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Creation of inorganic nanofiber electrolyte gels and exploration of their interfacial functions

Research Project

Project/Area Number 18H01730
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Review Section Basic Section 26040:Structural materials and functional materials-related
Research InstitutionTokyo Institute of Technology

Principal Investigator

Matsumoto Hidetoshi  東京工業大学, 物質理工学院, 教授 (40345393)

Project Period (FY) 2018-04-01 – 2022-03-31
Project Status Completed (Fiscal Year 2021)
Budget Amount *help
¥16,770,000 (Direct Cost: ¥12,900,000、Indirect Cost: ¥3,870,000)
Fiscal Year 2021: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2020: ¥4,680,000 (Direct Cost: ¥3,600,000、Indirect Cost: ¥1,080,000)
Fiscal Year 2019: ¥7,410,000 (Direct Cost: ¥5,700,000、Indirect Cost: ¥1,710,000)
Fiscal Year 2018: ¥3,380,000 (Direct Cost: ¥2,600,000、Indirect Cost: ¥780,000)
Keywordsナノファイバー / 電解質 / ゲル / 表面修飾 / イオン液体 / ナノファイバーシート / 電解質膜 / 高分子化イオン液体 / 無機ナノファイバー
Outline of Final Research Achievements

In this study, stable gel membranes were prepared from aqueous and organic electrolytes by using silica nanofibers with surface silanol groups and a higher aspect ratio. The nanofiber composite gels prepared from various electrolyte solutions exhibit the maximum ionic conductivities of the order of 0.01 S/cm at room temperature and can be used as stable electrolyte membranes in various electrochemical devices such as electric double layer capacitors, fuel cells, metal anode secondary batteries, and sensitized thermal cells. Furthermore, the formation of interactions between the nanofiber surface and an electrolyte component can improve the device properties

Academic Significance and Societal Importance of the Research Achievements

本研究で創製した新規な高機能電解質ゲルは二次電池やキャパシタの安全性や安定性の向上を可能にする。電解質ゲルは液漏れの心配がないため、デバイスのフレキシブル化・薄膜化にも有用であり、特にIoT分野において急速に普及が進む小型電子デバイス電源への展開が期待される。二次電池・キャパシタ以外にも、高機能電解質ゲルは、燃料電池、色素増感太陽電池、増感型熱利用電池、電気化学トランジスタなど各種電気化学デバイスへの応用が可能であり、社会的な波及効果は大きい。

Report

(5 results)
  • 2021 Annual Research Report   Final Research Report ( PDF )
  • 2020 Annual Research Report
  • 2019 Annual Research Report
  • 2018 Annual Research Report
  • Research Products

    (15 results)

All 2022 2021 2020 2019 2018

All Journal Article (6 results) (of which Peer Reviewed: 5 results,  Open Access: 3 results) Presentation (8 results) (of which Int'l Joint Research: 3 results,  Invited: 2 results) Book (1 results)

  • [Journal Article] Functional Design of Nanofiber Materials and Their Applications in Environment and Energy Fields2022

    • Author(s)
      松本英俊
    • Journal Title

      NIPPON GOMU KYOKAISHI

      Volume: 95 Issue: 4 Pages: 124-131

    • DOI

      10.2324/gomu.95.124

    • ISSN
      0029-022X, 1884-0442
    • Related Report
      2021 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Preparation of Perfluorosulfonated Ionomer Nanofibers by Solution Blow Spinning2021

    • Author(s)
      Masahiro Shinkawa, Kazunori Motai, Keita Eguchi, Wataru Takarada, Minoru Ashizawa, Hiroyasu Masunaga, Noboru Ohta, Yuhei Hayamizu, Hidetoshi Matsumoto
    • Journal Title

      Membranes

      Volume: 11 Issue: 6 Pages: 389-389

    • DOI

      10.3390/membranes11060389

    • Related Report
      2021 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] De Novo Ion-Exchange Membranes Based on Nanofibers2021

    • Author(s)
      Shaoling Zhang, Akihiko Tanioka, Hidetoshi Matsumoto
    • Journal Title

      Membranes

      Volume: 11 Issue: 9 Pages: 652-652

    • DOI

      10.3390/membranes11090652

    • Related Report
      2021 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Emerging Functions of Porous Separation Membranes Based on Nanofibers and Nanomaterials2021

    • Author(s)
      松本 英俊
    • Journal Title

      MEMBRANE

      Volume: 46 Issue: 4 Pages: 215-219

    • DOI

      10.5360/membrane.46.215

    • NAID

      130008077395

    • ISSN
      0385-1036, 1884-6440
    • Related Report
      2021 Annual Research Report
  • [Journal Article] Direct Laser Writing of Graphene Nanoribbon Thin Films for Supercapacitor Electrodes2020

    • Author(s)
      SHINKAWA Masahiro、SAITO Yoshitaka、ASHIZAWA Minoru、MATSUMOTO Hidetoshi
    • Journal Title

      Electrochemistry

      Volume: 88 Issue: 5 Pages: 413-417

    • DOI

      10.5796/electrochemistry.20-64073

    • NAID

      130007896972

    • ISSN
      1344-3542, 2186-2451
    • Year and Date
      2020-09-05
    • Related Report
      2020 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Mesoporous Hydrated Graphene Nanoribbon Electrodes for Efficient Supercapacitors: Effect of Nanoribbon Dispersion on Pore Structure2020

    • Author(s)
      Saito Yoshitaka、Ashizawa Minoru、Matsumoto Hidetoshi
    • Journal Title

      Bulletin of the Chemical Society of Japan

      Volume: 93 Issue: 11 Pages: 1268-1274

    • DOI

      10.1246/bcsj.20200161

    • NAID

      130007939800

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed
  • [Presentation] 溶液ブロー紡糸法を用いたパフルオスホン酸アイノマーのナノファイバー化2021

    • Author(s)
      新川真弘, 芦沢実, 茂田井和紀, 早水裕平, 松本英俊
    • Organizer
      第70回高分子学会年次大会
    • Related Report
      2021 Annual Research Report
  • [Presentation] ナノファイバー・ナノ材料を利用した多孔質分離膜の機能創出2021

    • Author(s)
      松本英俊
    • Organizer
      日本膜学会第43年会
    • Related Report
      2021 Annual Research Report
    • Invited
  • [Presentation] 機能性を付与した無機ナノファイバーと高分子ゲルを複合化した電解質の創製2021

    • Author(s)
      奥尾昂丈, 西村直美, 芦沢実, 嵯峨根史洋, 富永洋一, 松本英俊
    • Organizer
      第62回電池討論会
    • Related Report
      2021 Annual Research Report
  • [Presentation] 電気化学キャパシタへの応用を目指した複合カーボンナノファイバーシートの作製と評価2021

    • Author(s)
      芦葉舞, 芦沢実, 松本英俊
    • Organizer
      電気化学会第88回大会
    • Related Report
      2020 Annual Research Report
  • [Presentation] エネルギー・環境分野への展開を目指したナノファイバー材料の機能開拓2021

    • Author(s)
      松本英俊
    • Organizer
      高分子学会・高分子同友会勉強会
    • Related Report
      2020 Annual Research Report
    • Invited
  • [Presentation] Ionic liquid gel electrolytes containing inorganic nanofibers for quasisolid energy devices2019

    • Author(s)
      H. Matsumoto
    • Organizer
      2019 Japan-China Advanced Materials and Nanotechnology Symposium
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Gelation of ionic liquids by electrospun inorganic nanofibers for energy devices2018

    • Author(s)
      H. Matsumoto
    • Organizer
      International Nanofiber Symposium 2018
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Ionic liquid-based electrolytes containing inorganic nanofibers for quasisolid energy devices2018

    • Author(s)
      H. Matsumoto
    • Organizer
      The Fiber Society’s Spring 2018 Conference
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Book] Electrospun and Nanofibrous Membranes 1st Edition: Principles and Applications (Ali Kargari, Takeshi Matsuura, Mohammad Shirazi Eds.)2022

    • Author(s)
      Shaoling Zhang, Hidetoshi Matsumoto (Authored chapters in the book)
    • Total Pages
      662
    • Publisher
      Elsevier
    • ISBN
      9780128230329
    • Related Report
      2021 Annual Research Report

URL: 

Published: 2018-04-23   Modified: 2023-01-30  

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