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Fabrication of Fluorescent flexible organic crystals and their waveguide

Research Project

Project/Area Number 18H02052
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Review Section Basic Section 35030:Organic functional materials-related
Research InstitutionKochi University of Technology (2020-2021)
防衛大学校(総合教育学群、人文社会科学群、応用科学群、電気情報学群及びシステム工学群) (2018-2019)

Principal Investigator

Hayashi Shotaro  高知工科大学, 環境理工学群, 講師 (00532954)

Project Period (FY) 2018-04-01 – 2022-03-31
Project Status Completed (Fiscal Year 2021)
Budget Amount *help
¥17,810,000 (Direct Cost: ¥13,700,000、Indirect Cost: ¥4,110,000)
Fiscal Year 2021: ¥2,470,000 (Direct Cost: ¥1,900,000、Indirect Cost: ¥570,000)
Fiscal Year 2020: ¥1,820,000 (Direct Cost: ¥1,400,000、Indirect Cost: ¥420,000)
Fiscal Year 2019: ¥2,340,000 (Direct Cost: ¥1,800,000、Indirect Cost: ¥540,000)
Fiscal Year 2018: ¥11,180,000 (Direct Cost: ¥8,600,000、Indirect Cost: ¥2,580,000)
Keywords分子結晶 / エラスティック結晶 / 導波路 / 発光 / ウェーブガイド / 柔軟性分子結晶 / 弾力性 / 共役系分子 / フレキシブルクリスタル / 有機結晶 / π共役系分子 / 配向性 / 結晶 / 第一原理計算 / 柔軟性結晶材料 / 光学ウェーブガイド
Outline of Final Research Achievements

We have developed elastic molecular crystals consisting of various π-conjugated molecules. In addition, we investigated its flexibility and light-emitting function and expanded it to waveguide research. In order to achieve high flatness, we developed a π-conjugated molecule composed of a combination of a thiophene skeleton and fluoroarene, and obtained a luminescent single crystal that elastically deforms by its crystallization. On the other hand, in order to investigate this waveguide characteristic, a spatially resolved fluorescence spectrum capable of measuring the fluorescence spectrum at an arbitrary point was created separately from the laser irradiation position. The attenuation coefficient (waveguide performance) was calculated by plotting the distance (irradiation position-crystal edge) and PL intensity of a straight or bent molecular crystal.

Academic Significance and Societal Importance of the Research Achievements

ここでは発光性エラスティック結晶の実現とそれを利用したメカノクロミズムと光導波路を実現した。これは、結晶工学的に分子から選択的に弾性機能を示す結晶を狙って得る「非共有結合合成」に基づいており、結晶材料の設計という点で意義深い。また、メカノクロミズムと光導波路に向けた空間分解蛍光スペクトルの開発とそれを多用した分析によって、エラスティック結晶が変形に感度よくスペクトル変化を起こすことがあるという事実を発見できた。更に、光導波路においては低い減衰係数を示したことから、これまでとは異なる高効率な光伝送ツールとしての可能性が見出せた。

Report

(5 results)
  • 2021 Annual Research Report   Final Research Report ( PDF )
  • 2020 Annual Research Report
  • 2019 Annual Research Report
  • 2018 Annual Research Report
  • Research Products

    (31 results)

All 2022 2021 2020 2019 2018 Other

All Journal Article (15 results) (of which Peer Reviewed: 15 results,  Open Access: 1 results) Presentation (13 results) (of which Int'l Joint Research: 3 results,  Invited: 13 results) Book (1 results) Remarks (2 results)

  • [Journal Article] Mechanically Flexible and Optically Tunable Organic Crystal Resonator2022

    • Author(s)
      Shuai Zhao, Hiroshi Yamagishi, Osamu Oki, Yuta Ihara, Naoki Ichiji, Atsushi Kubo, Shotaro Hayashi, Yohei Yamamoto
    • Journal Title

      Advanced Optical Materials

      Volume: 10 Issue: 2 Pages: 2101808-2101808

    • DOI

      10.1002/adom.202101808

    • Related Report
      2021 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Elastic Molecular Crystals: Their Deformation-induced Reversible Unit Cell Changes with Specific Poisson Effect2022

    • Author(s)
      Shotaro Hayashi
    • Journal Title

      Bulletin of the Chemical Society of Japan

      Volume: - Issue: 5 Pages: 721-727

    • DOI

      10.1246/bcsj.20220040

    • Related Report
      2021 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Thermo-triggered Domino-like Single-Crystal-to-Single-Crystal Phase Transition from Face-to- edge to Face-to-face Packing of Anthracene2021

    • Author(s)
      Yuto Hino, Shotaro Hayashi
    • Journal Title

      Chemistry-A European Journal

      Volume: 27 Issue: 70 Pages: 17595-17600

    • DOI

      10.1002/chem.202103165

    • Related Report
      2021 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Functional flexible molecular crystals: intrinsic and mechanoresponsive properties2021

    • Author(s)
      Seki Tomohiro、Hoshino Norihisa、Suzuki Yasutaka、Hayashi Shotaro
    • Journal Title

      CrystEngComm

      Volume: - Issue: 34 Pages: 5686-5696

    • DOI

      10.1039/d1ce00388g

    • Related Report
      2021 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Curving Deformation-induced Photoluminescence Changes and Anisotropy Analysis in Elastic Organic Crystals2021

    • Author(s)
      Shotaro Hayashi
    • Journal Title

      CrystEngComm

      Volume: 23 Issue: 34 Pages: 5763-5767

    • DOI

      10.1039/d1ce00400j

    • Related Report
      2021 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Elastic Organic Crystals of π-Conjugated Molecules: New Concept for Materials Chemistry2020

    • Author(s)
      Shotaro Hayashi
    • Journal Title

      Symmetry

      Volume: 12 Issue: 12 Pages: 2022-2022

    • DOI

      10.3390/sym12122022

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Highly Crystalline and Efficient Red-emissive π-Conjugated Polymer Film: Tuning of Macrostructure for Light-emitting Properties2020

    • Author(s)
      Shotaro Hayashi
    • Journal Title

      Materials Advances

      Volume: 1 Issue: 4 Pages: 632-638

    • DOI

      10.1039/d0ma00218f

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Anisotropic Poisson’s Effect and Deformation‐induced Fluorescence Change of Elastic 9,10‐Dibromoanthrathene Single Crystals2020

    • Author(s)
      Hayashi Shotaro、Ishiwari Fumitaka、Fukushima Takanori、Mikage Shohei、Imamura Yutaka、Tashiro Motomichi、Katouda Michio
    • Journal Title

      Angewandte Chemie International Edition

      Volume: xx Issue: 37 Pages: 16195-16201

    • DOI

      10.1002/anie.202006474

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Facile Synthesis of ortho-Phenylene-Based Conjugated Polymers through Transformation of Cross-Conjugated Poly(2,3-diaryl[2]dendralene)s and their Optical Properties2019

    • Author(s)
      Toshio Koizumi, Tsuyoshi Kameda, Hironori, Saito, Ayumu Sato, Shotaro Hayashi
    • Journal Title

      Journal of Polymer Science: Part A: Polymer Chemistry

      Volume: 57 Issue: 7 Pages: 827-832

    • DOI

      10.1002/pola.29333

    • Related Report
      2019 Annual Research Report 2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis of Network Polymer Emitters: Tunable Detection of Chemicals by the Geometric Design2019

    • Author(s)
      Shotaro Hayashi, Shin-ichi Yamamoto, Koji Nishi, Atsushi Asano, Toshio Koizumi
    • Journal Title

      Polymer Journal

      Volume: 51 Pages: 1055-1061

    • NAID

      40022176708

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Direction-specific Fluorescence of an Engineered Organic Crystal and Its Mechanically Induced Shaping-caused New Face Appearance2019

    • Author(s)
      Shotaro Hayashi, Toshio Koizumi
    • Journal Title

      CrystEngComm

      Volume: 21 Pages: 5990-5994

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Elastic Organic Crystals of π-Conjugated Molecules: Anisotropic Densely Packed Supramolecular 3D Polymers Exhibit Mechanical Flexibility and Shape Tunability2019

    • Author(s)
      Shotaro Hayashi
    • Journal Title

      Polymer Journal

      Volume: 51 Pages: 813-823

    • NAID

      40022176735

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] A A Versatile Scaffold for Facile Synthesis of Fluorescent Cyano-substituted Stilbenes2019

    • Author(s)
      Shotaro Hayashi, Minami Sakamoto, Fumitaka Ishiwari, Takanori Fukushima, Shin-ichi Yamamoto, Toshio Koizumi
    • Journal Title

      Tetrahedron

      Volume: 75 Issue: 8 Pages: 1079-1084

    • DOI

      10.1016/j.tet.2019.01.012

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] 2,5-Dimethoxybenzene-1,4-dicarboxaldehyde: An Emissive Organic Crystal and Highly Efficient Fluorescent Waveguide2019

    • Author(s)
      Shotaro Hayashi, Toshio Koizumi, Natsumi Kamiya
    • Journal Title

      ChemPlusChem

      Volume: 84 Issue: 3 Pages: 247-251

    • DOI

      10.1002/cplu.201800597

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Creating Elastic Organic Crystals of π‐Conjugated Molecules with Bending Mechanofluorochromism and Flexible Optical Waveguide2018

    • Author(s)
      Shotaro Hayashi, Shun-ya Yamamoto, Daisuke Takeuchi, Yutaka Ie, Koji Takagi
    • Journal Title

      Angewandte Chemie International Edition

      Volume: 57 Issue: 52 Pages: 17002-17008

    • DOI

      10.1002/anie.201810422

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Presentation] Fluorescent Flexible Organic Crystals: Detailed Investigation of Their Deformation and Fluorescence Changes2022

    • Author(s)
      Shotaro Hayashi
    • Organizer
      PasifiChem
    • Related Report
      2021 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 柔軟性分子結晶学 機能性分子結晶の機械変形と光物性2021

    • Author(s)
      林 正太郎
    • Organizer
      九州地区高分子若手研究会・冬の講演会、高分子学会九州支部
    • Related Report
      2021 Annual Research Report
    • Invited
  • [Presentation] 柔軟性分子結晶学:発光性エラスティック結晶が開拓するフレキシブルウェーブガイド2021

    • Author(s)
      林 正太郎
    • Organizer
      2021年日本化学会中国四国支部大会 高知大会
    • Related Report
      2021 Annual Research Report
    • Invited
  • [Presentation] 機能性フレキシブル分子結晶の展開2021

    • Author(s)
      林 正太郎
    • Organizer
      分子系の複合電子機能 第181委員会
    • Related Report
      2021 Annual Research Report
    • Invited
  • [Presentation] エラスティック結晶 ~変形が導くナノ構造―物性変化~2020

    • Author(s)
      林 正太郎
    • Organizer
      繊維学会秋季大会
    • Related Report
      2020 Annual Research Report
    • Invited
  • [Presentation] エラスティック有機結晶:弾性変形機能と完全結晶繊維の作成2020

    • Author(s)
      林 正太郎
    • Organizer
      高知化学シンポジウム
    • Related Report
      2020 Annual Research Report
    • Invited
  • [Presentation] エラスティック有機結晶の開発とその発光特性および機械特性の解析2020

    • Author(s)
      林 正太郎
    • Organizer
      第69回高分子討論会
    • Related Report
      2020 Annual Research Report
    • Invited
  • [Presentation] Elastic Organic Crystals of π -Conjugated Molecules ~弾性変形が可能にする機能創出~2019

    • Author(s)
      林 正太郎
    • Organizer
      第126回純正・応用化学シンポジウム
    • Related Report
      2019 Annual Research Report
    • Invited
  • [Presentation] Elastic Organic Crystals of π -Conjugated Molecules2019

    • Author(s)
      林 正太郎
    • Organizer
      Japan Conference of Coordination Chemistry Design and construction of photoresponsive inorganic/organic molecular system
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 柔軟で稠密な三次元分子集合体の創成とその機能解析2019

    • Author(s)
      林 正太郎
    • Organizer
      高分子研究発表会 神戸 (高分子学会関西支部)
    • Related Report
      2019 Annual Research Report
    • Invited
  • [Presentation] 柔軟で稠密なπ造形システム~ Elastic Organic Crystals of π -Conjugated Molecules~2019

    • Author(s)
      林 正太郎
    • Organizer
      第2回神奈川地区講演会(高分子学会関東支部)
    • Related Report
      2019 Annual Research Report
    • Invited
  • [Presentation] Elastic Organic Crystals of π -Conjugated Molecules2019

    • Author(s)
      林 正太郎
    • Organizer
      24th International Conference on the Chemistry of the Organic Solid State
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 柔軟で稠密なπ造形システム~ Elastic Organic Crystals of π -Conjugated Molecules~2019

    • Author(s)
      林 正太郎
    • Organizer
      早稲田大学講演会
    • Related Report
      2019 Annual Research Report
    • Invited
  • [Book] 次世代のポリマー・高分子開発 ~新しい用途展開と将来展望~2019

    • Author(s)
      林 正太郎
    • Total Pages
      10
    • Publisher
      技術情報協会
    • ISBN
      4861047382
    • Related Report
      2019 Annual Research Report
  • [Remarks] Functional Polymer Chemistry

    • URL

      https://s1016forest.wixsite.com/kut-hayashi

    • Related Report
      2021 Annual Research Report 2019 Annual Research Report
  • [Remarks] 高知県公立大学法人 高知工科大学 環境理工学群 化学専攻 機能性高分子化学

    • URL

      https://s1016forest.wixsite.com/kut-hayashi

    • Related Report
      2020 Annual Research Report

URL: 

Published: 2018-04-23   Modified: 2023-01-30  

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