| Budget Amount *help |
¥14,040,000 (Direct Cost: ¥10,800,000、Indirect Cost: ¥3,240,000)
Fiscal Year 2022: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
Fiscal Year 2021: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
Fiscal Year 2020: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2019: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2018: ¥7,800,000 (Direct Cost: ¥6,000,000、Indirect Cost: ¥1,800,000)
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| Outline of Final Research Achievements |
The synthesis of organophosphine-organic/inorganic-polymer hybrid polymers with various structures has been established using P-C cross-coupling polymerization. Water-soluble polymer catalysts and novel materials with self-healing properties were developed by the application of the synthesized hybrid polymers, especially on complexation with transition metals. The P=S-polymer-Pd sub-nanoparticle catalysts have been shown to exhibit unique selectivity. In addition, many valuable findings on organophosphine chemistry were obtained, including the synthesis of chiral phosphines and cyclic phosphine compounds.
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