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Organometallic and Cluster Chemistry in M+I40etalloenzymes with Reducing Activities

Research Project

Project/Area Number 18GS0207
Research Category

Grant-in-Aid for Creative Scientific Research

Allocation TypeSingle-year Grants
Research InstitutionNagoya University

Principal Investigator

TATSUMI Kazuyuki  名古屋大学, 物質科学国際研究センター, 教授 (10155096)

Co-Investigator(Kenkyū-buntansha) KAZUNARI Yoshizawa  九州大学, 先導物質化学研究所, 教授 (30273486)
HIGUCHI Yoshiki  兵庫県立大学, 大学院・生命理学研究科, 教授 (90183574)
KAWAGUCHI Hiroyuki  東京工業大学, 大学院・理工学研究科, 教授 (20262850)
MATSUMOTO Tsuyoshi  名古屋大学, 大学院・理学研究科, 助教 (50311717)
OHKI Yasuhiro  名古屋大学, 大学院・理学研究科, 准教授 (10324394)
Project Period (FY) 2006 – 2010
Project Status Completed (Fiscal Year 2010)
Budget Amount *help
¥579,150,000 (Direct Cost: ¥445,500,000、Indirect Cost: ¥133,650,000)
Fiscal Year 2010: ¥102,960,000 (Direct Cost: ¥79,200,000、Indirect Cost: ¥23,760,000)
Fiscal Year 2009: ¥114,400,000 (Direct Cost: ¥88,000,000、Indirect Cost: ¥26,400,000)
Fiscal Year 2008: ¥114,400,000 (Direct Cost: ¥88,000,000、Indirect Cost: ¥26,400,000)
Fiscal Year 2007: ¥114,400,000 (Direct Cost: ¥88,000,000、Indirect Cost: ¥26,400,000)
Fiscal Year 2006: ¥132,990,000 (Direct Cost: ¥102,300,000、Indirect Cost: ¥30,690,000)
Keywords金属-硫黄クラスター / ニトロゲナーゼ / ヒドロゲナーゼ / 還元系金属酵素 / 金属硫黄クラスター / 小分子活性化 / アセチルCoA合成酵素 / COデヒドロゲナーゼ / 有機金属化学 / 金属酵素
Research Abstract

Through the integration of coordination/organometallic chemistry, structural biology, and theoretical chemistry, we have undertaken the chemical study of reductases, the importance of which has been noticed recently in connection with social needs for energy and food. Our accomplishments in this program have exceeded our expectations, and we have achieved significant results that provide clues in understanding the enzymatic function of reductases at the cluster active sites. We have succeeded in synthesizing favourable models of the active-sites of nitrogenase and hydrogenase, and their physicochemical properties have been clarified, enabling us to study the chemistry of these enzymes. From the theoretical analysis of the newly synthesized dinuclear complex that activates dinitrogen, we revealed its reaction mechanism, which also provides us with important information concerning the reaction mechanisms of nitrogenase and hydrogenases. We have also discovered the novel[4Fe-3S] cluster in the structure of an oxygen-tolerant[NiFe] hydrogenase.

Report

(6 results)
  • 2010 Annual Research Report   Final Research Report ( PDF )
  • 2008 Annual Research Report   Self-evaluation Report ( PDF )
  • 2007 Annual Research Report
  • 2006 Annual Research Report
  • Research Products

    (208 results)

All 2011 2010 2009 2008 2007 2006 Other

All Journal Article (103 results) (of which Peer Reviewed: 88 results) Presentation (90 results) Book (2 results) Remarks (13 results)

  • [Journal Article] Synthesis and Reactivity of Niobium Complexes Having a Tripodal Triaryloxide Ligand in Bidentate, Tridentate, and Tetradentate Coordination Modes2011

    • Author(s)
      F. Akagi, Y. Ishida, T. Matsuo, and H. Kawaguchi
    • Journal Title

      Dalton Trans.

      Volume: 40 Issue: 2 Pages: 2375-2382

    • DOI

      10.1039/b911082h

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Structural Basis for a[4Fe-3S] Cluster in the Oxygen-tolerant Membrane-bound[Ni-Fe]-hydrogenase2011

    • Author(s)
      Y. Shomura, K. Yoon, H. Nishihara, Y. Higuchi
    • Journal Title

      Nature

      Volume: 479 Issue: 7372 Pages: 253-257

    • DOI

      10.1038/nature10504

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Molybdenum-Catalyzed Transformation of Molecular Dinitrogen into Silylamine : Experimental and DFT Study on Remarkable Role of Ferrocenyldiphosphine Ligands2011

    • Author(s)
      H. Tanaka, A. Sasada, T. Kouno, M. Yuki, Y. Miyake, H. Nakanishi, Y. Nishibayashi, K. Yoshizawa
    • Journal Title

      Am. Chem. Soc.

      Volume: 133 Issue: 10 Pages: 3498-3506

    • DOI

      10.1021/ja109181n

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Computational Evidences for Hydrogen Generation via Reductive Cleavage of Water andα-H Abstraction on a Molybdenum Complex2011

    • Author(s)
      J. Li, K. Yoshizawa
    • Journal Title

      Angew. Chem. Int. Ed.

      Volume: 50 Issue: 50 Pages: 11972-11975

    • DOI

      10.1002/anie.201102917

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Dihydrogen activation by sulfido-bridged dinuclear Ru/Ge complexes : insight into the [NiFe] hydrogenase unready state2011

    • Author(s)
      Matsumoto, T.; Itakura, N.; Nakaya, Y.; Tatsumi, K.
    • Journal Title

      Chem.Commun.

      Volume: 47 Pages: 1030-1032

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Thiolate-Bridged Iron-Nickel Models for the Active Site of [NiFe] Hydrogenase2011

    • Author(s)
      Ohki, Y.; Tatsumi, K.
    • Journal Title

      Eur.J.Inorg.Chem.

      Volume: 31 Pages: 973-985

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Cooperative Catalytic Activation of Si-H Bonds by a Polar Ru-S Bond : Regioselective Low-Temperature C-H Silylation of Indoles under Neutral Conditions by a Friedel-Crafts Mechanism2011

    • Author(s)
      Klare, H.F.T.; Oestreich, M.; Ito, J.; Nishiyama, H.; Ohki, Y.; Tatsumi, K.
    • Journal Title

      J.Am.Chem.Soc.

      Volume: 133 Pages: 3312-3315

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] A Model for the CO-Inhibited Form of[NiFe] Hydrogenase : Synthesis of(CO) 3Fe(μ-StBu) 3Ni{SC6H3-2, 6-(mesityl) 2} and Reversible CO Addition at the Ni Site2010

    • Author(s)
      Y. Ohki, K. Yasumura, M. Ando, S. Shimokata, K. Tatsumi
    • Journal Title

      Proc. Natl. Acad. Sci. U. S. A

      Volume: 107 Issue: 9 Pages: 3994-3997

    • DOI

      10.1073/pnas.0913399107

    • Related Report
      2010 Final Research Report
  • [Journal Article] Synthesis and Reactions of Coordinatively Unsaturated Half-Sandwich Rhodium and Iridium Complexes Having a 2,6-Dimesitylbenzenethiolate Ligand2010

    • Author(s)
      Sakamoto, M.; Ohki, Y.; Tatsumi, K.
    • Journal Title

      Organometallics

      Volume: 29 Pages: 1761-7770

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Dodecanuclear-Ellipse and Decanuclear-Wheel Nickel(II) Thiolato Clusters with Efficient Femtosecond Nonlinear Absorption2010

    • Author(s)
      Zhang, C.; Matsumoto, T.; Samoc, M.; Petrie, S.; Meng, S.; Corkery, T.C.; Stranger, R.; Zhang, J.; Humphrey, M.G.; Tatsumi, K.
    • Journal Title

      Angew.Chem.Int.Ed.

      Volume: 49 Pages: 4209-4212

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] C-H Activation/Borylation of Furans and Thiophenes Catalyzed by a Half-Sandwich Iron N-Heterocyclic Carbene Complex2010

    • Author(s)
      Hatanaka, T.; Ohki, Y.; Tatsumi, K.
    • Journal Title

      Chem.Asian J.

      Volume: 5 Pages: 1657-1666

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis of Coordinatively Unsaturated Mesityliron Thiolate Complexes and Their Reactions with Elemental Sulfur2010

    • Author(s)
      Hashimoto, T.; Ohki, Y.; Tatsumi, K.
    • Journal Title

      Inorg.Chem.

      Volume: 49 Pages: 6102-6109

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] An Iron(II) Carbonyl Thiolato Complex Bearing 2-Methoxy-Pyridine : A Structural Model of the Active Site of [Fe] Hydrogenase2010

    • Author(s)
      Tanino, S.; Ohki, Y.; Tatsumi, K
    • Journal Title

      Chem.Asian J.

      Volume: 5 Pages: 1962-1964

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Exploring the Limits of Frustrated Lewis Pair Chemistry with Alkynes : Detection of a System that Favors 1,1-Carboboration over Cooperative 1,2-P/B-Addition2010

    • Author(s)
      Chen, C.; Eweiner, F.; Wibbeling, B.; Frchlich, R.; Senda, S.; Ohki, Y.; Tatsumi, K.; Grimme, S.; Kehr, G.; Erker, G.
    • Journal Title

      Chem.Asian J.

      Volume: 5 Pages: 2199-2208

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Monomeric Iron(II) Complexes Having Two Sterically Hindered Arylthiolates2010

    • Author(s)
      Ohki, Y.; Ohta, S.; Tatsumi, K.
    • Journal Title

      Inorg.Synth.

      Volume: 35 Pages: 137-143

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Coordination of Coenzyme M and Its Derivatives on Ni^<II> (tetraazacycle) Complexes : A Model for the Active Site of Methyl Coenzyme M Reductase2010

    • Author(s)
      Nishigaki, J.; Matsumoto, T.; Tatsumi, K.
    • Journal Title

      Eur.J.Inorg.Chem.

      Volume: 30 Pages: 5011-5017

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Dinuclear Nickel Complexes Modeling the Structure and Function of the Acetyl CoA Synthase Active-Site2009

    • Author(s)
      M. Ito, M. Kotera, T. Matsumoto, K. Tatsumi
    • Journal Title

      Proc. Natl. Acad. Sci. U. S. A

      Volume: 106 Issue: 29 Pages: 11862-11866

    • DOI

      10.1073/pnas.0900433106

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis, Structures, and Electronic Properties of[8Fe-7S] Cluster Complexes Modeling the Nitrogenase P-Cluster2009

    • Author(s)
      Y. Ohki, M. Imada, A. Murata, Y. Sunada, S. Ohta, M. Honda, T. Sasamori, N. Tokitoh, M. Katada, K. Tatsumi
    • Journal Title

      J. Am. Chem. Soc.

      Volume: 131 Issue: 36 Pages: 13168-13178

    • DOI

      10.1021/ja9055036

    • Related Report
      2010 Final Research Report
  • [Journal Article] Host Plant Genome Overcomes the Lack of a Bacterial Gene for Symbiotic Nitrogen Fixation2009

    • Author(s)
      T. Hakoyama, K. Niimi, H. Watanabe, R. Tabata, J. Matsubara, S. Sato, Y. Nakamura, S. Tabata, J. Li, T. Matsumoto, K. Tatsumi, M. Nomura, S. Tajima, M. Ishizuka, K. Yano, H. Imaizumi-Anraku, M. Kawaguchi, H. Kouchi, N. Suganuma
    • Journal Title

      Nature

      Volume: 462 Issue: 7272 Pages: 514-518

    • DOI

      10.1038/nature08594

    • NAID

      120002146280

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Reductive Coupling of Six Carbon Monoxides by a Ditantalum Hydride Complex2009

    • Author(s)
      T. Watanabe, Y. Ishida, T. Matsuo, H. Kawaguchi
    • Journal Title

      J. Am. Chem. Soc.

      Volume: 131 Issue: 10 Pages: 3474-3475

    • DOI

      10.1021/ja9007276

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] [NiFe] hydrogenases : structural and spectroscopic studies of the reaction mechanism2009

    • Author(s)
      H. Ogata, W. Lubitz, Y. Higuchi
    • Journal Title

      Dalton Trans.

      Volume: 37 Issue: 37 Pages: 7577-7587

    • DOI

      10.1039/b903840j

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Dinuclear Nickel Complexes Modeling the Structure and Function of the Acetyl CoA Synthase Active-Site2009

    • Author(s)
      M. Ito, M. Kotera, Y. Song, T. Matsumoto, K. Tatsumi,
    • Journal Title

      Proc. Natl. Acad. Sci. U.S.A. 106(in press)

    • Related Report
      2008 Self-evaluation Report
    • Peer Reviewed
  • [Journal Article] Structural Models for the Active Site of Acetyl-CoA Synthase: Synthesis of Dinuclear Nickel Complexes Having Thiolate, Isocyanide, and Thiourea on the Ni_p Site2009

    • Author(s)
      M. Ito, M. Kotera, Y. Song, T. Matsumoto, K. Tatsumi
    • Journal Title

      Inorg. Chem. 48

      Pages: 1250-1256

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis and Reactions of Mono- and Dinuclear Ni(I) Thiolate Complexes2009

    • Author(s)
      M. Ito, T. Matsumoto, K. Tatsumi
    • Journal Title

      Inorg. Chem. 48

      Pages: 2215-2223

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Cationic and Anionic Dinuclear Nickel Complexes [Ni(N_2S_2)Ni(dtc)]^n (n- -1, +1) Modeling the Active Site of Acetyl-CoA Synthase2009

    • Author(s)
      Y. Song, M. Ito, M. Kotera, T. Matsumoto, K. Tatsumi
    • Journal Title

      Chem. Lett. 38

      Pages: 184-185

    • NAID

      10025119498

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] A Dithiolate-Bridged (CN)_2(CO)Fe-Ni Complex Reproducing the IR Spectrum of [NiFe] Hy drogenase2009

    • Author(s)
      S. Tanino, Z. Li, Y. Ohki, K. Tatsumi
    • Journal Title

      Inorg. Chem. 48

      Pages: 2358-2360

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Reductive Coupling of Six Carbon Monoxides by a Ditantalum Hydride Complex2009

    • Author(s)
      T. Watanabe, Y. Ishida, T. Matsuo, H. Kawaguchi
    • Journal Title

      J. Am. Chem. Soc. 131

      Pages: 3474-3475

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Strategic Roles of Axial Histidines in Structure Formation and Redox Regulation of Tetraheme Cytochrome c_32009

    • Author(s)
      Y. Takayama, N. D. Werbeck, H. Komori, K. Morita, K. Ozawa, Y. Higuchi, H. Akutsu
    • Journal Title

      Biochemistry 47

      Pages: 9405-9415

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Comparison of the Reactivity of Bis(μ-oxo)Cu^<II> Cun^<III> and Cu^<III> Cu^<III> Species to Methane2009

    • Author(s)
      Y. Shiota, K. Yoshizawa
    • Journal Title

      Inorg. Chem. 48

      Pages: 838-845

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Thiolate-bridged dinuclear iron(tris-carbonyl)-nickel complexes relevant to the active site of[NiFe] hydrogenase2008

    • Author(s)
      Y. Ohki, K. Yasumura, K. Kuge, S. Tanino, M. Ando, Z. Li, K. Tatsumi
    • Journal Title

      Proc. Natl. Acad. Sci. U. S. A

      Volume: 105 Issue: 22 Pages: 7652-7657

    • DOI

      10.1073/pnas.0800538105

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] DFT Study on Chemical N2 Fixation by Using a Cubane-Type RuIr3S4 Cluster : Energy Profile for Binding and Reduction of N2 to Ammonia via Ru-N-NHx(x=1-3) Intermediates with Unique Structures2008

    • Author(s)
      H. Tanaka, H. Mori, H. Seino, M. Hidai, Y. Mizobe, K. Yoshizawa
    • Journal Title

      J. Am. Chem. Soc.

      Volume: 130 Issue: 28 Pages: 9037-9047

    • DOI

      10.1021/ja8009567

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Quantum Chemical Approach to the Mechanism for the Biological Conversion of Tyrosine to Dopaquinone2008

    • Author(s)
      T. Inoue, Y. Shiota, K. Yoshizawa
    • Journal Title

      J. Am. Chem. Soc.

      Volume: 130 Issue: 50 Pages: 16890-16897

    • DOI

      10.1021/ja802618s

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Thiolate-bridged dinuclear iron(tris-carbonyl)-nickel complexes relevant to the active site of [NiFe] hydrogenase2008

    • Author(s)
      Y. Ohki, K. Yasumura, K. Kuge, S. Tanino, M. Ando, Z. Li and K. Tatsumi
    • Journal Title

      Proc. Natl. Acad. Sci. U.S.A. 105

      Pages: 7652-7657

    • Related Report
      2008 Self-evaluation Report
    • Peer Reviewed
  • [Journal Article] C-H Bond Activation of Heteroarenes Mediated by a Half-Sandwich Iron Complex of N-Heterocyclic Carbene2008

    • Author(s)
      Y. Ohki, T. Hatanaka and K. Tatsumi
    • Journal Title

      J. Am. Chem. Soc. 130

      Pages: 17174-17186

    • Related Report
      2008 Self-evaluation Report
    • Peer Reviewed
  • [Journal Article] Reversible Heterolysis of H_2 Mediated by an M-S(thiolate) Bond (M=Rh, Ir) : A Mechanistic Implication for [NiFe] Hydrogenase2008

    • Author(s)
      Y. Ohki, M. Sakamoto and K. Tatsumi
    • Journal Title

      J. Am. Chem. Soc. 130

      Pages: 11610-11611

    • Related Report
      2008 Self-evaluation Report
    • Peer Reviewed
  • [Journal Article] A Functional Hydrogenase Model : Reversible Interconversion of H_2 and H_2O by a Hydroxo/Sulfido-Bridged Dinuclear Ruthenium-Germanium Complex2008

    • Author(s)
      T. Matsumoto, Y. Nakaya, N. Itakura and K. Tatsumi
    • Journal Title

      J. Am. Chem. Soc. 130

      Pages: 2458-2459

    • Related Report
      2008 Self-evaluation Report
    • Peer Reviewed
  • [Journal Article] Heterolytic Dihydrogen Activation by a Sulfidoand Oxo-Bridged Dinuclear Germanium-Ruthenium Complex2008

    • Author(s)
      T. Matsumoto, Y. Nakaya and K. Tatsumi
    • Journal Title

      Angew. Chem. Int. Ed. 47

      Pages: 1913-1915

    • Related Report
      2008 Self-evaluation Report
    • Peer Reviewed
  • [Journal Article] DFT Study on Chemical N_2 Fixation by Using a Cubane-Type RuIr_3S_4 Cluster: Energy Profile for Binding and Reduction of N_2 to Ammonia via Ru-N-NH_x (x=1-3) Intermediates with Unique Structures2008

    • Author(s)
      H. Tanaka, H. Mori, H. Seino, M. Hidai, Y. Mizobe, K. Yoshizawa
    • Journal Title

      J. Am. Chem. Soc. 130

      Pages: 9037-9047

    • Related Report
      2008 Annual Research Report 2008 Self-evaluation Report
    • Peer Reviewed
  • [Journal Article] Molybdenum Trisulfido-Chlorido Anion [MoClS_3]: A Versatile Precursor for Thiomolybdate Derivatives2008

    • Author(s)
      J. Ito, Y. Ohki, M. Iwata, K. Tatsumi
    • Journal Title

      Inorg. Chem. 47

      Pages: 3763-3771

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Thiolate-bridged dinuclear iron(tris-carbonyl)-nickel complexes relevant to the active site of [NiFe] hydroeenase2008

    • Author(s)
      Y. Ohki, K. Yasumura, K. Kuge, S. Tanino, M. Ando, Z. Li, K. Tatsumi
    • Journal Title

      Proc. Natl. Acad. Sci. U. S. A. 105

      Pages: 7652-7657

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Reactions at the Ru-S Bonds of Coordinatively Unsaturated Ruthenium Complexes Having Tethered 2, 6-Dimesitylphenyl Thiolate2008

    • Author(s)
      Y. Ohki, Y. Takikawa, H. Sadohara, C. Kesenheimer, B. Engendahl, E. Kapatsina, K. Tatsumi
    • Journal Title

      Chem. Asian J. 3

      Pages: 1625-1635

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Heterolytic Cleavage of Dihydrogen by Frustrated Lewis Pairs Derived from α-(Dimesitylph ospino)ferrocenes and B(C_6F_5)_32008

    • Author(s)
      D. P. Huber, G. Kehr, K. Bergander, R. Frolich, G. Erker, S. Tanino, Y. Ohki, K. Tatsumi
    • Journal Title

      Organometallics 27

      Pages: 5279-5284

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Reversible Heterolysis of H_2 Mediated by an M-S(thiolate) Bond (M=Rh, Ir): A Mechanistic Implication for [NiFe] Hydroeenase2008

    • Author(s)
      Y. Ohki, M. Sakamoto, K. Tatsumi
    • Journal Title

      J. Am. Chem. Soc. 130

      Pages: 11610-11611

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] C-H Bond Activation of Heteroarenes Mediated by a Half-Sandwich Iron Complex of N-He terocyclic Carbene2008

    • Author(s)
      Y. Ohki, T. Hatanaka, K. Tatsumi
    • Journal Title

      J. Am. Chem. Soc. 130

      Pages: 17174-17186

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Modulation of Third-Order Nonlinear Optical Properties by Backbone Modification of Poly meric Pillared-Layer Heterometallic Clusters2008

    • Author(s)
      C. Zhang, Y. Cao, J. Zhang, S. Meng, T. Matsumoto, Y. Song, J. Ma, Z. Chen, K. Tatsumi, M. G. Humphrey
    • Journal Title

      Adv. Mater. 20

      Pages: 1970-1875

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Metalation of Expanded Porphyrins: A Chemical Trigger Used To Produce Molecular Twisting and Mobius Aromaticity2008

    • Author(s)
      Y. Tanaka, S. Saito, S. Mori, N. Aratani, H. Shinokubo, N. Shibata, Y. Higuchi, Z. S. Yoon, K. S. Kim, S. B. Noh, J. K. Park, D. Kim, A. Osuka
    • Journal Title

      Angew. Chem. Int. Ed. 47

      Pages: 681-684

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Hydrogen Bonds of DsrD Protein Revealed by Neutron Crystallography2008

    • Author(s)
      T. Chatake, Y. Higuchi, N. Mizuno, I. Tanaka, N. Niimura, Y. Morimoto
    • Journal Title

      J. Synchrotron Rad. 15

      Pages: 277-280

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Crystallization and Preliminary X-ray Analysis of a Class II Release Factor RF3 from a Sulfate-reducing Bacterium2008

    • Author(s)
      K. Kihira, S. Numata, M. Kitamura, J. Kondo, S. Terawaki, Y. Shomura, H. Komori, N. Shibata, Y. Higuchi
    • Journal Title

      Acta crystallogr. F64

      Pages: 622-624

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Crystallization and Preliminary X-ray Crystallographic Study of Flavoredoxin from Desulfovi brio vulgaris Miyazaki F2008

    • Author(s)
      Y. Ueda, N. Shibata, D. Takeuchi, M. Kitamura, Y. Higuchi
    • Journal Title

      Acta crystallogr. F64

      Pages: 851-853

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] pH-Dependent Isotope Exchange and Hydrogenation Catalysed by Water-soluble NiRu Complexes as Functional Models for [NiFe] hydrogenases2008

    • Author(s)
      B. Kure, T. Matsumoto, K. Ichikawa, S. Fukuzumi, Y. Higuchi, T. Yasi, S. Ogo
    • Journal Title

      Dalton Trans.

      Pages: 4747-4755

    • NAID

      120002235780

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Orbital Views of the Electron Transport in Molecular Devices2008

    • Author(s)
      K. Yoshizawa, T. Tada, A. Staykov
    • Journal Title

      J. Am. Chem. Soc. 130

      Pages: 9406-9413

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Theoretical Analysis of the Reaction Mechanism of Biotin Carboxylase2008

    • Author(s)
      Y. Ito, H. Kondo, Y. Shiota, K. Yoshizawa
    • Journal Title

      J. Chem. Theor. Comput. 4

      Pages: 366-374

    • Related Report
      2008 Annual Research Report 2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Rutenium-Catalyzed Selective and Efficient Oxygenation of Hydrocarbons with Water as an Oxygen Source2008

    • Author(s)
      Y. Hirata, T. Kojima, Y. Mizutani, Y. Shiota, K. Yoshizawa, S. Fukuzumi
    • Journal Title

      Angew. Chem. Int. Ed 47

      Pages: 5772-5776

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Mechanism and Kinetics of Cyanide Destruction by Ferrate2008

    • Author(s)
      T. Kamachi, T. Nakayama, K. Yoshizawa
    • Journal Title

      Bull. Chem. Soc. Jpn. 81

      Pages: 1212-1218

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Theoretical Study of Long-Ranged Electron Transport in Molecular Junctions2008

    • Author(s)
      D. Nozaki, Y. Girard, K. Yoshizawa
    • Journal Title

      J. Phys. Chem. C. 112

      Pages: 17408-17415

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Combined Experimental and Theoretical Approach to Understand the Reactivity of a Monon uclear Cu(II)-Hydroperoxo Complex in Oxgenation Reactions2008

    • Author(s)
      T. Kamachi, Y. -M. Lee, T. Nishimi, J. Cho, K. Yoshizawa, W. Nam
    • Journal Title

      J. Phys. Chem. A. 112

      Pages: 13102-13108

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Quantum Chemical Approach to the Mechanism for the Biological Conversion of Tyrosine to Dopaquinone2008

    • Author(s)
      T. Inoue, Y. Shiota, K. Yoshizawa
    • Journal Title

      J. Am. Chem. Soc. 130

      Pages: 16890-16897

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Theoretical Study of the Direct Synthesis of H_2O_2 on Pd and Pd/Au Surfaces2008

    • Author(s)
      A. Staykov, T. Kamachi, T. Ishihara, K. Yoshizawa
    • Journal Title

      J. Phys. Chem. C. 112

      Pages: 19501-19505

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Heterolytic Dihydrogen Activation by a Sulfido-and Oxo-Bridged Dinuclear Germanium-Ruthenium Complex2008

    • Author(s)
      T. Matsumoto, Y. Nakaya, and K. Tatsumi
    • Journal Title

      Angew. Chem. Int. Ed. 47

      Pages: 1913-1915

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] A Functional Hydrogenase Model: Reversible Interconversion of H_2 and H_2O by a Hydroxo/Sulfido-Bridged Dinuclear Ruthenium-Germanium Complex2008

    • Author(s)
      T. Matsumoto, Y. Nakaya, N. Itakura, and K. Tatsumi
    • Journal Title

      J.Am. Chem. Soc. 130

      Pages: 2458-2459

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis of syn-2, 4-Dimercapto-1,3,2,4-dithiadigermetane and Its Application for Ge_2PdS_4 Cluster Synthesis2008

    • Author(s)
      T. Matsumoto, Y. Matsui, M. Ito, and K. Tatsumi
    • Journal Title

      Chem. Asian J. 3

      Pages: 607-613

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] 3-(Dimethylboryl) pyridine: Synthesis, Structure, and Remarkable Steric Effects in Scrambling Reactions2008

    • Author(s)
      S. Wakabayashi, S. Imamura, Y. Sugihara, M. Shimizu, T. Kitagawa, Y. Ohki, and K. Tatsumi
    • Journal Title

      J. Org. Chem. 73

      Pages: 81-87

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis of Ge_2NiS_4 Clusters and the Thermal Transformation to a Ge_4Ni_6St_<12> Cluster2008

    • Author(s)
      T. Matsumoto, Y. Matsui, M. Ito, and K. Tatsumi
    • Journal Title

      Inorg. Chem. 47

      Pages: 1901-1903

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis and Characterization of Novel Ferrocene-Containing Pyridyla mine Ligand and Their Ruthenium (II) Complexes: Electronic Communication through Hydrogen-bonded Amide Linkage2008

    • Author(s)
      T. Kojima, D. Noguchi, T. Nakayama, Y. Inagaki, Y. Shiota, K. Yoshizawa, K. Ohkubo, S. Fukuzumi
    • Journal Title

      Inorg. Chem. 47

      Pages: 886-895

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis of New[8Fe-7S] Clusters : A Topological Link Between the Core Structures of P-cluster, FeMo-co, and FeFe-co of Nitrogenases2007

    • Author(s)
      Y. Ohki, Y. Ikagawa, K. Tatsumi
    • Journal Title

      J. Am. Chem. Soc

      Volume: 129 Issue: 34 Pages: 10457-10465

    • DOI

      10.1021/ja072256b

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Dinitrogen Cleavage by a Diniobium Tetrahydride Complex : Formation of a Nitride and Its Conversion to Imide Species2007

    • Author(s)
      F. Akagil, T. Matsuo, H. Kawaguchi
    • Journal Title

      Angew. Chem. Int. Ed.

      Volume: 46 Issue: 46 Pages: 8778-8781

    • DOI

      10.1002/anie.200703336

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] The DIX domain of Dishevelled confers Wnt signaling by dynamic polymerization2007

    • Author(s)
      T. Schwarz-romond, M. Fiedler, N. Shibata, P. J. G. Butler, A. Kikuchi, Y. Higuchi, M. Beinz
    • Journal Title

      Nat. Struct. Mol. Biol

      Volume: 14 Issue: 6 Pages: 484-492

    • DOI

      10.1038/nsmb1247

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis of New [8Fe-7S] Clusters: A Topological Link Between the Core Structures of P-cluster, FeMo-co, and FeFe-co of Nitrogenases2007

    • Author(s)
      Y. Ohki, Y. Ikagawa and K. Tatsumi
    • Journal Title

      J. Am. Chem. Soc. 129

      Pages: 10457-10465

    • Related Report
      2008 Self-evaluation Report
    • Peer Reviewed
  • [Journal Article] Dinitrogen Cleavage by a Diniobium Tetrahydride Complex : Formation of a Nitride and Its Conversion to Imide Species2007

    • Author(s)
      F. Akagi, T. Matsuo, H. Kawaguchi
    • Journal Title

      Angew. Chem., Int. Ed. 46

      Pages: 8778-8781

    • Related Report
      2008 Self-evaluation Report
  • [Journal Article] The DIX Domain of Dishevelled Confers Wnt Signaling by Dynamic Polymerization2007

    • Author(s)
      T. Schwarz-Romond, M. Fiedler, N. Shibata, P. Jonathan G. Butler, A. Kikuchi, Y. Higuchi
    • Journal Title

      Nat. Struct. Mol. Biol. 14

      Pages: 484-492

    • Related Report
      2008 Self-evaluation Report
    • Peer Reviewed
  • [Journal Article] Synthesis and Characterization of Heteroleptic Iron (II) Thiolate Complexes with Weak Iron-Arene Interactions2007

    • Author(s)
      S. Ohta, Y. Ohki, Y. Ikagawa, R. Suizu, and K. Tatsumi
    • Journal Title

      J.Organomet. Chem. 692

      Pages: 4792-4799

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis of New [8Fe-7S] Clusters: A Topological Link Between the Core Structures of P-cluster, FeMo-co, and FeFe-co of Nitroeenases2007

    • Author(s)
      Y. Ohki, Y. Ikagawa, and K. Tatsumi
    • Journal Title

      J.Am. Chem. Soc. 129

      Pages: 10457-10465

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis and Dehydrogenation of M(AlH_4)_2 (M=Mg,Ca)2007

    • Author(s)
      K. Komiya, N. Morisaku, Y. Shinzato, K. Ikeda, S. Orimo, Y. Ohki, K. Tatsumi, H. Yukawa, and M. Morinaga
    • Journal Title

      J. Alloys Compd 446-447

      Pages: 237-241

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Anisole-Diphenoxide Ligands and Their Zirconium Dichloride and Dialkyl Complexes2007

    • Author(s)
      T. Matsuo, H. Kawaguchi
    • Journal Title

      Inorg. Chem. 46

      Pages: 8426-8434

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Dinitrogen Cleavage by a Diniobium Tetrahydride Complex: Formation of a Nitride and Its Conversion to Imide Species2007

    • Author(s)
      F. Akagi, T. Matsuo, H. Kawaguchi
    • Journal Title

      Angew. Chem., Int. Ed. 46

      Pages: 8778-8781

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Human DNA Replication-related Element Binding Factor (hDREF) Self-association via hATC Domain Is Necessary for Its Nuclear Accumulation and DNA Binding2007

    • Author(s)
      D. Yamashita, H. Komori, Y. Higuchi, T. Yamaguchi, T. Osumi and F. Hirose
    • Journal Title

      J. Biol. Chem. 282

      Pages: 7563-7575

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Crystal Structure of CO-sensing Transcription Activator CooA Bound to Exogenous Lieand Imidazole2007

    • Author(s)
      H. Komori, S. Inagaki, S. Yoshioka, S. Aono and Y. Higuchi
    • Journal Title

      J. Mol. Biol. 367

      Pages: 864-871

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Determination of the Role of the Carboxyl-terminal Leucine-122 in FMN-binding Protein by Mutational and Structural Analysis2007

    • Author(s)
      M. Kitamura, K. Terakawa, H. Inoue, T. Hayashida, K. Suto, Y. Morimoto, N. Yasuoka, N. Shibata and Y. Higuchi
    • Journal Title

      J. Biochem. 141

      Pages: 459-468

    • NAID

      10020099842

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] A Dinuclear Ni (mu-H) Ru Complex Derived from H_22007

    • Author(s)
      S. Ogo, R. Kabe, K, Uehara, B. Kure, T. Nishimura, S.C. Menon, R. Harada, S. Fukuzumi, Y. Higuchi, T. Ohhara, T. Tamada and R. Kuroki
    • Journal Title

      Science 316

      Pages: 585-587

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Nylon-oligomer degrading enzyme/substrate complex: catalytic mechanism of 6-aminohexanoate-dimer hydrolase2007

    • Author(s)
      S. Negoro, T. Ohki, N. Shibata, K. Sasa, H. Hayashi, H. Nakano, K. Yasuhira, D. Kato, M. Takeo, and Y. Higuchi
    • Journal Title

      J. Mol. Biol. 370

      Pages: 142-156

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Crystal structures of hydrogenase maturation protein HypE in the apo and ATP-bound forms2007

    • Author(s)
      Y. Shomura, H. Komori, N. Miyabe, M. Tomiyama, N. Shibata and Y. Higuchi
    • Journal Title

      J. Mol. Biol. 372

      Pages: 1045-1054

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Structure and Function of the Engineered Multicopper Oxidase, CueO from Escherichia coli2007

    • Author(s)
      K. Kataoka, H. Komori, Y. Ueki, Y. Konno, S. Tsujimura, Y. Higuchi, K. Kano and T. Sakurai
    • Journal Title

      J. Mol. Biol. 373

      Pages: 141-152

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Crystallization and preliminary X-ray crystallographic studies of the Axin DIX domain2007

    • Author(s)
      N. Shibata, Y. Tomimoto, T. Hanamura, R. Yamamoto, M. Ueda, Y. Ueda, N. Mizuno, H. Ogata, H. Komori, Y. Shomura, M. Kataoka, S. Shimizu, J. Kondo, H. Yamamoto, A. Kikuchi and Y. Higuchi
    • Journal Title

      Acta Crystallogr. F63

      Pages: 529-531

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] The DIX domain of Dishevelled confers Wnt signaling by dynamic poly merization2007

    • Author(s)
      T. Schwarz-Romond, M. Fiedler, N. Shibata, P. Jonathan G. Butler, A. Kikuchi, Y. Higuchi and M. Bienz
    • Journal Title

      Nature Structural and Molecular Biology 14

      Pages: 484-492

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Does Cob(II)alamin Act as a Conductor in Coenzyme B_<12> Dependent Mutases?2007

    • Author(s)
      P. M. Kozlowski, T. Kamachi, T. Toraya, K. Yoshizawa
    • Journal Title

      Angew. Chem. Int. Ed. 46

      Pages: 980-983

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Vibronic Interaction in Metalloporphyrin π-Anion Radicals2007

    • Author(s)
      K. Yoshizawa, T._Nakayama, T. Kamachi, P. M. Kozlowski
    • Journal Title

      J. Phys. Chem. A 111

      Pages: 852-857

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Photoswitching of Conductivity through a Diarylperfluorocyclopentene Nanowire2007

    • Author(s)
      A. Staykov, D. Nozaki, and K. Yoshizawa
    • Journal Title

      J. Phys. Chem. C 111

      Pages: 3517-3521

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Combined Experimental and Theoretical Evidence for Nonheme Iron (III) -Alkylperoxo Species as a Sluggish Oxidant in Oxygenation Reactions2007

    • Author(s)
      M. S Seo, T. Kamachi, T. Kouno, K. Murata, M. J. Park, K. Yoshizawa, W. Nam
    • Journal Title

      Angew. Chem. Int. Ed. 46

      Pages: 2291-2294

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Theoretical Study of Donor-p-Bridge-Acceptor Unimolecular Rectifier2007

    • Author(s)
      A. Staykov, D. Nozaki, K. Yoshizawa
    • Journal Title

      J. Phys. Chem. C 111

      Pages: 11699-11705

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Computational Mutation Analysis of Coenzyme B_<12>-Dependent Diol Dehydratase2007

    • Author(s)
      T. Kamachi, T. Toraya, K. Yoshizawa
    • Journal Title

      Chem. Eur. J. 13

      Pages: 7864-7873

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] DFT Analysis of Cubane-Type FeIr_3S_4 Clusters. Dinitrogen Binding and Activation at the Tetrahedral Fe Site2007

    • Author(s)
      P. M. Kozlowski, Y. Shiota, S. Gomita, H. Seino, Y. Mizobe, K. Yoshizawa
    • Journal Title

      Bull. Chem. Soc. Jpn. 80

      Pages: 2323-2328

    • NAID

      10020275408

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Zirconium Complexes of the Tridentate Bis(aryloxide)-N-Heterocyclic-Carbene Ligand : Chloride and Alkyl Functionalized Derivative2007

    • Author(s)
      D.Zhang, H.Aihara, T.Watanabe, T.Matsuo, H.Kawaguchi
    • Journal Title

      J.Orgnanomet.Chem. 692

      Pages: 234-242

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Does Cob(II)alamin Act as a Conductor in Coenzyme B_<12> Dependent Mutases?2007

    • Author(s)
      P.M.Kozlowski, T.Kamachi, T.Toraya, K.Yoshizawa
    • Journal Title

      Angew.Chem.Mt.Ed. 46

      Pages: 980-983

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Nickel(II) Thiolate Complexes with a Flexible cyclo-[Ni_<10>S_<20>] Framework2006

    • Author(s)
      C.Zhang, S.Takada, M.Kolzer, T.Matsumoto, K.Tatsumi
    • Journal Title

      Angew.Chem.Mt.Ed. 45

      Pages: 3768-3772

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Synthesis of Oxo- and Sulfido-bridged Germanium-Ruthenium Complexes and Reactions on the Chalcogenido Bridges2006

    • Author(s)
      T.Matsumoto, Y.Nakaya, K.Tatsumi
    • Journal Title

      Organometallics 25

      Pages: 4835-4845

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Reductive N-N Bond Cleavage of Diphenylhydrazine and Azobenzene Induced by Coordinatively Unsaturated Cp^*Fe{N(SiMe_3)_2}2006

    • Author(s)
      Y.Ohki, Y.Takikawa, T.Hatanaka, K.Tatsumi
    • Journal Title

      Organometallics 25

      Pages: 3111-3113

    • Related Report
      2006 Annual Research Report
  • [Journal Article] A Tantalum(V) Carbene Complex : Formation of a Carbene-Bis(phenoxide) Ligand by Sequential Proton and Hydride Abstraction2006

    • Author(s)
      T.Watanabe, T.Matsuo, H.Kawaguchi
    • Journal Title

      Inorg.Chem. 45

      Pages: 6580-6582

    • Related Report
      2006 Annual Research Report
  • [Journal Article] From Carbon Dioxide to Methane : Homogeneous Reduction of Carbon Dioxide with Hydrosilanes Catalyzed by Zirconium-Borane Complexes2006

    • Author(s)
      T.Matsuo, H.Kawaguchi
    • Journal Title

      J.Am.Chem.Soc. 128

      Pages: 12362-12363

    • Related Report
      2006 Annual Research Report
  • [Journal Article] High Fidelity Self-Sorting Assembling of meso-Cinchomeronimide Appended meso-meso Linked Zn(II) Diporphyrins2006

    • Author(s)
      T.Kamada, N.Aratani, T.Ikeda, N.Shibata, Y.Higuchi, A.Wakamiya, S.Yamaguchi, K.S.Kim, Z.S.Yoon, D.Kim, A.Osuka
    • Journal Title

      J.Am.Chem.Soc. 128

      Pages: 7670-7678

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Redox-Dependent Interaction of Cytochrome c_3 with [NiFe] Hydrogenase from D. vulgaris Miyazaki F2006

    • Author(s)
      N.Yahata, K.Ozawa, A.Nakahara, H.Ogata, Y.Higuchi, H.Akutsu
    • Journal Title

      Biochemistry 45

      Pages: 1653-1662

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Structure of the Cadherin-related Neuronal Receptor/Protocadherin-α First Extracellular Cadherin Domain Reveals Diversity across Cadherin Families2006

    • Author(s)
      H.Morishita, M.Umitsu, Y.Murata, N.Shibata, K.Udaka, Y.Higuchi, H.Akutsu, T.Yamaguchi, T.Yagi, T.Ikegami
    • Journal Title

      J.Biol.Chem. 281

      Pages: 33650-33663

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Conversion of Methane to Methanol at the Mononuclear and Dinuclear Copper Sites of Particulate Methane Monooxygenase (pMMO) : A DFT and QM/MM Study2006

    • Author(s)
      K.Yoshizawa, Y.Shiota
    • Journal Title

      J.Am.Chem.Soc. 128

      Pages: 9873-9881

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Catalytic Mechanism of Dopamine β-Monooxygenase Mediated by Cu(III)-Oxo2006

    • Author(s)
      K.Yoshizawa, N.Kihara, T.Kamachi, Y.Shiota
    • Journal Title

      Inorg.Chem. 45

      Pages: 3034-3041

    • Related Report
      2006 Annual Research Report
  • [Presentation] 酸素耐性膜結合型[NiFe]ヒドロゲナーゼのX線結晶構造解析-水素エネルギー利用に向けた基礎科学的研究-2011

    • Author(s)
      樋口芳樹
    • Organizer
      関西サイエンスフォーラム
    • Place of Presentation
      大阪
    • Year and Date
      2011-11-29
    • Related Report
      2010 Final Research Report
  • [Presentation] 還元系金属酵素の化学-自然に学ぶ-2011

    • Author(s)
      巽和行
    • Organizer
      The 5^<th> Waseda GCOE International Symposium on "Practical Chemical Wisdom"
    • Place of Presentation
      早稲田大学理工
    • Year and Date
      2011-01-13
    • Related Report
      2010 Final Research Report
  • [Presentation] 還元系金属酵素の化学-自然に学ぶ2011

    • Author(s)
      巽和行
    • Organizer
      The 5^<th> Waseda GCOE International Symposium on "Practical Chemical Wisdom"「化学知をめぐって」
    • Place of Presentation
      早稲田大学
    • Year and Date
      2011-01-13
    • Related Report
      2010 Annual Research Report
  • [Presentation] Small Molecule Activation by Group 5 Metal Hydrides Having Aryloxide Ligands2011

    • Author(s)
      H. Kawaguchi
    • Organizer
      3rd Erlangen Symposium on Redox-Active Metal Complexes : Control of Reactivity via Molecular Architecture
    • Place of Presentation
      Erlangen, Germany
    • Related Report
      2010 Final Research Report
  • [Presentation] Computational Mutation of Enzymatic Reactions2011

    • Author(s)
      K. Yoshizawa
    • Organizer
      International Symposium of Homogeneous and Heterogeneous Catalysis XV
    • Place of Presentation
      Berlin Free University, Berlin, Germany
    • Related Report
      2010 Final Research Report
  • [Presentation] Chemistry of Reductase2011

    • Author(s)
      巽和行
    • Organizer
      分子研研究会「金属錯体の機能化の現状と将来展望」
    • Place of Presentation
      岡崎
    • Related Report
      2010 Annual Research Report
  • [Presentation] Chemical and Biological Synthesis of Iron-Sulfide Clusters by Tinker-Toy Construction or by Self-Assembly2011

    • Author(s)
      Kazuyuki Tatsumi
    • Organizer
      International Symposium on Chemistry of Reductases IV
    • Place of Presentation
      Nagoya, Japan
    • Related Report
      2010 Annual Research Report
  • [Presentation] Model Chemistry of Acetyl-CoA Synthase and Methyl-CoM Reductase2010

    • Author(s)
      Tsuyoshi Matsumoto
    • Organizer
      Bioinorganic Seminar at Max-Planck Institute
    • Place of Presentation
      Marburg, Germany
    • Year and Date
      2010-07-05
    • Related Report
      2010 Annual Research Report
  • [Presentation] 還元系金属酵素の有機金属化学2010

    • Author(s)
      巽和行
    • Organizer
      有機合成化学協会講習会
    • Place of Presentation
      東京
    • Year and Date
      2010-06-23
    • Related Report
      2010 Annual Research Report 2010 Final Research Report
  • [Presentation] C-H Bond Activation and Borylation of Heteroarenes Promoted by Half-Sandwich Iron Complexes2010

    • Author(s)
      Yasuhiro Ohki
    • Organizer
      The 9th Joint Seminar between Nagoya University and University of Munster
    • Place of Presentation
      Nagoya University
    • Related Report
      2010 Annual Research Report
  • [Presentation] Thiolate-bridged Dinuclear Fe(CO)_3-Ni, Fe(CO)_2(CN)_2-Ni, and Fe(CO)(CN)_2-Ni" Complexes as Structural Models of the [NiFe] Hydrogenase Active Site2010

    • Author(s)
      Kazuyuki Tatsumi, Yasuhiro Ohki, Zilong Li, Soichiro Tanino
    • Organizer
      9^<th> International Hydrogenase Conference
    • Place of Presentation
      Uppsala, Sweden
    • Related Report
      2010 Annual Research Report
  • [Presentation] Organometallic Routes to Fe-S Clusters-Challenge to Model the Active Sites of Reductases-2010

    • Author(s)
      Kazuyuki Tatsumi, Yasuhiro Ohki
    • Organizer
      24^<th> International Conference on Organometallic Chemistry
    • Place of Presentation
      Taipei, Taiwan
    • Related Report
      2010 Annual Research Report
  • [Presentation] Recent Progress in the Synthesis of Fe-S Clusters relevant to the Active Sites of Reductases2010

    • Author(s)
      Kazuyuki Tatsumi, Yasuhiro Ohki
    • Organizer
      8^<th> China-Japan Joint Symposium on Metal Cluster Compounds
    • Place of Presentation
      Xian, China
    • Related Report
      2010 Annual Research Report
  • [Presentation] Chemistry of Reductases2010

    • Author(s)
      Kazuyuki Tatsumi
    • Organizer
      Frontier of Chemical Research, Texas A&M University
    • Place of Presentation
      Texas, USA
    • Related Report
      2010 Annual Research Report
  • [Presentation] Reductive Fusion of Two [Fe_4S_4] Clusters into an [Fe_8S_7] Core of Nitrogenase P-Cluster2010

    • Author(s)
      Yasuhiro Ohki, Norihiro Yamada, Kazuki Tanifuji, Kazuyuki Tatsumi
    • Organizer
      60th Anniversary Conference on Coordination Chemistry in Osaka
    • Place of Presentation
      Osaka, Japan
    • Related Report
      2010 Annual Research Report
  • [Presentation] Recent Progress in the Synthesis of Fe/S abd Fe/Mo/S Clusters-Challenge to Model the Active Sites of Nitrogenase-2010

    • Author(s)
      Kazuyuki Tatsumi
    • Organizer
      24^<th> Latin American Chemistry Congress
    • Place of Presentation
      Cartagena, Colombia
    • Related Report
      2010 Annual Research Report
  • [Presentation] New Synthetic Routes to Fe-S Clusters-Challenge to Modeling the Active Sites of Reductases2010

    • Author(s)
      Kazuyuki Tatsumi
    • Organizer
      11^<th> Eurasia Conference on Chemical Sciences
    • Place of Presentation
      The Dead Sea, Jordan
    • Related Report
      2010 Annual Research Report
  • [Presentation] Structural Models of the [NiFe] Hydrogenase Activge Site2010

    • Author(s)
      Kazuyuki Tatsumi
    • Organizer
      5^<th> Asian Biological Inorganic Chemistry Conference
    • Place of Presentation
      Kaohsiung, Taiwan
    • Related Report
      2010 Annual Research Report
  • [Presentation] Thiolate-bridged Dinuclear Fe(CO)_x(CN)_y-Ni Complexes (x,y=3,0;2,2;1,2) Modelling the Active Site of [NiFe] Hydrogenase2010

    • Author(s)
      Kazuyuki Tatsumi, Yasuhiro Ohki, Zilong Li, Soichiro Tanino, Kazunari Yasumura, Masaru Ando, Satoko Shimokata
    • Organizer
      Pacifichem2010
    • Place of Presentation
      Hawaii, USA
    • Related Report
      2010 Annual Research Report
  • [Presentation] Activation of Small Molecules Promoted by Coordinatively Unsaturated Half-sandwich Rhodium and Iridium Complexes of 2,6-Dimesitylphenyl Thiolate2010

    • Author(s)
      Kazuyuki Tatsumi, Mayumi Sakamoto, Yasuhiro Ohki
    • Organizer
      Pacifichem2010
    • Place of Presentation
      Hawaii, USA
    • Related Report
      2010 Annual Research Report
  • [Presentation] Dinuclear Nickel Complexes Modeling of the Active Site of Acetyl CoA Synthase : A Mechanistic Insight2010

    • Author(s)
      Tsuyoshi Matsumoto, Mikinao Ito, Kazuyuki Tatsumi
    • Organizer
      Pacifichem2010
    • Place of Presentation
      Hawaii USA
    • Related Report
      2010 Annual Research Report
  • [Presentation] Synthesis of [Fe_8S_7] Clusters Analogous to the Metal-Sulfur Clusters in Nitrogenase2010

    • Author(s)
      Yasuhiro Ohki, Kazuyuki Tatsumi
    • Organizer
      Pacifichem2010
    • Place of Presentation
      Hawaii USA
    • Related Report
      2010 Annual Research Report
  • [Presentation] 酵素の進化:構造と活性2009

    • Author(s)
      樋口芳樹
    • Organizer
      第34回生命の起源および進化学会学術講演会シンポジウム
    • Place of Presentation
      京都
    • Year and Date
      2009-03-18
    • Related Report
      2008 Annual Research Report
  • [Presentation] Activation of H2 by S-donor/O-donor-bridged Heterodunuclear Complexes relevant to the Function of[NiFe] Hydrogenase2009

    • Author(s)
      K. Tatsumi, T. Matsumoto, Y. Ohki
    • Organizer
      International Conference on Hydrogen and Hydrogen Storage : Methods and Materials
    • Place of Presentation
      Bangalore, India
    • Related Report
      2010 Final Research Report
  • [Presentation] Activation of H_2 by S-donor/O-donor-bridged Heterodunuclear Complexes relevant to the Function of [NiFe] Hydrogenase2009

    • Author(s)
      K. Tatsumi, T. Matsumoto, Y. Ohki
    • Organizer
      International Conference on Hydrogen and Hydrogen Storage: Methods and Materials
    • Place of Presentation
      Bangalore (India)
    • Related Report
      2008 Annual Research Report
  • [Presentation] ニトロゲナーゼの活性中心を模倣する鉄-硫黄クラスターの合成2009

    • Author(s)
      大木靖弘
    • Organizer
      特定領域研究「元素相乗系の化合物の化学」第4回シンポジウム
    • Place of Presentation
      広島
    • Related Report
      2008 Annual Research Report
  • [Presentation] Synthesis of Iron-Sulfur Clusters Relevant to the Active Sites of Nitrogenase2009

    • Author(s)
      K. Tatsumi, Y. Ohki
    • Organizer
      International Symposium on Chemistry of Reductases II
    • Place of Presentation
      名古屋
    • Related Report
      2008 Annual Research Report
  • [Presentation] 鉄錯体による芳香族C-H結合活性化反応の開発2009

    • Author(s)
      大木靖弘
    • Organizer
      第5回有機元素化学セミナー
    • Place of Presentation
      京都
    • Related Report
      2008 Annual Research Report
  • [Presentation] ニトロゲナーゼおよびヒドロゲナーゼ活性部位の人工構築2009

    • Author(s)
      大木靖弘
    • Organizer
      日本化学会第89春季年会
    • Place of Presentation
      船橋
    • Related Report
      2008 Annual Research Report
  • [Presentation] カルコゲン架橋複核錯体を利用した小分子活性化2009

    • Author(s)
      松本剛
    • Organizer
      日本化学会第89春季年会
    • Place of Presentation
      船橋
    • Related Report
      2008 Annual Research Report
  • [Presentation] Activation of Small Molecules by Niobium and Tantalum Complexes Bearing Phenoxide Ligands2009

    • Author(s)
      H. Kawaguchi
    • Organizer
      International Symposium on Chemistry of Reductases II
    • Place of Presentation
      名古屋
    • Related Report
      2008 Annual Research Report
  • [Presentation] 量子輸送現象における軌道理論2009

    • Author(s)
      吉澤一成
    • Organizer
      大学間連携事業シンポジウム
    • Place of Presentation
      名古屋
    • Related Report
      2008 Annual Research Report
  • [Presentation] DIXドメインの構造と機能2008

    • Author(s)
      樋口芳樹
    • Organizer
      第31回日本分子生物学会年会・第81回日本生化学会大会合同大会シンポジウム
    • Place of Presentation
      神戸
    • Year and Date
      2008-12-11
    • Related Report
      2008 Annual Research Report
  • [Presentation] 金属元素が操る生体酵素機能:ヒドロゲナーゼの化学2008

    • Author(s)
      巽和行
    • Organizer
      元素戦略・ナノクラスター連続研究会
    • Place of Presentation
      岡崎
    • Year and Date
      2008-12-10
    • Related Report
      2008 Annual Research Report
  • [Presentation] Wnt/β-cateninシグナル伝達系で働くDIXドメインの構造と機能2008

    • Author(s)
      樋口芳樹
    • Organizer
      第62回日本癌学会学術総会シンポジウム
    • Place of Presentation
      名古屋
    • Year and Date
      2008-10-30
    • Related Report
      2008 Annual Research Report
  • [Presentation] Thiolate-Bridged Dinuclear Fe-Ni Complexes Relevant to the Active Site of [NiFe] Hydrogenase2008

    • Author(s)
      Y. Ohki
    • Organizer
      China-Japan Joint Workshop on Organometallic Chemistry
    • Place of Presentation
      北京
    • Year and Date
      2008-10-09
    • Related Report
      2008 Annual Research Report
  • [Presentation] フェノキシド多座配位子を用いた多核錯体反応場の構築と反応2008

    • Author(s)
      川口博之
    • Organizer
      第58回錯体化学討論会
    • Place of Presentation
      金沢
    • Year and Date
      2008-09-20
    • Related Report
      2008 Annual Research Report
  • [Presentation] 遷移金属ヒドリド錯体による小分子活性化-配位子の効果-2008

    • Author(s)
      川口博之
    • Organizer
      分子研研究会「配位子場制御に基づく機能性錯体の創成と応用〜生体から触媒およびデバイスまで〜」
    • Place of Presentation
      岡崎
    • Year and Date
      2008-07-19
    • Related Report
      2008 Annual Research Report
  • [Presentation] New Synthetic Routes to Iron-Sulfur Clusters: Challenge to Model the Active Sites of Reductases2008

    • Author(s)
      K. Tatsumi
    • Organizer
      分子研研究会「配位子場制御に基づく機能性錯体の創成と応用-生体から触媒およびデバイスまで-」
    • Place of Presentation
      岡崎
    • Year and Date
      2008-07-18
    • Related Report
      2008 Annual Research Report
  • [Presentation] 日独共同大学院プログラム-大学院教育国際化の取り組み2008

    • Author(s)
      巽和行
    • Organizer
      分子研研究会「教育・研究環境のあるべき姿」
    • Place of Presentation
      岡崎
    • Year and Date
      2008-05-07
    • Related Report
      2008 Annual Research Report
  • [Presentation] 量子化学計算による酵素化学反応へのアプローチ2008

    • Author(s)
      吉澤一成
    • Organizer
      九州大学情報基盤センターセミナー
    • Place of Presentation
      福岡
    • Year and Date
      2008-04-25
    • Related Report
      2008 Annual Research Report
  • [Presentation] ニトロゲナーゼ活性中心の精密無機合成2008

    • Author(s)
      大木靖弘
    • Organizer
      第7回 生体金属機能を利用した物質変換システム研究会
    • Place of Presentation
      名古屋工業大学
    • Year and Date
      2008-01-28
    • Related Report
      2007 Annual Research Report
  • [Presentation] DIXドメインの構造と機能2008

    • Author(s)
      樋口芳樹
    • Organizer
      プロテオミクス・構造生物学講演会
    • Place of Presentation
      岡崎カンファレンスセンター
    • Year and Date
      2008-01-13
    • Related Report
      2007 Annual Research Report
  • [Presentation] フェノキシド多座配位子を用いた多核錯体反応場の構築と反応2008

    • Author(s)
      川口博之
    • Organizer
      第58回錯体化学討論会(シンポジウム:ヘテロ元素架橋多核サイトでの特異な反応性)
    • Place of Presentation
      金沢大学
    • Related Report
      2010 Final Research Report
  • [Presentation] Dihydrogen Activation by Dinuclear Ge-Ru Complexes Modeling [NiFe] Hydrogenase2008

    • Author(s)
      T. Matsumoto
    • Organizer
      The 2nd International Symposium on Concerto Catalysis
    • Place of Presentation
      東京
    • Related Report
      2008 Annual Research Report
  • [Presentation] New Synthetic Routes to Fe-S Clusters2008

    • Author(s)
      K. Tatsumi
    • Organizer
      Gordon Research Conference on Iron-Sulfur Enzymes
    • Place of Presentation
      New London (USA)
    • Related Report
      2008 Annual Research Report
  • [Presentation] [NiFe]ヒドロゲナーゼ活性中心の人工構築:有機金属錯体と金属酵素の接点に迫る2008

    • Author(s)
      大木靖弘
    • Organizer
      第41回有機金属若手の会夏の学校
    • Place of Presentation
      神戸
    • Related Report
      2008 Annual Research Report
  • [Presentation] ニトロゲナーゼ活性中心の人工構築に向けた鉄-硫黄クラスター合成反応の制御2008

    • Author(s)
      大木靖弘
    • Organizer
      第21回生物無機化学夏季セミナー
    • Place of Presentation
      京都
    • Related Report
      2008 Annual Research Report
  • [Presentation] A New Synthetic Route to Iron-Sulfide Clusters Modeling the Active Site of Nitrogenase2008

    • Author(s)
      K. Tatsumi, Y. Ohki
    • Organizer
      The 21^<st> Congress of the International Union of Crystallography
    • Place of Presentation
      大阪
    • Related Report
      2008 Annual Research Report
  • [Presentation] Chalcogenide-Bridged Ru-Ge Dinuclear Complexes: Protonation Effects upon Structure and Reactions2008

    • Author(s)
      T. Matsumoto
    • Organizer
      The 6th joint seminar University of Munster-Nagoya University
    • Place of Presentation
      名古屋
    • Related Report
      2008 Annual Research Report
  • [Presentation] S(O)-Bridged Heteridinuclear Complexes Modeling the Active Site Structure and Function of [NiFe] Hydrogenase2008

    • Author(s)
      K. Tatsumi, T. Matsumoto, Y. Ohki
    • Organizer
      7^<th> Japan-China Joint Symposium on Metal Cluster Compounds
    • Place of Presentation
      札幌
    • Related Report
      2008 Annual Research Report
  • [Presentation] 還元系金属酵素:化学の新たな挑戦2008

    • Author(s)
      巽和行
    • Organizer
      特定領域研究「実在系の分子理論」シンポジウム
    • Place of Presentation
      札幌
    • Related Report
      2008 Annual Research Report
  • [Presentation] Quantum Chemical Approach to Bioinorganic Chemistry: Structure-Reactivity Relationship in Enzymatic Reactions2008

    • Author(s)
      K. Yoshizawa
    • Organizer
      The 2nd International Symposium on "Molecular Theory for Real Systems"
    • Place of Presentation
      岡崎
    • Related Report
      2008 Annual Research Report
  • [Presentation] Computational Mutation Analysis of Coenzyme B_<12>-Dependent Diol Dehy dratase2008

    • Author(s)
      K. Yoshizawa
    • Organizer
      The Eighth Triennial Congress of the World Asso ciation of Theoretical and Computational Chemists (WATOC 2008)
    • Place of Presentation
      Sydney (Australia)
    • Related Report
      2008 Annual Research Report
  • [Presentation] 量子輸送現象における軌道理論2008

    • Author(s)
      吉澤一成
    • Organizer
      分子科学討論会
    • Place of Presentation
      福岡
    • Related Report
      2008 Annual Research Report
  • [Presentation] QM/MM Study of the Catalytic Mechanism of Tyrosinase2008

    • Author(s)
      K. Yoshizawa
    • Organizer
      The Fourth Asian Biological Inorganic Chemistry Conference (AsBIC IV)
    • Place of Presentation
      Jeju (Korea)
    • Related Report
      2008 Annual Research Report
  • [Presentation] Quantum Chemical Study on the Biological Conversion of Tyrosine to Dopaquinone2008

    • Author(s)
      K. Yoshizawa
    • Organizer
      The IUMRS International Conference in Asia 2008
    • Place of Presentation
      名古屋
    • Related Report
      2008 Annual Research Report
  • [Presentation] S-Donor/O-Donor-Bridged Heterodinuclear Complexes Modeling the Active Site Structure and Function of [NiFe] Hydrogenase2008

    • Author(s)
      K. Tatsumi, T. Matsumoto, Y. Ohki
    • Organizer
      International Symposium on Chemistry of Reductases
    • Place of Presentation
      Nagoya, Japan
    • Related Report
      2007 Annual Research Report
  • [Presentation] 還元系金属酵素の有機金属化学とクラスター化学2007

    • Author(s)
      巽和行
    • Organizer
      平成19年度 東京工業大学資源化学研究所講演会
    • Place of Presentation
      東京工業大学
    • Year and Date
      2007-12-18
    • Related Report
      2007 Annual Research Report
  • [Presentation] International Graduate Schools", DAAD Seminar Series, Science Cooperation between Germany and Japan -Crossing the Bridge between Teaching and Research2007

    • Author(s)
      K. Tatsumi
    • Organizer
      University and Business
    • Place of Presentation
      Osaka, Japan
    • Year and Date
      2007-10-05
    • Related Report
      2007 Annual Research Report
  • [Presentation] 古くて新しい還元系金属酵素?生物無機化学の新展開,「金属イオンを含む新しい生体分子の創製と実践的活用」2007

    • Author(s)
      巽和行
    • Organizer
      錯体化学討論会、シンポジウム
    • Place of Presentation
      名古屋
    • Year and Date
      2007-09-25
    • Related Report
      2010 Final Research Report
  • [Presentation] 還元系金属酵素:化学の新たな挑戦2007

    • Author(s)
      巽和行
    • Organizer
      九州大学先導物質化学研究所開所式
    • Place of Presentation
      福岡
    • Year and Date
      2007-09-03
    • Related Report
      2007 Annual Research Report
  • [Presentation] Metal-Sulfide-Cluster Synthesis? Challenge to Model the Active Sites of Reductases-2007

    • Author(s)
      K. Tatsumi
    • Organizer
      The 5th National Symposium on Structural Chemistry(5^<th> NSSC)
    • Place of Presentation
      Fuzhou, China
    • Related Report
      2010 Final Research Report
  • [Presentation] A New Synthetic Route to Iron Sulfide Clusters Modeling the Active Sites of Nitrogenase and Hydrogenase2007

    • Author(s)
      K. Tatsumi, Y. Ohki
    • Organizer
      Japan-USA Joint Symposium on Chemistry of Coordination Space (JUJS-CCS 2007)
    • Place of Presentation
      Evanston, USA
    • Related Report
      2007 Annual Research Report
  • [Presentation] A New Aspect of Fe/S-Cluster Synthesis -Relevance to the Active Sites of Nitrogenase and Hydrogenase2007

    • Author(s)
      K. Tatsumi, Y. Ohki
    • Organizer
      The 13th International Conference on Bioinorganic Chemistry (ICBIC13)
    • Place of Presentation
      Wien, Austria
    • Related Report
      2007 Annual Research Report
  • [Presentation] Activation of Molecular Hydrogen by Chalcogen-Bridged Dinuclear W-Ru and Ge-Ru Complexes -Relevance to Hydrogenase-2007

    • Author(s)
      K. Tatsumi, T. Matsumoto, Y. Ohki
    • Organizer
      1st Asian Conference on Coordination Chemistry
    • Place of Presentation
      Okazaki, Japan
    • Related Report
      2007 Annual Research Report
  • [Presentation] A New Aspect of Metal-Sulfide-Cluster Synthesis -Challenge to Model the Active Sites of Reductases-2007

    • Author(s)
      K. Tatsumi
    • Organizer
      5th National Symposium on Structural Chemistry (5th NSSC)
    • Place of Presentation
      Fuzhou, China
    • Related Report
      2007 Annual Research Report
  • [Presentation] A New Aspect of Metal-Sulfide-Cluster Synthesis -Challenge to Model the Active Sites of Reductases-2007

    • Author(s)
      K. Tatsumi
    • Organizer
      International Workshop on Bioinorganic and Organometallic Perspectives in Activation of Small Molecules
    • Place of Presentation
      Okazaki, Japan
    • Related Report
      2007 Annual Research Report
  • [Presentation] 金属酵素の鉄硫黄クラスター活性部位の人工構築と電子状態2007

    • Author(s)
      巽和行
    • Organizer
      理研シンポジウム「分子系の構造と電子状態-『生物物質科学』を目指して」
    • Place of Presentation
      理化学研究所
    • Related Report
      2007 Annual Research Report
  • [Presentation] 古くて新しい還元系金属酵素-生物無機化学の新展開-2007

    • Author(s)
      巽和行
    • Organizer
      第57回錯体化学討論会
    • Place of Presentation
      名古屋工業大学
    • Related Report
      2007 Annual Research Report
  • [Presentation] ヒドロゲナーゼに学ぶゲルマニウムールテニウム複核錯体の可逆な水素活性化2007

    • Author(s)
      松本剛
    • Organizer
      東京工業大学理学研究流動機構シンポジウム"元素の個性-どう見るか、どうつくるか、どう使うか-
    • Place of Presentation
      東京工業大学
    • Related Report
      2007 Annual Research Report
  • [Presentation] Dinuclear Nickel Complexes modeling Acetyl-CoA Synthase2007

    • Author(s)
      T. Matsumoto, M. Ito, K. Tatsumi
    • Organizer
      The 13th International Conference on Bioinorganic Chemistry (ICBIC13)
    • Place of Presentation
      Wien, Austria
    • Related Report
      2007 Annual Research Report
  • [Presentation] Inorganic Synthesis of the Nitrogenase Active Sites: from a discovery to a logic2007

    • Author(s)
      Y. Ohki
    • Organizer
      Am2Net Symposium
    • Place of Presentation
      Munster, Germany
    • Related Report
      2007 Annual Research Report
  • [Presentation] Synthesis of the P-cluster [8Fe-7S] Core of Nitrogenase2007

    • Author(s)
      Y. Ohki
    • Organizer
      The 3rd Joint Seminar between Nagoya University and University of Munster
    • Place of Presentation
      Nagoya, Japan
    • Related Report
      2007 Annual Research Report
  • [Presentation] Benzylidene-bridged Diziroconium Complexes Supported by Anisole-diphenoxide Ligands2007

    • Author(s)
      H. Kawaguchi
    • Organizer
      The First Asian Conference on Coordination Chemistry
    • Place of Presentation
      Okazaki, Japan
    • Related Report
      2007 Annual Research Report
  • [Presentation] 還元系フェノキシド錯体による小分子活性化2007

    • Author(s)
      川口博之
    • Organizer
      分子研研究会「金属と分子集合」
    • Place of Presentation
      分子科学研究所
    • Related Report
      2007 Annual Research Report
  • [Presentation] Activation of Small Molecules by Niobium Complexes Having Triphenoxide Ligands2007

    • Author(s)
      H. Kawaguchi
    • Organizer
      Workshop on Bioinorganic and Organometallic Perspectives in Activation of Small Molecules
    • Place of Presentation
      Okazaki, Japan
    • Related Report
      2007 Annual Research Report
  • [Presentation] Structural chemistry of hydrogen metabolism by[NiFe] hydrogenase based on its high resolution x-ray structure2007

    • Author(s)
      Y. Higuchi, H. Ogata, N. Mizuno, M. Hamada, H. Komori, M. Takata, T. Tamada and R. Kuroki.
    • Organizer
      2nd International Symposium on Diffraction Structural Biology 2007
    • Place of Presentation
      Tokyo, Japan
    • Related Report
      2007 Annual Research Report
  • [Presentation] 高輝度X線結晶構造解析に基づく酵素反応機構の解明2007

    • Author(s)
      樋口芳樹
    • Organizer
      日本物理学会第62回年次大会
    • Place of Presentation
      北海道大学
    • Related Report
      2007 Annual Research Report
  • [Presentation] The mechanism of CO sensing in the heme-based CO sensor CooA revealed by the crystal structure of the exogenous ligand bound form2007

    • Author(s)
      S. Aono, S. Inagaki, S. Yoshioka, H. Komori, and Y. Higuchi
    • Organizer
      The 13th International Conference on Bioinorganic Chemistry (ICBIC13)
    • Place of Presentation
      Wien, Austria
    • Related Report
      2007 Annual Research Report
  • [Presentation] Approach to Subatomic Resolution Protein Crystal Structures2007

    • Author(s)
      A. Nakagawa, Y. Higuchi, S. -Y. Park, K. Inaka, H. Tanaka, M. Sato, T. Kobayashi and T. Tanaka
    • Organizer
      2nd International Symposium on Diffraction Structural Biology 2007
    • Place of Presentation
      Tokyo, Japan
    • Related Report
      2007 Annual Research Report
  • [Presentation] Hydrogen bonds of a DNA binding protein DsrD revealed by neutron crystallography2007

    • Author(s)
      T. Chatake, Y. Higuchi, N. Mizuno, I. Tanaka, N. Niimura and Y. Morimoto
    • Organizer
      2nd International Symposium on Diffraction Structural Biology 2007
    • Place of Presentation
      Tokyo, Japan
    • Related Report
      2007 Annual Research Report
  • [Presentation] Incoherent electron transport in nanosized molecules2007

    • Author(s)
      K. Yoshizawa
    • Organizer
      International Symposium on Frontier in Computational Science of Nanoscale Transport (FCSNT2007)
    • Place of Presentation
      東京理科大学
    • Related Report
      2007 Annual Research Report
  • [Presentation] Computational approach to catalytic mechanism for alkane hydroxylation by metalloenzymes2007

    • Author(s)
      K. Yoshizawa
    • Organizer
      The 13th International Conference on Bioinorganic Chemistry (ICBIC13)
    • Place of Presentation
      Wien, Austria
    • Related Report
      2007 Annual Research Report
  • [Presentation] Methane hydroxylation by transition-metal oxides and metalloenzymes2007

    • Author(s)
      K. Yoshizawa
    • Organizer
      The Third Asisn Pacific Conference on Theoretical & Combutational Chemistry (APCTC3)
    • Place of Presentation
      Beijing, china
    • Related Report
      2007 Annual Research Report
  • [Presentation] 量子化学計算によるB12依存ジオールデヒドラターゼのミューテーション解析2007

    • Author(s)
      吉澤一成
    • Organizer
      情報計算化学生物学会(CBI学会)
    • Place of Presentation
      広島
    • Related Report
      2007 Annual Research Report
  • [Presentation] Quantum Chemical Approach to Enzymatic Reactions2007

    • Author(s)
      K. Yoshizawa
    • Organizer
      Workshop on Bioinorganic and Organometallic Perspectives in Activation of Small Molecules
    • Place of Presentation
      Okazaki, Japan
    • Related Report
      2007 Annual Research Report
  • [Presentation] Frontier Orbital View of the Quantum Transport in Molecular Nanowires2007

    • Author(s)
      K. Yoshizawa
    • Organizer
      The Second Japan-Czech-Slovakia Joint Symposium for Theoretical/Computational Chemistry
    • Place of Presentation
      Kyoto, Japan
    • Related Report
      2007 Annual Research Report
  • [Presentation] Active site of[NiFe] hydrogenase-inhibited, unready, ready and active states2006

    • Author(s)
      Y. Higuchi
    • Organizer
      8th European Biological Inorganic Chemistry Conference(EUROBIC8)
    • Place of Presentation
      Portugal
    • Related Report
      2010 Final Research Report
  • [Presentation] Recent Progress in the Synthesis of Fe/S abd Fe/Mo/S Clusters

    • Author(s)
      K. Tatsumi
    • Organizer
      24^<th> Latin American Chemistry Congress
    • Place of Presentation
      Cartagena, Colombia
    • Related Report
      2010 Final Research Report
  • [Book] Methane Hydroxylation by First Row Transition Metal Oxides2007

    • Author(s)
      K. Yoshizawa, K. Morokuma, D. G. Musaev. Eds
    • Publisher
      Computational Modeling of Principles and Mechanisms of Transition Metal-Based Homogeneous Catalytic Processes
    • Related Report
      2008 Self-evaluation Report
  • [Book] Methane Hydroxylation by First Row Transition Metal Oxides2007

    • Author(s)
      K. Yoshizawa, K. Morokuma, D. G. Musaev, Ed.
    • Publisher
      Wiley-VCH(In press)
    • Related Report
      2007 Annual Research Report
  • [Remarks] 受賞等巽和行、平成23年サイボルト賞(ドイツ)

    • Related Report
      2010 Final Research Report
  • [Remarks] 巽和行、平成23年ミュンスター大学名誉博士号(ドイツ)

    • Related Report
      2010 Final Research Report
  • [Remarks] 大木靖弘、第58回日本化学会進歩賞

    • Related Report
      2010 Final Research Report
  • [Remarks] 大木靖弘、平成21年度文部科学大臣表彰若手科学者賞

    • Related Report
      2010 Final Research Report
  • [Remarks] 吉澤一成、第28回日本化学会学術賞

    • Related Report
      2010 Final Research Report
  • [Remarks] 吉澤一成, BCSJ賞、平成20年10月

    • Related Report
      2010 Final Research Report
  • [Remarks]

    • URL

      http://inorg.chem.nagoya-u.ac.jp/frame.html

    • Related Report
      2010 Final Research Report
  • [Remarks] 報道等(a)雑誌論文(12)の内容が下記に報道される.NHKニュース,毎日新聞,産経新聞,日本経済新聞,神戸新聞,化学工業日報,朝日コム(平成23年10月17日),Chemical & Engineering News(October 24, 2011 Vol.89, No.43, P37), Angewandte Highlights(DOI:10.1002/anie.201108761).

    • Related Report
      2010 Final Research Report
  • [Remarks] (b)雑誌論文(1)の内容がScience誌のEditor’s Choiceに紹介される(Science 2007,317,1297).

    • Related Report
      2010 Final Research Report
  • [Remarks]

    • URL

      http://www.chem.nagoya-u.ac.jp/~ic/grant/index.html

    • Related Report
      2010 Annual Research Report
  • [Remarks] 大木靖弘、第58回日本化学会進歩賞

    • Related Report
      2008 Self-evaluation Report
  • [Remarks] 大木靖弘、平成21年度文部科学大臣表彰若手科学者賞

    • Related Report
      2008 Self-evaluation Report
  • [Remarks]

    • URL

      http://www.chem.nagoya-u.acjp/~ic/grant/index.html

    • Related Report
      2008 Annual Research Report

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Published: 2006-04-01   Modified: 2016-04-21  

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