• Search Research Projects
  • Search Researchers
  • How to Use
  1. Back to previous page

Elucidation of ion-surface reactions on a interstellar dust surface: exploring their unknown roles in molecular evolution

Research Project

Project/Area Number 18H01273
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Review Section Basic Section 17010:Space and planetary sciences-related
Research InstitutionInstitute of Physical and Chemical Research

Principal Investigator

Nakai Yoichi  国立研究開発法人理化学研究所, 仁科加速器科学研究センター, 専任研究員 (30260194)

Co-Investigator(Kenkyū-buntansha) 日高 宏  北海道大学, 低温科学研究所, 助教 (00400010)
Project Period (FY) 2018-04-01 – 2021-03-31
Project Status Completed (Fiscal Year 2021)
Budget Amount *help
¥17,810,000 (Direct Cost: ¥13,700,000、Indirect Cost: ¥4,110,000)
Fiscal Year 2020: ¥2,600,000 (Direct Cost: ¥2,000,000、Indirect Cost: ¥600,000)
Fiscal Year 2019: ¥3,640,000 (Direct Cost: ¥2,800,000、Indirect Cost: ¥840,000)
Fiscal Year 2018: ¥11,570,000 (Direct Cost: ¥8,900,000、Indirect Cost: ¥2,670,000)
Keywordsイオン表面反応 / 星間化学過程 / 星間化学
Outline of Final Research Achievements

We have performed experimental studies of the reactions between low-energy molecular ions and the surface of interstellar dust ice, for which there was little experimental information. For this purpose, we have developed an experimental apparatus using a reactive scattered ion mass spectrometry (RIS), which is more sensitive than the conventional detection methods for chemical species existing on the surface. The method was improved so that the advantage of RIS could be utilized for chemical species on the low-temperature ice surface. As a result, we have achieved high detection sensitivity for chemical species on low-temperature ice surface. The reaction products were observed after irradiating the surface of the ice thin film formed on the cooled metal substrate with low-energy CH3+ ions. We obtained experimental results indicating the formation of methanol molecules due to the irradiation of the CH3+ ions to the ice surface.

Academic Significance and Societal Importance of the Research Achievements

本研究での実験結果は,低エネルギーのイオンと極低温氷表面との分子生成反応実験として,我々の知る限り,世界で初めて得られた結果である.これは以前の理論的予測を支持するものとなった.実験的情報の不足もあり,低エネルギーのイオンと氷表面との反応による分子生成は,これまでの星間雲での分子生成のモデルでは取り入れられてこなかった.しかし,今後その重要性を適切に評価する必要が出てくるだろう.また,極低温氷表面上の化学種の高感度検出法として,反応性散乱イオン質量分析法が有用であることが示された.

Report

(4 results)
  • 2021 Final Research Report ( PDF )
  • 2020 Annual Research Report
  • 2019 Annual Research Report
  • 2018 Annual Research Report
  • Research Products

    (10 results)

All 2021 2020 2019 2018

All Journal Article (3 results) (of which Int'l Joint Research: 1 results,  Peer Reviewed: 3 results) Presentation (7 results) (of which Int'l Joint Research: 2 results)

  • [Journal Article] Delivery of electrons by proton-hole transfer in ice at 10 K: Role of surface OH radicals2021

    • Author(s)
      K. Kitajima, Y. Nakai, W. M. C. Sameera, M. Tsuge, A. Miyazaki, H. Hidaka, A. Kouchi, N. Watanabe
    • Journal Title

      J. Phys. Chem. Lett.

      Volume: 12 Issue: 1 Pages: 704-710

    • DOI

      10.1021/acs.jpclett.0c03345

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed
  • [Journal Article] CH3O radical binding on hexagonal water ice and amorphous solid water2021

    • Author(s)
      W. M. C. Sameera, B. Senevirathne, S. Andersson, M. Al-lbadi, H. Hidaka, A. Kouchi, G. Nyman, N. Watanabe
    • Journal Title

      J. Phy. Chem. A

      Volume: 125 Issue: 1 Pages: 387-393

    • DOI

      10.1021/acs.jpca.0c09111

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Photostimulated desorption of OH radicals from amorphous solid water: Evidence for the interaction of visible light with an OH-ice complex2020

    • Author(s)
      A. Miyazaki, N. Watanabe, W. M. C. Sameera, Y. Nakai, M. Tsuge, T. Hama, H. Hidaka, A. Kouchi
    • Journal Title

      Phys. Rev. A

      Volume: 102 Issue: 5 Pages: 052822-052822

    • DOI

      10.1103/physreva.102.052822

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed
  • [Presentation] Development of an analysis equipment for detecting trace adsorbate molecules on amorphous solid water by reactive ion scattering method2021

    • Author(s)
      Hiroshi HIDAKA, Atsuki ISHIBASHI, Yasuhiro OBA, Akira KOUCHI, Naoki WATANABE
    • Organizer
      43rd COSPAR Scientific Assembly
    • Related Report
      2020 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 低エネルギーイオンと低温氷表面との反応実験装置開発の現状22021

    • Author(s)
      中井 陽一、日高 宏、渡部 直樹
    • Organizer
      日本物理学会第76回年次大会
    • Related Report
      2020 Annual Research Report
  • [Presentation] 極低温アモルファス氷への紫外光・電子線同時照射による負の氷透過電流生成2020

    • Author(s)
      北島 謙生、中井 陽一、W. M. C. Sameera、宮崎 彩音、柘植 雅士、日髙 宏、香内 晃、渡部 直樹
    • Organizer
      原子衝突学会第45回年会
    • Related Report
      2020 Annual Research Report
  • [Presentation] 低エネルギーイオンと低温氷表面との反応実験装置開発の現状2020

    • Author(s)
      中井陽一,日高宏,渡辺直樹
    • Organizer
      日本物理学会第75回年次大会
    • Related Report
      2019 Annual Research Report
  • [Presentation] 星間塵表面を模擬した低温氷表面と低エネルギーイオンとの反応実験装置の開発2019

    • Author(s)
      中井陽一,日高宏,渡辺直樹
    • Organizer
      原子衝突学会第第44回年会
    • Related Report
      2019 Annual Research Report
  • [Presentation] Laboratory experiment for hydrogenation of C60 fullerenes deposited on a solid surface under low temperature conditions2018

    • Author(s)
      Yoichi Nakai, Naoki Watanabe, Yasuhiro Oba
    • Organizer
      The Olympian Symposium 2018 on "Gas and stars from milli- to mega- parsecs"
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 低温薄膜状C60固体にトラップされた水素分子の振動回転励起の赤外吸収スペクトル2018

    • Author(s)
      中井陽一,渡部直樹
    • Organizer
      原子衝突学会第43回年会
    • Related Report
      2018 Annual Research Report

URL: 

Published: 2018-04-23   Modified: 2023-01-30  

Information User Guide FAQ News Terms of Use Attribution of KAKENHI

Powered by NII kakenhi