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In situ AFM Observation of a Polymer Droplet Spreading on a Substrate at the Molecular Level

Research Project

Project/Area Number 18H02025
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Review Section Basic Section 35020:Polymer materials-related
Research InstitutionYamagata University

Principal Investigator

Kumaki Jiro  山形大学, 大学院有機材料システム研究科, 教授 (00500290)

Project Period (FY) 2018-04-01 – 2021-03-31
Project Status Completed (Fiscal Year 2020)
Budget Amount *help
¥17,420,000 (Direct Cost: ¥13,400,000、Indirect Cost: ¥4,020,000)
Fiscal Year 2020: ¥4,550,000 (Direct Cost: ¥3,500,000、Indirect Cost: ¥1,050,000)
Fiscal Year 2019: ¥5,460,000 (Direct Cost: ¥4,200,000、Indirect Cost: ¥1,260,000)
Fiscal Year 2018: ¥7,410,000 (Direct Cost: ¥5,700,000、Indirect Cost: ¥1,710,000)
Keywords展開挙動 / 高分子ブレンド融液 / 原子間力顕微鏡 / 高分子孤立鎖 / プレカーサーフィルム
Outline of Final Research Achievements

The behavior of a polymer melt spreading on a substrate is not well-understood at present. If we could observe the spreading behavior of the droplet by atomic force microscopy (AFM) at the molecular level, our understanding of polymer surface phenomena will be significantly improved. In this study, we observed the precursor film formed ahead of a spreading droplet of an isotactic poly(methyl methacrylate)(it-PMMA)/oligo (MMA) blend on mica in situ in real time. We successfully observed it-PMMA chains flowing in the precursor film. The spreading behavior of the droplet and the it-PMMA molecules flowing in the precursor film was strongly affected by humidity.

Academic Significance and Societal Importance of the Research Achievements

高分子のぬれ、摩擦、接着等の表面現象の解明は実用的にも極めて重要であるが、表面、界面は極めて限られた領域であるため、これらの現象を分子レベルでとらえるのは極めて困難であり、現在でも不明な点が多い。本研究では、高分子の融液が基板上に展開する様子を、原子間力顕微鏡を用いて、初めて高分子の分子鎖1本のレベルで観察することに成功した。直接観察することにより、高分子鎖が基板にトラップされたり、基板面で速度を変化させながら流動する場合があることがわかった。高分子の表面現象を理解するために、重要な観察手法を確立できたものと考えられる。

Report

(4 results)
  • 2020 Annual Research Report   Final Research Report ( PDF )
  • 2019 Annual Research Report
  • 2018 Annual Research Report
  • Research Products

    (26 results)

All 2021 2020 2019 2018 Other

All Journal Article (8 results) (of which Peer Reviewed: 8 results) Presentation (15 results) (of which Int'l Joint Research: 4 results,  Invited: 6 results) Book (1 results) Remarks (2 results)

  • [Journal Article] In Situ AFM Observation of Folded‐Chain Crystallization of a Low‐Molecular‐Weight Isotactic Poly(methyl methacrylate) in a Langmuir Monolayer at the Molecular Level2021

    • Author(s)
      Ono Yuki、Kumaki Jiro
    • Journal Title

      Macromolecular Chemistry and Physics

      Volume: 222 Issue: 5 Pages: 2000372-2000372

    • DOI

      10.1002/macp.202000372

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Self-Assembly of Linear and Cyclic Polylactide Stereoblock Copolymers with a Parallel and Antiparallel Chain Arrangement Distinguishing Their Directions on a Water Surface2020

    • Author(s)
      Iwashima Kenta、Yamamoto Takuya、Tezuka Yasuyuki、Kumaki Jiro
    • Journal Title

      Langmuir

      Volume: 36 Issue: 22 Pages: 6216-6221

    • DOI

      10.1021/acs.langmuir.0c00769

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Preparation of a Si(111) Atomically Flat Substrate via Wet Etching and Evaluation as an AFM Substrate for Observations of Isolated Chains, Crystals, and Crystallization of Isotactic Poly(methyl methacrylate) at the Molecular Level2020

    • Author(s)
      Sasahara Yuki、Miyake Yuya、Kumaki Jiro
    • Journal Title

      Langmuir

      Volume: 36 Issue: 26 Pages: 7494-7504

    • DOI

      10.1021/acs.langmuir.0c01098

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed
  • [Journal Article] In situ AFM Observation of the Movements of Isolated Isotactic Poly(methyl methacrylate) Chains in a Precursor Film of an Oligo(methyl methacrylate) Droplet Spreading on Mica2020

    • Author(s)
      Watanabe Yasuhiro、Ichinohe Hayato、Kumaki Jiro
    • Journal Title

      Langmuir

      Volume: 36 Issue: 41 Pages: 12327-12335

    • DOI

      10.1021/acs.langmuir.0c02299

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Extended-Chain Crystallization and Stereocomplex Formation of Polylactides in a Langmuir Monolayer2020

    • Author(s)
      Kenji Watanabe, Jiro Kumaki
    • Journal Title

      Polymer J.

      Volume: 52 Issue: 6 Pages: 601-613

    • DOI

      10.1038/s41428-020-0312-2

    • NAID

      40022335707

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Fabrication of a Polymer Molecularly Flat Substrate by Thermal Nanoimprinting and AFM Observation of Polymer Chains Deposited on It2019

    • Author(s)
      Ryota Umetsu, Jiro Kumaki
    • Journal Title

      Macromolecules

      Volume: 52 Issue: 17 Pages: 6555-6565

    • DOI

      10.1021/acs.macromol.9b01280

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Atomic Force Microscopy of Single Polymer Chains on a Substrate at Temperatures above the Bulk Glass Transition Temperatures.2019

    • Author(s)
      Ryo Fujita, Kenshiro Frudate, Jiro Kumaki
    • Journal Title

      Polymer

      Volume: 168 Pages: 21-28

    • DOI

      10.1016/j.polymer.2019.02.014

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] In Situ Real-Time Observation of Polymer Folded-Chain Crystallization by Atomic Force Microscopy at the Molecular Level.2018

    • Author(s)
      Yuki Ono, Jiro Kumaki
    • Journal Title

      Macromolecules

      Volume: 51 Issue: 19 Pages: 7629-7636

    • DOI

      10.1021/acs.macromol.8b01428

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Presentation] It-PMMA折りたたみ鎖結晶の結晶化過程の高分解能AFM観察2020

    • Author(s)
      小野裕貴、熊木治郎
    • Organizer
      第69回高分子学会年次大会
    • Related Report
      2020 Annual Research Report
  • [Presentation] it-PMMA孤立鎖の結晶化挙動観察2020

    • Author(s)
      高橋佑朔, 熊木治郎
    • Organizer
      第69回高分子討論会
    • Related Report
      2020 Annual Research Report
  • [Presentation] it-PMMA単分子膜の結晶化過程の実時間高分解能AFM観察2020

    • Author(s)
      黒岩知寛, 小野裕貴, 熊木治郎
    • Organizer
      第69回高分子討論会
    • Related Report
      2020 Annual Research Report
  • [Presentation] it-PMMA孤立鎖の結晶化挙動観察2020

    • Author(s)
      高橋佑朔, 熊木治郎
    • Organizer
      2020高分子学会東北支部研究発表会
    • Related Report
      2020 Annual Research Report
  • [Presentation] 基板上に展開するブレンド融液中の高分子孤立鎖のin situ AFM観察2019

    • Author(s)
      渡邉康宏、熊木治郎
    • Organizer
      第68回高分子学会年次大会
    • Related Report
      2019 Annual Research Report
  • [Presentation] 高分子構造の分子鎖レベル高分解能AFM観察2019

    • Author(s)
      熊木治郎
    • Organizer
      高分子材料のレオロジーの基礎と分子構造の分析・評価、ブルカージャパン㈱講演会
    • Related Report
      2019 Annual Research Report
    • Invited
  • [Presentation] スピン塗布膜での高分子1本の形態と動きの観察2019

    • Author(s)
      熊木治郎
    • Organizer
      第3回極限ナノ造形・構造物性研究会・公開講演会(応用物理学会)
    • Related Report
      2019 Annual Research Report
    • Invited
  • [Presentation] PMMAステレオコンプレックスの孤立鎖状態からの形成挙動観察2019

    • Author(s)
      加藤大樹、影山諒、熊木治郎
    • Organizer
      第68回高分子討論会
    • Related Report
      2019 Annual Research Report
  • [Presentation] In Situ Real-Time Observation of Polymer Folded-Chain Crystallization by Atomic Force Microscopy at the Molecular Level2019

    • Author(s)
      Jiro Kumaki
    • Organizer
      International Discussion Meeting on Polymer Crystallization (IDMPC) 2019
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] In-Situ High-Magnification AFM Observation of PMMA Stereocomplex Formation from Isolated Chains2019

    • Author(s)
      Daiki Kato, Jiro Kumaki
    • Organizer
      The Second International Conference of Polymeric and Organic Materials in Yamagata University (IPOMY)
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] In Situ AFM Observation of Isolated Single Chains Solubilized in a Spreading Polymer Blend Melt2019

    • Author(s)
      Yasuhiro Watanabe, Jiro Kumaki
    • Organizer
      The First International Conference of Polymeric and Organic Materials in Yamagata University (IPOMY)
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] AFM Observation of the Movements of Single Linear Chains in a Precursor Film of a Spreading Polymer Blend Melt2019

    • Author(s)
      Yasuhiro Watanabe, Jiro Kumaki
    • Organizer
      American Physical Society March Meeting 2019
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 高分子鎖構造の原子間力顕微鏡観察2019

    • Author(s)
      熊木治郎
    • Organizer
      東北大学多元物質科学研究所講演会
    • Related Report
      2018 Annual Research Report
    • Invited
  • [Presentation] 高分子鎖構造の原子間力顕微鏡観察2018

    • Author(s)
      熊木治郎
    • Organizer
      高分子学会関東高分子若手研究会2018春の講演会
    • Related Report
      2018 Annual Research Report
    • Invited
  • [Presentation] 高分子鎖構造の原子間力顕微鏡観察2018

    • Author(s)
      熊木治郎
    • Organizer
      高分子学会東北支部夏季ゼミ
    • Related Report
      2018 Annual Research Report
    • Invited
  • [Book] 高分子基礎科学 第2版2020

    • Author(s)
      熊木治郎,青木百合子、青島貞人、赤木和夫、秋吉一成他
    • Total Pages
      478
    • Publisher
      東京化学同人
    • Related Report
      2019 Annual Research Report
  • [Remarks] 山形大学 熊木研究室

    • URL

      http://kumaki-lab.yz.yamagata-u.ac.jp/index.html

    • Related Report
      2020 Annual Research Report 2019 Annual Research Report 2018 Annual Research Report
  • [Remarks] 山形大学教員情報

    • URL

      http://yudb.kj.yamagata-u.ac.jp/html/100000173_ja.html

    • Related Report
      2020 Annual Research Report 2019 Annual Research Report 2018 Annual Research Report

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Published: 2018-04-23   Modified: 2022-01-27  

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