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Visualization of Structure/Reactivity of Heterogeneous Catalysts by Operando Spatio/Temporal Imaging XAFS

Research Project

Project/Area Number 18H01940
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Review Section Basic Section 32010:Fundamental physical chemistry-related
Research InstitutionNagoya University

Principal Investigator

Tada Mizuki  名古屋大学, 物質科学国際研究センター, 教授 (70396810)

Project Period (FY) 2018-04-01 – 2021-03-31
Project Status Completed (Fiscal Year 2020)
Budget Amount *help
¥17,420,000 (Direct Cost: ¥13,400,000、Indirect Cost: ¥4,020,000)
Fiscal Year 2020: ¥3,770,000 (Direct Cost: ¥2,900,000、Indirect Cost: ¥870,000)
Fiscal Year 2019: ¥6,890,000 (Direct Cost: ¥5,300,000、Indirect Cost: ¥1,590,000)
Fiscal Year 2018: ¥6,760,000 (Direct Cost: ¥5,200,000、Indirect Cost: ¥1,560,000)
Keywordsイメージング / XAFS / CT / オペランド計測 / 固体触媒 / 複合酸化物 / 触媒 / 酸化物 / 可視化
Outline of Final Research Achievements

We have developed XAFS-spectroscopy-imaging techniques combining hard X-ray imaging techniques and X-ray Absorption Fine Structure (spectroscopy) for the visualization of spatial element information inside solid materials. XAFS imaging provides spatial distribution of each element, oxidation state, local coordination structure inside solid particles and crystals and we visualized the reaction diffusions inside mixed oxides and solid catalysts by the XAFS imaging techniques. We succeeded in visualizing the oxidation reaction track inside ceria-zirconia solid-solution materials and redox reaction behaviors of Cr-doped iron oxide crystals for the first time.

Academic Significance and Societal Importance of the Research Achievements

固体の機能性材料は、触媒をはじめとした様々な分野で用いられており、不均質な固体機能性材料中の元素の状態や分布、酸化状態の違い、局所構造の分布などはこれまで明らかにすることができなかった。本研究成果によって、不均質な固体材料中の個々の元素の化学状態の違いを可視化できるようになり、触媒特性や吸着特性などと関連する元素の反応分布や拡散を直接理解することができるようになった。

Report

(4 results)
  • 2020 Annual Research Report   Final Research Report ( PDF )
  • 2019 Annual Research Report
  • 2018 Annual Research Report
  • Research Products

    (42 results)

All 2021 2020 2019 2018 Other

All Int'l Joint Research (1 results) Journal Article (8 results) (of which Peer Reviewed: 8 results,  Open Access: 1 results) Presentation (33 results) (of which Int'l Joint Research: 11 results,  Invited: 16 results)

  • [Int'l Joint Research] Kansas Univ.(米国)

    • Related Report
      2018 Annual Research Report
  • [Journal Article] 3D Operando Imaging and Quantification of Inhomogeneous Electrochemical Reactions in Composite Battery Electrodes2020

    • Author(s)
      Yuta Kimura, Aina Tomura, Mahunnop Fakkao, Takashi Nakamura, Nozomu Ishiguro, Oki Sekizawa, Kiyofumi Nitta, Tomoya Uruga, Toyoki Okumura, Mizuki Tada, Yoshiharu Uchimoto, Koji Amezawa
    • Journal Title

      J. Phys. Chem. Lett.

      Volume: 11 Issue: 9 Pages: 3629-3636

    • DOI

      10.1021/acs.jpclett.0c00876

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Reversible structural transformation and redox properties of Cr-loaded iron oxide dendrites studied by in situ XANES spectroscopy2020

    • Author(s)
      1.H. Matsui, N. Ishiguro, Y. Suzuki, K. Wakamatsu, C. Yamada, K. Sato, N. Maejima, T. Uruga, and M. Tada
    • Journal Title

      Phys. Chem. Chem. Phys.

      Volume: 22 Issue: 48 Pages: 28093-28099

    • DOI

      10.1039/d0cp04416d

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Oxygen Reduction Reaction Performance Tuning on Pt Nanoparticle/MWCNT Catalysts by Gd Species2020

    • Author(s)
      K. Ichihashi, S. Muratsugu, H. Matsui, K. Higashi, O. Sekizawa, T. Uruga, and M. Tada
    • Journal Title

      J. Phys. Chem. C

      Volume: 124 Issue: 49 Pages: 26925-26936

    • DOI

      10.1021/acs.jpcc.0c09308

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Operando XAFS Imaging of Distribution of Pt Cathode Catalysts in PEFC MEA2019

    • Author(s)
      Matsui Hirosuke、Maejima Naoyuki、Ishiguro Nozomu、Tan Yuanyuan、Uruga Tomoya、Sekizawa Oki、Sakata Tomohiro、Tada Mizuki
    • Journal Title

      The Chemical Record

      Volume: 19 Issue: 7 Pages: 1380-1392

    • DOI

      10.1002/tcr.201800123

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Reversible low-temperature redox activity and selective oxidation catalysis derived from the concerted activation of multiple metal species on Cr and Rh-incorporated ceria catalysts2019

    • Author(s)
      Satoru Ikemoto, Xiubing Huang, Satoshi Muratsugu, Shoko Nagase, Takanori Koitaya, Hirosuke Matsui, Gen-ichi Yokota, Takatoshi Sudoh, Ayako Hashimoto, Yuanyuan Tan, Susumu Yamamoto, Jiayi Tang, Iwao Matsuda, Jun Yoshinobu, Toshihiko Yokoyama, Shinpei Kusaka, Ryotaro Matsuda, Mizuki Tada
    • Journal Title

      Physical Chemistry Chemical Physics

      Volume: 21 Issue: 37 Pages: 20868-20877

    • DOI

      10.1039/c9cp04625a

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Oxygen-Diffusion-Driven Oxidation Behavior and Tracking Areas Visualized by X-ray Spectro-Ptychography with Unsupervised Learning2019

    • Author(s)
      M. Hirose, N. Ishiguro, K. Shimomura, D. N. Nguyen, H. Matsui, H. C. Dam, M. Tada, Y. Takahashi
    • Journal Title

      Coommunication Chemistry

      Volume: 2 Issue: 1 Pages: 1-7

    • DOI

      10.1038/s42004-019-0147-y

    • Related Report
      2019 Annual Research Report 2018 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] PtCo/C Cathode Catalyst Degradation in a Polymer Electrolyte Fuel Cell Investigated by an Infographic Approach Combining Three-Dimensional Spectroimaging and Unsupervised Learning2019

    • Author(s)
      Tan Yuanyuan、Matsui Hirosuke、Ishiguro Nozomu、Uruga Tomoya、Nguyen Duong-Nguyen、Sekizawa Oki、Sakata Tomohiro、Maejima Naoyuki、Higashi Kotaro、Dam Hieu Chi、Tada Mizuki
    • Journal Title

      The Journal of Physical Chemistry C

      Volume: 123 Issue: 31 Pages: 18844-18853

    • DOI

      10.1021/acs.jpcc.9b05005

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Operando XAFS Imaging of Distribution of Pt Cathode Catalysts in PEFC MEA2019

    • Author(s)
      H. Matsui, N. Maejima, N. Ishiguro, Y. Tan, T. Uruga, O. Sekizawa, T. Sakata, M. Tada
    • Journal Title

      Chemical Record

      Volume: 19

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Presentation] Operando三次元XAFSイメージングによる触媒内現象の可視化2021

    • Author(s)
      唯 美津木
    • Organizer
      化学工学会反応工学部会第14回触媒劣化セミナー
    • Related Report
      2020 Annual Research Report
    • Invited
  • [Presentation] 可視化イメージングを基盤とする触媒インフォグラフィ2021

    • Author(s)
      唯 美津木
    • Organizer
      触媒・電池元素戦略研究拠点第17回公開シンポジウム
    • Related Report
      2020 Annual Research Report
    • Invited
  • [Presentation] MOFの分子吸着過程のin situ XAFSイメージング2020

    • Author(s)
      坂本裕俊, 松井公佑, 山田笑菜, 堀彰宏, 松田亮太郎, 永見哲夫, 加藤弘泰, 東晃太朗, 宇留賀朋哉, 唯美津木
    • Organizer
      第34回日本放射光学会年会放射光科学合同シンポジウム
    • Related Report
      2020 Annual Research Report
  • [Presentation] 金属-ゴム界面の接着層に関するCT-XAFSイメージング2020

    • Author(s)
      村本雄太, 松井公佑, 宇留賀朋哉, 唯美津木
    • Organizer
      第34回日本放射光学会年会放射光科学合同シンポジウム
    • Related Report
      2020 Annual Research Report
  • [Presentation] Preparation and Ammoxidation Performances of Copper and Ruthenium Incorporated Ceria2020

    • Author(s)
      C. Chen, S. Ikemoto, G. Yokota, S. Muratsugu, M. Tada
    • Organizer
      日本化学会第101回春季年会
    • Related Report
      2020 Annual Research Report
  • [Presentation] オペランドCT-XAFSによるMOF結晶内の分子吸着過程の三次元イメージング2020

    • Author(s)
      山田笑菜, 坂本裕俊, 松井公佑, 堀彰宏, 松田亮太郎, 永見哲夫, 加藤弘泰, 東晃太朗, 宇留賀朋哉, 唯美津木
    • Organizer
      日本化学会第101回春季年会
    • Related Report
      2020 Annual Research Report
  • [Presentation] イメージングXAFSが拓く反応インフォグラフィー2020

    • Author(s)
      唯 美津木
    • Organizer
      表面真空学会関東支部講演会
    • Related Report
      2020 Annual Research Report
    • Invited
  • [Presentation] Infography of Heterogeneous Catalysts by 3D Spectro-Imaging and Unsupervised Learning2020

    • Author(s)
      M. Tada
    • Organizer
      17th International Congress on Catalysis
    • Related Report
      2020 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Reversible Low-temperature Redox and Catalytic Performances of Cr and Rh-incorporated Ceria Catalysts2019

    • Author(s)
      S. Ikemoto, S. Muratsugu, H. Matsui, T. Koitaya, A. Hashimoto, M. Tada
    • Organizer
      錯体化学会第69回討論会
    • Related Report
      2019 Annual Research Report
  • [Presentation] NO Reduction Performances of Cr and Rh-incorporated Ceria Catalysts2019

    • Author(s)
      S. Ikemoto, S. Muratsugu, and M. Tada
    • Organizer
      日本化学会第100春季年会
    • Related Report
      2019 Annual Research Report
  • [Presentation] Reaction Infography for Materials Science2019

    • Author(s)
      M. Tada
    • Organizer
      The 1st Workshop of Reaction Infography (R-ing) Unit
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Reaction Infography for Heterogeneous Catalysts2019

    • Author(s)
      M. Tada
    • Organizer
      NU-UoE JD and JSPS CtC Joint Workshop on “New Horizons in Chemistry and Materials Science”
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Preparation and Operando Imaging of Pt-bimetallic Electrocatalysts for Polymer Electrolyte Fuel Cell2019

    • Author(s)
      M. Tada, S. Muratsugu, H. Matsui
    • Organizer
      5th Japan-Taiwan-Singapore-Hong Kong Quadrilateral Symposium on Coordination Chemistry (QSCC2019)
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 反応インフォグラフィー: 可視化が拓く物質科学2019

    • Author(s)
      唯美津木
    • Organizer
      サステイナブル社会のための最先端触媒化学・表面科学講演会
    • Related Report
      2019 Annual Research Report
    • Invited
  • [Presentation] Crドープ酸化鉄結晶のドーパントサイト解析とレドックス特性2019

    • Author(s)
      松井公佑, 石黒志, 関澤央輝, 宇留賀朋哉, 唯美津木
    • Organizer
      第32回日本放射光学会年会
    • Related Report
      2018 Annual Research Report
  • [Presentation] Cr, Rh含有セリア結晶内の酸化還元に伴うCe酸化数分布の可視化2019

    • Author(s)
      若松昂平, 松井公佑, 石黒志, 邨次智, 関澤央輝, 宇留賀朋哉, 唯美津木
    • Organizer
      第32回日本放射光学会年会
    • Related Report
      2018 Annual Research Report
  • [Presentation] 3D Imaging of Heterogeneous Catalysts2019

    • Author(s)
      M. Tada
    • Organizer
      Workshop on “Solid-State Electrochemistry for Coordination Complexes”
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] XAFS Imaging of Solid Catalysts2019

    • Author(s)
      M. Tada
    • Organizer
      International Symposium on Heterogeneous Catalysis for Sustainable Energy and Chemical Production
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Low-temperature Redox Behavior and Selective Oxidation Performances of Ceria-based Mixed Oxides with Cr and Rh2019

    • Author(s)
      S. Ikemoto, H. Matsui, S. Muratsugu, M. Tada
    • Organizer
      日本化学会第99春季年会
    • Related Report
      2018 Annual Research Report
  • [Presentation] CT-XAFSを用いたバルク型全固体リチウムイオン電池合剤電極内の不均一反応のオペランド可視化計測2019

    • Author(s)
      戸村愛菜, 木村勇太, Fakkao Mahunnop, 中村崇司, 石黒志, 関澤央輝, 新田清文, 宇留賀朋哉, 奥村豊旗, 唯美津木, 内本喜晴, 雨澤浩史
    • Organizer
      電気化学会第86回大会
    • Related Report
      2018 Annual Research Report
  • [Presentation] Operando XAFS Imaging of Heterogeneous Catalysts2018

    • Author(s)
      M. Tada
    • Organizer
      MIRAI Materials Science Workshop 2018
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] X-ray Imaging of Heterogeneous Catalysts and Electrocatalysts2018

    • Author(s)
      M. Tada
    • Organizer
      Gordon Research Conference on Catalysis 2018
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Three-dimensional Chemical Imaiging of Oxygen Storage and Release Particles by Hard X-ray Spectro-Ptychography2018

    • Author(s)
      M. Hirose, N. Ishiguro, K. Shimomura, H. Matsui, M. Tada, and Y. Takahashi
    • Organizer
      Coherence 2018: International Workshop on Phase Retrieval and Coherent Scattering
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Visualization of Ce Chemical States and Oxygen Diffusion in Ceria-Zirconia Particles by X-ray Spectro-Ptychography2018

    • Author(s)
      N. Ishiguro, M. Hirose, K. Shimomura, N. Burdet, H. Matsui, Y. Takahashi, and M. Tada
    • Organizer
      International Symposium on Relations between Homogeneous and Heterogeneous Catalysis (ISHHC 18)
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 第一・第二周期遷移金属を導入したセリア系複合酸化物の調製、レドックス特性と触媒反応2018

    • Author(s)
      池本悟, X. Huang, 永瀬晶子, 横田元一, 邨次智, 唯美津木
    • Organizer
      錯体化学会第68回討論会
    • Related Report
      2018 Annual Research Report
  • [Presentation] 放射光を利用した触媒のキャラクタリゼーション2018

    • Author(s)
      唯 美津木
    • Organizer
      シンポジウム「東北放射光SLiT-Jと触媒研究」
    • Related Report
      2018 Annual Research Report
    • Invited
  • [Presentation] Nanoscale Chemical Imaging of Three-Way Catalyst Pt/Ce2Zr2Ox Particles by Ptychographic-XAFS2018

    • Author(s)
      M. Hirose, N. Ishiguro, K. Shimomura, H. Matsui, M. Tada, and Y. Takahashi
    • Organizer
      14th Inetrnational Conference on X-ray Microscopy (XRM2018)
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] タイコグラフィXAFSによる三元触媒Pt/Ce2Zr2Ox粒子の酸化状態ナノイメージング2018

    • Author(s)
      広瀬真, 石黒志, 下村啓, 松井公佑, 唯美津木, 高橋幸生
    • Organizer
      第21回XAFS討論会
    • Related Report
      2018 Annual Research Report
  • [Presentation] オペランドCT-XAFSを用いたバルク型全固体リチウムイオン電池用合剤電極内反応分布の定量的解析2018

    • Author(s)
      木村勇太, 戸村愛菜, Fakkao Mahunnop, 中村崇司, 石黒志, 関澤央輝, 新田清文, 宇留賀朋哉, 奥村豊旗, 唯美津木, 内本喜晴, 雨澤浩史
    • Organizer
      2018年電気化学秋季大会
    • Related Report
      2018 Annual Research Report
  • [Presentation] オペランドCT-XAFSによるバルク型全固体リチウムイオン電池用合剤電極における反応分布形成要因の解明2018

    • Author(s)
      木村勇太, 戸村愛菜, Fakkao Mahunnop, 中村崇司, 石黒志, 関澤央輝, 新田清文, 宇留賀朋哉, 奥村豊旗, 唯美津木, 内本喜晴, 雨澤浩史
    • Organizer
      第59回電池討論会
    • Related Report
      2018 Annual Research Report
  • [Presentation] イメージングXAFSと情報処理による可視化2018

    • Author(s)
      唯 美津木
    • Organizer
      第10回岩澤コンファレンス
    • Related Report
      2018 Annual Research Report
    • Invited
  • [Presentation] 硬X線XAFSイメージングによる固体触媒材料の可視化2018

    • Author(s)
      唯 美津木
    • Organizer
      第38回表面科学会学術講演会
    • Related Report
      2018 Annual Research Report
    • Invited
  • [Presentation] 3次元XAFSイメージングによる固体触媒の可視化研究2018

    • Author(s)
      唯 美津木
    • Organizer
      SPring-8利用推進協議会GSC研究会
    • Related Report
      2018 Annual Research Report
    • Invited

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Published: 2018-04-23   Modified: 2022-01-27  

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