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Selective dehydration of diols catalyzed by crystalline composite oxides

Research Project

Project/Area Number 18H01784
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Review Section Basic Section 27030:Catalyst and resource chemical process-related
Research InstitutionChiba University

Principal Investigator

Sato Satoshi  千葉大学, 大学院工学研究院, 教授 (30187190)

Co-Investigator(Kenkyū-buntansha) 山田 泰弘  千葉大学, 大学院工学研究院, 准教授 (90546780)
Project Period (FY) 2018-04-01 – 2021-03-31
Project Status Completed (Fiscal Year 2020)
Budget Amount *help
¥17,550,000 (Direct Cost: ¥13,500,000、Indirect Cost: ¥4,050,000)
Fiscal Year 2020: ¥5,200,000 (Direct Cost: ¥4,000,000、Indirect Cost: ¥1,200,000)
Fiscal Year 2019: ¥5,070,000 (Direct Cost: ¥3,900,000、Indirect Cost: ¥1,170,000)
Fiscal Year 2018: ¥7,280,000 (Direct Cost: ¥5,600,000、Indirect Cost: ¥1,680,000)
Keywords結晶性複合酸化物 / ジルコン酸イットリウム / 選択的脱水反応 / ブタンジオール / ブタジエン / 不飽和アルコール / ジオール / 選択脱水反応 / 複合酸化物触媒 / 脱水反応
Outline of Final Research Achievements

This study deals with the development of production of 1,3-butadiene (BD) from biomass-derived butanediols (BDO) using composite oxide catalysts with high crystallinity. It is important to form an intermediate unsaturated alcohol (UOL) from BDO for the efficient production of BD. Composite oxides, such as YbFexMnyO3 and rare earth zirconate (RZO), were focused to achieve high performance of the BDO dehydration catalyst. In the preliminary screening, Yb2Zr2O7 was found to be a candidate catalyst. In the 16 RZOs, RZOs with heavy rare earth composed of fluorite structure. The heavy RZOs showed high selectivity to UOLs in the dehydration of 1,3- and 1,4-BDO. In addition, Y2Zr2O7 showed the highest performance in the formation of BD from the BDOs. It is proved that cubic fluorite Y2Zr2O7 with high crystallinity, which exposed oxygen defect sites on the surface with 12.5% oxygen sites, exhibits high catalytic activity and high selectivity to BD in the dehydration of 1,3- and 1,4-BDO.

Academic Significance and Societal Importance of the Research Achievements

触媒化学の発展の上で、フルオライト型複合酸化物の特定結晶面の酸素欠損点が1,3-および1,4-BDOの脱水活性点であることおよびそのような欠損点を希土類ジルコン酸塩の表面に構築できることを提案した学術的意義は大きい。また、将来的に供給不足が懸念されるブタジエン製造の選択肢を与えるプロセスに必要な高性能な触媒を提案できた社会的意義は大きいと言える。

Report

(4 results)
  • 2020 Annual Research Report   Final Research Report ( PDF )
  • 2019 Annual Research Report
  • 2018 Annual Research Report
  • Research Products

    (22 results)

All 2021 2020 2019 2018 Other

All Int'l Joint Research (1 results) Journal Article (7 results) (of which Int'l Joint Research: 1 results,  Peer Reviewed: 7 results,  Open Access: 1 results) Presentation (14 results) (of which Invited: 1 results)

  • [Int'l Joint Research] Hebei University of Technology(中国)

    • Related Report
      2019 Annual Research Report
  • [Journal Article] Preparative chemistry of calcia-stabilized ZrO2 for vapor-phase dehydration of 1,4-butanediol2021

    • Author(s)
      Y. Matsumura, T. Kojima, Y. Yamada, S. Sato
    • Journal Title

      Molecular Catalysis

      Volume: 530 Pages: 111343-111343

    • DOI

      10.1016/j.mcat.2020.111343

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Selective production of 1,3-butadiene from 1,3-butanediol over Y2Zr2O7 catalyst2021

    • Author(s)
      Y. Matsumura, A. Matsuda, Y. Yamada, S. Sato
    • Journal Title

      Bull. Chem. Soc. Jpn

      Volume: 94 Issue: 6 Pages: 1651-1658

    • DOI

      10.1246/bcsj.20210070

    • NAID

      130008066586

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Dehydration of biomass-derived butanediols over rare earth zirconate catalysts2020

    • Author(s)
      A. Matsuda, Y. Matsumura, K. Nakazono, F. Sato, R. Takahashi, Y. Yamada, S. Sato
    • Journal Title

      Catalysts

      Volume: 10 Issue: 12 Pages: 1392-1392

    • DOI

      10.3390/catal10121392

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Production of 1,3-butadiene from biomass-derived C4 alcohols2020

    • Author(s)
      Daolai Sun, Yue Li, Chenhui Yang, Yijie Su, Yasuhiro Yamada, Satoshi Sato
    • Journal Title

      Fuel Processing Technology

      Volume: 197 Pages: 106193-106193

    • DOI

      10.1016/j.fuproc.2019.106193

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Efficient formation of γ-valerolactone in the vapor-phase hydrogenation of levulinic acid over Cu-Co/alumina catalyst2020

    • Author(s)
      Daichi Yanase, Rei Yoshida, Shuhei Kanazawa, Yasuhiro Yamada, Satoshi Sato
    • Journal Title

      Catalysis Communications

      Volume: 139 Pages: 105967-105967

    • DOI

      10.1016/j.catcom.2020.105967

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Catalytic dehydration of 1,3-butanediol over oxygen-defected fluorite Yb<inf>2</inf>Zr<inf>2</inf>O<inf>7</inf>2019

    • Author(s)
      Takuma Nemoto, Yasuhiro Yamada, Fumiya Sato, Ryoji Takahashi, Satoshi Sato
    • Journal Title

      Molecular Catalysis

      Volume: 473 Pages: 110399-110399

    • DOI

      10.1016/j.mcat.2019.110399

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Vapor-phase catalytic dehydration of butanediols to unsaturated alcohols over yttria-stabilized zirconia catalysts2019

    • Author(s)
      Shota Ohtsuka, Takuma Nemoto, Rikako Yotsumoto, Yasuhiro Yamada, Fumiya Sato, Ryoji Takahashi, Satoshi Sato
    • Journal Title

      Applied Catalysis A: General

      Volume: 575 Pages: 48-57

    • DOI

      10.1016/j.apcata.2019.02.013

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Presentation] 修飾シリカ触媒によるクロチルアルコールの気相脱水反応2021

    • Author(s)
      小澤知弘・山田泰弘・佐藤智司
    • Organizer
      第127回触媒討論会(千葉、千葉大学、2020/3/16-17)1P51
    • Related Report
      2020 Annual Research Report
  • [Presentation] 1,3-ブタンジオールの脱水反応による選択的ブタジエン生成2021

    • Author(s)
      松村佳孝・山田泰弘・佐藤智司
    • Organizer
      第127回触媒討論会(千葉、千葉大学、2020/3/16-17)1P52
    • Related Report
      2020 Annual Research Report
  • [Presentation] 1,4-ブタンジオールの脱水反応による選択的ブタジエン生成2021

    • Author(s)
      松田麻実・山田泰弘・佐藤智司
    • Organizer
      第127回触媒討論会(千葉、千葉大学、2020/3/16-17)1P53
    • Related Report
      2020 Annual Research Report
  • [Presentation] Sc2O3触媒による 2,3-ブタンジオールの 1,3-ブタジエンへの選択的脱水反応2021

    • Author(s)
      中園和希・山田泰弘・佐藤智司
    • Organizer
      第127回触媒討論会(千葉、千葉大学、2020/3/16-17)1P54
    • Related Report
      2020 Annual Research Report
  • [Presentation] 修飾シリカ触媒によるクロチルアルコールの気相異性化反応2020

    • Author(s)
      小澤知弘・山田泰弘・佐藤智司
    • Organizer
      第126回触媒討論会(浜松、静岡大学、2020/9/16-18)2D15
    • Related Report
      2020 Annual Research Report
  • [Presentation] Sc2O3触媒による 2,3-ブタンジオールの選択的脱水反応2020

    • Author(s)
      中園和希・山田泰弘・佐藤智司
    • Organizer
      第126回触媒討論会(浜松、静岡大学、2020/9/16-18)3I06
    • Related Report
      2020 Annual Research Report
  • [Presentation] 水熱処理Y2O3-ZrO2触媒による1,3-ブタンジオールの気相脱水反応2020

    • Author(s)
      松村佳孝・山田泰弘・佐藤智司
    • Organizer
      第126回触媒討論会(浜松、静岡大学、2020/9/16-18)3I09
    • Related Report
      2020 Annual Research Report
  • [Presentation] イットリア-ジルコニア触媒による1,4-ブタンジオールの選択的脱水反応2020

    • Author(s)
      松田麻実・山田泰弘・佐藤智司
    • Organizer
      第126回触媒討論会(浜松、静岡大学、2020/9/16-18)3I10
    • Related Report
      2020 Annual Research Report
  • [Presentation] Y2O3-ZrO2 触媒による 1,3-ブタンジオールの気相脱水反応2020

    • Author(s)
      松村佳孝、山田泰弘、佐藤智司
    • Organizer
      触媒学会、第125回触媒討論会
    • Related Report
      2019 Annual Research Report
  • [Presentation] Cu-Co/Al2O3 系触媒によるレブリン酸の気相ラクトン化反応2020

    • Author(s)
      柳瀬大地、山田泰弘、佐藤智司
    • Organizer
      触媒学会、第125回触媒討論会
    • Related Report
      2019 Annual Research Report
  • [Presentation] イットリア安定化ジルコニア触媒による1,3-ブタンジオールの気相脱水反応2019

    • Author(s)
      佐藤智司、根本拓磨、山田泰弘
    • Organizer
      触媒学会、第124回触媒討論会
    • Related Report
      2019 Annual Research Report
  • [Presentation] Zr系複合酸化物触媒による1,3-ブタンジオールの気相脱水反応2018

    • Author(s)
      根本拓磨、山田泰弘、佐藤智司
    • Organizer
      触媒学会、第122回触媒討論会
    • Related Report
      2018 Annual Research Report
  • [Presentation] ジルコニア系触媒を用いたブタンジオール類の脱水反応2018

    • Author(s)
      大塚翔太、山田泰弘、佐藤智司
    • Organizer
      触媒学会、第122回触媒討論会
    • Related Report
      2018 Annual Research Report
  • [Presentation] 不均一系触媒によるバイオマス由来多価アルコールの選択的変換反応の開発2018

    • Author(s)
      佐藤智司
    • Organizer
      触媒学会、第122回触媒討論会
    • Related Report
      2018 Annual Research Report
    • Invited

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Published: 2018-04-23   Modified: 2022-01-27  

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