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Elucidation and demonstration of design solutions for fuel cell electrodes that minimize energy loss

Research Project

Project/Area Number 18H01383
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Review Section Basic Section 19020:Thermal engineering-related
Research InstitutionOsaka University

Principal Investigator

Tsushima Shohji  大阪大学, 工学研究科, 教授 (30323794)

Co-Investigator(Kenkyū-buntansha) 鈴木 崇弘  大阪大学, 工学研究科, 助教 (90711630)
Project Period (FY) 2018-04-01 – 2022-03-31
Project Status Completed (Fiscal Year 2021)
Budget Amount *help
¥17,290,000 (Direct Cost: ¥13,300,000、Indirect Cost: ¥3,990,000)
Fiscal Year 2021: ¥2,860,000 (Direct Cost: ¥2,200,000、Indirect Cost: ¥660,000)
Fiscal Year 2020: ¥2,860,000 (Direct Cost: ¥2,200,000、Indirect Cost: ¥660,000)
Fiscal Year 2019: ¥2,860,000 (Direct Cost: ¥2,200,000、Indirect Cost: ¥660,000)
Fiscal Year 2018: ¥8,710,000 (Direct Cost: ¥6,700,000、Indirect Cost: ¥2,010,000)
Keywords燃料電池 / 物質輸送 / ナノマイクロ構造制御 / 数理最適化
Outline of Final Research Achievements

This research was conducted to clarify and demonstrate the design solution of the porous electrode called catalyst layer, that minimizes the energy loss in the polymer electrolyte fuel cell. Considering electrode materials and voids in the catalyst layer and their volume fractions, a three-dimensional reaction transport structure model with the two-phase flow behavior was developed, and the design factors and energy loss of the electrode catalyst layer were investigated. For the demonstration, we developed the microprinting technology and carried out cross-section analysis and thermal analysis measurement to clarify the mechanism by which the porous structure was different in the microprinting catalyst layer and the cell performance was improved. We have acquired the structural analysis method and structural control technology that are the basis for elucidating and demonstrating the design solution of the fuel cell electrodes for the minimization of energy loss.

Academic Significance and Societal Importance of the Research Achievements

固体高分子形燃料電池は,次世代の自動車用動力源として国内外で活発な研究開発が進められています.さらなる普及拡大のためには,エネルギー効率の向上によるシステムコストの低減が求められます.本研究では,固体高分子形燃料電池のエネルギー効率向上の鍵となる電極に着目し,内部構造ならびに材料分布の設計と実現についての研究開発を実施しました.電池構造にもとづいて性能を予測するシミュレーションモデルを構築し,材料分布の形成が電池性能の向上をもたらすことを示しました.実際に,構造化された電極をマイクロプリンティング技術により作製し,従来手法とは異なる空隙構造により,燃料電池性能が向上する機構を明らかにしました.

Report

(4 results)
  • 2021 Final Research Report ( PDF )
  • 2020 Annual Research Report
  • 2019 Annual Research Report
  • 2018 Annual Research Report
  • Research Products

    (16 results)

All 2020 2019 2018

All Journal Article (3 results) (of which Peer Reviewed: 3 results,  Open Access: 2 results) Presentation (13 results) (of which Int'l Joint Research: 5 results,  Invited: 2 results)

  • [Journal Article] Analysis of ionomer distribution and Pt/C agglomerate size in catalyst layers by two-stage ion-beam processing2020

    • Author(s)
      T. Suzuki, S. Okada, S. Tsushima
    • Journal Title

      Journal of the Electrochemical Society

      Volume: 167 Issue: 12 Pages: 124513-124513

    • DOI

      10.1149/1945-7111/abad6a

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Investigation of gas transport properties of PEMFC catalyst layers using a microfluidic device2020

    • Author(s)
      T. Suzuki, Y. Nakata, F. Tsutsui, S. Tsushima
    • Journal Title

      Journal of the Electrochemical Society

      Volume: 167 Issue: 12 Pages: 124519-124519

    • DOI

      10.1149/1945-7111/abaf28

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] 電池デバイスにおける究極の電極構造を目指して:固体高分子形燃料電池とレドックスフロー電池への取り組み2020

    • Author(s)
      津島将司,鈴木崇弘
    • Journal Title

      伝熱

      Volume: 59 Pages: 33-39

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed
  • [Presentation] 並行マイクロ流路間酸素透過測定と多孔質構造評価によるPEFC触媒層内ガス輸送解析2020

    • Author(s)
      筒井史朗,鈴木崇弘,津島将司
    • Organizer
      第57回日本伝熱シンポジウム
    • Related Report
      2020 Annual Research Report
  • [Presentation] インクジェット印刷により作製したPEFC触媒層の構造と発電性能2020

    • Author(s)
      清水祐樹,爰川里帆,村田良介,鈴木崇弘,津島将司
    • Organizer
      第57回日本伝熱シンポジウム
    • Related Report
      2020 Annual Research Report
  • [Presentation] PEFC電極スラリー乾燥過程の軟X線顕微観察2020

    • Author(s)
      宮澤直之,鈴木崇弘,津島将司
    • Organizer
      第57回日本伝熱シンポジウム
    • Related Report
      2020 Annual Research Report
  • [Presentation] アイオノマー対カーボン比の異なる固体高分子形燃料電池触媒層のガス輸送計測と解析2020

    • Author(s)
      筒井史朗,鈴木崇弘,津島将司
    • Organizer
      日本機械学会2020年度年次大会
    • Related Report
      2020 Annual Research Report
  • [Presentation] インクジェット法とドクターブレード法により作製したPEFC触媒層の構造と発電性能2020

    • Author(s)
      清水祐樹,鈴木崇弘,津島将司
    • Organizer
      日本機械学会2020年度年次大会
    • Related Report
      2020 Annual Research Report
  • [Presentation] Rheological and impedance measurements and analysis of catalyst ink prepared by different mixing processes2020

    • Author(s)
      T. Suzuki, S. Kitamura, S. Tsushima
    • Organizer
      238th ECS Meeting
    • Related Report
      2020 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Measurement and analysis of gas transport properties in catalyst layers of polymer electrolyte fuel cell with different ionomer to carbon ratio2020

    • Author(s)
      F. Tsutsui, T. Suzuki, S. Tsushima
    • Organizer
      238th ECS Meeting
    • Related Report
      2020 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Fabrication and Evaluation of Catalyst Layers in Polymer Electrolyte Fuel Cells: A Comparison of Decal and Inkjet Printing Techniques2020

    • Author(s)
      Y. Shimizu, T. Suzuki, S. Tsushima,
    • Organizer
      238th ECS Meeting
    • Related Report
      2020 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Investigation of Gas Transport Properties of PEMFC Catalyst Layers by Using a Microfluidic Device2019

    • Author(s)
      T. Suzuki, Y. Nakata, S. Tsushima
    • Organizer
      236th ECS Meeting
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] study on rheological and dielectric properties of carbon/ionomer dispersions prepared by different mixing processes2019

    • Author(s)
      S. Kitamura, T. Suzuki, S. Tsushima
    • Organizer
      The Fifth International Symposium on Innovative Materials and Processes in Energy Systems (IMPRES2019)
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 固体高分子形燃料電池における二相流動促進に向けた電極構造制御2019

    • Author(s)
      津島将司, 鈴木崇弘
    • Organizer
      日本機械学会関西支部 第20回秋季技術交流フォーラム 気液二相流技術懇話会
    • Related Report
      2019 Annual Research Report
    • Invited
  • [Presentation] 電気化学エネルギー変換デバイスの魅力と課題-固体高分子形燃料電池とレドックスフロー電池を中心として-2019

    • Author(s)
      津島将司
    • Organizer
      日本機械学会関西支部燃焼懇話会・内燃機関懇話会
    • Related Report
      2019 Annual Research Report
    • Invited
  • [Presentation] イオンビーム二段階加工によるIC比の異なるPEFC触媒層内アイオノマー分布解析2018

    • Author(s)
      岡田真也, 鈴木崇弘, 津島将司
    • Organizer
      熱工学コンファレンス2018講演論文集
    • Related Report
      2018 Annual Research Report

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Published: 2018-04-23   Modified: 2023-01-30  

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