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Elucidation of specific catalysis of boron nitride

Research Project

Project/Area Number 18H01785
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Review Section Basic Section 27030:Catalyst and resource chemical process-related
Research InstitutionKyushu University

Principal Investigator

Takagaki Atsushi  九州大学, 工学研究院, 准教授 (30456157)

Co-Investigator(Kenkyū-buntansha) 吉田 真明  山口大学, 大学院創成科学研究科, 准教授(テニュアトラック) (00582206)
Project Period (FY) 2018-04-01 – 2021-03-31
Project Status Completed (Fiscal Year 2020)
Budget Amount *help
¥17,420,000 (Direct Cost: ¥13,400,000、Indirect Cost: ¥4,020,000)
Fiscal Year 2020: ¥2,990,000 (Direct Cost: ¥2,300,000、Indirect Cost: ¥690,000)
Fiscal Year 2019: ¥2,990,000 (Direct Cost: ¥2,300,000、Indirect Cost: ¥690,000)
Fiscal Year 2018: ¥11,440,000 (Direct Cost: ¥8,800,000、Indirect Cost: ¥2,640,000)
Keywords窒化ホウ素 / 固体塩基触媒 / ニトロアルドール反応 / 多孔質材料 / ボールミル / 二酸化炭素 / 熱分解 / B-K XAFS / 酸塩基触媒 / 構造解析 / 酸化的脱水素 / 触媒作用
Outline of Final Research Achievements

A boron nitride catalyst was developed as a new solid acid-base catalyst. When highly crystalline hexagonal boron nitride was ball milled, amino groups and hydroxyl groups were generated, demonstrating both acid-base functionality. Despite the weak basicity, it showed excellent activity in the nitroaldol reaction, the Knoevenagel condensation reaction, and the low-temperature glucose isomerization reaction. Boron nitride was synthesized by a pyrolysis method using boric acid and urea. All the samples synthesized by the method had micropores and were able to adsorb carbon dioxide. It was also found that by controlling the ratio of precursor, porosity with mesopores was obtained at the same time. The catalysts showed activity in the nitroaldol reaction and the synthesis of cyclic carbonate from carbon dioxide and epoxide, and a good correlation was found between the activity and the pore structure.

Academic Significance and Societal Importance of the Research Achievements

グラファイトと同様の結晶構造を有する窒化ホウ素は化学的に安定であるためこれまで自身が触媒として機能することは想定されていなかった。しかし、本研究により窒化ホウ素が酸塩基性を有する優れた固体触媒となることを明らかにした。ボールミル粉砕処理をすることで表面積が増大することに加え表面への官能基の導入に成功した。さらに、ホウ酸と窒素含有化合物を出発原料として用い熱分解法により窒化ホウ素を合成すると、二酸化炭素を吸着できるミクロ孔や物質拡散に効率的なメソ孔を同時に有する、新たな多孔質固体酸塩基触媒となることを見いだした。

Report

(4 results)
  • 2020 Annual Research Report   Final Research Report ( PDF )
  • 2019 Annual Research Report
  • 2018 Annual Research Report
  • Research Products

    (19 results)

All 2020 2019 2018

All Journal Article (7 results) (of which Peer Reviewed: 7 results,  Open Access: 2 results) Presentation (12 results) (of which Int'l Joint Research: 3 results,  Invited: 4 results)

  • [Journal Article] Effects of post-thermal treatments of ball-milled boron nitrides on solid base catalysis2020

    • Author(s)
      Takagaki Atsushi
    • Journal Title

      Catalysis Today

      Volume: 352 Pages: 279-286

    • DOI

      10.1016/j.cattod.2019.11.007

    • Related Report
      2020 Annual Research Report 2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Porous Boron Nitride as a Weak Solid Base Catalyst2020

    • Author(s)
      Nakamura Shohei、Takagaki Atsushi、Watanabe Motonori、Yamada Kanta、Yoshida Masaaki、Ishihara Tatsumi
    • Journal Title

      ChemCatChem

      Volume: 12 Issue: 23 Pages: 6033-6039

    • DOI

      10.1002/cctc.202001435

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Enhancement of solid base activity for porous boron nitride catalysts by controlling active structure using post treatment2020

    • Author(s)
      Takagaki Atsushi、Nakamura Shohei、Watanabe Motonori、Kim Yoonyoung、Song Jun Tae、Jimura Keiko、Yamada Kanta、Yoshida Masaaki、Hayashi Shigenobu、Ishihara Tatsumi
    • Journal Title

      Applied Catalysis A: General

      Volume: 608 Pages: 117843-117843

    • DOI

      10.1016/j.apcata.2020.117843

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Production of 5-Hydroxymethylfurfural from Glucose in Water by Using Transition Metal-Oxide Nanosheet Aggregates2019

    • Author(s)
      Takagaki Atsushi
    • Journal Title

      Catalysts

      Volume: 9 Issue: 10 Pages: 818-818

    • DOI

      10.3390/catal9100818

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Rational Design of Metal Oxide Solid Acids for Sugar Conversion2019

    • Author(s)
      Takagaki
    • Journal Title

      Catalysts

      Volume: 9 Issue: 11 Pages: 907-907

    • DOI

      10.3390/catal9110907

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Effects of ball-milling treatment on physicochemical properties and solid base activity of hexagonal boron nitrides2019

    • Author(s)
      Namba Shoichiro、Takagaki Atsushi、Jimura Keiko、Hayashi Shigenobu、Kikuchi Ryuji、Ted Oyama S.
    • Journal Title

      Catalysis Science & Technology

      Volume: 9 Issue: 2 Pages: 302-309

    • DOI

      10.1039/c8cy00940f

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Oxidative Dehydrogenation of Ethane Using Ball-milled Hexagonal Boron Nitride2018

    • Author(s)
      Honda Yusuke、Takagaki Atsushi、Kikuchi Ryuji、Oyama S. Ted
    • Journal Title

      Chemistry Letters

      Volume: 47 Issue: 9 Pages: 1090-1093

    • DOI

      10.1246/cl.180510

    • NAID

      130007472111

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Presentation] 弱塩基性を有する多孔質窒化ホウ素によるニトロアルドール反応2020

    • Author(s)
      高垣敦、中村昇平、渡邊源規、山田寛太、吉田真明、石原達己
    • Organizer
      第126回触媒討論会
    • Related Report
      2020 Annual Research Report
  • [Presentation] 窒化ホウ素固体塩基触媒による二酸化炭素とエポキシドからの環状カーボネート合成2020

    • Author(s)
      宮本鉄平、高垣敦、SONG Jun Tae、渡邊源規、石原達己
    • Organizer
      第127回触媒討論会
    • Related Report
      2020 Annual Research Report
  • [Presentation] 窒化ホウ素光触媒によるCO2変換2020

    • Author(s)
      村上安嗣、高垣敦、SONG Jun Tae、渡邊源規、石原達己
    • Organizer
      第127回触媒討論会
    • Related Report
      2020 Annual Research Report
  • [Presentation] Physicochemical Properties and Solid Base Activity of Ball-milled Hexagonal Boron Nitrides2019

    • Author(s)
      Atsushi Takagaki, Keiko Jimura, Shigenobu Hayashi, Ryuji Kikuchi, S. Ted Oyama
    • Organizer
      The 17th Korea-Japan Symposium on Catalysis
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 窒化ホウ素の有する特異的触媒作用2019

    • Author(s)
      高垣敦
    • Organizer
      触媒学会元素戦略研究会 第7回元素戦略に基づいた触媒設計シンポジウム
    • Related Report
      2019 Annual Research Report
    • Invited
  • [Presentation] ボールミル処理窒化ホウ素のキャラクタリゼーションと固体塩基触媒作用2019

    • Author(s)
      高垣敦、吉田真明、治村圭子、林繁信、石原達己
    • Organizer
      第49回石油・石油化学討論会
    • Related Report
      2019 Annual Research Report
  • [Presentation] 熱分解法により合成した窒化ホウ素触媒によるニトロアルドール反応2019

    • Author(s)
      中村昇平、高垣敦、石原達己
    • Organizer
      第124回触媒討論会
    • Related Report
      2019 Annual Research Report
  • [Presentation] 高表面積窒化ホウ素の合成とニトロアルドール反応における高活性化2019

    • Author(s)
      中村昇平、高垣敦、石原達己
    • Organizer
      第56回化学関連支部合同九州大会
    • Related Report
      2019 Annual Research Report
  • [Presentation] 木質系バイオフューエル合成のための固体塩基BN触媒の開発2019

    • Author(s)
      中村昇平、高垣敦、石原達己
    • Organizer
      第49回石油・石油化学討論会
    • Related Report
      2019 Annual Research Report
  • [Presentation] Ball-milled Boron Nitride as a Novel Solid Acid-Base Catalyst2018

    • Author(s)
      Atsushi Takagaki, Shusaku Torii, Shoichiro Namba, Keiko Jimura, Shigenobu Hayashi, Ryuji Kikuchi, S. Ted Oyama
    • Organizer
      2018 International Symposium on Advancement and Prospect of Catalysis Science & Technology
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Hexagonal Boron Nitride as a Solid Acid-Base Catalyst2018

    • Author(s)
      Atsushi Takagaki, Shusaku Torii, Shoichiro Namba, Keiko Jimura, Shigenobu Hayashi, Ryuji Kikuchi, S. Ted Oyama
    • Organizer
      he 8th Tokyo Conference on Advanced Catalytic Science and Technology (TOCAT8)
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 無機層状化合物の固体酸塩基触媒への応用2018

    • Author(s)
      高垣敦
    • Organizer
      第12回触媒道場
    • Related Report
      2018 Annual Research Report
    • Invited

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Published: 2018-04-23   Modified: 2022-01-27  

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