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Creation of new optical function by a control of band orbital hybridization in semiconducting silicides

Research Project

Project/Area Number 18H01477
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Review Section Basic Section 21050:Electric and electronic materials-related
Research InstitutionKyushu Institute of Technology

Principal Investigator

TERAI Yoshikazu  九州工業大学, 大学院情報工学研究院, 教授 (90360049)

Project Period (FY) 2018-04-01 – 2021-03-31
Project Status Completed (Fiscal Year 2020)
Budget Amount *help
¥17,420,000 (Direct Cost: ¥13,400,000、Indirect Cost: ¥4,020,000)
Fiscal Year 2020: ¥2,730,000 (Direct Cost: ¥2,100,000、Indirect Cost: ¥630,000)
Fiscal Year 2019: ¥6,630,000 (Direct Cost: ¥5,100,000、Indirect Cost: ¥1,530,000)
Fiscal Year 2018: ¥8,060,000 (Direct Cost: ¥6,200,000、Indirect Cost: ¥1,860,000)
Keywordsシリサイド半導体 / 鉄シリサイド / 電子構造制御 / バンド軌道制御 / 光学機能の創出
Outline of Final Research Achievements

Be-ta iron silicide semiconductors (β-FeSi2) is a new optical material that shows light-emitting and light-receiving functions in the optical communication wavelength of 1.5 um. The purpose of this research is to enhance the light-emitting intensity by control of its electronic structure due to adding a third element of Ru. As a result, we succeeded in the growth of (β-Fe1-xRux)Si2 up to x = 0.57. Then, it was found that the addition of Ru induces the desired change in electronic structure and the increases of the emission intensity at 1.5 um.

Academic Significance and Societal Importance of the Research Achievements

現在の光ファイバー光通信で用いられる波長1.5 um帯の半導体レーザーは希少金属や有害物質を含有した材料で作製されている.本研究では,地球上に豊富に存在し,人体に無害な元素で構成される新規光半導体の光通信応用を念頭に,既存機能の代替だけでなく,新機能発現のための学術研究を実施した.従来物質と大きく異なる電子構造をシリサイド半導体は有しており,本研究では,その電子構造を第3元素添加により制御可能であることを見いだした学術的意義がある.

Report

(4 results)
  • 2020 Annual Research Report   Final Research Report ( PDF )
  • 2019 Annual Research Report
  • 2018 Annual Research Report
  • Research Products

    (44 results)

All 2021 2020 2019 2018 Other

All Int'l Joint Research (3 results) Journal Article (10 results) (of which Int'l Joint Research: 3 results,  Peer Reviewed: 10 results,  Open Access: 2 results) Presentation (28 results) (of which Int'l Joint Research: 4 results) Remarks (3 results)

  • [Int'l Joint Research] Automation and Control Processes/Far Eastern Branch/Russian Academy of Sciences(ロシア連邦)

    • Related Report
      2020 Annual Research Report
  • [Int'l Joint Research] Institute of/Automation and Control Processes/FEB, RAS(ロシア連邦)

    • Related Report
      2019 Annual Research Report
  • [Int'l Joint Research] Institute of/Automation and Control Processes/FEB, RAS(ロシア連邦)

    • Related Report
      2018 Annual Research Report
  • [Journal Article] Photoreflectance spectra of highly-oriented Mg2Si(111)//Si(111) films2020

    • Author(s)
      Y. Terai, H. Hoshida, R. Kinoshita, A. Shevlyagin, I. Chernev and A. Gouralnik
    • Journal Title

      Japanese Journal of Applied Physics : Conference Proceedings

      Volume: 8 Pages: 011004-011004

    • DOI

      10.7567/jjapcp.8.011004

    • Related Report
      2020 Annual Research Report 2019 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Probing the Mg2Si/Si(111) heterojunction for photovoltaic applications2020

    • Author(s)
      Alexander Shevlyagin, Igor Chernev, Nikolay Galkin, Andrey Gerasimenko, Anton Gutakovskii, Hirofumi Hoshida, Yoshikazu Terai, Naofumi Nishikawa, Keisuke Ohdaira
    • Journal Title

      Solar Energy

      Volume: 211 Pages: 383-395

    • DOI

      10.1016/j.solener.2020.09.085

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Photoluminescence properties of polycrystalline β-FeSi2 grown by RF magnetron sputtering2020

    • Author(s)
      Yoshikazu Terai, Hiroki Nishi and Naohiro Oka
    • Journal Title

      Japanese Journal of Applied Physics

      Volume: 59 Issue: SF Pages: SFFC01-SFFC01

    • DOI

      10.7567/1347-4065/ab656e

    • NAID

      210000157901

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Significant enhancement of photoresponsivity in As-doped n-BaSi2 epitaxial films by atomic hydrogen passivation2020

    • Author(s)
      Sho Aonuki, Yudai Yamashita, Takuma Sato, Zhihao Xu, Kazuhiro Gotoh , Kaoru Toko , Yoshikazu Terai, Noritaka Usami, and Takashi Suemasu
    • Journal Title

      Applied Physics Express

      Volume: 13 Issue: 5 Pages: 051001-051001

    • DOI

      10.35848/1882-0786/ab8725

    • NAID

      120007127620

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Investigation of defect levels in BaSi2 epitaxial films by photoluminescence and the effect of atomic hydrogen passivation2019

    • Author(s)
      Benincasa Louise、Hoshida Hirofumi、Deng Tianguo、Sato Takuma、Xu Zhihao、Toko Kaoru、Terai Yoshikazu、Suemasu Takashi
    • Journal Title

      Journal of Physics Communications

      Volume: 3 Issue: 7 Pages: 075005-075005

    • DOI

      10.1088/2399-6528/ab2fa1

    • NAID

      120007133014

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Polarized Raman spectra of β-FeSi2 epitaxial film grown by molecular beam epitaxy2018

    • Author(s)
      Yoshikazu Terai, Haruki Yamaguchi, Hiroaki Tsukamoto, Naoki Murakoso, and Hirofumi Hoshida
    • Journal Title

      AIP Advances

      Volume: 8 Issue: 10

    • DOI

      10.1063/1.5042801

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Detection of local vibrational modes induced by intrinsic defects in undoped BaSi2 light absorber layers using Raman spectroscopy2018

    • Author(s)
      Takuma Sato, Hirofumi Hoshida, Ryota Takabe, Kaoru Toko, Yoshikazu Terai, and Takashi Suemasu
    • Journal Title

      Journal of Applied Physics

      Volume: 124 Issue: 2 Pages: 025301-025301

    • DOI

      10.1063/1.5029320

    • NAID

      120007134086

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Growth of Ru2Si3 Polycrystalline Thin Films by Solid Phase Epitaxy in Ru-Si Amorphous Layers2018

    • Author(s)
      Kenta Setojima, Shuya Ikeda, Kazuya Ogi and Yoshikazu Terai
    • Journal Title

      Defect and Diffusion Forum

      Volume: 386 Pages: 33-37

    • DOI

      10.4028/www.scientific.net/ddf.386.33

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Growth of Sb-Doped β-FeSi2 Epitaxial Films and Optimization of Donor Activation Conditions2018

    • Author(s)
      Hajime Eguchi, Motoki Iinuma, Hirofumi Hoshida, Naoki Murakoso and Yoshikazu Terai
    • Journal Title

      Defect and Diffusion Forum

      Volume: 386 Pages: 38-42

    • DOI

      10.4028/www.scientific.net/ddf.386.38

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Identification of Vibrational Modes in BaSi<sub>2</sub> Epitaxial Films by Infrared and Raman Spectroscopy2018

    • Author(s)
      Hoshida Hirofumi、Murakoso Naoki、Suemasu Takashi、Terai Yoshikazu
    • Journal Title

      Defect and Diffusion Forum

      Volume: 386 Pages: 43-47

    • DOI

      10.4028/www.scientific.net/ddf.386.43

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Presentation] β-(Fe1-xRux)Si2多結晶薄膜の作製と発光特性評価2021

    • Author(s)
      吉原 怜,西 大樹,寺井慶和
    • Organizer
      2021年 第68回応用物理学会春季学術講演会
    • Related Report
      2020 Annual Research Report
  • [Presentation] n-Ru2Si3/p-Siヘテロ接合における光応答特性の評価(II)2020

    • Author(s)
      西 大樹,寺井慶和
    • Organizer
      2020年 第81回応用物理学会秋季学術講演会
    • Related Report
      2020 Annual Research Report
  • [Presentation] スパッタリング法によるβ-Fe1-xRuxSi2多結晶薄膜の作製2020

    • Author(s)
      篠村 太輔,西 大樹,寺井 慶和
    • Organizer
      2020年 第81回応用物理学会秋季学術講演会
    • Related Report
      2020 Annual Research Report
  • [Presentation] β-FeSi2 pnホモ型接合素子の作製と分光感度評価2020

    • Author(s)
      木下涼太, 山戸一輝, 寺井慶和
    • Organizer
      2020年度 応用物理学会九州支部学術講演会
    • Related Report
      2020 Annual Research Report
  • [Presentation] Photoresponse spectra of n-Ru2Si3/p-Si hetero-junction grown by solid phase epitaxy2020

    • Author(s)
      Hiroki Nishi and Yoshikazu Terai
    • Organizer
      8th International Symposium on Applied Engineering and Sciences
    • Related Report
      2020 Annual Research Report
    • Int'l Joint Research
  • [Presentation] β-FeSi2 pnホモ接合素子の作製と光応答特性2020

    • Author(s)
      木下涼太,山戸一輝,寺井慶和
    • Organizer
      2021年 第68回応用物理学会春季学術講演会
    • Related Report
      2020 Annual Research Report
  • [Presentation] Dependence of electrical conduction properties on activation conditions in Sb-doped β-FeSi2 epitaxial films2019

    • Author(s)
      Mitsuki Abe, Hajime Eguchi, Hirofumi Hoshida and Yoshikazu Terai
    • Organizer
      Asia-Pacific Conference on Green Technology with Silicides and Related Materials (APAC-SILICIDE 2019), July 20, 2019, Miyazaki, Japan
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Photoluminescence properties of polycrystalline β-FeSi2 grown by RF magnetron sputtering2019

    • Author(s)
      Hiroki Nishi, Naohiro Oka and Yoshikazu Terai
    • Organizer
      Asia-Pacific Conference on Green Technology with Silicides and Related Materials (APAC-SILICIDE 2019), July 20, 2019, Miyazaki, Japan
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Photoreflectance spectra of highly-oriented Mg2Si(111)//Si(111) films2019

    • Author(s)
      R. Kinoshita, H. Hoshida, A. Shevlyagin, I. Chernev, A. Gouralnik, and Y. Terai
    • Organizer
      Asia-Pacific Conference on Green Technology with Silicides and Related Materials (APAC-SILICIDE 2019), July 20, 2019, Miyazaki, Japan
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] n-Ru2Si3/p-Si pn接合素子の作製と光応答特性2019

    • Author(s)
      西 大樹,瀬戸島 健太,寺井慶和
    • Organizer
      2019年 第80回応用物理学会秋季学術講演会
    • Related Report
      2019 Annual Research Report
  • [Presentation] Sb添加β-FeSi2エピタキシャル膜におけるSi/Fe組成比の最適化2019

    • Author(s)
      木下涼太,阿部光希,江口元,寺井慶和
    • Organizer
      2019年 第80回応用物理学会秋季学術講演会
    • Related Report
      2019 Annual Research Report
  • [Presentation] 固相成長法により作製したRu2Si3多結晶薄膜の光学特性評価2019

    • Author(s)
      西 大樹,瀬戸島 健太,寺井 慶和
    • Organizer
      第11回半導体材料・デバイスフォーラム
    • Related Report
      2019 Annual Research Report
  • [Presentation] n-Ru2Si3/p-Si pn接合素子における光応答特性の評価2019

    • Author(s)
      西 大樹,寺井慶和
    • Organizer
      2020年 第67回応用物理学会春季学術講演会
    • Related Report
      2019 Annual Research Report
  • [Presentation] 固相成長β-FeSi2ナノ結晶の発光寿命評価2018

    • Author(s)
      阿部光希,N. G. Galkin,寺井慶和
    • Organizer
      第18回シリサイド系半導体・夏の学校
    • Related Report
      2018 Annual Research Report
  • [Presentation] B添加β-FeSi2/Si多結晶積層構造における1.5 μm発光の基板依存性2018

    • Author(s)
      池田 修哉,岡 直大, 寺井 慶和
    • Organizer
      第18回シリサイド系半導体・夏の学校
    • Related Report
      2018 Annual Research Report
  • [Presentation] BaSi2エピタキシャル膜における光変調反射率スペクトルのBa/Siフラックス比依存性2018

    • Author(s)
      星田裕文,末益 崇,寺井慶和
    • Organizer
      2018年 第79回応用物理学会秋季学術講演会
    • Related Report
      2018 Annual Research Report
  • [Presentation] Investigation of defect levels in undoped-BaSi2 epitaxial films by PL measurement2018

    • Author(s)
      L. Benincasa, H. Hoshida, T. Deng, M. Sato, K. Toko, Y. Terai, and T. Suemasu
    • Organizer
      2018年 第79回応用物理学会秋季学術講演会
    • Related Report
      2018 Annual Research Report
  • [Presentation] Identification of Raman vibrational modes in BaSi2 epitaxial film by depolarization ratio2018

    • Author(s)
      H. Hirofumi, N. Murakoso, T. Suemasu, Y. Terai
    • Organizer
      Fourth Asian School-Conference on Physics and Technology of Nanostructured Materials
    • Related Report
      2018 Annual Research Report
  • [Presentation] Growth of Sb-doped β-FeSi2 epitaxial films and optimization of donor activation conditions2018

    • Author(s)
      Hajime Eguchi, Motoki Iinuma, Hirofumi Hoshida, Naoki Murakoso and Yoshikazu Terai
    • Organizer
      Fourth Asian School-Conference on Physics and Technology of Nanostructured Materials
    • Related Report
      2018 Annual Research Report
  • [Presentation] Growth of Ru2Si3 polycrystalline thin films by solid phase epitaxy in Ru-Si amorphous layers2018

    • Author(s)
      K. Setojima, S. Ikeda, K. Ogi, N. Oka, Y. Terai
    • Organizer
      Fourth Asian School-Conference on Physics and Technology of Nanostructured Materials
    • Related Report
      2018 Annual Research Report
  • [Presentation] 偏光ラマン測定を用いたBaSi2エピタキシャル膜の分子振動評価2018

    • Author(s)
      星田裕文,末益 崇,寺井慶和
    • Organizer
      第10回半導体材料・デバイスフォーラム
    • Related Report
      2018 Annual Research Report
  • [Presentation] Sb添加β-FeSi2エピタキシャル膜の作製とドナー活性化条件の最適化2018

    • Author(s)
      江口 元,飯沼 元輝,星田 裕文,村社 尚紀,寺井 慶和
    • Organizer
      第10回半導体材料・デバイスフォーラム
    • Related Report
      2018 Annual Research Report
  • [Presentation] Sb添加β-FeSi2エピタキシャル膜におけるSb置換サイトの検証2018

    • Author(s)
      阿部光希,江口元,星田裕文,寺井慶和
    • Organizer
      平成30年度応用物理学会九州支部学術講演会
    • Related Report
      2018 Annual Research Report
  • [Presentation] Si/B添加β-FeSi2/Si多重積層構造における発光スペクトル評価2018

    • Author(s)
      岡 直大,瀬戸島 健太,寺井 慶和
    • Organizer
      平成30年度応用物理学会九州支部学術講演会
    • Related Report
      2018 Annual Research Report
  • [Presentation] Si/B添加β-FeSi2/Si積層構造における1.5 μm発光の活性層厚依存性2018

    • Author(s)
      岡 直大,佐藤隆治,寺井慶和
    • Organizer
      2019年 第66回応用物理学会春季学術講演会
    • Related Report
      2018 Annual Research Report
  • [Presentation] Sb添加β-FeSi2エピタキシャル膜におけるドナー活性化条件の最適化(II)2018

    • Author(s)
      江口 元,阿部光希,木下涼太,村上智樹,寺井慶和
    • Organizer
      2019年 第66回応用物理学会春季学術講演会
    • Related Report
      2018 Annual Research Report
  • [Presentation] Study of the origin of defect levels in undoped-BaSi2 epitaxial films by PL measurement2018

    • Author(s)
      L. Benincasa, H. Hoshida, T. Deng, T. Sato, K. Toko, Y. Terai, and T. Suemasu
    • Organizer
      2019年 第66回応用物理学会春季学術講演会
    • Related Report
      2018 Annual Research Report
  • [Presentation] Mg2Si(111)//Si(111)高配向膜における光変調反射率スペクトルの評価2018

    • Author(s)
      星田裕文, S. Alexander, I. Chernev, N.G. Galkin, 寺井慶和
    • Organizer
      2019年 第66回応用物理学会春季学術講演会
    • Related Report
      2018 Annual Research Report
  • [Remarks] 九州工業大学 研究者情報

    • URL

      https://hyokadb02.jimu.kyutech.ac.jp/html/100000800_ja.html

    • Related Report
      2020 Annual Research Report
  • [Remarks] 九州工業大学研究者詳細

    • URL

      https://research02.jimu.kyutech.ac.jp/html/100000800_ja.html

    • Related Report
      2019 Annual Research Report 2018 Annual Research Report
  • [Remarks] 九州工業大学寺井研究室

    • URL

      http://brave.cse.kyutech.ac.jp/

    • Related Report
      2019 Annual Research Report 2018 Annual Research Report

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Published: 2018-04-23   Modified: 2022-01-27  

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