Elucidation of physical properties of lead-free perovskite semiconductors as high efficiency solar cell materials

• Project/Area Number: 18H01888
• Research Category: Grant-in-Aid for Scientific Research (B)
• Allocation Type: Single-year Grants
• Section: 一般
• Review Section: Basic Section 30010:Crystal engineering-related
• Research Institution: University of Tsukuba
• Principal Investigator: Matsuishi Kiyoto 筑波大学, 数理物質系, 教授 (10202318)
• Project Period (FY): 2018-04-01 – 2021-03-31
• Project Status: Completed (Fiscal Year 2020)
• Budget Amount: ¥17,030,000 (Direct Cost: ¥13,100,000、Indirect Cost: ¥3,930,000); Fiscal Year 2020: ¥2,470,000 (Direct Cost: ¥1,900,000、Indirect Cost: ¥570,000); Fiscal Year 2019: ¥3,510,000 (Direct Cost: ¥2,700,000、Indirect Cost: ¥810,000); Fiscal Year 2018: ¥11,050,000 (Direct Cost: ¥8,500,000、Indirect Cost: ¥2,550,000)
• Keywords: ペロブスカイト半導体 / 太陽電池 / 光物性 / 高圧物性 / 構造物性 / 鉛フリー / 有機無機複合材料 / 太陽電池材料

Outline of Final Research Achievements

As lead-free perovskite semiconductors for solar cell materials, we focused on Sn-halide, Ge-halide, and double perovskite systems. In Ge-halide and double perovskite systems, we elucidated characteristic structural changes with temperature and pressure which accompanied intriguing changes in electronic and optical properties. For Sn-halide perovskite solar cells, we proposed several additives by utilizing co-additive engineering and achieved the suppression of oxidation of Sn ions and the significant improvement of perovskite film quality, resulting in the improvement of power conversion efficiency and device stability.

Academic Significance and Societal Importance of the Research Achievements

Sn系ペロブスカイト太陽電池において共添加剤による結晶安定化と高変換効率化及びデバイス安定化の指針を得ることができた点は、鉛フリーペロブスカイト太陽電池の実用化に向けて学術的且つ社会的意義がある。また、非鉛系ペロブスカイト半導体の単結晶を用いた精密物性測定により、構造物性と光・電子物性との相関を明らかにした点は、今後の鉛フリーペロブスカイト太陽電池の材料設計を行う上で貴重な知見となり、学術的意義がある。

Research Products

• [Int'l Joint Research] Dongguk University(韓国)
• [Journal Article] Chemical passivation of the under coordinated Pb2+ defects in inverted planar perovskite solar cells via β-diketone Lewis base additives (2021)
  • Author(s): Abdel-Shakour Muhammad、Chowdhury Towhid H.、Matsuishi Kiyoto、Moritomo Yutaka、Islam Ashraful
  • Journal Title: Photochemical & Photobiological Sciences Volume: 20 Issue: 3 Pages: 357-367
  • DOI: 10.1007/s43630-021-00023-z
  • Peer Reviewed / Int'l Joint Research
• [Journal Article] High‐Efficiency Tin Halide Perovskite Solar Cells: The Chemistry of Tin (II) Compounds and Their Interaction with Lewis Base Additives during Perovskite Film Formation (2020)
  • Author(s): Abdel-Shakour Muhammad.、Chowdhury Towhid H.、Matsuishi Kiyoto、Bedja Idriss、Moritomo Yutaka、Islam Ashraful
  • Journal Title: Solar RRL Volume: 5 Issue: 1 Pages: 2000606-2000606
  • DOI: 10.1002/solr.202000606
  • Peer Reviewed / Int'l Joint Research
• [Journal Article] Influence of anti-solvents on CH3NH3PbI3 films surface morphology for fabricating efficient and stable inverted planar perovskite solar cells (2018)
  • Author(s): Emrul Kayesh Md.、Matsuishi Kiyoto、Chowdhury Towhid H.、Kaneko Ryuji、Lee Jae-Joon、Noda Takeshi、Islam Ashraful
  • Journal Title: Thin Solid Films Volume: 663 Pages: 105-115
  • DOI: 10.1016/j.tsf.2018.08.015
  • Peer Reviewed / Int'l Joint Research
• [Journal Article] Enhanced Photovoltaic Performance of Perovskite Solar Cells by Copper Chloride (CuCl2) as an Additive in Single Solvent Perovskite Precursor (2018)
  • Author(s): Emrul Kayesh Md.、Matsuishi Kiyoto、Chowdhury Towhid H.、Kaneko Ryuji、Noda Takeshi、Islam Ashraful
  • Journal Title: Electronic Materials Letters Volume: 14 Issue: 6 Pages: 712-717
  • DOI: 10.1007/s13391-018-0075-5
  • Peer Reviewed
• [Journal Article] Enhanced Photovoltaic Performance of FASnI3-Based Perovskite Solar Cells with Hydrazinium Chloride Coadditive (2018)
  • Author(s): Kayesh Md. Emrul、Chowdhury Towhid H.、Matsuishi Kiyoto、Kaneko Ryuji、Kazaoui Said、Lee Jae-Joon、Noda Takeshi、Islam Ashraful
  • Journal Title: ACS Energy Letters Volume: 3 Issue: 7 Pages: 1584-1589
  • DOI: 10.1021/acsenergylett.8b00645
  • Peer Reviewed / Int'l Joint Research
• [Journal Article] Coadditive Engineering with 5-Ammonium Valeric Acid Iodide for Efficient and Stable Sn Perovskite Solar Cells (2018)
  • Author(s): Kayesh Md. Emrul、Matsuishi Kiyoto、Kaneko Ryuji、Kazaoui Said、Lee Jae-Joon、Noda Takeshi、Islam Ashraful
  • Journal Title: ACS Energy Letters Volume: 4 Issue: 1 Pages: 278-284
  • DOI: 10.1021/acsenergylett.8b02216
  • Peer Reviewed / Int'l Joint Research
• [Presentation] AgとBiを用いた鉛フリーハライド系ダブルペロブスカイト半導体の作製と光物性 (2021)
  • Author(s): 石川大輔、松石清人
  • Organizer: 第68回応用物理学会春季学術講演会
• [Presentation] Ag・In系ダブルペロブスカイト半導体の作製と高圧下の光物性Ⅱ (2021)
  • Author(s): 目黒悠介、松石清人
  • Organizer: 第68回応用物理学会春季学術講演会
• [Presentation] Ge系ペロブスカイト半導体の構造と光物性（Ⅱ） (2020)
  • Author(s): 齋藤 瑞生、鈴木 涼平、高橋 美和子、神山 祟、松石 清人、片岡 邦光、萩原 雅人、鳥居 周輝
  • Organizer: 第81回応用物理学会秋季学術講演会
• [Presentation] Ge系ペロブスカイト半導体の結晶構造と相転移 (2020)
  • Author(s): 齋藤 瑞生、鈴木 涼平、高橋 美和子、松石 清人、神山 祟、萩原 雅人、鳥居 周輝、片岡邦光
  • Organizer: 日本結晶学会2020年度年会
• [Presentation] Suppression of the Pb2+ defects in the perovskite films using Lewis-base additives in perovskite solar cells (2020)
  • Author(s): Muhammad Abdel-Shakour, Towhid H. Chowdhury, Kiyoto Matsuishi, Ashraful Islam
  • Organizer: International Online Conference on Hybrid Materials and Optoelectronic Devices (HYBRIDOE)
  • Int'l Joint Research
• [Presentation] Ge系ペロブスカイト半導体の構造と光物性 (2020)
  • Author(s): 齋藤 瑞生、鈴木 涼平、Tan Zhijian、高橋 美和子、神山 祟、松石 清人
  • Organizer: 第67回応用物理学会春季学術講演会
• [Presentation] CuとBiを用いた鉛フリーハライド系ダブルペロブスカイト半導体の作製と光物性 (2019)
  • Author(s): 石川 大輔、松石清人
  • Organizer: 第80回応用物理学会秋季学術講演会
• [Presentation] 鉛フリーハライド系ダブルペロブスカイト半導体の作製と超高圧下の光物性 (2019)
  • Author(s): 目黒 悠介、松石清人
  • Organizer: 第80回応用物理学会秋季学術講演会
• [Presentation] 長鎖アミンでサイズ制御したCH3NH3PbBr3ナノ粒子の作製と光学特性 (2019)
  • Author(s): 久永尊瑚、松石清人
  • Organizer: 第80回応用物理学会秋季学術講演会
• [Presentation] Co-additive Engineering with Bifunctional Additive for Enhanced Performance and Improved Stability of Sn-based Perovskites Solar Cells (2019)
  • Author(s): Md. Emrul Kayesh, Kiyoto Matsuishi, Towhid H. Chowdhury, Ryuji Kaneko, Said Kazaoui, Jae-Joon Lee, Takeshi Noda, Ashraful Islam
  • Organizer: International Conference on Perovskite and Organic Photovoltaics and Optoelectronics (IPEROP2019)
  • Int'l Joint Research
• [Presentation] Coadditive and Compositional Engineering for High Performance Lead-Free Perovskite Solar Cells (2019)
  • Author(s): Md. Emrul KAYESH, Kiyoto MATSUISHI, Jae-Joon LEE, Ashraful ISLAM
  • Organizer: Global Photovoltaic Conference 2019 (GPVC2019)
  • Int'l Joint Research
• [Presentation] Ge系ペロブスカイト半導体の作製と光物性 (2018)
  • Author(s): 鈴木涼平, 松石清人
  • Organizer: 第79回応用物理学会秋季学術講演会
• [Presentation] 極性溶媒の異なるCH3NH3PbBr3ナノ粒子の光学特性と安定性 (2018)
  • Author(s): 久永尊瑚、松石清人
  • Organizer: 第79回応用物理学会秋季学術講演会
• [Presentation] ナフタレン発色団を有する鉛ハロゲン層状ペロブスカイトの発光におけるエネルギー移動:圧力効果とハロゲン置換効果(Ⅱ) (2018)
  • Author(s): 下村 直矢、松石 清人
  • Organizer: 第79回 応用物理学会 秋季学術講演会
• [Presentation] Co-additive Engineering of Lead Free Perovskites Solar Cells for Enhanced Photovoltaic Performance and Improved Stability (2018)
  • Author(s): Md. Emrul Kayesh, Kiyoto Matsuishi, Towhid H. Chowdhury, Ryuji Kaneko, Said Kazaoui, Jae-Joon Lee, Takeshi Noda, Ashraful Islam
  • Organizer: 第79回応用物理学会秋季学術講演会