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Exploring surface functional chemistry of inorganic composite nanostructures

Research Project

Project/Area Number 18H01709
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Review Section Basic Section 26020:Inorganic materials and properties-related
Research InstitutionHiroshima University

Principal Investigator

INUMARU Kei  広島大学, 先進理工系科学研究科(工), 教授 (80270891)

Co-Investigator(Kenkyū-buntansha) 片桐 清文  広島大学, 先進理工系科学研究科(工), 教授 (30432248)
樽谷 直紀  広島大学, 先進理工系科学研究科(工), 助教 (60806199)
田中 将嗣  九州工業大学, 大学院工学研究院, 准教授 (90597650)
Project Period (FY) 2018-04-01 – 2022-03-31
Project Status Completed (Fiscal Year 2022)
Budget Amount *help
¥17,290,000 (Direct Cost: ¥13,300,000、Indirect Cost: ¥3,990,000)
Fiscal Year 2021: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000)
Fiscal Year 2020: ¥4,420,000 (Direct Cost: ¥3,400,000、Indirect Cost: ¥1,020,000)
Fiscal Year 2019: ¥4,420,000 (Direct Cost: ¥3,400,000、Indirect Cost: ¥1,020,000)
Fiscal Year 2018: ¥6,370,000 (Direct Cost: ¥4,900,000、Indirect Cost: ¥1,470,000)
Keywords多孔体 / CO2吸着剤 / 人工光合成 / 層状複水酸化物 / LDH / 光触媒 / 水分解 / 助触媒 / 二酸化炭素吸着剤 / 金属間化合物 / 界面 / エピタキシー / 磁性 / 二酸化炭素 / CCS
Outline of Final Research Achievements

In this research, specific interfaces are created at the nano level in various inorganic composite structures. Components of the composite structure communicate with each other through the interfaces by transferring and/or exchanging chemical species, mechanical forces, electrons or holes, and so on. We explored the controlling factors for the functions of composite photocatalytic systems that decompose organic molecules in water, epitaxial thin films of an antiferromagnetic material, composite photocatalytic systems that exchange electrons and holes at the interface, and layered materials in which molecules (CO2) are exchanged between interlayer spaces and the outside of the particles. In these systems, the roles of both "things" exchanged through the interfaces and interfaces themselves have been highlighted as controlling factors for functions and phenomena of the composite structures.

Academic Significance and Societal Importance of the Research Achievements

界面現象は複雑であることが多いが,本研究では,複合構造の構成要素をそれぞれ結晶性物質や制御されたナノ構造をもつ物質・材料などとすることによって,現象や機能の複雑性を構成要素間の注目する界面のみに帰することができるように選択することを目指した.その結果,複雑な界面現象の支配因子をある程度有効に浮き彫りにすることができた.このことから,このようなアプローチが複合構造の界面機能化学に一定の学理を見出す軸となり得る可能性を,本研究は示すことができたと考える.

Report

(5 results)
  • 2022 Final Research Report ( PDF )
  • 2021 Annual Research Report
  • 2020 Annual Research Report
  • 2019 Annual Research Report
  • 2018 Annual Research Report
  • Research Products

    (30 results)

All 2023 2022 2021 2020 2019 2018

All Journal Article (1 results) (of which Peer Reviewed: 1 results) Presentation (27 results) (of which Int'l Joint Research: 6 results,  Invited: 6 results) Book (1 results) Patent(Industrial Property Rights) (1 results)

  • [Journal Article] メソポーラスシリカで包含した光触媒粒子複合体の機能2018

    • Author(s)
      犬丸啓・片桐清文
    • Journal Title

      J. Soc. Inorg. Mater., Japan

      Volume: 25 Pages: 156-161

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Presentation] Co3O4助触媒粒子とKCaSrTa5O15半導体光触媒の粒子混合系による水分解反応2023

    • Author(s)
      松原 正真、川口 堅大、安西 淳、樽谷 直紀、片桐 清文、犬丸 啓
    • Organizer
      日本セラミックス協会2023年年会
    • Related Report
      2021 Annual Research Report
  • [Presentation] 水分解光触媒における Ca -Mn 系酸化物およびホウアルミニムの助触媒作用2022

    • Author(s)
      福﨑亮太、樽谷直紀、片桐清文、犬丸啓
    • Organizer
      第60回セラミックス基礎科学討論会
    • Related Report
      2021 Annual Research Report
  • [Presentation] Mg/Al比の異なるMg-Al LDHの熱分解過程の解析2022

    • Author(s)
      松田海斗、樽谷直紀、片桐清文、犬丸啓
    • Organizer
      日本セラミックスス協会2022年年会
    • Related Report
      2021 Annual Research Report
  • [Presentation] 無機ナノ複合体の構造と機能:スポンジ結晶,光触媒,層状複水酸化物2022

    • Author(s)
      犬丸啓
    • Organizer
      触媒学会第60回触媒研究懇談会
    • Related Report
      2021 Annual Research Report
    • Invited
  • [Presentation] LDHの構成金属種が熱分解挙動とCO2吸着 /脱離特性に与える効果2022

    • Author(s)
      松田海斗、樽谷直紀、片桐清文、犬丸啓
    • Organizer
      日本セラミックス協会第35回秋季シンポジウム
    • Related Report
      2021 Annual Research Report
  • [Presentation] LDH ナノ粒子CO2吸着剤の希薄なCO2への応答性とそのサイクル特性2021

    • Author(s)
      松田海斗、樽谷直紀、片桐清文、犬丸啓
    • Organizer
      日本セラミックス協会第34回秋季シンポジウム
    • Related Report
      2021 Annual Research Report
  • [Presentation] DAC用吸着剤としてのLDHナノ粒子の合成とCO2吸着特性2021

    • Author(s)
      松田海斗,樽谷直紀,片桐清文,犬丸啓
    • Organizer
      日本セラミックス協会2021年年会
    • Related Report
      2020 Annual Research Report
  • [Presentation] Mg-Al 層状複水酸化物ナノ粒子のCO2放出挙動に与える組成と化学修飾の効果2020

    • Author(s)
      福﨑亮太,川下実央,樽谷直紀,片桐清文,犬丸啓
    • Organizer
      第126回触媒討論会
    • Related Report
      2020 Annual Research Report
  • [Presentation] 層状複水酸化物ナノ粒子CO2吸着剤の繰り返し性能と動作機構2020

    • Author(s)
      川下実央,片桐清文,犬丸啓
    • Organizer
      第58回セラミックス基礎科学討論会
    • Related Report
      2019 Annual Research Report
  • [Presentation] (NH4)4SiW12O40 スポンジ結晶の密度測定とAr吸着による細孔構造解析2020

    • Author(s)
      松田海斗,小林優斗,道下晃,犬丸啓
    • Organizer
      日本セラミックス協会2020年年会
    • Related Report
      2019 Annual Research Report
  • [Presentation] 無機複合ナノ構造の機能開発 - 触媒・光触媒・吸着剤 -2019

    • Author(s)
      犬丸 啓
    • Organizer
      2019年度触媒学会西日本支部 第10回触媒化学研究発表会
    • Related Report
      2019 Annual Research Report
    • Invited
  • [Presentation] 層状複水酸化物ナノ粒子CO2 吸着剤の繰り返し特性と構造変化の解析2019

    • Author(s)
      川下 実央,奥田 彩花,片桐 清文,犬丸 啓
    • Organizer
      第124回触媒討論会
    • Related Report
      2019 Annual Research Report
  • [Presentation] Controlling Selectivity and Activity of Nanostructured Photocatalysts2019

    • Author(s)
      Kei Inumaru
    • Organizer
      The 13th Pacific Rim Conference of Ceramic Societies
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] CO2 release behaviors of layered double hydroxide nanoparticles in repeated adsorption-desorption cycles2019

    • Author(s)
      Mio Kawashimo, Ayaka Okuda, Kiyofumi Katagiri, Kei Inumaru
    • Organizer
      The 13th Pacific Rim Conference of Ceramic Societies
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Unique Properties of Nanospaces of Mesoporous Silica - TiO2 Particles Composite Photocatalysts for Decomposition of Organic Molecules in Water2019

    • Author(s)
      Saki Sadamori, Yusuke Kunisaki, Kiyofumi Katagiri, Kei Inumaru
    • Organizer
      Japan-Korea International Seminar on Ceramics(JK Ceramics 36)
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 無機酸化物複合ナノ構造の構築と機能 ― スポンジ 結晶の発見からナノ光触媒まで ―2019

    • Author(s)
      犬丸 啓
    • Organizer
      第57回粉体に関する討論会
    • Related Report
      2019 Annual Research Report
    • Invited
  • [Presentation] Analysis of antiferromagnetic CrN finite cluster models by first principle calculation2019

    • Author(s)
      Hideaki Okamoto, Kei Inumaru
    • Organizer
      Japan-Korea International Seminar on Ceramics(JK Ceramics 36)
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Nanostructured Metal Oxide Materials: From Discovery of Sponge Crystals to Nano-photocatalysts2019

    • Author(s)
      Kei Inumaru
    • Organizer
      第29回日本MRS年次大会
    • Related Report
      2019 Annual Research Report
    • Invited
  • [Presentation] 分子プローブ法による(NH4)xH4-xSiW12O40スポンジ結晶のミクロ細孔径の測定2019

    • Author(s)
      小林 優斗,盛田 祐輔,犬丸 啓
    • Organizer
      第33回日本吸着学会研究発表会
    • Related Report
      2019 Annual Research Report
  • [Presentation] 層状複水酸化物のCO2吸収・放出特性に与える金属元素とナノ粒子化の効果2019

    • Author(s)
      奥田彩花・片桐清文・犬丸啓
    • Organizer
      第57回セラミックス基礎科学討論会
    • Related Report
      2018 Annual Research Report
  • [Presentation] メソポーラスシリカ包含TiO2粒子の 光触媒活性に与える有機物吸着能の効果2019

    • Author(s)
      定森早紀・國崎佑介・片桐清文・犬丸啓
    • Organizer
      日本セラミックス協会2019年年会
    • Related Report
      2018 Annual Research Report
  • [Presentation] 層状複水酸化物ナノ粒子のCO2 放出挙動とその繰り返し特性2019

    • Author(s)
      川下 実央・奥田 彩花・片桐 清文・犬丸 啓
    • Organizer
      日本セラミックス協会2019年年会
    • Related Report
      2018 Annual Research Report
  • [Presentation] Photocatlytic CO2 Reduction by Mesoporous Silica-Coated Photocatalyst Particles2018

    • Author(s)
      Kei Inumaru, Koki Ikeda
    • Organizer
      International Symposium on Zeolites and Microporous Crystals (ZMPC) 2018
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] MBE によるCrN 薄膜の合成と反強磁性転移に与えるエピタキシーの効果2018

    • Author(s)
      今田有香・日野伶哉・池田圭・和泉怜志・犬丸啓
    • Organizer
      日本セラミックス協会 第31回秋季シンポジウム
    • Related Report
      2018 Annual Research Report
  • [Presentation] 層状複水酸化物ナノ粒子の CO2吸収・放出挙動に与える金属元素と粒径の効果2018

    • Author(s)
      奥田彩花・飯尾奈々 ・片桐清文 ・犬丸啓
    • Organizer
      第122回触媒討論会
    • Related Report
      2018 Annual Research Report
  • [Presentation] 酸化チタン光触媒の有機物分解選択性に及ぼすシリカ被覆の効果と有機修飾による機能化2018

    • Author(s)
      定森早紀・國崎佑介・片桐清文・犬丸啓
    • Organizer
      第122回触媒討論会
    • Related Report
      2018 Annual Research Report
  • [Presentation] Chromium Nitride Epitaxial Thin Films: Growth and Control of Electronic Properties and Magnetic Transition2018

    • Author(s)
      Kei INUMARU
    • Organizer
      Korea-Japan International Seminar on Ceramics(KJ Ceramics 29)
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research / Invited
  • [Book] マテリアルス・インフォマティクス開発事例最前線2021

    • Author(s)
      犬丸啓(分担執筆)
    • Total Pages
      322
    • Publisher
      出版社NTS
    • Related Report
      2020 Annual Research Report
  • [Patent(Industrial Property Rights)] 二酸化炭素の吸着方法、および二酸化炭素の脱離方法2019

    • Inventor(s)
      犬丸啓・片桐清文・奥田彩花・川下実央
    • Industrial Property Rights Holder
      犬丸啓・片桐清文・奥田彩花・川下実央
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      2019-036956
    • Filing Date
      2019
    • Related Report
      2018 Annual Research Report

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Published: 2018-04-23   Modified: 2024-01-30  

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