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Development of bioelectrochemical electrodes unit using low-cost air cathode capable of simultaneous removal of organic matter and nitrogen with generating electric power from organic wastewater

Research Project

Project/Area Number 18H01565
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Review Section Basic Section 22060:Environmental systems for civil engineering-related
Research InstitutionGunma University

Principal Investigator

Watanabe Tomohide  群馬大学, 大学院理工学府, 教授 (60251120)

Co-Investigator(Kenkyū-buntansha) 石飛 宏和  群馬大学, 大学院理工学府, 助教 (00708406)
窪田 恵一  群馬大学, 大学院理工学府, 助教 (50707510)
Project Period (FY) 2018-04-01 – 2021-03-31
Project Status Completed (Fiscal Year 2021)
Budget Amount *help
¥16,640,000 (Direct Cost: ¥12,800,000、Indirect Cost: ¥3,840,000)
Fiscal Year 2020: ¥4,420,000 (Direct Cost: ¥3,400,000、Indirect Cost: ¥1,020,000)
Fiscal Year 2019: ¥5,590,000 (Direct Cost: ¥4,300,000、Indirect Cost: ¥1,290,000)
Fiscal Year 2018: ¥6,630,000 (Direct Cost: ¥5,100,000、Indirect Cost: ¥1,530,000)
Keywords微生物燃料電池 / 廃水処理 / エアカソード / 硝化 / 窒素処理 / 硝化脱窒 / 酸素還元反応触媒
Outline of Final Research Achievements

A low-cost and high-activity ORR catalysts were prepared by nitrogen-doping of powdered activated carbon. Optimum and/or acceptable conditions for making the cost-effective air breathing cathodes were obtained experimentally such as the N-dope activated carbon catalyst loading, lesser content of Nafion, possible alternative binder materials for making the catalyst layer and stainless-steel woven wire meshes as alternative base electrode instead of conventional carbon materials. Improved performance of a long-term nitrogen removal and power generation was demonstrated in MFC equipped with the air cathode covered by a separator with pre-enriched nitrifying biofilm. The better materials as separators in this system were also obtained. An electrode unit, a set of the air cathode, a separator with pre-enriched nitrifying biofilm, carbon felt anode and current collectors is assembled and was demonstrated simultaneous removal of organic matter and nitrogen with generating electric power.

Academic Significance and Societal Importance of the Research Achievements

本研究において、系内で安定的に窒素処理を進行させること、活性炭を原料として従来に比べて大幅に廉価なORR触媒やエアカソードの作製条件に関わる知見が得られたこと、さらには、電極をユニット化して利用する可能性も実証したことのそれぞれに学術的な意義がある。また、MFCの仕組みを応用した含窒素有機性廃水に対する新しい省・創エネルギー型処理システムの実用へ向けた課題の克服に寄与する可能性を有することに社会的意義があると考えられる。

Report

(4 results)
  • 2021 Final Research Report ( PDF )
  • 2020 Annual Research Report
  • 2019 Annual Research Report
  • 2018 Annual Research Report
  • Research Products

    (16 results)

All 2022 2021 2020 2019 2018 Other

All Presentation (13 results) (of which Int'l Joint Research: 4 results) Book (2 results) Remarks (1 results)

  • [Presentation] エアカソードへ重ねた硝化能を有する多孔性膜の効果と材質の影響2022

    • Author(s)
      劉澤,佐藤司,篠原雅人,窪田恵一,渡邉智秀
    • Organizer
      第56回日本水環境学会年会
    • Related Report
      2020 Annual Research Report
  • [Presentation] 硝化細菌生物膜を有するセパレータ―の一槽式微生物燃料電池への設置効果2020

    • Author(s)
      入澤友規,窪田恵一,渡邉智秀
    • Organizer
      第22回化学工学会学生発表会(東京大会)
    • Related Report
      2019 Annual Research Report
  • [Presentation] エアカソードの触媒層調整条件が微生物燃料電池の性能へ及ぼす影響2020

    • Author(s)
      成塚宏平,窪田恵一,石飛宏和,渡邉智秀
    • Organizer
      第54回日本水環境学会年会
    • Related Report
      2019 Annual Research Report
  • [Presentation] Long-term performance of TN removal and power generation in a single chamber MFC using a separator with pre-enriched nitrifying biofilm2019

    • Author(s)
      Tomohide Watanabe, Atsuko Kawata, Shun Tanno, Song Xue, and Keiichi. Kubota
    • Organizer
      16th IWA World Conference on Anaerobic Digestion (AD-16)
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Mitigation effect of a microporous sheet with pre-enriched nitrifying biofilm on long-term deterioration in TN removal and power generation in a single-chamber MFC2019

    • Author(s)
      Tomohide Watanabe, Atsuko Kawata, Shun Tanno and Keiichi Kubota
    • Organizer
      International society for microbial electrochemistry and technology global conference (ISMET7)
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Power generation in a MFC with an air cathode fabricated under different preparation condition for a catalytic layer using a nitrogen-doped activated carbon catalyst2019

    • Author(s)
      Kouhei Narizuka, Hirokazu Ishitobi, Keiichi Kubota and Tomohide Watanabe
    • Organizer
      International society for microbial electrochemistry and technology global conference (ISMET7)
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 活性炭触媒を用いたエアカソードを適用した微生物燃料電池の特性2019

    • Author(s)
      佐々木拓真,成塚宏平,窪田恵一,渡邉智秀
    • Organizer
      第21回化学工学会学生発表会(東京大会)
    • Related Report
      2018 Annual Research Report
  • [Presentation] 硝化能を有する多孔質シートを設置した一槽式微生物燃料電池の特性2019

    • Author(s)
      川田敦子,丹野 峻,窪田恵一,渡邉智秀
    • Organizer
      第53回日本水環境学会年会
    • Related Report
      2018 Annual Research Report
  • [Presentation] 一槽式微生物燃料電池の性能に及ぼす窒素ドープ炭素質触媒層作製条件の影響2019

    • Author(s)
      成塚宏平,佐々木拓真,窪田恵一,渡邉智秀
    • Organizer
      第53回日本水環境学会年会
    • Related Report
      2018 Annual Research Report
  • [Presentation] 炭素質触媒と金属メッシュを用いるエアカソードを適用した微生物燃料電池の特性2019

    • Author(s)
      後藤博登,窪田恵一,渡邉智秀
    • Organizer
      第53回日本水環境学会年会
    • Related Report
      2018 Annual Research Report
  • [Presentation] 炭素質触媒を用いたエアカソードの作製条件が微生物燃料電池の性能へ及ぼす影響2018

    • Author(s)
      成塚宏平,後藤博登,窪田恵一,渡邉智秀
    • Organizer
      化学工学会室蘭大会2018
    • Related Report
      2018 Annual Research Report
  • [Presentation] Long-term performance of TN removal and power generation in a MFC using an air-cathode covered with nitrifying biofilm2018

    • Author(s)
      T. Watanabe, N. Kojima, S. Xue, W. Takahashi and K. Kubota
    • Organizer
      IWA World Water Congress & Exhibition 2018
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 炭素質触媒と金属メッシュを用いたエアカソードの特性2018

    • Author(s)
      後藤博登,成塚宏平,窪田恵一,渡邉智秀
    • Organizer
      第55回環境工学研究フォーラム
    • Related Report
      2018 Annual Research Report
  • [Book] バイオテクノロジーシリーズ 微生物を用いた発電および水素生産2021

    • Author(s)
      渡邉一哉監修 渡邉智秀,窪田恵一 他 38名 (分担執筆)
    • Total Pages
      245
    • Publisher
      (株)シーエムシー出版
    • ISBN
      9784781316253
    • Related Report
      2020 Annual Research Report
  • [Book] 環境エンジニアリングにおける電気化学的技術2020

    • Author(s)
      公益社団法人 日本水環境学会 電気化学的技術研究委員会(榊原豊,岸本直之,渡邉智秀 他10名)
    • Total Pages
      174
    • Publisher
      デザインエッグ社
    • ISBN
      9784815017361
    • Related Report
      2019 Annual Research Report
  • [Remarks] 渡邉・窪田研究室ホームページ

    • URL

      https://environ.ees.st.gunma-u.ac.jp/index.html

    • Related Report
      2020 Annual Research Report 2019 Annual Research Report 2018 Annual Research Report

URL: 

Published: 2018-04-23   Modified: 2023-01-30  

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