| Budget Amount *help |
¥17,680,000 (Direct Cost: ¥13,600,000、Indirect Cost: ¥4,080,000)
Fiscal Year 2020: ¥2,730,000 (Direct Cost: ¥2,100,000、Indirect Cost: ¥630,000)
Fiscal Year 2019: ¥5,980,000 (Direct Cost: ¥4,600,000、Indirect Cost: ¥1,380,000)
Fiscal Year 2018: ¥8,970,000 (Direct Cost: ¥6,900,000、Indirect Cost: ¥2,070,000)
|
|---|
| Outline of Final Research Achievements |
Triphenoxylbenzen-baseed ligands built metal complexes of group 13 elements, such as boron or aluminum (cage-shaped metal complexes). It acted as an effective catalystic reactions; 1) selective recognition of aromatic compounds over aliphatic ones, 2) stereoselective glycosylation, 3) catalytic glycosylation of fluorinated sugar, 4) machine-learining based design of catalyst for selective reactions, 5) activation of catalytic ability by irradiation of UV or visible light. The cage-shaped metal complexes were tuned by many factors for precise control of Lewis acidity and catalytic activity. These characteristic feature enabled the complex to be an effective catalyst and expected to be an other types of reaction systems.
|
