| Budget Amount *help |
¥17,160,000 (Direct Cost: ¥13,200,000、Indirect Cost: ¥3,960,000)
Fiscal Year 2021: ¥4,160,000 (Direct Cost: ¥3,200,000、Indirect Cost: ¥960,000)
Fiscal Year 2020: ¥4,160,000 (Direct Cost: ¥3,200,000、Indirect Cost: ¥960,000)
Fiscal Year 2019: ¥4,160,000 (Direct Cost: ¥3,200,000、Indirect Cost: ¥960,000)
Fiscal Year 2018: ¥4,680,000 (Direct Cost: ¥3,600,000、Indirect Cost: ¥1,080,000)
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| Outline of Final Research Achievements |
Here we studied the synthesis of multinuclear complexes consisting of both transition metal ions as an electron-rich redox-active center and alkali metal ions as a Lewis acid. Such complexes can act as a bifunctional system capable of strongly polarizing substrates, thereby achieving activation small molecules such as dinitrogen and carbon dioxide. For example, the Ti-K complex prepared by the reaction of the titanium precursor with a potassium reagent is found to promote the coupling of dinitrogen and carbon dioxide via N-C bond formation, yielding hydrazide derivatives.
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