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Highly functional bipolar electrochemical devices with high performance

Research Project

Project/Area Number 18H02001
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Review Section Basic Section 34020:Analytical chemistry-related
Research InstitutionUniversity of Tsukuba

Principal Investigator

Suzuki Hiroaki  筑波大学, 数理物質系, 教授 (20282337)

Project Period (FY) 2018-04-01 – 2021-03-31
Project Status Completed (Fiscal Year 2020)
Budget Amount *help
¥17,550,000 (Direct Cost: ¥13,500,000、Indirect Cost: ¥4,050,000)
Fiscal Year 2020: ¥3,640,000 (Direct Cost: ¥2,800,000、Indirect Cost: ¥840,000)
Fiscal Year 2019: ¥3,510,000 (Direct Cost: ¥2,700,000、Indirect Cost: ¥810,000)
Fiscal Year 2018: ¥10,400,000 (Direct Cost: ¥8,000,000、Indirect Cost: ¥2,400,000)
Keywordsバイポーラ電気化学 / 銀/塩化銀 / イオン感応膜 / 金属接続 / クーロメトリー / マイクロフルイディクス / 電位制御 / 電気化学発光 / 3電極系 / レドックスサイクリング / バイオセンシング / 非分極性電極 / 金属置換
Outline of Final Research Achievements

Bipolar electrochemistry is a new electrochemical technique that features generation of potential difference between a solution and electrically isolated electrodes (bipolar electrode) that are not connected to any external instruments. By forming Ag/AgCl or an ion-selective membrane on a part of the bipolar electrodes, the interfacial potential differences of the parts were fixed and redox reactions on both poles could be controlled. The technique was also used to connect solutions in microfabricated electrochemical systems using metal connections, which can be a basis in creating more advanced integrated electrochemical microfluidic devices. The metal connection was also effective in improving the sensitivity of a coulometric device that features detection of silver deposited accompanying the oxidation of an analyte.

Academic Significance and Societal Importance of the Research Achievements

従来の3電極系と比べ、バイポーラ電気化学系は多数の分子の一括同時検出に有利であるが、その基本的挙動については未知のところが多かった。本研究では、従来の研究から一歩踏み込んで、バイポーラ電極の挙動をより詳細に解析し、これまで知られていなかった性質を明らかにした。本研究では、電気的に浮いたバイポーラ電極上の界面電位制御を試みたが、これは検出感度の向上等、バイポーラ系の高性能化に有利である。また、この研究を通じて、従来の液絡接続に代わる金属接続という手法が新たに生み出されたが、これは高度な電気化学/マイクロフルイディクデバイスを構築する上での基盤となりうる。

Report

(4 results)
  • 2020 Annual Research Report   Final Research Report ( PDF )
  • 2019 Annual Research Report
  • 2018 Annual Research Report
  • Research Products

    (14 results)

All 2021 2020 2019

All Journal Article (2 results) (of which Int'l Joint Research: 1 results,  Peer Reviewed: 2 results) Presentation (12 results)

  • [Journal Article] Microfabricated electrochemical sensing devices2020

    • Author(s)
      F. Sassa, G. C. Biswas, and H. Suzuki
    • Journal Title

      Lab Chip

      Volume: 20 Issue: 8 Pages: 1358-1389

    • DOI

      10.1039/c9lc01112a

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Active junctions to improve sensitivity and detection limit of a microdevice based on coulometry coupled with silver metallization2019

    • Author(s)
      I. Anshori, S. Takie, and H. Suzuki
    • Journal Title

      Electrianalysis

      Volume: 31 Issue: 9 Pages: 1630-1634

    • DOI

      10.1002/elan.201800825

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Presentation] バイポーラ電極アレイによる化学イメージング2021

    • Author(s)
      薛安汝, Nurul Asyikeen Ab Mutalib, 鄧懿, 鈴木博章
    • Organizer
      令和3年 電気学会全国大会
    • Related Report
      2020 Annual Research Report
  • [Presentation] Control of Interfacial Potentials on Bipolar Electrodes Using Ion-Selective Membranes2021

    • Author(s)
      Nurul Asyikeen Ab Mutalib, Yi Deng, An-Ju Hsueh, and Hiroaki Suzuki
    • Organizer
      2021年 電気化学会第88回大会(第68回化学センサ研究発表会)
    • Related Report
      2020 Annual Research Report
  • [Presentation] Control of Reactions on Bipolar Electrodes Using Ion-Selective Membrane2020

    • Author(s)
      Nurul Asyikeen Ab Mutalib, Ken Tsuyuki, Chia-Chien Wu, Hiroaki Suzuki
    • Organizer
      18th International Meeting on Chemical Sensors
    • Related Report
      2020 Annual Research Report
  • [Presentation] Microfluidic devices using electrochemical micropumps and microvalves for autonomous solution processing2020

    • Author(s)
      Chengrui Ma, Hiroaki Suzuki
    • Organizer
      PRiME 2020
    • Related Report
      2020 Annual Research Report
  • [Presentation] Control of Reactions on Bipolar Electrodes Using Ion-Selective Membranes2020

    • Author(s)
      Nurul Asyikeen Ab Mutalib, Chia-Chien Wu, Ken Tsuyuki, Hiroaki Suzuki
    • Organizer
      PRiME 2020
    • Related Report
      2020 Annual Research Report
  • [Presentation] イオン選択性膜によるバイポーラ電極上での 反応制御2020

    • Author(s)
      Chia-Chien Wu,Nurul Asyikeen Ab Mutalib,露木健、鈴木博章
    • Organizer
      令和2年電気学会全国大会
    • Related Report
      2019 Annual Research Report
  • [Presentation] 微小電気化学デバイスにおける金属接続の効果2019

    • Author(s)
      佐藤優成,假屋洸希,栗原寿明,鈴木博章
    • Organizer
      第36回「センサ・マイクロマシンと応用システム」シンポジウム
    • Related Report
      2019 Annual Research Report
  • [Presentation] Control of the Potential on Bipolar Electrodes for Mutiplexed Detection2019

    • Author(s)
      Nurul Asyikeen Ab Mutalib,Koki Kariya,Toshiaki Kurihara, and Hiroaki Suzuki
    • Organizer
      第36回「センサ・マイクロマシンと応用システム」シンポジウム
    • Related Report
      2019 Annual Research Report
  • [Presentation] 金属接続された微小3電極系の挙動2019

    • Author(s)
      佐藤優成、假屋洸希、栗原寿明、鈴木博章
    • Organizer
      令和元年度E部門総合研究会
    • Related Report
      2019 Annual Research Report
  • [Presentation] 銀/塩化銀によるバイポーラ電気化学系における電位制御2019

    • Author(s)
      ヌル アシキン アブ ムタリブ
    • Organizer
      2019年電気化学会第86回大会
    • Related Report
      2018 Annual Research Report
  • [Presentation] 金属接続微小3電極系における参照極の分離2019

    • Author(s)
      佐藤優成
    • Organizer
      2019年電気化学会第86回大会
    • Related Report
      2018 Annual Research Report
  • [Presentation] 銀/塩化銀によるバイポーラ電極の電位制御2019

    • Author(s)
      ヌル アシキン アブ ムタリブ
    • Organizer
      平成31年電気学会全国大会
    • Related Report
      2018 Annual Research Report

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Published: 2018-04-23   Modified: 2022-01-27  

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