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Construction of coordination network with a concerted active space

Research Project

Project/Area Number 18H01991
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Review Section Basic Section 34010:Inorganic/coordination chemistry-related
Research InstitutionTokyo Institute of Technology

Principal Investigator

Kawano Masaki  東京工業大学, 理学院, 教授 (30247217)

Co-Investigator(Kenkyū-buntansha) 大津 博義  東京工業大学, 理学院, 助教 (10547087)
Project Period (FY) 2018-04-01 – 2021-03-31
Project Status Completed (Fiscal Year 2020)
Budget Amount *help
¥17,550,000 (Direct Cost: ¥13,500,000、Indirect Cost: ¥4,050,000)
Fiscal Year 2020: ¥4,550,000 (Direct Cost: ¥3,500,000、Indirect Cost: ¥1,050,000)
Fiscal Year 2019: ¥4,680,000 (Direct Cost: ¥3,600,000、Indirect Cost: ¥1,080,000)
Fiscal Year 2018: ¥8,320,000 (Direct Cost: ¥6,400,000、Indirect Cost: ¥1,920,000)
Keywords配位高分子 / 結晶化学 / X線構造解析 / オレフィンの分離 / 協奏的反応空間
Outline of Final Research Achievements

C3-symmetric ligands were prepared by replacement of one coordination site of this methane-type ligand with another functional group such as a hydroxyl group. Self-assembly of cubane-type copper iodide with a methane-type tetradentate ligand and the C3-symmetric ligand produced a mixed-ligand coordination network in which the C3 symmetric ligand was partially replaced with the methane-type ligand. At the substituted site, a labile water was coordinated instead of pyridine and hydrogen-bonded to the hydroxyl group of the C3 ligand. Therefore, the ability for selective encapsulation of guest was examined using various alkanes and olefins. For example, when competitive encapsulation behavior was investigated using hexane and 1-hexene, the coordination network containing C3 symmetric ligands had 1.5 times higher olefin selectivity than the coordination network composed of methane-type ligands.

Academic Significance and Societal Importance of the Research Achievements

配位子の一部が違う官能基で修飾された配位子を混合することによりその比率が比較的小さい時には速度論的自己集合により基本となるネットワーク骨格を保持しながら複数の配位子が共存した細孔が修飾されたネットワーク錯体を構築できることを実証した。その構造は元の構造と比べると不安定であり準安定な構造であるが、一度溶液から単離すると応用研究が可能な十分な安定性がある。この事実は、あるネットワーク錯体の細孔を機能化したいときに簡便で実利的方法であり、様々な応用が可能な設計性の高い材料である。これは配位結合が速度論的に置換活性でありかつ比較的強い結合だからである。

Report

(4 results)
  • 2020 Annual Research Report   Final Research Report ( PDF )
  • 2019 Annual Research Report
  • 2018 Annual Research Report
  • Research Products

    (77 results)

All 2021 2020 2019 2018 Other

All Int'l Joint Research (3 results) Journal Article (22 results) (of which Int'l Joint Research: 22 results,  Peer Reviewed: 22 results,  Open Access: 22 results) Presentation (51 results) (of which Int'l Joint Research: 14 results,  Invited: 7 results) Patent(Industrial Property Rights) (1 results)

  • [Int'l Joint Research] POSTECH(韓国)

    • Related Report
      2020 Annual Research Report
  • [Int'l Joint Research] POSTECH(韓国)

    • Related Report
      2019 Annual Research Report
  • [Int'l Joint Research] POSTECH/浦項工科大学(PAL)(韓国)

    • Related Report
      2018 Annual Research Report
  • [Journal Article] Pyridinium modification of a hexaazaphenalene skeleton: structure and spectroelectrochemical analysis2020

    • Author(s)
      Deekamwong Krittanun、Usov Pavel M.、Ohtsu Hiroyoshi、Kawano Masaki
    • Journal Title

      CrystEngComm

      Volume: 22 Issue: 36 Pages: 5987-5994

    • DOI

      10.1039/d0ce00850h

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Kinetic Assembly of Porous Coordination Networks Leads to Trapping Unstable Elemental Allotropes2020

    • Author(s)
      Ohtsu Hiroyoshi、Usov Pavel M.、Kawano Masaki
    • Journal Title

      Advances in Organic Crystal Chemistry

      Volume: - Pages: 221-250

    • DOI

      10.1007/978-981-15-5085-0_12

    • ISBN
      9789811550843, 9789811550850
    • Related Report
      2020 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Emergence of electrical conductivity in a flexible coordination polymer by using chemical reduction2020

    • Author(s)
      Fuku Kentaro, Miyata Momoka, Takaishi Shinya, Yoshida Takefumi, Yamashita Masahiro, Hoshino Norihisa, Akutagawa Tomoyuki, Ohtsu Hiroyoshi, Kawano Masaki, Iguchi Hiroaki
    • Journal Title

      Chemical Communications

      Volume: 56 Issue: 61 Pages: 8619-8622

    • DOI

      10.1039/d0cc03062g

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Ionic-caged heterometallic bismuth?platinum complex exhibiting electrocatalytic CO2 reduction2020

    • Author(s)
      Yoshida Takefumi、Ahsan Habib Md.、Zhang Hai-Tao、Izuogu David Chukwuma、Abe Hitoshi、Ohtsu Hiroyoshi、Yamaguchi Tadashi、Breedlove Brian K.、Thom Alex J. W.、Yamashita Masahiro
    • Journal Title

      Dalton Transactions

      Volume: 49 Issue: 8 Pages: 2652-2660

    • DOI

      10.1039/c9dt04817k

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Amyloid‐like Nanofibrillation of Metal‐Organic Complex Arrays Ruled by Their Precisely Designed Metal Sequences2020

    • Author(s)
      Rajmohan Rajamani、Vrla Geoffrey、Ueki Hisanori、Sajna Kappamveettil、Takei Toshiaki、Ohtsu Hiroyoshi、Kawano Masaki、Vairaprakash Pothiappan、Tashiro Kentaro
    • Journal Title

      Chemistry Asian Journal

      Volume: 15 Issue: 6 Pages: 766-769

    • DOI

      10.1002/asia.201901674

    • Related Report
      2020 Annual Research Report 2019 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Highly Mesoporous Metal‐Organic Frameworks as Synergistic Multimodal Catalytic Platforms for Divergent Cascade Reactions2020

    • Author(s)
      Dutta Soumen、Kumari Nitee、Dubbu Sateesh、Jang Sun Woo、Kumar Amit、Ohtsu Hiroyoshi、Kim Junghoon、Cho Seung Hwan、Kawano Masaki、Lee In Su
    • Journal Title

      Angewandte Chemie International Edition

      Volume: 59 Issue: 9 Pages: 3416-3422

    • DOI

      10.1002/anie.201916578

    • Related Report
      2020 Annual Research Report 2019 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] A Diprotonated Porphyrin as an Electron Mediator in Photoinduced Electron Transfer in Hydrogen-Bonded Supramolecular Assemblies2019

    • Author(s)
      W. Suzuki, H. Kotani, T. Ishizuka, M. Kawano, H. Sakai, T. Hasobe, K. Ohkubo, S. Fukuzumi, T. Kojima
    • Journal Title

      The Journal of the Physical Chemistry C

      Volume: 123 Issue: 18 Pages: 11529-11538

    • DOI

      10.1021/acs.jpcc.9b02449

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Heterochiral Doped Supramolecular Coordination Networks for High-Performance Optoelectronics2019

    • Author(s)
      Shang Xiaobo、Song Inho、Lee Jeong Hyeon、Choi Wanuk、Ohtsu Hiroyoshi、Jung Gwan Yeong、Ahn Jaeyong、Han Myeonggeun、Koo Jin Young、Kawano Masaki、Kwak Sang Kyu、Oh Joon Hak
    • Journal Title

      ACS Applied Materials & Interfaces

      Volume: NA Issue: 22 Pages: 20174-20182

    • DOI

      10.1021/acsami.9b04653

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Solid-Gas Phase Synthesis of Coordination Networks by Using Redox‐Active Ligands and Elucidation of Their Oxidation Reaction2019

    • Author(s)
      Den Taizen、Usov Pavel M.、Kim Jaejun、Hashizume Daisuke、Ohtsu Hiroyoshi、Kawano Masaki
    • Journal Title

      Chemistry - A European Journal

      Volume: 25 Issue: 49 Pages: 11512-11520

    • DOI

      10.1002/chem.201902105

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Do Anionic π Molecules Aggregate in Solution? A Case Study with Multi‐interactive Ligands and Network Formation2019

    • Author(s)
      Nakanishi Keisuke、Ohtsu Hiroyoshi、Fukuhara Gaku、Kawano Masaki
    • Journal Title

      Chemistry - A European Journal

      Volume: 25 Issue: 66 Pages: 15182-15188

    • DOI

      10.1002/chem.201903764

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Control of anisotropy of a redox-active molecule-based film leads to non-volatile resistive switching memory2019

    • Author(s)
      Kim Jaejun、Ohtsu Hiroyoshi、Den Taizen、Deekamwong Krittanun、Muneta Iriya、Kawano Masaki
    • Journal Title

      Chemical Science

      Volume: 10 Issue: 47 Pages: 10888-10893

    • DOI

      10.1039/c9sc04213j

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Consecutive oxidative additions of iodine on undulating 2D coordination polymers: Formation of I-Pt-I chains and inhomogeneous layers2019

    • Author(s)
      Ryo Ohtani, Riho Yamamoto, Hiroyoshi Ohtsu, Masaki Kawano, Jenny Pirillo, Yuh Hijikata, Masaaki Sadakiyo, Leonard F. Lindoye, and Shinya Hayami
    • Journal Title

      Dalton Transactions

      Volume: 印刷中 Issue: 21 Pages: 7198-7202

    • DOI

      10.1039/c8dt04624g

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] An Organic Mixed-Valence Ligand for Multistate Redox-Active Coordination Networks2018

    • Author(s)
      Ha Joo Yeon、Koo Jin Young、Ohtsu Hiroyoshi、Yakiyama Yumi、Kim Kimoon、Hashizume Daisuke、Kawano Masaki
    • Journal Title

      Angewandte Chemie International Edition

      Volume: 57 Issue: 17 Pages: 4717-4721

    • DOI

      10.1002/anie.201713035

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Spectroscopic, Electronic and Computational Properties of a Mixed Tetrachalcogenafulvalene and its Charge Transfer Complex2018

    • Author(s)
      Walwyn, R. J.; Chan, B.; Usov, P. M.; Solomon, M. B.; Duyker, S. G.; Koo, J. Y.; Kawano, M.; Turner, P.; Kepert, C. J.; D'Alessandro, D. M.
    • Journal Title

      J. Mater. Chem. C

      Volume: 6 Issue: 5 Pages: 1092-1104

    • DOI

      10.1039/c7tc03853d

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Tris(2-hydroxyphenyl)triazasumanene: bowl-shaped excited-state intramolecular proton transfer (ESIPT) fluorophore coupled with aggregation-induced enhanced emission (AIEE)2018

    • Author(s)
      Kaewmati Patcharin、Yakiyama Yumi、Ohtsu Hiroyoshi、Kawano Masaki、Haesuwannakij Setsiri、Higashibayashi Shuhei、Sakurai Hidehiro
    • Journal Title

      Materials Chemistry Frontiers

      Volume: 2 Issue: 3 Pages: 514-519

    • DOI

      10.1039/c7qm00530j

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Intermediate-Spin Iron(III) Complexes Having a Redox-Noninnocent Macrocyclic Tetraamido Ligand2018

    • Author(s)
      Kojima Takahiko、Ogishima Fumiya、Nishibu Takahisa、Kotani Hiroaki、Ishizuka Tomoya、Okajima Toshihiro、Nozawa Shunsuke、Shiota Yoshihito、Yoshizawa Kazunari、Ohtsu Hiroyoshi、Kawano Masaki、Shiga Takuya、Oshio Hiroki
    • Journal Title

      Inorganic Chemistry

      Volume: NA Issue: 16 Pages: 9683-9695

    • DOI

      10.1021/acs.inorgchem.8b00037

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Stepwise Synthesis via Mechanochemical Reaction for Multistate Redox-active 2D Zinc(II) Coordination Network2018

    • Author(s)
      Ha Joo Yeon、Deekamwong Krittanun、Ohtsu Hiroyoshi、Kim Kimoon、Hashizume Daisuke、Kawano Masaki
    • Journal Title

      Chemistry Letters

      Volume: 47 Issue: 9 Pages: 1184-1186

    • DOI

      10.1246/cl.180546

    • NAID

      130007472129

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Dearomative oxidative rearrangement of [3]cyclo-1,8-carbazolylene2018

    • Author(s)
      Yasui Masamichi, Kengo Hanaya, Takeshi Sugai, Shuhei Higashibayashi
    • Journal Title

      Chem. Lett.

      Volume: 47 Issue: 11 Pages: 95-96

    • DOI

      10.1246/cl.180637

    • NAID

      130007504955

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Chiral self-sorted multifunctional supramolecular biocoordination polymers and their applications in sensors2018

    • Author(s)
      Shang Xiaobo、Song Inho、Jung Gwan Yeong、Choi Wanuk、Ohtsu Hiroyoshi、Lee Jeong Hyeon、Koo Jin Young、Liu Bo、Ahn Jaeyong、Kawano Masaki、Kwak Sang Kyu、Oh Joon Hak
    • Journal Title

      Nature Communications

      Volume: 9 Issue: 1 Pages: 3933-3933

    • DOI

      10.1038/s41467-018-06147-8

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Platinum(II) Terpyridine Complex That Switches Its Photochemical Reactivity in Response to Its Chromic Behavior in the Crystalline State2018

    • Author(s)
      Tashiro Kentaro、Ohtsu Hiroyoshi、Kawano Masaki、Kojima Tatsuhiro、Kato Tatsuhisa
    • Journal Title

      Inorganic Chemistry

      Volume: 57 Issue: 21 Pages: 13079-13082

    • DOI

      10.1021/acs.inorgchem.8b02400

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Synthesis of Re(I) Rings Comprising Different Re(I) Units and Their Light-Harvesting Abilities2018

    • Author(s)
      Yamazaki Yasuomi、Rohacova Jana、Ohtsu Hiroyoshi、Kawano Masaki、Ishitani Osamu
    • Journal Title

      Inorganic Chemistry

      Volume: 57 Issue: 24 Pages: 15158-15171

    • DOI

      10.1021/acs.inorgchem.8b02421

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Triazasumanene: An Isoelectronic Heteroanalogue of Sumanene2018

    • Author(s)
      Tan Qitao、Kaewmati Patcharin、Higashibayashi Shuhei、Kawano Masaki、Yakiyama Yumi、Sakurai Hidehiro
    • Journal Title

      Bulletin of the Chemical Society of Japan

      Volume: 91 Issue: 4 Pages: 531-537

    • DOI

      10.1246/bcsj.20170384

    • NAID

      130006707614

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Presentation] 多点相互作用性配位子を用いた巨大細孔を有する細孔性ネットワーク錯体の構造と中分子の包接挙動2021

    • Author(s)
      古野 那菜、和田 雄貴、大津 博義、河野 正規
    • Organizer
      日本化学会 第101春季年会
    • Related Report
      2020 Annual Research Report
  • [Presentation] アルキル鎖を有するジアザフェナレン誘導体の合成及び物性評価2021

    • Author(s)
      小名 健介、大津 博義、河野 正規
    • Organizer
      日本化学会 第101春季年会
    • Related Report
      2020 Annual Research Report
  • [Presentation] ネットワーク錯体における空間を介した電荷移動相互作用の解明2021

    • Author(s)
      奥山 万理恵、大津 博義、河野 正規
    • Organizer
      日本化学会 第101春季年会
    • Related Report
      2020 Annual Research Report
  • [Presentation] ピリジン置換ジアザフェナレン誘導体の合成と物性評価2021

    • Author(s)
      淺田 七海、Pavel Usov、大津 博義、河野 正規
    • Organizer
      日本化学会 第101春季年会
    • Related Report
      2020 Annual Research Report
  • [Presentation] Kinetic assembly of flexible porous coordination networks and iodine adsorption behavior2021

    • Author(s)
      Kim Joonsik,Hiroyoshi Ohtsu,Tatsuya Kanamaru,Daisuke Hashizume, Masaki Kawano
    • Organizer
      日本化学会 第101春季年会
    • Related Report
      2020 Annual Research Report
  • [Presentation] π-π stacking aggregation of anionic ligands, the photophysical properties, and the application to network formation2021

    • Author(s)
      河野正規
    • Organizer
      第70回錯体化学討論会
    • Related Report
      2020 Annual Research Report
    • Invited
  • [Presentation] 芳香環窒素原子に局在化したn軌道のホストーゲスト分子間相互作用2020

    • Author(s)
      和田雄貴、大津博義、河野正規
    • Organizer
      日本結晶学会 70周年記念大会
    • Related Report
      2020 Annual Research Report
  • [Presentation] 相互作用性細孔を有するネットワーク錯体の速度論的創製と ヨウ素吸着挙動2020

    • Author(s)
      大津博義、金丸達也、Kim Joonsik、河野正規
    • Organizer
      日本結晶学会 70周年記念大会
    • Related Report
      2020 Annual Research Report
  • [Presentation] A series of pyridyl-functionalized diazaphenalenes for the construction of electroactive materials2020

    • Author(s)
      ○Nanami Asada,Pavel Usov, Hiroyoshi Ohtsu, Masaki Kawano
    • Organizer
      日本化学会第100春季年会2020
    • Related Report
      2019 Annual Research Report
  • [Presentation] Utilization of Isocyanide-based Ligands for the Construction of Conductive Coordination Frameworks2020

    • Author(s)
      ○Pavel Usov, Hiroyoshi Ohtsu, Masaki Kawano
    • Organizer
      日本化学会第100春季年会2020
    • Related Report
      2019 Annual Research Report
  • [Presentation] Kinetic assembly of porous coordination networks with CuI units and their application to alkane / alkene separation2020

    • Author(s)
      ○Tatsuya Kanamaru, Hiroyoshi Ohtsu, Masaki Kawano
    • Organizer
      日本化学会第100春季年会2020
    • Related Report
      2019 Annual Research Report
  • [Presentation] Multi-interactive hexaazaphenalene-based pyridinium ligands and their incorporation into coordination networks2020

    • Author(s)
      ○Krittanun Deekamwong, Hiroyoshi Ohtsu, Masaki Kawano
    • Organizer
      日本化学会第100春季年会2020
    • Related Report
      2019 Annual Research Report
  • [Presentation] Synthesis of coordination networks with multi-interactive ligands and their applications2020

    • Author(s)
      ○Yuki Wada, Hiroyoshi Ohtsu, Masaki Kaawano
    • Organizer
      日本化学会第100春季年会2020
    • Related Report
      2019 Annual Research Report
  • [Presentation] Kinetic Assembly Of Porous Coordination Networks2019

    • Author(s)
      河野 正規
    • Organizer
      JSPS A3プログラム 第2回日中韓フォーサイトセミナー
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Control of anisotropy of redox-active molecule-based film leads to non-volatile resistive switching memory2019

    • Author(s)
      河野 正規
    • Organizer
      AsCA2019
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 柔軟なTd対称配位子を用いた細孔性ネットワーク錯体の速度論的合成2019

    • Author(s)
      ○金丸達也, 大津博義, 河野正規
    • Organizer
      錯体化学会 第69回討論会
    • Related Report
      2019 Annual Research Report
  • [Presentation] Emissive network formation from kinetically assembled CuBr network2019

    • Author(s)
      ○Marie Okuyama, Hiroyoshi Ohtsu, Masaki Kawano
    • Organizer
      錯体化学会 第69回討論会
    • Related Report
      2019 Annual Research Report
  • [Presentation] Utilization of Isocyanide-based Ligands for the Construction of Conductive Coordination Frameworks2019

    • Author(s)
      ○Pavel Usov, Hiroyoshi Ohtsu, Masaki Kawano
    • Organizer
      錯体化学会 第69回討論会
    • Related Report
      2019 Annual Research Report
  • [Presentation] Photoactive hexaazaphenalene ligand-based frameworks and its applications2019

    • Author(s)
      ○Krittanun Deekamwong, Nakanishi Keisuke, Ohtsu Hiroyoshi , Kawano Masaki
    • Organizer
      錯体化学会 第69回討論会
    • Related Report
      2019 Annual Research Report
  • [Presentation] Kinetic Assembly of Porous Coordination Networks utilizing Labile Cu-Halide Clusters2019

    • Author(s)
      ○Hiroyoshi Ohtsu, Miho Takakusagi, Tatsuya Kanamaru, Marie Okuyama, Masaki Kawano
    • Organizer
      7th Asian Conference on Coordination Chemistry (ACCC7)
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Multi-interactive hexaazaphenalene-based pyridinium ligands and their incorporation into coordination networks2019

    • Author(s)
      ○Krittanun Deekamwong, Pavel M. Usov, Hiroyoshi Ohtsu, Masaki Kawano
    • Organizer
      7th Asian Conference on Coordination Chemistry (ACCC7)
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Synthesis of coordination networks by controlling multi-interactive ligands and their applications2019

    • Author(s)
      ○Yuki Wada, Hiroyoshi Ohtsu, Masaki Kawano
    • Organizer
      錯体化学会 第69回討論会
    • Related Report
      2019 Annual Research Report
  • [Presentation] Multi-interactive molecules/MOFs for device applications2019

    • Author(s)
      ○Yuki Wada, Hiroyoshi Ohtsu, Masaki Kawano
    • Organizer
      JSPS A3プログラム 第2回日中韓フォーサイトセミナー
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Versatile solution states of a multi-interactive ligand lead to wide variety of porous coordination networks2019

    • Author(s)
      ○Hiroyoshi Ohtsu, Keisuke Nakanishi, Nozumu Odagawa, Gaku Fukuhara, Masaki Kawano
    • Organizer
      CEMSupra
    • Related Report
      2019 Annual Research Report
  • [Presentation] Utilization of Isocyanide-based Ligands for the Construction of Conductive Coordination Frameworks2019

    • Author(s)
      ○Pavel Usov, Hiroyoshi Ohtsu, Masaki Kawano
    • Organizer
      CEMSupra
    • Related Report
      2019 Annual Research Report
  • [Presentation] Multi-interactive hexaazaphenalene-based pyridinium ligands and their incorporation into coordination networks2019

    • Author(s)
      ○Krittanun Deekamwong, Pavel Usov, Hiroyoshi Ohtsu, Masaki Kawano
    • Organizer
      CEMSupra
    • Related Report
      2019 Annual Research Report
  • [Presentation] Synthesis of coordination networks by controlling multi-interactive ligands and their applications2019

    • Author(s)
      ○Yuki Wada, Hiroyoshi Ohtsu, Masaki Kawano
    • Organizer
      CEMSupra
    • Related Report
      2019 Annual Research Report
  • [Presentation] Kinetic assembly of porous coordination networks using Td-symmetry ligands2019

    • Author(s)
      ○Tatsuya Kanamaru, Hiroyoshi Ohtsu, Masaki Kawano
    • Organizer
      CEMSupra
    • Related Report
      2019 Annual Research Report
  • [Presentation] Emissive network formation from kinetically assembled CuBr network2019

    • Author(s)
      ○Marie Okuyama, Hiroyoshi Ohtsu, Masaki Kawano
    • Organizer
      CEMSupra
    • Related Report
      2019 Annual Research Report
  • [Presentation] Photophysical properties of a multi-interactive ligand and syntheses of coordination networks by ligand aggregation2019

    • Author(s)
      〇NAKANISHI Keisuke, OHTSU Hiroyoshi, FUKUHARA Gaku, KAWANO Masaki
    • Organizer
      日本化学会 第99春季年会
    • Related Report
      2018 Annual Research Report
  • [Presentation] Kinetic assembly of porous coordination networks2018

    • Author(s)
      河野正規
    • Organizer
      43rd International Conference on Coordination Chemistry(ICCC2018)
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Kinetic assembly of porous coordination networks2018

    • Author(s)
      河野正規
    • Organizer
      Impressions of the Second Japan-Dresden Symposium 2018 (iJaDe2018)
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Kinetic assembly of porous coordination networks2018

    • Author(s)
      河野正規
    • Organizer
      Asian Crystallographic Association (AsCA2018)
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] The synthesis of porous coordination networks using a multi interactive ligand2018

    • Author(s)
      〇小田川 望, 大津博義, 河野 正規
    • Organizer
      錯体化学会 第67回討論会
    • Related Report
      2018 Annual Research Report
  • [Presentation] Syntheses of Coordination Networks with a Redox-Active Ligand2018

    • Author(s)
      〇田 泰然, Kim Jaejun, 大津 博義, 河野 正規
    • Organizer
      錯体化学会 第67回討論会
    • Related Report
      2018 Annual Research Report
  • [Presentation] Kinetic Assembly of Porous Coordination Networks Using C3-symmetric Ligands2018

    • Author(s)
      〇高草木 美穂, 大津 博義, 河野 正規
    • Organizer
      錯体化学会 第67回討論会
    • Related Report
      2018 Annual Research Report
  • [Presentation] Kinetic synthesis of porous coordination networks using Td-symmetry ligands2018

    • Author(s)
      〇Tatsuya Kanamaru, Masaki Kawano, Hiroyoshi Ohtsu
    • Organizer
      錯体化学会 第68回討論会
    • Related Report
      2018 Annual Research Report
  • [Presentation] Symmetric control of multi-interactive ligands for coordination network formation2018

    • Author(s)
      〇Yuuki Wada, Masaki Kawano, Hiroyoshi Ohtsu
    • Organizer
      錯体化学会 第68回討論会
    • Related Report
      2018 Annual Research Report
  • [Presentation] Kinetic Assembly of Cooperative Porous Coordination Networks Using C3-symmetric Ligands2018

    • Author(s)
      〇Miho Takakusagi, Hiroyoshi Ohtsu, Masaki Kawano
    • Organizer
      錯体化学会 第68回討論会
    • Related Report
      2018 Annual Research Report
  • [Presentation] Zinc Iodide-based redox active coordination networks2018

    • Author(s)
      〇Taizen Den, Jaejun Kim, Hiroyoshi Ohtsu, Masaki Kawano
    • Organizer
      43rd International Conference on Coordination Chemistry(ICCC2018)
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Kinetic Assembly of Cooperative Porous Coordination Networks Using C3-symmetric Ligands2018

    • Author(s)
      〇Miho Takakusagi, Hiroyoshi OHTSU, Masaki KAWANO
    • Organizer
      43rd International Conference on Coordination Chemistry(ICCC2018)
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Channel opening of columnar coordination network for detection of polycyclic aromatic hydrocarbons2018

    • Author(s)
      〇Jaejun Kim, Masaki Kawano*
    • Organizer
      122nd Korean Chemical Society(KCS) General meeting
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Multi-carboxylic acids as co-ligands to extend voids in the structure of zinc and TPHAP coordination2018

    • Author(s)
      〇Krittanun Deekamwong, Hiroyoshi Ohtsu, Masaki Kawano*
    • Organizer
      122nd Korean Chemical Society(KCS) General meeting
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 多点相互作用配位子の置換基制御によるネットワーク錯体合成?2018

    • Author(s)
      〇和田雄貴, 大津博義, 河野正規
    • Organizer
      日本結晶学会 2018年度年会および総会(CrSJ2018)
    • Related Report
      2018 Annual Research Report
  • [Presentation] Td対称配位子とCuIクラスターを有する細孔性ネットワーク錯体の速度論的生成2018

    • Author(s)
      〇金丸達也, 大津博義, 河野正規
    • Organizer
      日本結晶学会 2018年度年会および総会(CrSJ2018)
    • Related Report
      2018 Annual Research Report
  • [Presentation] Multi-carboxylic acids as co-ligands to extend voids in the structure of cadmium and TPHAP coordination system2018

    • Author(s)
      ◯Krittanun Deekamwong, Hiroyoshi Ohtsu, Masaki Kawano
    • Organizer
      日本結晶学会 2018年度年会および総会(CrSJ2018)
    • Related Report
      2018 Annual Research Report
  • [Presentation] Chemiresistive Sensor based on Redox-active Porous Coordination Networks2018

    • Author(s)
      〇Jaejun Kim, Jin Young Koo, Hojeong Yu, 焼山佑美, 小島達弘, 大津博義, Joon Hak Oh, 河野正規
    • Organizer
      錯体化学会 第66回討論会
    • Related Report
      2018 Annual Research Report
  • [Presentation] Zinc Iodide-based redox active coordination networks2018

    • Author(s)
      〇Taizen Den, Jaejun Kim, Hiroyoshi Ohtsu, Masaki Kawano
    • Organizer
      錯体化学会 第68回討論会
    • Related Report
      2018 Annual Research Report
  • [Presentation] The synthesis of Porous Coordination Networks using a Multi-interactive Ligand2018

    • Author(s)
      〇Nozomu Odagawa, Hiroyoshi OHTSU, Masaki KAWANO
    • Organizer
      43rd International Conference on Coordination Chemistry(ICCC2018)
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Design of an Organic Mixed-Valence Ligand for Multistate Redox-Active Porous Coordination Networks2018

    • Author(s)
      〇J. Y. Ha, D. Hashizume, M. Kawano
    • Organizer
      43rd International Conference on Coordination Chemistry(ICCC2018)
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Utilization of Isocyanide-Based Ligands for the Construction of Conductive Metal-Organic Frameworks2018

    • Author(s)
      〇Pavel Usov, Masaki Kawano
    • Organizer
      Metal-Organic Frameworks (MOF2018)
    • Related Report
      2018 Annual Research Report
  • [Patent(Industrial Property Rights)] 細孔性ネットワーク錯体、結晶構造解析用資料の作成方法及び分子構造決定方法2018

    • Inventor(s)
      河野正規、大津博義
    • Industrial Property Rights Holder
      河野正規、大津博義
    • Industrial Property Rights Type
      特許
    • Filing Date
      2018
    • Related Report
      2018 Annual Research Report

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Published: 2018-04-23   Modified: 2022-12-28  

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