| Budget Amount *help |
¥16,900,000 (Direct Cost: ¥13,000,000、Indirect Cost: ¥3,900,000)
Fiscal Year 2021: ¥2,600,000 (Direct Cost: ¥2,000,000、Indirect Cost: ¥600,000)
Fiscal Year 2020: ¥2,600,000 (Direct Cost: ¥2,000,000、Indirect Cost: ¥600,000)
Fiscal Year 2019: ¥2,600,000 (Direct Cost: ¥2,000,000、Indirect Cost: ¥600,000)
Fiscal Year 2018: ¥9,100,000 (Direct Cost: ¥7,000,000、Indirect Cost: ¥2,100,000)
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| Outline of Final Research Achievements |
We aimed to create probe molecules for visualization of chain-scissoring points in polymer mechanochemistry. We have clarified the substituent effect on photostability and photoreaction quantum yields of photochromic molecules, which can be potentially used as probe molecules. We synthesized a polymer compound containing photochromic molecules and confirmed that the photochromic molecules exhibit the same photoresponsive properties in the polymer as in the case of the molecular skeleton alone, and investigated mechanochemical reactions of the polymer compound.
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