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Ordered structure formation in polymer-brush-decorated-particle/liquid-crystal mixed system

Research Project

Project/Area Number 18H02033
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Review Section Basic Section 35020:Polymer materials-related
Research InstitutionKyoto University

Principal Investigator

OHNO Kohji  京都大学, 化学研究所, 准教授 (00335217)

Project Period (FY) 2018-04-01 – 2021-03-31
Project Status Completed (Fiscal Year 2020)
Budget Amount *help
¥17,290,000 (Direct Cost: ¥13,300,000、Indirect Cost: ¥3,990,000)
Fiscal Year 2020: ¥5,850,000 (Direct Cost: ¥4,500,000、Indirect Cost: ¥1,350,000)
Fiscal Year 2019: ¥5,850,000 (Direct Cost: ¥4,500,000、Indirect Cost: ¥1,350,000)
Fiscal Year 2018: ¥5,590,000 (Direct Cost: ¥4,300,000、Indirect Cost: ¥1,290,000)
Keywords微粒子 / ポリマーブラシ / 液晶 / コロイド / 表面・界面 / 高分子合成 / 高分子構造・物性 / ナノ材料 / 表面・界面物性 / 自己組織化
Outline of Final Research Achievements

The purpose of this study is to systematically investigate the dispersibility and arrangement behavior of polymer-brush-decorated hybrid particles in liquid crystals, and to develop a novel colloid/liquid-crystal dispersion system that is attracting attention both academically and practically. We here have developed a technology that can control the orientation behavior of liquid crystals to a surface by the type of polymer brush grafted on fine particles. It should be noted that we could found disclination structures such as hexadecapolar and baseball types, which are rarely reported. In addition, we succeeded in expanding this technique into rod-shaped particles and found the orientation behavior of liquid crystal peculiar to anisotropic fine particles. Furthermore, we clarified that the arrangement state of fine particles in the liquid crystal can be controlled by appropriately selecting polymer brush grated on the surfaces.

Academic Significance and Societal Importance of the Research Achievements

液晶中でのコロイド粒子の配列制御に関する研究は、微粒子の表面構造・化学組成の重要性が認識されているにも関わらず、それらを化学的により積極的に制御されてこなかった。本研究では、独自のポリマーブラシ付与微粒子の合成技術を活かし、様々な構造パラメータを有する微粒子を設計しそれらに対する液晶の配向挙動を系統的に評価することで、液晶の配向挙動を制御できる技術を開発できたことは意義深い。液晶の応用はディスプレイのみにとどまらないことを考慮すれば、本研究の知見が多方面で活用されると期待できる。

Report

(4 results)
  • 2020 Annual Research Report   Final Research Report ( PDF )
  • 2019 Annual Research Report
  • 2018 Annual Research Report
  • Research Products

    (20 results)

All 2020 2019 Other

All Int'l Joint Research (2 results) Journal Article (8 results) (of which Int'l Joint Research: 3 results,  Peer Reviewed: 8 results) Presentation (9 results) (of which Int'l Joint Research: 4 results,  Invited: 5 results) Book (1 results)

  • [Int'l Joint Research] Michigan State University(米国)

    • Related Report
      2020 Annual Research Report
  • [Int'l Joint Research] University of Queensland(オーストラリア)

    • Related Report
      2020 Annual Research Report
  • [Journal Article] Aluminum-Based Initiators from Thiols for Epoxide Polymerizations2020

    • Author(s)
      Safaie Niloofar、Rawal Bandana、Ohno Kohji、Ferrier Robert C.
    • Journal Title

      Macromolecules

      Volume: 53 Issue: 19 Pages: 8181-8191

    • DOI

      10.1021/acs.macromol.0c00464

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Convenient Synthesis of Very-Thick Concentrated Polymer Brushes by Atom Transfer Radical Polymerization in an Ionic Liquid2020

    • Author(s)
      Hsu Shu-Yao、Ohno Kohji、Sakakibara Keita、Tsujii Yoshinobu
    • Journal Title

      Macromolecules

      Volume: 53 Issue: 18 Pages: 7936-7943

    • DOI

      10.1021/acs.macromol.0c00161

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Improving tribological properties of oil-based lubricants using hybrid colloidal additives2020

    • Author(s)
      Beheshti Amir、Huang Yun、Ohno Kohji、Blakey Idriss、Stokes Jason R.
    • Journal Title

      Tribology International

      Volume: 144 Pages: 106130-106130

    • DOI

      10.1016/j.triboint.2019.106130

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Controlled Synthesis of Concentrated Polymer Brushes with Ultralarge Thickness by Surface-Initiated Atom Transfer Radical Polymerization under High Pressure2020

    • Author(s)
      Hsu Shu-Yao、Kayama Yuzo、Ohno Kohji、Sakakibara Keita、Fukuda Takeshi、Tsujii Yoshinobu
    • Journal Title

      Macromolecules

      Volume: 53 Issue: 1 Pages: 132-137

    • DOI

      10.1021/acs.macromol.9b02072

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Structural Color Materials Using Polymer-Brush-Decorated Hybrid Particles2019

    • Author(s)
      Ohno Kohji、Mizuta Yuuki
    • Journal Title

      ACS Applied Polymer Materials

      Volume: 2 Issue: 2 Pages: 368-375

    • DOI

      10.1021/acsapm.9b00839

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Polymer-Brush-Decorated Graphene Oxide: Precision Synthesis and Liquid-Crystal Formation2019

    • Author(s)
      Ohno Kohji、Zhao Chenzhou、Nishina Yuta
    • Journal Title

      Langmuir

      Volume: 35 Issue: 33 Pages: 10900-10909

    • DOI

      10.1021/acs.langmuir.9b01747

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Polymer-brush-decorated colloidal platelets: precision synthesis and self-assembly2019

    • Author(s)
      Ohno Kohji、Masuda Shota、Ogawa Hiroki
    • Journal Title

      Polymer Chemistry

      Volume: 10 Issue: 21 Pages: 2686-2696

    • DOI

      10.1039/c9py00436j

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Grafting of Polymer Brushes from Xanthate‐Functionalized Silica Particles2019

    • Author(s)
      Ohno Kohji、Yahata Yoshikazu、Sakaue Motokazu、Ladmiral Vincent
    • Journal Title

      Chemistry A European Journal

      Volume: 25 Issue: 8 Pages: 2059-2068

    • DOI

      10.1002/chem.201805121

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Presentation] ポリマーブラシと微粒子の複合化2020

    • Author(s)
      大野工司
    • Organizer
      ポリマーフロンティア21
    • Related Report
      2020 Annual Research Report
    • Invited
  • [Presentation] ポリマー修飾粒子の自己組織化2020

    • Author(s)
      大野工司
    • Organizer
      ソフトマター工学分科会講演会
    • Related Report
      2020 Annual Research Report
    • Invited
  • [Presentation] Self-Assembly in Colloidal Dispersion of Polymer-Brush-Decorated Hybrid Particles2019

    • Author(s)
      Kohji Ohno
    • Organizer
      The 16th Pacific Polymer Conference (PPC16)
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Ordered Structure Formation in Colloidal Dispersion of Polymer-Brush-Decorated Particles2019

    • Author(s)
      Kohji Ohno, Haruhisa Ohno
    • Organizer
      Okinawa Colloids 2019
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Polymer-Brush-Decorated Hybrid Particles: Controlled Synthesis and Self-assembly2019

    • Author(s)
      Kohji Ohno
    • Organizer
      ADVANCES IN POLYMER SCIENCEAND RUBBER TECHNOLOGY
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] ポリマーブラシの精密合成とコロイド化学の融合2019

    • Author(s)
      大野工司
    • Organizer
      精密ネットワークポリマー研究会
    • Related Report
      2019 Annual Research Report
    • Invited
  • [Presentation] Binary Colloid Crystals from Nucleobase-Containing-Polymer-Brush-Decorated Particles2019

    • Author(s)
      Kohji Ohno
    • Organizer
      ACS Colloid & Surface Science Symposium
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 水素結合性ポリマーブラシ付与複合微粒子による二成分系コロイド結晶の構築2019

    • Author(s)
      大野晴久、辻井敬亘、大野工司
    • Organizer
      第68回高分子討論会
    • Related Report
      2019 Annual Research Report
  • [Presentation] 水素結合性ポリマーブラシ付与複合微粒子による二成分系コロイド結晶の構築2019

    • Author(s)
      大野晴久、辻井敬亘、大野工司
    • Organizer
      第68回高分子学会年次大会
    • Related Report
      2019 Annual Research Report
  • [Book] コロイド結晶の形成とその応用2020

    • Author(s)
      中村 浩、山中淳平
    • Total Pages
      251
    • Publisher
      シーエムシー出版
    • ISBN
      9784781315027
    • Related Report
      2020 Annual Research Report

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Published: 2018-04-23   Modified: 2022-01-27  

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