• Search Research Projects
  • Search Researchers
  • How to Use
  1. Back to previous page

Development of novel alkane dehydrogenation process by redox lattice S species on sulfide catalysts

Research Project

Project/Area Number 18H01775
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Review Section Basic Section 27020:Chemical reaction and process system engineering-related
Research InstitutionShizuoka University

Principal Investigator

Watanabe Ryo  静岡大学, 工学部, 准教授 (80548884)

Co-Investigator(Kenkyū-buntansha) 福原 長寿  静岡大学, 工学部, 教授 (30199260)
Project Period (FY) 2018-04-01 – 2021-03-31
Project Status Completed (Fiscal Year 2020)
Budget Amount *help
¥17,550,000 (Direct Cost: ¥13,500,000、Indirect Cost: ¥4,050,000)
Fiscal Year 2020: ¥2,210,000 (Direct Cost: ¥1,700,000、Indirect Cost: ¥510,000)
Fiscal Year 2019: ¥5,460,000 (Direct Cost: ¥4,200,000、Indirect Cost: ¥1,260,000)
Fiscal Year 2018: ¥9,880,000 (Direct Cost: ¥7,600,000、Indirect Cost: ¥2,280,000)
Keywordsレドックス / アルカン / 脱水素 / 格子硫黄 / 硫化物 / プロパン脱水素 / 鉄硫化物 / 低級アルカン / 硫化水素
Outline of Final Research Achievements

A novel catalytic process for alkane dehydrogenation was investigated in which a high concentration of hydrogen sulfide (H2S) coexisted in the dehydrogenation of alkanes of propane and butane, expecting for the lattice S2- in the sulfide catalyst is continuously regenerated. It was found that Fe-based catalysts are effective in the dehydrogenation process, and that the cofeeding H2S continuously regenerated sulfur defects on the catalysts. The Fe-based catalyst exhibited an excellent stability due to smooth redox cycling.

Academic Significance and Societal Importance of the Research Achievements

アルカン脱水素プロセスは,石油化学製品として利用価値の低いアルカンからオレフィンを高選択的に製造できる。現在,工業的に稼動している脱水素プロセスでは,短時間の反応の後に再生処理を施すサイクリックな再生方式が採用され,連続的にオレフィンを製造できる新規な触媒や代替触媒プロセスが望まれている。本研究にて開発した反応システムは,急速な触媒失活により触媒再生を必要とする従来の脱水素プロセスを刷新する,新しい触媒プロセスの開拓につながる。

Report

(4 results)
  • 2020 Annual Research Report   Final Research Report ( PDF )
  • 2019 Annual Research Report
  • 2018 Annual Research Report
  • Research Products

    (21 results)

All 2021 2020 2019 2018

All Journal Article (3 results) (of which Peer Reviewed: 3 results) Presentation (18 results) (of which Invited: 3 results)

  • [Journal Article] Effect of Support Species on Performance of Transition Metal-based Catalysts for Propane Dehydrogenation with Co-feeding of H<sub>2</sub>S2020

    • Author(s)
      WATANABE Ryo、HIRATA Nozomu、YODA Yuta、FUSHIMI Yuya、FUKUHARA Choji
    • Journal Title

      Journal of the Japan Petroleum Institute

      Volume: 63 Issue: 4 Pages: 228-237

    • DOI

      10.1627/jpi.63.228

    • NAID

      130007868020

    • ISSN
      1346-8804, 1349-273X
    • Year and Date
      2020-07-01
    • Related Report
      2020 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Effect of support species on performance of transition metal-based catalysts for propane dehydrogenation with co-feeding of H2S2020

    • Author(s)
      Watanabe Ryo、Hirata Nozomu、Yoda Yuta、Fushimi Yuya、Fukuhara Choji
    • Journal Title

      Journal of the Japan Petroleum Institute

      Volume: 63(4)

    • NAID

      130007868020

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Formation of active species for propane dehydrogenation with hydrogen sulfide co-feeding over transition metal catalyst2019

    • Author(s)
      Watanabe Ryo、Hirata Nozomu、Miura Kazuya、Yoda Yuta、Fushimi Yuya、Fukuhara Choji
    • Journal Title

      Applied Catalysis A: General

      Volume: 587 Pages: 117238-117238

    • DOI

      10.1016/j.apcata.2019.117238

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Presentation] 鉄硫化物触媒によるH2S共存下のプロパン脱水素の反応機構解析2021

    • Author(s)
      渡部 綾、依田裕太、平田 望、河野芳海、福原長寿
    • Organizer
      化学工学会86年会
    • Related Report
      2020 Annual Research Report
  • [Presentation] H2S共存のプロパン脱水素でFe系触媒が示す高い耐久性と格子S2-の関係2021

    • Author(s)
      依田裕太、渡部 綾、平田 望、河野芳海、福原長寿
    • Organizer
      触媒学会第127回触媒討論会
    • Related Report
      2020 Annual Research Report
  • [Presentation] 軽質炭化水素の脱水素における鉄系触媒の反応特性評価2020

    • Author(s)
      渡部 綾、横山遵匡、依田裕太、宮城裕一、柏木翔太、大塩敦保、福原長寿
    • Organizer
      第50回石油・石油化学討論会
    • Related Report
      2020 Annual Research Report
  • [Presentation] レドックス系硫化物触媒の格子硫黄を活用するアルカン脱水素:気相H2Sの促進効果2020

    • Author(s)
      渡部 綾
    • Organizer
      第14回触媒道場
    • Related Report
      2020 Annual Research Report
    • Invited
  • [Presentation] Fe系触媒の格子硫黄を活用した低級アルカン(C2-C4)の脱水素:気相H2Sの促進効果2020

    • Author(s)
      渡部 綾、依田裕太、平田 望、河野芳海、福原長寿
    • Organizer
      化学工学会第51会秋季大会
    • Related Report
      2020 Annual Research Report
  • [Presentation] Fe-Ru系触媒によるC2~C4アルカン類のH2S共存型脱水素の反応特性2020

    • Author(s)
      依田裕太、渡部 綾、平田 望、河野芳海、福原長寿
    • Organizer
      第126回触媒討論会
    • Related Report
      2020 Annual Research Report
  • [Presentation] 小分子アルカン類のH2S共存型脱水素におけるFe系触媒の効果2020

    • Author(s)
      渡部綾, 依田裕太, 平田望, 河野芳海, 福原長寿
    • Organizer
      第125回触媒討論会
    • Related Report
      2019 Annual Research Report
  • [Presentation] Fe系触媒の格子硫黄を活用した低級アルカン(C2-C4)の脱水素:気相H2Sの促進効果2020

    • Author(s)
      渡部 綾, 依田 裕太, 平田 望, 河野 芳海, 福原 長寿
    • Organizer
      化学工学会 第85年会
    • Related Report
      2019 Annual Research Report
  • [Presentation] High performance of Ru-added Fe/SiO2 catalyst for propane dehydrogenation under H2S co-feeding2019

    • Author(s)
      Ryo WATANABE, Yuta YODA, Nozomu HIRATA, Yoshiumi KOHNO, Choji FUKUHARA
    • Organizer
      Asian Pacific Confederation of Chemical Engineering (APCChE)
    • Related Report
      2019 Annual Research Report
  • [Presentation] H2S共存のプロパ ン脱水素に対するFe系触媒への貴金属成分の添加効果2019

    • Author(s)
      渡部綾,依田裕太,平田望,河 野芳海,福原長寿
    • Organizer
      第124回触媒討論会
    • Related Report
      2019 Annual Research Report
  • [Presentation] Effect of co-supplying H2S on propane degydrogenation peformance of Fe-based catalyst2019

    • Author(s)
      Ryo Watanabe, Yuta Yoda, Nozomu Hirata, Choji Fukuhara
    • Organizer
      The 8th Asia-Pacific Congress on Catalysis
    • Related Report
      2019 Annual Research Report
  • [Presentation] 硫化水素が共存したプロパン脱水素におけるFe系触媒へのRu添加の効果2019

    • Author(s)
      渡部 綾、依田裕太、平田 望、河野芳海、福原長寿
    • Organizer
      石油学会第68回研究発表会
    • Related Report
      2019 Annual Research Report
  • [Presentation] H2S共存下におけるFe系触媒のC3,C4系アルカン脱水素の反応特性2019

    • Author(s)
      渡部 綾,依田裕太,平田 望,河野芳海,福原長寿
    • Organizer
      化学工学会 第84年会
    • Related Report
      2018 Annual Research Report
  • [Presentation] H2S共存下における遷移金属触媒上のブタン脱水素反応系路の検討2019

    • Author(s)
      平田 望,渡部 綾,依田裕太,河野芳海,福原長寿
    • Organizer
      触媒学会 第123回触媒討論会
    • Related Report
      2018 Annual Research Report
  • [Presentation] Novel dehydrogenation process for olefin production by sulfide redox of transition metal-based catalyst2018

    • Author(s)
      Ryo Watanabe
    • Organizer
      IWPI 2018
    • Related Report
      2018 Annual Research Report
    • Invited
  • [Presentation] Fe系触媒によるC3,C4系アルカンの脱水素に及ぼす硫化水素の共存効果2018

    • Author(s)
      渡部 綾,平田 望,河野芳海,福原長寿
    • Organizer
      石油学会 第48回石油・石油化学討論会
    • Related Report
      2018 Annual Research Report
  • [Presentation] レドックス型格子アニオン種による新規なアルカン脱水素プロセス2018

    • Author(s)
      渡部 綾
    • Organizer
      JPIJS講演会
    • Related Report
      2018 Annual Research Report
    • Invited
  • [Presentation] 硫化水素共存下における Fe/SiO2 触媒の n-ブタ ンの脱水素反応特性2018

    • Author(s)
      平田望,渡部綾,河野芳海,福原 長寿
    • Organizer
      触媒学会 第122回触媒討論会
    • Related Report
      2018 Annual Research Report

URL: 

Published: 2018-04-23   Modified: 2022-01-27  

Information User Guide FAQ News Terms of Use Attribution of KAKENHI

Powered by NII kakenhi