| Budget Amount *help |
¥17,680,000 (Direct Cost: ¥13,600,000、Indirect Cost: ¥4,080,000)
Fiscal Year 2021: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2020: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2019: ¥7,150,000 (Direct Cost: ¥5,500,000、Indirect Cost: ¥1,650,000)
Fiscal Year 2018: ¥7,930,000 (Direct Cost: ¥6,100,000、Indirect Cost: ¥1,830,000)
|
|---|
| Outline of Final Research Achievements |
In order to develop organic devices such as organic field effect transistors responding to the application of magnetic field or irradiation of circularly polarized light, new molecular conductors with paramagnetic metal ions and chiral luminescent metal complexes were synthesized. As for the organic magnetic semiconductors, TTF-metal complexes with Schiff base type coordination sites were prepared. Details of the interaction between electron conduction and magnetic properties of Cu(II) complexes with Schiff base type TTF-ligands were investigated by SQUID and ESR measurements, and theoretical calculations. TTF-metal complexes with delocalized pi-conjugation between TTF and metal coordination site exhibited relatively high electron conduction.
New Pt complex with axially chiral ligands showed circularly polarized phosphorescence in the thin film state. We also succeeded in development of apparatus for simultaneous measurements of both right and left handed circularly polarized lights.
|
