| Budget Amount *help |
¥17,160,000 (Direct Cost: ¥13,200,000、Indirect Cost: ¥3,960,000)
Fiscal Year 2020: ¥5,720,000 (Direct Cost: ¥4,400,000、Indirect Cost: ¥1,320,000)
Fiscal Year 2019: ¥5,720,000 (Direct Cost: ¥4,400,000、Indirect Cost: ¥1,320,000)
Fiscal Year 2018: ¥5,720,000 (Direct Cost: ¥4,400,000、Indirect Cost: ¥1,320,000)
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| Outline of Final Research Achievements |
In this project, we aimed at developing the chemistry of molecular sandwich clusters and rice-ball clusters. We found that polycyclic aromatic compounds or hetero-arenes can be introduced at a cluster-site of a cycloheptatriene-supported metal cluster. We also found that a metal-metal edge bonds in a cyclononatetraenyl sandwich cluster provide a ligand-unsupported docking site for extra metal moieties. Furthermore, we successfully isolated and characterized the rice-ball Pd13 clusters by using cycloheptatrienyl ligands.
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