annual Research Report
  • [Presentation] Photonic characteristics of nanocrystalline porous silicon treated by high-pressure water vapor annealing2008

    • Author(s)
      B. Gelloz and N. Koshida
    • Organizer
      Int. Conf. on Porous Semiconductors Science and Technology
    • Place of Presentation
      Mallorca, Spain
    • Year and Date
      2008-03-12
    • Related Report
      2007 Annual Research Report
  • [Presentation] Polarization memory in enhanced photoluminescence of porous silicon as a trace of energy transfer to embedded laser dye molecules2008

    • Author(s)
      A. Chouket, B. Gelloz, H. Koyama H. Elhouichet, M. Oueslati, and N. Koshida
    • Organizer
      Int. Conf. on Porous Semiconductors Science and Technology
    • Place of Presentation
      Mallorca, Spain
    • Year and Date
      2008-03-12
    • Related Report
      2007 Annual Research Report
  • [Presentation] Carrier transport mechanisms in cathodically biased meso-porous p^+-Siagainst solutions containing Fe^<2+> and Co^<2+> species2008

    • Author(s)
      Farida Hamadache and B. Gelloz
    • Organizer
      Int. Conf. on Porous Semiconductors Science and Technology
    • Place of Presentation
      Mallorca, Spain
    • Year and Date
      2008-03-10
    • Related Report
      2007 Annual Research Report
  • [Presentation] Light-emissive nonvolatile memory based on nanocrystalline porous Si2007

    • Author(s)
      B. Gelloz, Y. Yoshida and N. Koshida
    • Organizer
      4th IEEE Int. Conf. on Group IV Photonics
    • Place of Presentation
      Tokyo
    • Year and Date
      2007-09-20
    • Related Report
      2007 Annual Research Report
  • [Presentation] Cavity Effect in Nanocrystalline Porous Silicon Ballistic Lighting Device2007

    • Author(s)
      B. Gelloz, M. Sato and N. Koshida
    • Organizer
      Int. Conf. on Solid State Devices and Materials
    • Place of Presentation
      Tsukuba
    • Year and Date
      2007-09-19
    • Related Report
      2007 Annual Research Report
  • [Presentation] Photonic and related device applications of nano-crystalline silicon (invited).2007

    • Author(s)
      N. Koshida and B. Gelloz
    • Organizer
      SPIE Optics East
    • Place of Presentation
      Boston, USA
    • Year and Date
      2007-09-12
    • Related Report
      2007 Annual Research Report
  • [Presentation] Photonic, electronic, and acoustic devices based on nanocrystalline silicon (invited).2007

    • Author(s)
      N. Koshida and B. Gelloz
    • Organizer
      Int. Conf. on Optical, Optoelectronic and Photonic Mater. And Applications
    • Place of Presentation
      London, UK
    • Year and Date
      2007-07-30
    • Related Report
      2007 Annual Research Report
  • [Presentation] Characteristics of nanocrystalline ballistic cold cathode in liquids as anactive electrode2007

    • Author(s)
      T. Ohta, B. Gelloz and N. Koshida
    • Organizer
      Int. Vacuum Nanoelectronics Conf.
    • Place of Presentation
      Chicago, USA
    • Year and Date
      2007-07-11
    • Related Report
      2007 Annual Research Report
  • [Presentation] Functional Devices Based on Quantum-sized Nanosilicon (Invited)2007

    • Author(s)
      N. Koshida and B. Gelloz
    • Organizer
      2007 Asia-Pacific Workshop on Fundamentals and Applications of Advanced Semiconductor Devices
    • Place of Presentation
      Gyeongju, Korea
    • Year and Date
      2007-06-25
    • Related Report
      2007 Annual Research Report
  • [Presentation] Polarization memory of blue and red Luminescence from nanocrystalline porous silicon Treated by high-pressure water vapor annealing2007

    • Author(s)
      B. Gelloz, H. Koyama and N. Koshida
    • Organizer
      5th Int. Conf. on Silicon Epitaxy and Heterostructures
    • Place of Presentation
      Marseille, France
    • Year and Date
      2007-05-24
    • Related Report
      2007 Annual Research Report
  • [Remarks]

    • URL

      http://www.tuat.ac.jp/~koslab

    • Related Report
      2007 Annual Research Report

URL: 

Published: 2006-04-01   Modified: 2016-04-21  

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