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Strain-managements of oxide catalysts for large scale generation of carbon-free hydrogen

Research Project

Project/Area Number 18H01741
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Review Section Basic Section 26050:Material processing and microstructure control-related
Research InstitutionTohoku University

Principal Investigator

Todoroki Naoto  東北大学, 環境科学研究科, 准教授 (10734345)

Project Period (FY) 2018-04-01 – 2022-03-31
Project Status Completed (Fiscal Year 2021)
Budget Amount *help
¥17,680,000 (Direct Cost: ¥13,600,000、Indirect Cost: ¥4,080,000)
Fiscal Year 2020: ¥5,590,000 (Direct Cost: ¥4,300,000、Indirect Cost: ¥1,290,000)
Fiscal Year 2019: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2018: ¥9,100,000 (Direct Cost: ¥7,000,000、Indirect Cost: ¥2,100,000)
Keywords電極触媒 / 水電解 / 酸素発生反応 / 金属酸化物 / 真空蒸着 / 単結晶 / イリジウム酸化物 / 界面 / 格子歪み / ステンレス鋼 / ナノ構造 / 異相界面 / CO2フリー水素 / 酸化物触媒 / 歪みマネジメント / エピタキシャル成長 / ヘテロ構造 / 酸化物 / 歪み制御
Outline of Final Research Achievements

In this study, we investigated the effect of strain on the crystal lattice of oxide catalysts on the catalytic activity of cobalt oxides, which are known as oxygen evolution catalysts for alkaline water electrolysis. Cobalt oxide nano-thin films were formed on Pt and Ir single crystal substrates by arc plasma deposition, and their microstructures and electrochemical oxygen evolution electrocatalytic activity were evaluated. The electrocatalytic properties and structural stability of the nano-thin films were highly dependent on the deposited metal substrate elements and were particularly high on Ir substrates. These results suggest that lattice strain due to lattice mismatch between substrate and catalyst layer affects the catalytic properties.

Academic Significance and Societal Importance of the Research Achievements

本研究の遂行により、酸化物触媒と金属基板の相互作用により酸素発生触媒活性を向上するための重要な基礎的知見が得られた。酸素発生反応用触媒は、水素社会を実現するためのキーテクノロジーの一つである水電解水素製造装置のボトルネック技術であり、本研究で得られた知見を実用材料に生かすことにより、水電解法による水素製造効率の向上、水素コストの低減が期待される。

Report

(4 results)
  • 2021 Final Research Report ( PDF )
  • 2020 Annual Research Report
  • 2019 Annual Research Report
  • 2018 Annual Research Report
  • Research Products

    (18 results)

All 2021 2020 2019 2018

All Journal Article (8 results) (of which Peer Reviewed: 4 results,  Open Access: 3 results) Presentation (10 results) (of which Int'l Joint Research: 2 results)

  • [Journal Article] Electrochemical Stability of Stainless-Steel-Made Anode for Alkaline Water Electrolysis: Surface Catalyst Nanostructures and Oxygen Evolution Overpotentials Under Applying Potential Cycle Loading2021

    • Author(s)
      N. Todoroki, T. Wadayama
    • Journal Title

      Electrochemistry Communications

      Volume: 122 Pages: 106902-106902

    • DOI

      10.1016/j.elecom.2020.106902

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Online electrochemical mass spectrometry combined with the rotating disk electrode method for direct observations of potential-dependent molecular behaviors in the electrode surface vicinity2020

    • Author(s)
      N. Todoroki, H. Tsurumaki, H. Tei, T. Mochizuki, T. Wadayama
    • Journal Title

      Journal of the Electrochemical Society

      Volume: 167 Issue: 10 Pages: 106503-106503

    • DOI

      10.1149/1945-7111/ab9960

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] ドライプロセス法による表面原子構造制御に立脚した燃料電池触媒の開発2020

    • Author(s)
      轟直人
    • Journal Title

      燃料電池

      Volume: 20 Pages: 50-56

    • Related Report
      2020 Annual Research Report
  • [Journal Article] よく規定された合金系電極触媒表面モデルのドライプロセス合成と特性評価2019

    • Author(s)
      轟直人, 和田山智正
    • Journal Title

      Denki Kagaku

      Volume: 87 Issue: Autumn Pages: 250-257

    • DOI

      10.5796/denkikagaku.19-TE0006

    • NAID

      130007703278

    • ISSN
      2433-3255, 2433-3263
    • Year and Date
      2019-09-05
    • Related Report
      2019 Annual Research Report
  • [Journal Article] Development of Energy Conversion Catalytic Materials Based on Surface Scientific Approach2019

    • Author(s)
      轟直人
    • Journal Title

      Materia Japan

      Volume: 58 Issue: 6 Pages: 328-332

    • DOI

      10.2320/materia.58.328

    • NAID

      130007657063

    • ISSN
      1340-2625, 1884-5843
    • Year and Date
      2019-06-01
    • Related Report
      2019 Annual Research Report
  • [Journal Article] Hetero-Layered Ni-Fe Hydroxide/Oxide Nanostructures Generated on Stainless-Steel Substrate for Efficient Alkaline Water Splitting2019

    • Author(s)
      N. Todoroki, T. Wadayama
    • Journal Title

      ACS Applied Materials and Interfaces

      Volume: 11 Issue: 47 Pages: 44161-44169

    • DOI

      10.1021/acsami.9b14213

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Oxygen Reduction Reaction Activity for Cobalt-Deposited Pt(111) Model Catalyst Surfaces in Alkaline Solution2018

    • Author(s)
      Naoto Todoroki and Toshimasa Wadayama
    • Journal Title

      Electrochemistry

      Volume: 86 Issue: 5 Pages: 243-245

    • DOI

      10.5796/electrochemistry.18-00024

    • NAID

      130007481431

    • ISSN
      1344-3542, 2186-2451
    • Year and Date
      2018-09-05
    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Oxygen Reduction and Oxygen Evolution Reaction Activity on Co/Pt(111) Surfaces in Alkaline Solution2018

    • Author(s)
      Naoto Todoroki and Toshimasa Wadayama
    • Journal Title

      ECS Transactions

      Volume: 86 Issue: 13 Pages: 569-574

    • DOI

      10.1149/08613.0569ecst

    • Related Report
      2018 Annual Research Report
  • [Presentation] TiO2(110)基板上にアークプラズマ堆積したIrO2の酸素発生特性2021

    • Author(s)
      林 謙汰, 横井 瑞穂, 轟 直人, 和田山 智正
    • Organizer
      日本金属学会2021年春期講演大会
    • Related Report
      2020 Annual Research Report
  • [Presentation] 気相法により作製したIrO2/TiO2(110)表面系の酸素発生反応特性2021

    • Author(s)
      轟 直人, 林 謙汰, 横井 瑞穂, 和田山 智正
    • Organizer
      電気化学会第88回大会
    • Related Report
      2020 Annual Research Report
  • [Presentation] Ni-Fe Hydroxide/Oxide Nanostructures generated on Stainless Steels for Efficient Alkaline Water Electrolysis2020

    • Author(s)
      Naoto Todoroki, Toshimasa Wadayama
    • Organizer
      71st ISE Annual Meeting ‘Belgrade Online’
    • Related Report
      2020 Annual Research Report
    • Int'l Joint Research
  • [Presentation] アルカリ水電解酸素発生反応電極としてのステンレス鋼の比較検討2020

    • Author(s)
      四之宮 新, 轟 直人,和田山 智正
    • Organizer
      日本金属学会2020年春期講演大会
    • Related Report
      2019 Annual Research Report
  • [Presentation] アルカリ水電解模擬環境におけるステンレス鋼酸素発生電極の電気化学的安定性2020

    • Author(s)
      轟 直人, 四之宮 新, 和田山 智正
    • Organizer
      電気化学会第87回大会
    • Related Report
      2019 Annual Research Report
  • [Presentation] ステンレス鋼のアルカリ水電解電極への応用に向けた基礎検討2019

    • Author(s)
      轟 直人, 和田山 智正
    • Organizer
      日本鉄鋼協会第178回秋季講演大会
    • Related Report
      2019 Annual Research Report
  • [Presentation] NiFe水酸化物皮膜を形成したステンレス鋼酸素発生電極の電気化学的耐久性2019

    • Author(s)
      轟 直人, 和田山 智正
    • Organizer
      第43回電解技術討論会-ソーダ工業技術討論会-
    • Related Report
      2019 Annual Research Report
  • [Presentation] アルカリ水電解酸素発生電極としてのステンレス鋼の検討2019

    • Author(s)
      轟直人, 和田山智正
    • Organizer
      電気化学会第86回大会
    • Related Report
      2018 Annual Research Report
  • [Presentation] Oxygen Reduction and Oxygen Evolution Reaction Activity on Co/Pt(111) Surfaces in Alkaline Solution2018

    • Author(s)
      N. Todoroki, T. Wadayama
    • Organizer
      AiMES2018
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] ステンレス表面酸化皮膜のナノ構造と酸素発生特性2018

    • Author(s)
      轟直人,和田山智正
    • Organizer
      第42回電解技術討論会-ソーダ工業技術討論会-
    • Related Report
      2018 Annual Research Report

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Published: 2018-04-23   Modified: 2023-01-30  

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