| Project/Area Number |
18F18333
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| Research Category |
Grant-in-Aid for JSPS Fellows
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| Allocation Type | Single-year Grants |
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| Section | 外国 |
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| Review Section |
Basic Section 34010:Inorganic/coordination chemistry-related
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| Research Institution | Institute of Physical and Chemical Research |
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Principal Investigator |
侯 召民 国立研究開発法人理化学研究所, 開拓研究本部, 主任研究員 (10261158)
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| Co-Investigator(Kenkyū-buntansha) |
MO ZHENBO 国立研究開発法人理化学研究所, 開拓研究本部, 外国人特別研究員
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| Project Period (FY) |
2018-11-09 – 2021-03-31
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| Project Status |
Completed (Fiscal Year 2019)
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| Budget Amount *help |
¥2,400,000 (Direct Cost: ¥2,400,000)
Fiscal Year 2019: ¥1,200,000 (Direct Cost: ¥1,200,000)
Fiscal Year 2018: ¥600,000 (Direct Cost: ¥600,000)
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| Keywords | titanium / N2 activation / N2 transformation / rigid ligands / dinitrogen activation / hydrogenation / alkyl complex / hydride complex / dinitrogen complex / PNP ligation |
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| Outline of Annual Research Achievements |
Studies on N2 activation by transition metal hydride complexes are of particular interest and importance, but studies on well-defined N2 metal hydride complexes are still very limited. We report the synthesis and diverse transformations of a N2 dititanium hydride complex bearing the rigid acridane-based acriPNP-pincer ligands. This complex enabled N2 cleavage and hydrogenation even without additional reagents. Furthermore, diverse transformations of the N2 unit with a variety of organometallic compounds have been well established at the rigid acriPNP-ligated dititanium framework. This work has revealed many unprecedented aspects of N2 reaction chemistry, and may help open a new avenue for the design and synthesis of well-defined metal hydride complexes for N2 fixation and transformation.
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| Research Progress Status |
翌年度、交付申請を辞退するため、記入しない。
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| Strategy for Future Research Activity |
翌年度、交付申請を辞退するため、記入しない。
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