Deep water cycle inferred from volatiles in nominally anhydrous minerals from mantle

• Project/Area Number: 18H01320
• Research Category: Grant-in-Aid for Scientific Research (B)
• Allocation Type: Single-year Grants
• Section: 一般
• Review Section: Basic Section 17040:Solid earth sciences-related
• Research Institution: Japan Agency for Marine-Earth Science and Technology
• Principal Investigator: SHIMIZU Kenji 国立研究開発法人海洋研究開発機構, 超先鋭研究開発部門(高知コア研究所), 副主任研究員 (30420491)
• Co-Investigator(Kenkyū-buntansha): 石川 晃 東京工業大学, 理学院, 准教授 (20524507)
• Project Period (FY): 2018-04-01 – 2021-03-31
• Project Status: Completed (Fiscal Year 2020)
• Budget Amount: ¥17,290,000 (Direct Cost: ¥13,300,000、Indirect Cost: ¥3,990,000); Fiscal Year 2020: ¥3,380,000 (Direct Cost: ¥2,600,000、Indirect Cost: ¥780,000); Fiscal Year 2019: ¥6,370,000 (Direct Cost: ¥4,900,000、Indirect Cost: ¥1,470,000); Fiscal Year 2018: ¥7,540,000 (Direct Cost: ¥5,800,000、Indirect Cost: ¥1,740,000)
• Keywords: マントル捕獲岩 / 揮発性物質 / 二次イオン質量分析計 / 地球内部物質循環 / 無水鉱物 / 含水量 / SIMS / 地球内部水循環 / マントル鉱物 / 揮発性元素 / マントル構成鉱物

Outline of Final Research Achievements

Major factor for the chemical heterogeneity of the Earth’s mantle is the global water cycle of the Earth’s interior. In the previous works, this issue was discussed using volcanic rocks (volcanic glasses and melt inclusions), which is the melting product of mantle. In this study, we developed the analytical methods for measuring the trace amounts of water, fluorine, sulfur and chlorine in the mantle minerals (olivine), and established a system to collect volatile data from mantle minerals.

Academic Significance and Societal Importance of the Research Achievements

鉱物中の極微量な揮発性物質濃度を高精度、高分解能で量産ができるようになった。今後は海洋島火山のマントル捕獲岩に限らず、中央海嶺、島弧、大陸など様々なテクトニックセッティングに産するかんらん岩に含まれるマントル鉱物に応用することが可能になり、玄武岩ガラス中の揮発性物質とマントル鉱物中の揮発性物質の両方の研究からアプローチして地球内部の水循環に制約を与えていくという新しい研究を展開することが期待できる。

Research Products

• [Journal Article] Analytical Method of Sulfur Speciation of Volcanic Glass and Melt Inclusions using Soft X-ray Microbeam (2021)
  • Author(s): 清水 健二、柏原 輝彦、為則 雄祐
  • Journal Title: SPring-8/SACLA Research Report Volume: 9 Issue: 1 Pages: 11-15
  • DOI: 10.18957/rr.9.1.11
  • NAID: 130007976074
  • ISSN: 2187-6886
  • Year and Date: 2021-01-28
  • Peer Reviewed / Open Access
• [Journal Article] Persistent gas emission originating from a deep basaltic magma reservoir of an active volcano: the case of Aso volcano, Japan (2021)
  • Author(s): Kawaguchi Masataka、Hasenaka Toshiaki、Koga Kenneth T.、Rose-Koga Estelle F.、Yasuda Atsushi、Hokanishi Natsumi、Mori Yasushi、Shimizu Kenji、Ushikubo Takayuki
  • Journal Title: Contributions to Mineralogy and Petrology Volume: 176 Issue: 1
  • DOI: 10.1007/s00410-020-01761-6
  • Peer Reviewed / Open Access / Int'l Joint Research
• [Journal Article] Magma Source Evolution Following Subduction Initiation: Evidence From the Element Concentrations, Stable Isotope Ratios, and Water Contents of Volcanic Glasses From the Bonin Forearc (IODP Expedition 352) (2021)
  • Author(s): Coulthard Daniel A.、Reagan Mark K.、Shimizu Kenji、Bindeman Ilya N.、Brounce Maryjo、Almeev Renat R.、Ryan Jeffrey、Chapman Timothy、Shervais John、Pearce Julian A.
  • Journal Title: Geochemistry, Geophysics, Geosystems Volume: 22 Issue: 1
  • DOI: 10.1029/2020gc009054
  • Peer Reviewed / Open Access / Int'l Joint Research
• [Journal Article] Magmatic Response to Subduction Initiation, Part II: Boninites and Related Rocks of the Izu‐Bonin Arc From IODP Expedition 352 (2021)
  • Author(s): Shervais John W.、Reagan Mark K.、Godard Marguerite、Prytulak Julie、Ryan Jeffrey G.、Pearce Julian A.、Almeev Renat R.、Li Hongyan、Haugen Emily、Chapman Timothy、Kurz Walter、Nelson Wendy R.、Heaton Daniel E.、Kirchenbaur Maria、Shimizu Kenji、Sakuyama Tetsuya、Vetter Scott K.、Li Yibing、Whattam Scott
  • Journal Title: Geochemistry, Geophysics, Geosystems Volume: 22 Issue: 1
  • DOI: 10.1029/2020gc009093
  • Peer Reviewed / Open Access / Int'l Joint Research
• [Journal Article] Silicate melt inclusions in the new millennium: A review of recommended practices for preparation, analysis, and data presentation (2021)
  • Author(s): Rose-Koga E.F.、Bouvier A.-S.、Gaetani G.A.、Wallace P.J.、Allison C.M.、Andrys J.A.、Angeles de la Torre C.A.、Barth A.、Bodnar R.J.、Bracco Gartner A.J.J.、Butters D.、Castillejo A.、Chilson-Parks B.、Choudhary B.R.、Cluzel N.、Cole M.、Cottrell E.、Shimizu K.など
  • Journal Title: Chemical Geology Volume: 570 Pages: 120145-120145
  • DOI: 10.1016/j.chemgeo.2021.120145
  • Peer Reviewed / Open Access / Int'l Joint Research
• [Journal Article] Microbial sulfate reduction plays an important role at the initial stage of subseafloor sulfide mineralization (2020)
  • Author(s): Nozaki Tatsuo、Nagase Toshiro、Ushikubo Takayuki、Shimizu Kenji、Ishibashi Jun-ichiro、and the D/V Chikyu Expedition 909 Scientists
  • Journal Title: Geology Volume: 49 Issue: 2 Pages: 222-227
  • DOI: 10.1130/g47943.1
  • NAID: 120007017117
  • Peer Reviewed / Open Access
• [Journal Article] Determination of total CO2 in melt inclusions with shrinkage bubbles (2020)
  • Author(s): Hanyu Takeshi、Yamamoto Junji、Kimoto Katsunori、Shimizu Kenji、Ushikubo Takayuki
  • Journal Title: Chemical Geology Volume: 557 Pages: 119855-119855
  • DOI: 10.1016/j.chemgeo.2020.119855
  • Peer Reviewed / Open Access
• [Journal Article] Mineral compositions and thermobarometry of basalts and boninites recovered during IODP Expedition 352 to the Bonin forearc (2020)
  • Author(s): Whattam Scott A.、Shervais John W.、Reagan Mark K.、Coulthard Daniel A.、Pearce Julian A.、Jones Peter、Seo Jieun、Putirka Keith、Chapman Timothy、Heaton Daniel、Li Hongyan、Nelson Wendy R.、Shimizu Kenji、Stern Robert J.
  • Journal Title: American Mineralogist Volume: 105 Issue: 10 Pages: 1490-1507
  • DOI: 10.2138/am-2020-6640
  • Peer Reviewed / Int'l Joint Research
• [Journal Article] Temporal Evolution of Proto-Izu-Bonin-Mariana Arc Volcanism over 10 Myr: Constraints from Statistical Analysis of Melt Inclusion Compositions (2020)
  • Author(s): Hamada Morihisa、Iwamori Hikaru、Brandl Philipp A、Ushikubo Takayuki、Shimizu Kenji、Ito Motoo、Li He、Savov Ivan P
  • Journal Title: Journal of Petrology Volume: - Issue: 1 Pages: 1-29
  • DOI: 10.1093/petrology/egaa022
  • Peer Reviewed / Open Access / Int'l Joint Research
• [Journal Article] Petit-spot volcanoes on the oldest portion of the Pacific plate (2019)
  • Author(s): Hirano Naoto、Machida Shiki、Sumino Hirochika、Shimizu Kenji、Tamura Akihiro、Morishita Taisei、Iwano Hideki、Sakata Shuhei、Ishii Teruaki、Arai Shoji、Yoneda Shigekazu、Danhara Tohru、Hirata Takafumi
  • Journal Title: Deep Sea Research Part I: Oceanographic Research Papers Volume: 154 Pages: 103142-103142
  • DOI: 10.1016/j.dsr.2019.103142
  • Peer Reviewed
• [Journal Article] Identifying volatile mantle trend with the water?fluorine?cerium systematics of basaltic glass (2019)
  • Author(s): Shimizu Kenji、Ito Motoo、Chang Qing、Miyazaki Takashi、Ueki Kenta、Toyama Chiaki、Senda Ryoko、Vaglarov Bogdan S.、Ishikawa Tsuyoshi、Kimura Jun-Ichi
  • Journal Title: Chemical Geology Volume: 522 Pages: 283-294
  • DOI: 10.1016/j.chemgeo.2019.06.014
  • Peer Reviewed / Open Access / Int'l Joint Research
• [Journal Article] <i>In situ</i> analyses of hydrogen and sulfur isotope ratios in basaltic glass using SIMS (2019)
  • Author(s): Shimizu, K., T. Ushikubo, T. Murai, F. Matsu’ura, Y. Ueno
  • Journal Title: GEOCHEMICAL JOURNAL Volume: 53 Issue: 3 Pages: 195-207
  • DOI: 10.2343/geochemj.2.0559
  • NAID: 130007662306
  • ISSN: 0016-7002, 1880-5973
  • Peer Reviewed / Open Access / Int'l Joint Research
• [Journal Article] Buoyant hydrous mantle plume from the mantle transition zone (2019)
  • Author(s): Kuritani, T., Xia, Q.-K., Kimura, J.-I., Liu, J., Shimizu, K., Ushikubo, T., Zhao, D., Nakagawa, M., and Yoshimura, S.
  • Journal Title: Scientific Reports Volume: 印刷中 Issue: 1 Pages: 6549-6549
  • DOI: 10.1038/s41598-019-43103-y
  • Peer Reviewed / Open Access / Int'l Joint Research
• [Journal Article] Magmatic Response to Subduction Initiation: Part 1. Fore-arc Basalts of the Izu-Bonin Arc From IODP Expedition 352 (2019)
  • Author(s): Shervais John W.、Reagan Mark、Haugen Emily、Almeev Renat R.、Pearce Julian A.、Prytulak Julie、Ryan Jeffrey G.、Whattam Scott A.、Godard Marguerite、Chapman Timothy、Li Hongyan、Kurz Walter、Nelson Wendy R.、Heaton Daniel、Kirchenbaur Maria、Shimizu Kenji、Sakuyama Tetsuya、Li Yibing、Vetter Scott K.
  • Journal Title: Geochemistry, Geophysics, Geosystems Volume: 20 Issue: 1 Pages: 314-338
  • DOI: 10.1029/2018gc007731
  • Peer Reviewed / Int'l Joint Research
• [Journal Article] Tiny droplets of ocean island basalts unveil Earth’s deep chlorine cycle (2019)
  • Author(s): Hanyu, T., Shimizu, K., Ushikubo, T., Kimura, J.-I., Chang, Q., Hamada, M., Ito, M., Iwamori, H., Ishikawa, T.
  • Journal Title: Nature Communications Volume: 10 Issue: 1 Pages: 60-60
  • DOI: 10.1038/s41467-018-07955-8
  • Peer Reviewed / Open Access / Int'l Joint Research
• [Journal Article] Suspected meteorite fragments in marine sediments from East Antarctica (2018)
  • Author(s): Naresh C. Pant, Francisco J. Jimenez-Espejo, Cary P. Cook, Paromita Biswas, Robert Mckay, Claudio Marchesi, Motoo Ito, Dewashish Upadhyay, Junichiro Kuroda, Kenji Shimizu, Ryoko Senda, Tina Van De Flierdt, Yoshinori Takano, Katsuhiko Suzuki, Carlota Escutia and Prakash K. Shrivastava
  • Journal Title: ANTARCTIC SCIENCE Volume: 30 Issue: 5 Pages: 307-321
  • DOI: 10.1017/s0954102018000299
  • Peer Reviewed / Open Access / Int'l Joint Research
• [Presentation] Verification and correction of matrix effect on water concentration of volcanic glasses by SIMS (2020)
  • Author(s): Shimizu K., T. Ushikubo, T. Kuritani, N. Hirano, S. Yamashita
  • Organizer: Goldshmidt Conference 2020
• [Presentation] Water Content in Nominally Anhydrous Mineral of Crust/Mantle Boundary Recovered by International Oman Drilling Project: Analytical Strategy and Methods (2020)
  • Author(s): Asyraf, M., Morishita, T., Shimizu, K., Ushikubo, T., Itano, K., Guotana, M., Science Party Oman Drilling Project Phase II
  • Organizer: International Conference on Ophiolites and the Oceanic Lithosphere: Results of the Oman Drilling Project and Related Research
  • Int'l Joint Research
• [Presentation] Water Content in Nominally Anhydrous Minerals of the Crust/Mantle Boundary Recovered by International Oman Drilling Project: Scientific Strategy and Preliminary Results (2020)
  • Author(s): Morishita, T., Asyraf, M., Shimizu, K., Ushikubo, T., Itano, K., Guotana, Senda, R., Yoshikawa, M., Science Party Oman Drilling Project Phase II
  • Organizer: International Conference on Ophiolites and the Oceanic Lithosphere: Results of the Oman Drilling Project and Related Research
  • Int'l Joint Research
• [Presentation] SIMSによる玄武岩質ガラスの水素、硫黄同位体比分析法とその応用 (2019)
  • Author(s): 清水 健二, 牛久保 孝行, 村居 呂一, 松浦 史宏, 上野 雄一郎
  • Organizer: 日本地球惑星科学連合2019年大会
• [Presentation] Estimation of the origin of Pitcairn Island OIB by Independent Component Analysis (2019)
  • Author(s): Ozawa, T., Iwamori, H., Takeshi Hanyu, T., Hamada, M., Shimizu, K., Ushikubo, T., Kimura, J-I, Chang, Q., Nakamura, H., Ito, M.
  • Organizer: 日本地球惑星科学連合2019年大会
  • Int'l Joint Research
• [Presentation] Decoding pre-eruptive magma evolution and water behavior from plagioclase phenocrysts: Application to the Hoei eruption of Mt. Fuji (2019)
  • Author(s): Iizuka, T., Harada, C., Shimizu, K., Ushikubo, T., Hamada, M., Yoshimoto, M.
  • Organizer: 日本地球惑星科学連合2019年大会
  • Int'l Joint Research
• [Presentation] Magma evolution during the Aso-3 caldera-forming eruption cycle deduced from the chemistry of plagioclase phenocrysts (2019)
  • Author(s): Matsukida, Y., Iizuka, T., Ushikubo, T., Shimizu, K., Geshi, N., Miyagi, I., Hamada, M.
  • Organizer: 日本地球惑星科学連合2019年大会
  • Int'l Joint Research
• [Presentation] Secular evolution of proto-Izu-Bonin-Mariana arc volcanism: Constraints from statistical analysis of melt inclusion compositions (2019)
  • Author(s): Hamada, M., Iwamori, H., Brandl, P.A., Ushikubo, T., Shimizu, K., Ito, M., Li, H., Savov, I.P.
  • Organizer: 日本地球惑星科学連合2019年大会
  • Int'l Joint Research
• [Presentation] Development for In-Situ Volatile Element Abundances, and Hydrogen and Sulfur 2-Isotope Analyses of Silicate Glasses by SIMS (2019)
  • Author(s): Ushikubo, T., Shimizu, K.
  • Organizer: 82nd Annual Meeting of The Meteoritical Society 2019
  • Int'l Joint Research
• [Presentation] 炭酸塩化された海洋地殻リサイクルの証拠；HIMU玄武岩のメルト包有物より (2019)
  • Author(s): 羽生毅、木村純一、常青、浜田盛久、清水健二、牛久保孝行, 伊藤元雄、石川剛志、岩森光
  • Organizer: 日本地球化学会第66回年会
• [Presentation] SIMSによる火山ガラス含水量分析に関するマトリックス効果の検証と補正の試み (2019)
  • Author(s): 清水健二, 牛久保孝行, 桂木悠希, 平野直人, 山下茂
  • Organizer: 日本地球化学会第66回年会
• [Presentation] 妙高火山の関山噴火(43 ka)と貫ノ木噴火(41 ka)のメルト包有物の揮発性成分分析 (2019)
  • Author(s): 浜田盛久， Rose-Koga, E.F., Koga, K.T., 牛久保孝行，清水健二，原田英男，山口佳昭
  • Organizer: 日本鉱物科学会2019年年会
• [Presentation] 気泡のあるメルト包有物の二酸化炭素精密測定 (2019)
  • Author(s): 羽生毅、山本順司、木元克典、中村由里子、清水健二、牛久保孝行
  • Organizer: 日本火山学会2019年秋季大会
• [Presentation] 中国東北部五大連池市周辺域の新生代アルカリ玄武岩に含まれるメルト包有物の地球科学的特徴 (2019)
  • Author(s): 林 裕馬, 柵山 徹也, 清水 健二, 牛久保 孝行
  • Organizer: 日本火山学会2019年秋季大会
• [Presentation] The geochemical characteristics of olivine-hosted melt inclusions in Quaternary potassic basalts around Wudalianchi area, NE China (2019)
  • Author(s): Hayashi, Y., Sakuyama, T., Shimizu, K., Ushikubo, T., Kimura, J-I, Hanyu, T., Wei, T.
  • Organizer: American Geophysical Union Fall Meeting 2019
  • Int'l Joint Research
• [Presentation] ハワイ沖ロイヒ、キラウエア深海底ガラス中の揮発性物質濃度と水素同位体比-地球の水の起源物質を求めて- (2018)
  • Author(s): 清水健二, 牛久保孝行, 兼岡一郎
  • Organizer: 日本地球惑星科学連合2018年大会
  • Invited
• [Presentation] Volatile concentrations and hydrogen isotope ratios of submarine glasses from Loihi and Kilauea (2018)
  • Author(s): Shimizu K., Ushikubo T., Kaneoka I.
  • Organizer: Goldschimdt Conference
  • Int'l Joint Research
• [Patent(Industrial Property Rights)] 研磨方法 (2020)
  • Inventor(s): 清水健二
  • Industrial Property Rights Holder: 海洋研究開発機構
  • Industrial Property Rights Type: 特許
  • Filing Date: 2020
  • Acquisition Date: 2020