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Fluctuations of valence electrons in liquid metals: toward understanding destabilized metallic states

Research Project

Project/Area Number 18H01142
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Review Section Basic Section 13010:Mathematical physics and fundamental theory of condensed matter physics-related
Research InstitutionKumamoto University (2020)
Kyoto University (2018-2019)

Principal Investigator

Matsuda Kazuhiro  熊本大学, 大学院先端科学研究部(理), 教授 (50362447)

Project Period (FY) 2018-04-01 – 2021-03-31
Project Status Completed (Fiscal Year 2020)
Budget Amount *help
¥17,550,000 (Direct Cost: ¥13,500,000、Indirect Cost: ¥4,050,000)
Fiscal Year 2020: ¥3,250,000 (Direct Cost: ¥2,500,000、Indirect Cost: ¥750,000)
Fiscal Year 2019: ¥5,850,000 (Direct Cost: ¥4,500,000、Indirect Cost: ¥1,350,000)
Fiscal Year 2018: ¥8,450,000 (Direct Cost: ¥6,500,000、Indirect Cost: ¥1,950,000)
Keywords液体金属 / 非弾性散乱 / 電子状態
Outline of Final Research Achievements

To gain microscopic understanding for valence electronic state in liquid metals, we carried out the investigation for observing the electron dynamical structure factor, which is the momentum-frequency spectrum of the space-time correlation of the electron density fluctuations. By using synchrotron-based inelastic X-ray scattering technique, we succeeded to measure dynamical structure factors of valence electrons in liquid lithium and sodium over a wide range of momentum-energy transfers. From obtained dynamical structure factors, we derived a wave-number dependent static density response function of valence electrons in the liquid. Furthermore, we used dynamical density response functions to clarify the real space-time screening dynamics of valence electrons induced by a point charge disturbance.

Academic Significance and Societal Importance of the Research Achievements

金属元素の中でも最も自由電子的なアルカリ金属を対象として、溶融状態を長時間安定に保持する試料セル技術と、放射光を用いた非弾性X線散乱とを組み合わせることにより、液体リチウムにおける電子密度応答関数を実験的に初めて導出した。測定対象を電子ガスモデルのプロトタイプ系であるアルカリ金属としていることが大きな特徴である。電子密度応答関数は、電子間の相互作用を反映する重要な物理量であり、密度汎関数法などの理論計算手法においても、交換相関効果の基礎を与える。本研究における実験で得られた電子密度応答関数に関する知見は、電子間相互作用の理解を、実験的立場から深化させていく上で有用な情報となり得るものと考える。

Report

(4 results)
  • 2020 Annual Research Report   Final Research Report ( PDF )
  • 2019 Annual Research Report
  • 2018 Annual Research Report
  • Research Products

    (32 results)

All 2020 2019 2018 Other

All Int'l Joint Research (5 results) Journal Article (18 results) (of which Int'l Joint Research: 14 results,  Peer Reviewed: 18 results,  Open Access: 3 results) Presentation (9 results) (of which Invited: 2 results)

  • [Int'l Joint Research] NSRRC, Taiwan(その他の国・地域)

    • Related Report
      2020 Annual Research Report
  • [Int'l Joint Research] University of Illinois(米国)

    • Related Report
      2020 Annual Research Report
  • [Int'l Joint Research] University of Helsinki(フィンランド)

    • Related Report
      2020 Annual Research Report
  • [Int'l Joint Research] Univ. Grenoble Alpes, CNRS, LPMMC(フランス)

    • Related Report
      2020 Annual Research Report
  • [Int'l Joint Research] NSRRC, Taiwan(その他の国・地域)

    • Related Report
      2019 Annual Research Report
  • [Journal Article] Static density response function studied by inelastic x-ray scattering: Friedel oscillations in solid and liquid Li2020

    • Author(s)
      Hagiya Toru、Matsuda Kazuhiro、Hiraoka Nozomu、Kajihara Yukio、Kimura Koji、Inui Masanori
    • Journal Title

      Physical Review B

      Volume: 102 Issue: 5

    • DOI

      10.1103/physrevb.102.054208

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] X‐Ray Compton Scattering Study of Liquid Sodium at Elevated Temperatures2020

    • Author(s)
      Matsuda Kazuhiro、Kimura Koji、Hagiya Toru、Kajihara Yukio、Inui Masanori、Hiraoka Nozomu、Tamura Kozaburo、Sakurai Yoshiharu
    • Journal Title

      physica status solidi (b)

      Volume: 257 Issue: 11 Pages: 2000187-2000187

    • DOI

      10.1002/pssb.202000187

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Experimental observation of density fluctuations in liquid metals associated with liquid-liquid, liquid-gas and metal-nonmetal transitions2020

    • Author(s)
      Kajihara Y、Inui M、Ohara K、Matsuda K
    • Journal Title

      Journal of Physics: Condensed Matter

      Volume: 32 Issue: 27 Pages: 274001-274001

    • DOI

      10.1088/1361-648x/ab7d66

    • Related Report
      2020 Annual Research Report 2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Peculiar temperature dependence of dynamical sound speed in liquid Se50Te50 by inelastic x-ray scattering2020

    • Author(s)
      Inui M、Kajihara Y、Tsuchiya Y、Hosokawa S、Matsuda K、Uchiyama H、Tsutsui S、Baron A Q R
    • Journal Title

      Journal of Physics: Condensed Matter

      Volume: 32 Issue: 21 Pages: 214003-214003

    • DOI

      10.1088/1361-648x/ab6d8e

    • Related Report
      2020 Annual Research Report 2019 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Furnace for Inelastic X‐Ray Scattering from Liquids up to 1600°C2020

    • Author(s)
      Baron Alfred Q. R.、Inui Masanori、Ishikawa Daisuke、Matsuda Kazuhiro、Kajihara Yukio、Nakajima Yoichi、Taguchi Kazuhiko、Hattori Yasunori
    • Journal Title

      physica status solidi (b)

      Volume: 257 Issue: 11 Pages: 2000093-2000093

    • DOI

      10.1002/pssb.202000093

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Plasmons in Liquid Metals Studied by Inelastic X-ray Scattering2020

    • Author(s)
      Kimura Koji、Hagiya Toru、Matsuda Kazuhiro、Hiraoka Nozomu
    • Journal Title

      Zeitschrift fur Physikalische Chemie

      Volume: 235 Issue: 1-2 Pages: 81-98

    • DOI

      10.1515/zpch-2020-1619

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Structure and Electronic State in a Fluid Alkali Metal: Synchrotron Radiation Studies2020

    • Author(s)
      Matsuda Kazuhiro、Tamura Kozaburo
    • Journal Title

      Zeitschrift fur Physikalische Chemie

      Volume: 235 Issue: 1-2 Pages: 25-36

    • DOI

      10.1515/zpch-2020-1615

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Direct observation of the momentum distribution and renormalization factor in lithium2020

    • Author(s)
      Hiraoka N.、Yang Y.、Hagiya T.、Niozu A.、Matsuda K.、Huotari S.、Holzmann M.、Ceperley D. M.
    • Journal Title

      Physical Review B

      Volume: 101 Issue: 16

    • DOI

      10.1103/physrevb.101.165124

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Quantum Monte Carlo Compton profiles of solid and liquid lithium2020

    • Author(s)
      Yang Yubo、Hiraoka Nozomu、Matsuda Kazuhiro、Holzmann Markus、Ceperley David M.
    • Journal Title

      Physical Review B

      Volume: 101 Issue: 16

    • DOI

      10.1103/physrevb.101.165125

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Sound Speed in Glassy AsxSe1-x (x=0.4, 0.5 and 0.6) by Inelastic X-Rays Scattering2020

    • Author(s)
      Inui Masanori、Matsuda Kazuhiro、Hosokawa Shinya、Nakajima Yoichi、Tsutsui Satoshi、Ishikawa Daisuke、Baron Alfred Q. R.
    • Journal Title

      physica status solidi (b)

      Volume: 257 Issue: 11 Pages: 2000134-2000134

    • DOI

      10.1002/pssb.202000134

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Characterizing crystalline defects in single nanoparticles from angular correlations of single-shot diffracted X-rays2020

    • Author(s)
      Niozu Akinobu, et al.
    • Journal Title

      IUCrJ

      Volume: 7 Issue: 2 Pages: 276-286

    • DOI

      10.1107/s205225252000144x

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Detection of collective optic excitations in molten NaI2019

    • Author(s)
      Hosokawa、Inui、Bryk、Mryglod、Pilgrim、Kajihara、Matsuda、Ohmasa、Tsutsui
    • Journal Title

      Condensed Matter Physics

      Volume: 22 Issue: 4 Pages: 43602-43602

    • DOI

      10.5488/cmp.22.43602

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Structural studies on fluid sulfur at high temperatures and high pressures: I. Atomic dynamics investigated by inelastic x-ray scattering2019

    • Author(s)
      Inui M.、Kajihara Y.、Chiba A.、Matsuda K.、Tsutsui S.、Baron A.Q.R.
    • Journal Title

      Journal of Non-Crystalline Solids

      Volume: 522 Pages: 119571-119571

    • DOI

      10.1016/j.jnoncrysol.2019.119571

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Ultrafast Structural Dynamics of Nanoparticles in Intense Laser Fields2019

    • Author(s)
      Nishiyama Toshiyuki、Kumagai Yoshiaki、Niozu Akinobu、Fukuzawa Hironobu、Motomura Koji、Bucher Maximilian、Ito Yuta、Takanashi Tsukasa、Asa Kazuki、Sato Yuhiro、You Daehyun、Li Yiwen、Ono Taishi、Kukk Edwin、Miron Catalin、Neagu Liviu、Katayama Tetsuo、他17名
    • Journal Title

      Physical Review Letters

      Volume: 123 Issue: 12 Pages: 123201-123201

    • DOI

      10.1103/physrevlett.123.123201

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Dynamical sound speed and structural inhomogeneity in liquid Te studied by inelastic x-ray scattering2019

    • Author(s)
      M. Inui, Y. Kajihara, S. Hosokawa, K. Matsuda, Y. Tsuchiya, S. Tsutsui, and A. Q. R. Baron
    • Journal Title

      Journal of Non-Crystalline Solids X

      Volume: 1 Pages: 100006-100006

    • DOI

      10.1016/j.nocx.2018.100006

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Plasmons in Liquid Rb at Elevated Temperatures Studied by Inelastic X-ray Scattering2018

    • Author(s)
      Hagiya Toru、Matsuda Kazuhiro、Hiraoka Nozomu、Hayashi Hiroyuki、Kimura Koji、Kajihara Yukio、Inui Masanori
    • Journal Title

      Journal of the Physical Society of Japan

      Volume: 87 Issue: 8 Pages: 084703-084703

    • DOI

      10.7566/jpsj.87.084703

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Viscoelastic anomaly accompanying anti-crossing behaviour in liquid As2Se32018

    • Author(s)
      M. Inui, A. Q. R. Baron, Y. Kajihara, K. Matsuda, S. Hosokawa, K. Kimura, Y. Tsuchiya, F. Shimojo, M. Yao, S. Tsutsui, D. Ishikawa, and K. Tamura
    • Journal Title

      Journal of Physics: Condensed Matter

      Volume: 30 Issue: 28 Pages: 28LT02-28LT02

    • DOI

      10.1088/1361-648x/aacab5

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Static and dynamic structures of liquid Ba8Ga16Sn30: a melt of the thermoelectric clathrate compounds2018

    • Author(s)
      M. Inui, K. Suekuni, Y. Kajihara, S. Hosokawa, T. Takabatake, Y. Nakajima, K. Matsuda, K. Ohara, H. Uchiyama, and S. Tsutsui
    • Journal Title

      Journal of Physics: Condensed Matter

      Volume: 30 Issue: 45 Pages: 455101-455101

    • DOI

      10.1088/1361-648x/aae3f3

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Presentation] 液体ナトリウムのX線コンプトン散乱2020

    • Author(s)
      松田和博, 木村耕治, 萩谷透, 梶原行夫, 乾雅祝, 平岡望, 田村剛三郎, 櫻井吉晴
    • Organizer
      日本高圧力学会 第61回高圧討論会
    • Related Report
      2020 Annual Research Report
  • [Presentation] 低密度化金属流体の物性研究:構造と電子ダイナミクス2020

    • Author(s)
      松田和博
    • Organizer
      日本物理学会 秋季大会
    • Related Report
      2020 Annual Research Report
    • Invited
  • [Presentation] 非弾性X線散乱実験を用いたLiの密度応答関数の決定2020

    • Author(s)
      萩谷透、桜澤智大 、松田和博 、平岡望、梶原行夫、木村耕治、乾雅祝
    • Organizer
      第33回日本放射光学会年会・放射光科学合同シンポジウム
    • Related Report
      2019 Annual Research Report
  • [Presentation] 非弾性X線散乱による流体アルカリ金属の電子状態観測2020

    • Author(s)
      松田和博
    • Organizer
      日本物理学会 第75回年次大会(2020年)
    • Related Report
      2019 Annual Research Report
    • Invited
  • [Presentation] 非弾性X線散乱実験を用いた液体Liの遮蔽電子密度の決定2019

    • Author(s)
      萩谷透、鄭允敦、櫻澤智大、松田和博、平岡望、乾雅祝、梶原行夫、木村耕治
    • Organizer
      日本物理学会 2019年秋季大会
    • Related Report
      2019 Annual Research Report
  • [Presentation] Determination of density response function in solid and liquid Li2019

    • Author(s)
      T. Hagiya, Y. Jeong, T. Sakurazawa, K. Matsuda, N. Hiraoka, M. Inui, Y. Kajihara, K. Kimura
    • Organizer
      14th International Conference on the Structure of Non-Crystalline Materials
    • Related Report
      2019 Annual Research Report
  • [Presentation] 非弾性X線散乱実験によるアルカリ金属液体の電子密度応答2019

    • Author(s)
      萩谷透、鄭允敦、櫻澤智大、仁王頭明伸、松田和博、平岡望、乾雅祝、梶原行夫、木村耕治
    • Organizer
      第32回日本放射光学会年会・放射光科学合同シンポジウム
    • Related Report
      2018 Annual Research Report
  • [Presentation] 非弾性X線散乱実験を用いたアルカリ金属における電子密度応答の時空間マッピング2018

    • Author(s)
      萩谷透、鄭允敦 、櫻澤智大、松田和博、平岡望、乾雅祝、梶原行夫、木村耕治
    • Organizer
      放射光学会若手研究会「放射光科学Xインフォマティクス」
    • Related Report
      2018 Annual Research Report
  • [Presentation] 非弾性X線散乱実験による液体リチウムの電子密度応答2018

    • Author(s)
      萩谷透、鄭允敦、櫻澤智大、松田和博、平岡望、乾雅祝、梶原行夫、木村耕治
    • Organizer
      日本物理学会 2018年秋季大会
    • Related Report
      2018 Annual Research Report

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Published: 2018-04-23   Modified: 2022-01-27  

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