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Development of a nickel catalyst added with zinc contributing to purification of groundwater polluted with nitrate

Research Project

Project/Area Number 18H01780
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Review Section Basic Section 27030:Catalyst and resource chemical process-related
Research InstitutionHokkaido University

Principal Investigator

Kamiya Yuichi  北海道大学, 地球環境科学研究院, 教授 (10374638)

Co-Investigator(Kenkyū-buntansha) 大友 亮一  北海道大学, 地球環境科学研究院, 准教授 (10776462)
Project Period (FY) 2018-04-01 – 2021-03-31
Project Status Completed (Fiscal Year 2020)
Budget Amount *help
¥17,550,000 (Direct Cost: ¥13,500,000、Indirect Cost: ¥4,050,000)
Fiscal Year 2020: ¥3,250,000 (Direct Cost: ¥2,500,000、Indirect Cost: ¥750,000)
Fiscal Year 2019: ¥2,990,000 (Direct Cost: ¥2,300,000、Indirect Cost: ¥690,000)
Fiscal Year 2018: ¥11,310,000 (Direct Cost: ¥8,700,000、Indirect Cost: ¥2,610,000)
Keywords地下水汚染 / 硝酸態窒素 / 担持ニッケル触媒 / 助触媒添加 / Zn添加効果 / 担持Ni触媒 / 反応速度論解析 / 汚染地下水浄化 / 硝酸イオン / 助触媒 / 亜鉛 / 水中硝酸イオン還元 / 担体効果 / 助触媒効果 / 地下水浄化 / ニッケル触媒 / ヒドロキシルアミン / 不動態膜 / 亜鉛添加
Outline of Final Research Achievements

Expose of supported nickel catalysts to air made their catalytic activity lost in reduction of nitrate with hydrogen in water. Thus, to bring out their inherent catalytic performances, it was necessary to remove air from the reaction systems as much as possible. The catalytic performances of supported nickel catalysts for reduction of nitrate with hydrogen in water were significantly changed depending on support for nickel and co-catalyst added to nickel. It was found that a supported nickel catalyst with alumina support and zinc as a co-catalyst with 0.04 of atomic ratio of zinc to nickel showed high catalytic activity and suppressed undesirable ammonia formation.

Academic Significance and Societal Importance of the Research Achievements

貴重な水資源である地下水の硝酸イオンによる汚染が日本を含め世界各地で問題になっている。本研究の成果は、汚染地下水を浄化する有望な技術の一つである触媒反応による水中硝酸イオン水素化分解に関するものであり、この反応に対して飲用に望ましくないアンモニアの生成を大きく抑制し、かつ安価な触媒を提供するための基盤技術を提供する。

Report

(4 results)
  • 2020 Annual Research Report   Final Research Report ( PDF )
  • 2019 Annual Research Report
  • 2018 Annual Research Report
  • Research Products

    (5 results)

All 2021 2020 2019 2018 Other

All Journal Article (1 results) (of which Peer Reviewed: 1 results) Presentation (3 results) (of which Int'l Joint Research: 1 results) Remarks (1 results)

  • [Journal Article] Catalytic reduction of nitrate in water over alumina-supported nickel catalyst toward purification of polluted groundwater2020

    • Author(s)
      Kobune Marina、Takizawa Dai、Nojima Jun、Otomo Ryoichi、Kamiya Yuichi
    • Journal Title

      Catalysis Today

      Volume: in press Pages: 204-211

    • DOI

      10.1016/j.cattod.2020.01.037

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Presentation] 水中硝酸イオン還元反応に活性を示す担持ニッケル触媒への亜鉛添加効果2021

    • Author(s)
      小口幸子、小船茉理奈、大友亮一、神谷裕一
    • Organizer
      化学系学協会北海道支部2021年冬季研究発表会
    • Related Report
      2020 Annual Research Report
  • [Presentation] Catalytic reduction of nitrate in water over alumina-supported nickel catalyst2019

    • Author(s)
      Marina Kobune, Dai Takizawa, Jun Nojima, Ryoichi Otomo, Yuichi Kamiya
    • Organizer
      17th Korea-Japan Symposium on Catalysis
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 担持ニッケル触媒による水中硝酸イオン還元反応の速度論解析2018

    • Author(s)
      小船茉理奈、瀧澤大、野島淳、大友亮一、神谷裕一
    • Organizer
      第122回触媒討論会
    • Related Report
      2018 Annual Research Report
  • [Remarks] 神谷研究室研究業績(2018年度)

    • URL

      https://www.ees.hokudai.ac.jp/ems/stuff/kamiya/html/research_accomplishment-2018.html

    • Related Report
      2018 Annual Research Report

URL: 

Published: 2018-04-23   Modified: 2022-01-27  

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