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Development of artificial photosynthesis system driven by interfacial photo-excitation process

Research Project

Project/Area Number 18H02055
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Review Section Basic Section 36010:Inorganic compounds and inorganic materials chemistry-related
Research InstitutionTokyo Institute of Technology

Principal Investigator

Miyauchi Masahiro  東京工業大学, 物質理工学院, 教授 (60443230)

Project Period (FY) 2018-04-01 – 2023-03-31
Project Status Completed (Fiscal Year 2022)
Budget Amount *help
¥16,900,000 (Direct Cost: ¥13,000,000、Indirect Cost: ¥3,900,000)
Fiscal Year 2022: ¥2,470,000 (Direct Cost: ¥1,900,000、Indirect Cost: ¥570,000)
Fiscal Year 2021: ¥5,070,000 (Direct Cost: ¥3,900,000、Indirect Cost: ¥1,170,000)
Fiscal Year 2020: ¥4,160,000 (Direct Cost: ¥3,200,000、Indirect Cost: ¥960,000)
Fiscal Year 2019: ¥3,380,000 (Direct Cost: ¥2,600,000、Indirect Cost: ¥780,000)
Fiscal Year 2018: ¥1,820,000 (Direct Cost: ¥1,400,000、Indirect Cost: ¥420,000)
Keywords光触媒 / 界面電荷移動遷移 / 薄膜 / ナノクラスター / 可視光 / 水分解 / ケルビンプローブ顕微鏡 / 半導体 / 界面電荷移動 / 人工光合成 / 界面 / 励起
Outline of Final Research Achievements

Interfacial charge transfer (IFCT) is known to drive photocatalysis under visible light. However, its mechanism study is insufficient and its reactions are limited to the organic decomposition. Herein, the purpose of this study is to prove the IFCT mechanism clearer and to achieve the photocatalytic overall water splitting under visible light using the IFCT mechanism. Based on a well-defined thin film model sample, I successfully visualized the IFCT by Kelvin probe force microscopy. In addition, chemical reaction sites are also visualized by observing photo-deposited metal particles by atomic force microscopy. Further, we fabricated the Cu(II) nanoclusters-grafted TiO2 electrode and achieved its water splitting reaction under visible light.

Academic Significance and Societal Importance of the Research Achievements

本研究で確立した「よく定義された薄膜モデルを用いたケルビンプローブ顕微鏡/原子間力顕微鏡による観察」は、様々な物質の界面での電荷移動や化学反応サイトを理解する一助となる。また、本研究では界面電荷移動遷移(IFCT)の機構を用い、これまでこの遷移では報告例の無かった「可視光照射による水分解反応」を達成した。今後、この機構を用いた様々な物質の人工光合成への展開も期待できる。

Report

(6 results)
  • 2022 Annual Research Report   Final Research Report ( PDF )
  • 2021 Annual Research Report
  • 2020 Annual Research Report
  • 2019 Annual Research Report
  • 2018 Annual Research Report
  • Research Products

    (36 results)

All 2023 2022 2021 2020 2019 2018 Other

All Int'l Joint Research (1 results) Journal Article (19 results) (of which Int'l Joint Research: 6 results,  Peer Reviewed: 19 results,  Open Access: 7 results) Presentation (15 results) (of which Int'l Joint Research: 10 results,  Invited: 10 results) Book (1 results)

  • [Int'l Joint Research] Central South University(中国)

    • Related Report
      2019 Annual Research Report
  • [Journal Article] Direct Interfacial Excitation from TiO2 to Cu(II) Nanoclusters Enables Cathodic Photoresponse for Hydrogen Evolution under Visible‐Light Irradiation2023

    • Author(s)
      Wardhana Aufandra C.、Yamaguchi Akira、Adachi Kiyohiro、Hashizume Daisuke、Miyauchi Masahiro
    • Journal Title

      Small

      Volume: 2206893 Issue: 20 Pages: 1-7

    • DOI

      10.1002/smll.202206893

    • Related Report
      2022 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Bandgap widening through doping for improving the photocatalytic oxidation ability of narrow-bandgap semiconductors2023

    • Author(s)
      Yang Yue、Toyoda Masayuki、Yamaguchi Akira、Cho Yohei、El Aisnada An Niza、Abe Hideki、Ueda Shigenori、Okunaka Sayuri、Saito Susumu、Liu Min、Tokudome Hiromasa、Miyauchi Masahiro
    • Journal Title

      Physical Chemistry Chemical Physics

      Volume: 25 Issue: 1 Pages: 255-261

    • DOI

      10.1039/d2cp02994d

    • Related Report
      2022 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Synthesis and Characterization of the Orthorhombic Sn3O4 Polymorph2023

    • Author(s)
      Liu Yang‐Shin、Yamaguchi Akira、Yang Yue、Aisnada An Niza El、Uchida Sho、Abe Hideki、Ueda Shigenori、Yamaguchi Kenji、Tanabe Toyokazu、Miyauchi Masahiro
    • Journal Title

      Angewandte Chemie International Edition

      Volume: 62 Issue: 17 Pages: 1-6

    • DOI

      10.1002/anie.202300640

    • Related Report
      2022 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Direct imaging of visible-light-induced one-step charge separation at the chromium oxide/strontium titanate interface2022

    • Author(s)
      Wardhana Aufandra Cakra、Yasuhara Sou、Yu Min-Wen、Yamaguchi Akira、Nagao Tadaaki、Ishii Satoshi、Miyauchi Masahiro
    • Journal Title

      Journal of Materials Chemistry A

      Volume: 10 Issue: 2 Pages: 752-761

    • DOI

      10.1039/d1ta08950a

    • Related Report
      2021 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Visible-Light-Induced CO2 Reduction by Mixed-Valence Tin Oxide2021

    • Author(s)
      Liu Yang-Shin、Yamaguchi Akira、Yang Yue、Abe Hideki、Ueda Shigenori、Tanabe Toyokazu、Miyauchi Masahiro
    • Journal Title

      ACS Applied Energy Materials

      Volume: 4 Issue: 12 Pages: 13415-13419

    • DOI

      10.1021/acsaem.1c02896

    • Related Report
      2021 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Active site separation of photocatalytic steam reforming of methane using a gas-phase photoelectrochemical system2021

    • Author(s)
      Kujirai Tomoki、Yamaguchi Akira、Fujita Takeshi、Abe Hideki、Miyauchi Masahiro
    • Journal Title

      Chemical Communications

      Volume: 57 Issue: 65 Pages: 8007-8010

    • DOI

      10.1039/d1cc02914b

    • Related Report
      2021 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Fabrication of Hydrogen Boride Thin Film by Ion Exchange in MgB22021

    • Author(s)
      T. Hirabayashi, S. Yasuhara, S. Shoji, A. Yamaguchi, H. Abe, S. Ueda, H. Zhu, T. Kondo, and M. Miyauchi
    • Journal Title

      Molecules

      Volume: 26 Issue: 20 Pages: 6212-6212

    • DOI

      10.3390/molecules26206212

    • Related Report
      2021 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Temperature dependence on bandgap of semiconductor photocatalysts2020

    • Author(s)
      Y. Cho, A. Yamaguchi, R. Uehara, S. Yasuhara, T. Hoshina, M. Miyauchi
    • Journal Title

      The Journal of Chemical Physics

      Volume: 152 Issue: 23 Pages: 231101-231101

    • DOI

      10.1063/5.0012330

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Acid Assisted Synthesis of HB Sheets through Exfoliation of MgB2 Bulk in Organic Media2020

    • Author(s)
      Kawamura Reiya、Yamaguchi Akira、Shimada Chika、Ishibiki Ryota、Fujita Takeshi、Kondo Takahiro、Miyauchi Masahiro
    • Journal Title

      Chemistry Letters

      Volume: 49 Issue: 10 Pages: 1194-1196

    • DOI

      10.1246/cl.200203

    • NAID

      130007923163

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Green light active photocatalyst for complete oxidation of organic molecules2020

    • Author(s)
      Yang Yue、Yamaguchi Akira、Jiang Haoyang、van der Kooy Annabel、Okunaka Sayuri、Hosogai Mariko、Tokudome Hiromasa、Miyauchi Masahiro
    • Journal Title

      Chemical Communications

      Volume: 56 Issue: 64 Pages: 9210-9213

    • DOI

      10.1039/d0cc03279d

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Antiviral Effect of Visible Light-Sensitive CuxO/TiO2 Photocatalyst2020

    • Author(s)
      Miyauchi Masahiro、Sunada Kayano、Hashimoto Kazuhito
    • Journal Title

      Catalysts

      Volume: 10 Issue: 9 Pages: 1093-1093

    • DOI

      10.3390/catal10091093

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Visible-light-driven dry reforming of methane using a semiconductor-supported catalyst2020

    • Author(s)
      Cho Yohei, Shoji Shusaku, Yamaguchi Akira, Hoshina Takuya, Fujita Takeshi, Abe Hideki, Miyauchi Masahiro
    • Journal Title

      Chemical Communications

      Volume: 56 Issue: 33 Pages: 4611-4614

    • DOI

      10.1039/d0cc00729c

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Visible-light-driven photocatalysis via reductant-to-band charge transfer in Cr(III) nanocluster-loaded SrTiO3 system2020

    • Author(s)
      Cakra Wardhana Aufandra、Yamaguchi Akira、Shoji Shusaku、Liu Min、Fujita Takeshi、Hitosugi Taro、Miyauchi Masahiro
    • Journal Title

      Applied Catalysis B: Environmental

      Volume: 270 Pages: 118883-118883

    • DOI

      10.1016/j.apcatb.2020.118883

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Photoinduced hydrogen release from hydrogen boride sheets2019

    • Author(s)
      Reiya Kawamura, Nguyen Thanh Cuong, Takeshi Fujita, Ryota Ishibiki, Toru Hirabayashi, Akira Yamaguchi, Iwao Matsuda, Susumu Okada, Takahiro Kondo, Masahiro Miyauchi
    • Journal Title

      Nature Communications

      Volume: 10 Issue: 1 Pages: 4880-4880

    • DOI

      10.1038/s41467-019-12903-1

    • NAID

      120007127794

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Synergistic photothermal and photochemical partial oxidation of methane over noble metals incorporated in mesoporous silica2019

    • Author(s)
      Jiang Haoyang、Peng Xiaobo、Yamaguchi Akira、Fujita Takeshi、Abe Hideki、Miyauchi Masahiro
    • Journal Title

      Chemical Communications

      Volume: 55 Issue: 91 Pages: 13765-13768

    • DOI

      10.1039/c9cc06170c

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Optical properties of single crystalline copper iodide with native defects: Experimental and density functional theoretical investigation2019

    • Author(s)
      Koyasu Satoshi、Umezawa Naoto、Yamaguchi Akira、Miyauchi Masahiro
    • Journal Title

      Journal of Applied Physics

      Volume: 125 Issue: 11 Pages: 115101-115101

    • DOI

      10.1063/1.5082865

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Growth of Large Single Crystals of Copper Iodide by a Temperature Difference Method Using Feed Crystal Under Ambient Pressure2018

    • Author(s)
      Koyasu Satoshi、Umezawa Naoto、Baniecki John D.、Yamaguchi Akira、Miyauchi Masahiro
    • Journal Title

      Crystal Growth & Design

      Volume: 18 Issue: 11 Pages: 6748-6756

    • DOI

      10.1021/acs.cgd.8b01024

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Visible-Light-Active Photoelectrochemical Z-Scheme System Based on Top 5 Clarke-Number Elements2018

    • Author(s)
      Miyamoto Hironao、Matsuzaki Kosuke、Yamaguchi Akira、Miyauchi Masahiro
    • Journal Title

      ACS Applied Energy Materials

      Volume: 1 Issue: 11 Pages: 5954-5959

    • DOI

      10.1021/acsaem.8b00978

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Photocatalytic CO2 Reduction Using a Pristine Cu2ZnSnS4 Film Electrode under Visible Light Irradiation2018

    • Author(s)
      Yoshida Toshiki、Yamaguchi Akira、Umezawa Naoto、Miyauchi Masahiro
    • Journal Title

      The Journal of Physical Chemistry C

      Volume: 122 Issue: 38 Pages: 21695-21702

    • DOI

      10.1021/acs.jpcc.8b04241

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Presentation] Elucidation of Interfacial Charge Excitation in Visible-light-active Cr2O3/SrTiO3 Photocatalyst System2021

    • Author(s)
      Aufandra Cakra Wardhana, Satoshi Ishii, Sou Yasuhara, Akira Yamaguchi, Masahiro Miyauchi
    • Organizer
      電気化学会第88回大会
    • Related Report
      2021 Annual Research Report
  • [Presentation] Antimicrobial Effect of Photocatalyst and Application to Products2021

    • Author(s)
      M Miyauchi
    • Organizer
      8th International Conference for Universal Design in the Cloud 2021
    • Related Report
      2021 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] TiO2-based Photocatalyst for Gas-Phase CO2 Recycling2021

    • Author(s)
      Masaru Kushida, Akira Yamaguchi, Masahiro Miyauchi
    • Organizer
      Materials Research Meeting 2021
    • Related Report
      2021 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Reaction site Separation of Photocatalytic Steam Reforming of Methane With Gas-Phase Photoelectrochemical System2021

    • Author(s)
      Tomoki Kujirai, Akira Yamaguchi, Takeshi Fujita, Hideki Abe, Masahiro Miyauchi
    • Organizer
      Materials Research Meeting 2021
    • Related Report
      2021 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Current situation on photocatalytic technology in Japan2020

    • Author(s)
      M. Miyauchi
    • Organizer
      Committee of Asian Standardization for Photocatalytic Material and Products (CASP2020)
    • Related Report
      2020 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Bandgap widening of BiVO4 by diluting Bi orbital component for higher oxidation activity2020

    • Author(s)
      Yue Yang, Akira Yamaguchi, Yohei Cho, Sayuri Okunaka, Hiromasa Tokudome, Masahiro Miyauchi
    • Organizer
      第25回シンポジウム「光触媒反応の最近の展開」
    • Related Report
      2020 Annual Research Report
  • [Presentation] Visible-Light-Active Photocatalysis over Chromium (III)-grafted Strontium Titanate2019

    • Author(s)
      Aufandra Cakra Wardhana, Akira Yamaguchi, Shusaku Shoji, Taro Hitosugi, Masahiro Miyauchi
    • Organizer
      2019年電気化学秋季大会, Sep. 2019.
    • Related Report
      2019 Annual Research Report
  • [Presentation] Metal-oxide-bases photocatalyst for energy and environment,2019

    • Author(s)
      M. Miyauchi
    • Organizer
      Tokyo Institute of Technology and Imperial College London's 2nd Workshop on Plastic Electronics
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Photo-induced Dry Reforming of Methane Using Metal Nanoparticles/ Metal Oxide Photocatalysts2019

    • Author(s)
      Masahiro Miyauchi, Shusaku Shoji, Yohei Cho, Akira Yamaguchi, Takeshi Fujita, Hideki Abe
    • Organizer
      Collaborative Conference on Advanced Materials 2019
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Photocatalytic Uphill Conversion of Natural Gas Reforming2019

    • Author(s)
      Masahiro Miyauchi, Shusaku Shoji, Yohei Cho, Akira Yamaguchi, Takeshi Fujita, Hideki Abe
    • Organizer
      第3回光触媒国際シンポジウム
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Metal-oxide-bases photocatalyst for energy and environment2019

    • Author(s)
      M. Miyauchi
    • Organizer
      Tokyo Institute of Technology and Imperial College London's 2nd Workshop on Plastic Electronics
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] TiO2 Based Photocatalyst for Environmental Remediation Using the Concept of Interfacial Charge Transfer Driven by Visible Light2018

    • Author(s)
      M. Miyauchi
    • Organizer
      Energy Materials and Nanotechnology 2018 (EMN 2018)
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Interfacial Charge Transfer between Ultrathin CuOx Film and Rutile TiO2 and Its Application for Efficient Photocatalysis2018

    • Author(s)
      M. Miyauchi
    • Organizer
      22nd International Conference on Photochemical Conversion and Storage of Solar Energy
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 温和な溶液プロセスによるナノクラスター担持光触媒の開発2018

    • Author(s)
      宮内雅浩
    • Organizer
      日本セラミックス協会 第31回秋季シンポジウム
    • Related Report
      2018 Annual Research Report
    • Invited
  • [Presentation] 環境浄化と人工光合成、それぞれの光触媒の設計2018

    • Author(s)
      宮内雅浩
    • Organizer
      光触媒工業会2018年度技術研究会
    • Related Report
      2018 Annual Research Report
    • Invited
  • [Book] 抗菌・抗ウイルス剤の最新動向2021

    • Author(s)
      宮内雅浩
    • Total Pages
      365
    • Publisher
      シーエムシー出版
    • ISBN
      9784781316017
    • Related Report
      2021 Annual Research Report

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Published: 2018-04-23   Modified: 2024-01-30  

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