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X-ray fluorescence analysis harmless to cultural heritages for the next 100-1,000 years

Research Project

Project/Area Number 18H00753
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Review Section Basic Section 03060:Cultural assets study-related
Research InstitutionTokyo Institute of Technology

Principal Investigator

Oguri Yoshiyuki  東京工業大学, 科学技術創成研究院, 教授 (90160829)

Co-Investigator(Kenkyū-buntansha) 長谷川 純  東京工業大学, 科学技術創成研究院, 准教授 (90302984)
羽倉 尚人  東京都市大学, 理工学部, 准教授 (00710419)
Project Period (FY) 2018-04-01 – 2023-03-31
Project Status Completed (Fiscal Year 2022)
Budget Amount *help
¥16,510,000 (Direct Cost: ¥12,700,000、Indirect Cost: ¥3,810,000)
Fiscal Year 2022: ¥2,600,000 (Direct Cost: ¥2,000,000、Indirect Cost: ¥600,000)
Fiscal Year 2021: ¥3,250,000 (Direct Cost: ¥2,500,000、Indirect Cost: ¥750,000)
Fiscal Year 2020: ¥2,860,000 (Direct Cost: ¥2,200,000、Indirect Cost: ¥660,000)
Fiscal Year 2019: ¥5,070,000 (Direct Cost: ¥3,900,000、Indirect Cost: ¥1,170,000)
Fiscal Year 2018: ¥2,730,000 (Direct Cost: ¥2,100,000、Indirect Cost: ¥630,000)
Keywords蛍光X線分析 / 陽子線励起X線放出 / 吸収端 / 検出下限 / 放射線損傷 / 吸収線量 / 文化財 / 無機系顔料 / 荷電粒子励起X線放出 / 静電イオン加速器 / 赤外分光分析
Outline of Final Research Achievements

As a low-dose high-sensitivity trace element analytical method for precious cultural heritage samples, we constructed and tested an X-ray fluorescence spectrometry system which uses quasi-monochromatic X-rays generated by irradiating a metal target with a proton beam as an excitation source. Cu-containing standard samples simulating Japanese paintings were measured and the detection limit for Cu was evaluated. As a result, it was found that by matching the energy of the primary X-ray to the absorption edge of the element to be measured, the dose to obtain the same detection limit performance as compared to conventional XRF can be significantly reduced. A simulated sample containing a mixture of Cu- and Co-based pigments was also measured, and we found that Co could be selectively measured with high accuracy and low dose using a Cu target.

Academic Significance and Societal Importance of the Research Achievements

人文科学と理工学の境界領域に位置する横断的分野の研究課題であり,従来医療や機器分析等で用いられてきた一般的なX線装置では利用されなかったMeV級イオンビーム技術を積極的に採用したことに技術的特徴がある.従来とは異なるメカニズムを用いて比較的低コストで単色の高品質なX線を発生させ,これにより文化財に含まれる微量元素の高感度・低線量分析を可能とした点に学術的意義がある.貴重な人類の文化遺産を傷つけることなく,より精密に測定評価して後世に伝えてゆくための有効な手法を提案したもので,文化財科学だけでなく,将来は体内微量物質の直接測定等,様々な技術分野への展開も期待される点で社会的意義も大きい.

Report

(6 results)
  • 2022 Annual Research Report   Final Research Report ( PDF )
  • 2021 Annual Research Report
  • 2020 Annual Research Report
  • 2019 Annual Research Report
  • 2018 Annual Research Report
  • Research Products

    (12 results)

All 2023 2022 2021 2020 2019 Other

All Journal Article (2 results) (of which Peer Reviewed: 1 results,  Open Access: 2 results) Presentation (8 results) (of which Int'l Joint Research: 1 results) Remarks (2 results)

  • [Journal Article] Low-radiation dose XRF excited by MeV protons for cultural heritage samples2023

    • Author(s)
      Y. Oguri, H. Fukuda, J. Hasegawa and N. Hagura
    • Journal Title

      Heritage Science

      Volume: - Issue: 1

    • DOI

      10.1186/s40494-023-00946-z

    • Related Report
      2022 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Proton-Induced Ge KX-Ray Source for Low-Dose XRF of Cu in Cultural Heritage Samples2021

    • Author(s)
      Y. Oguri
    • Journal Title

      Bull. Lab. Adv. Nucl. Energy

      Volume: 6 Pages: 47-48

    • Related Report
      2021 Annual Research Report
    • Open Access
  • [Presentation] Ge標的へのMeV陽子線照射で発生した準単色X線を用いた文化財試料中のCuの低線量XRF分析2022

    • Author(s)
      小栗慶之,長谷川 純,福田一志,羽倉尚人
    • Organizer
      日本原子力学会2022年秋の大会
    • Related Report
      2022 Annual Research Report
  • [Presentation] 陽子線励起XRFによる日本画用絵具の低線量分析 - 在来型XRFとの比較 -2022

    • Author(s)
      小栗慶之,長谷川 純,福田一志,羽倉尚人
    • Organizer
      第36回PIXEシンポジウム
    • Related Report
      2022 Annual Research Report
  • [Presentation] タンデム静電加速器用小型冷陰極PIG負イオン源のエミッタンス測定2022

    • Author(s)
      劉 洪甫, 羽倉尚人, 河原林 順, 小栗慶之
    • Organizer
      日本原子力学会 2022年春の年会, 3C07, 2022年3月16-18日(オンライン)
    • Related Report
      2021 Annual Research Report
  • [Presentation] Particle Orbit Optimization in the Beam Extraction Region of a Cold Cathode PIG Negative Ion Source for Electrostatic Tandem Accelerators2021

    • Author(s)
      H. Liu , N. Hagura, J. Kawarabayashi and Y. Oguri
    • Organizer
      17th International Conference on Particle Induce X-ray Emission, P5, 11-15 Oct. 2021 (Online)
    • Related Report
      2021 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 都市大タンデムの現状(2019-2020) ~冷陰極PIG負イオン源の改良とWDS-PIXEの開発~2021

    • Author(s)
      羽倉尚人, 小栗慶之, 渡部 創
    • Organizer
      第68回応用物理学会春季学術講演会, 16p-Z34-2, 2021年3月16-19日(オンライン開催)
    • Related Report
      2020 Annual Research Report
  • [Presentation] イオンビーム及びX線照射に伴う模擬文化財試料の損傷のFT-IR測定2020

    • Author(s)
      小栗慶之,長谷川 純,福田一志,羽倉尚人
    • Organizer
      日本原子力学会 2020年春の年会
    • Related Report
      2019 Annual Research Report
  • [Presentation] 陽子線励起単色X線を励起源とした文化財分析用低線量XRF2019

    • Author(s)
      小栗慶之,小林泰智,長谷川 純,福田一志,羽倉尚人
    • Organizer
      日本原子力学会 2019年秋の大会
    • Related Report
      2019 Annual Research Report
  • [Presentation] PIXE分析に伴う和紙試料の損傷のFT-IR測定2019

    • Author(s)
      小栗慶之,長谷川 純,福田一志,羽倉尚人
    • Organizer
      第35回 PIXEシンポジウム
    • Related Report
      2019 Annual Research Report
  • [Remarks] 研究テーマ:微量元素の高感度イオンビーム分析技術

    • URL

      http://www.lane.iir.titech.ac.jp/~yoguri/research/research.html

    • Related Report
      2019 Annual Research Report
  • [Remarks] 微量元素の高感度イオンビーム分析技術

    • URL

      http://www.nr.titech.ac.jp/~yoguri/research/research.html

    • Related Report
      2018 Annual Research Report

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Published: 2018-04-23   Modified: 2024-01-30  

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