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Development of a new type of high strength Ni based heat resistant alloys by controlling the precipitation of hexagonal (orthorhombic) intermetallic compounds

Research Project

Project/Area Number 18H01731
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Review Section Basic Section 26040:Structural materials and functional materials-related
Research InstitutionTokyo Institute of Technology

Principal Investigator

Kobayashi Satoru  東京工業大学, 物質理工学院, 准教授 (60455847)

Project Period (FY) 2018-04-01 – 2021-03-31
Project Status Completed (Fiscal Year 2020)
Budget Amount *help
¥17,160,000 (Direct Cost: ¥13,200,000、Indirect Cost: ¥3,960,000)
Fiscal Year 2020: ¥3,640,000 (Direct Cost: ¥2,800,000、Indirect Cost: ¥840,000)
Fiscal Year 2019: ¥4,030,000 (Direct Cost: ¥3,100,000、Indirect Cost: ¥930,000)
Fiscal Year 2018: ¥9,490,000 (Direct Cost: ¥7,300,000、Indirect Cost: ¥2,190,000)
Keywords組織制御 / 耐熱合金 / 格子ミスフィット / 耐熱金属材料 / Ni基耐熱合金
Outline of Final Research Achievements

Relationship between the precipitation of delta-Ni3Nb (D0a) phase and eta-Ni3Ti (D024) phase and the lattice misfit between the delta(eta) phases and the Ni (fcc) matrix phase were investigated in model Ni-Cr-Mo-Nb and Ni-Cr-Mo-Ti based alloys to aim at designing polycrystalline Ni based alloys with better temperature capability. Discontinuous precipitation (DC) tends to occur at lower temperatures while continuous precipitation (CP) dominates at higher temperatures in the two alloy systems. The addition of Mo promotes CP with respect to DC while that of Ti promotes DC rather than CP in delta phase precipitation alloys. A replacement of Ti with Mo promotes CP with respect to DP in eta phase precipitation alloys at 800 degree C. The observed effects are discussed in terms of chemical driving force, interfacial energy between the matrix phase and the delta(eta) phases, and coherency strain caused by the formation of the metastable phases prior to the formation of delta(eta) phases.

Academic Significance and Societal Importance of the Research Achievements

本課題により得られる成果は、母相/析出相間の格子ミスフィットと析出モード,析出形態,及び析出物の安定性の関係に関する金属物理学の学問領域の理解に貢献するとともに耐熱材料全般の強化基盤技術の深化を促し,従来使用されているNi基鍛造合金の強度設計手法・寿命評価法の向上を通じてジェットエンジンや発電プラント用ガスタービン等の熱機関の高効率化・長寿命化・省資源化に貢献する。

Report

(4 results)
  • 2020 Annual Research Report   Final Research Report ( PDF )
  • 2019 Annual Research Report
  • 2018 Annual Research Report
  • Research Products

    (11 results)

All 2021 2020 2019

All Journal Article (5 results) (of which Peer Reviewed: 1 results) Presentation (5 results) (of which Int'l Joint Research: 2 results) Patent(Industrial Property Rights) (1 results)

  • [Journal Article] Ni基合金におけるNi3M(M: Ti, Nb)相の析出形態に及ぼす合金元素の効果2021

    • Author(s)
      岡本真幸、小林覚、竹山雅夫
    • Journal Title

      学振123委員会研究報告

      Volume: 62 Pages: 61-71

    • Related Report
      2020 Annual Research Report
  • [Journal Article] Alloying effects on the competition between discontinuous precipitation versus continuous precipitation of delta/eta phases in model Ni-based superalloys2020

    • Author(s)
      Satoru Kobayashi, Tomoki Otsuka, Rikuryo Watanabe, Kyosuke Sgitani, Masaki Okamoto, Kako Tokutomi
    • Journal Title

      Superalloys 2020

      Volume: XX

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Ni 基合金におけるη-Ni3Ti 相の析出挙動に及ぼす合金元素の効果2020

    • Author(s)
      岡本真幸,鷺谷亨輔,小林覚,竹山雅夫
    • Journal Title

      学振123委員会研究報告

      Volume: 61

    • Related Report
      2019 Annual Research Report
  • [Journal Article] γ’’ 強化型Ni 基合金における組織形成に及ぼす合金元素の効果2020

    • Author(s)
      鷺谷亨輔,小林覚,竹山雅夫,佐藤順,伊達正芳
    • Journal Title

      学振123委員会研究報告

      Volume: 61

    • Related Report
      2019 Annual Research Report
  • [Journal Article] 複合拡散対法を用いたNi-Cr-Ti-Mo4元合金におけるγ-Ni/η-Ni3Ti相間の相平衡の決定と格子ミスフィットの評価2019

    • Author(s)
      渡邊六龍、岡本真幸、鷺谷享輔、小林覚
    • Journal Title

      耐熱金属材料第123委員会研究報告

      Volume: 60

    • Related Report
      2018 Annual Research Report
  • [Presentation] Ni基合金におけるNi3M(M: Ti, Nb)相の析出形態に及ぼす合金元素の効果2021

    • Author(s)
      岡本真幸,小林覚,竹山雅夫
    • Organizer
      学振123委員会研究報告会
    • Related Report
      2020 Annual Research Report
  • [Presentation] Alloying effects on the competition between discontinuous precipitation versus continuous precipitation of delta/eta phases in model Ni-based superalloys2021

    • Author(s)
      小林覚
    • Organizer
      Superalloys2020
    • Related Report
      2020 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Ni 基合金におけるη-Ni3Ti 相の析出挙動に及ぼす合金元素の効果2020

    • Author(s)
      岡本真幸,鷺谷亨輔,小林覚,竹山雅夫
    • Organizer
      学振123委員会研究報告
    • Related Report
      2019 Annual Research Report
  • [Presentation] γ’’ 強化型Ni 基合金における組織形成に及ぼす合金元素の効果2020

    • Author(s)
      鷺谷亨輔,小林覚,竹山雅夫,佐藤順,伊達正芳
    • Organizer
      学振123委員会研究報告
    • Related Report
      2019 Annual Research Report
  • [Presentation] Effects of Mo additino on γ-Ni/η-Ni3Ti lattice mismatch in Ni-base alloys2019

    • Author(s)
      Satoru Kobayashi
    • Organizer
      TMS annual meeting
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Patent(Industrial Property Rights)] Ni基耐熱合金2020

    • Inventor(s)
      小林覚
    • Industrial Property Rights Holder
      小林覚
    • Industrial Property Rights Type
      特許
    • Filing Date
      2020
    • Acquisition Date
      2020
    • Related Report
      2019 Annual Research Report

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Published: 2018-04-23   Modified: 2022-01-27  

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