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Preparation of new Preyssler-type tungstates and application as functional materials

Research Project

Project/Area Number 18H02058
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Review Section Basic Section 36010:Inorganic compounds and inorganic materials chemistry-related
Research InstitutionHiroshima University

Principal Investigator

Sadakane Masahiro  広島大学, 先進理工系科学研究科(工), 教授 (10342792)

Project Period (FY) 2018-04-01 – 2021-03-31
Project Status Completed (Fiscal Year 2020)
Budget Amount *help
¥17,680,000 (Direct Cost: ¥13,600,000、Indirect Cost: ¥4,080,000)
Fiscal Year 2020: ¥3,510,000 (Direct Cost: ¥2,700,000、Indirect Cost: ¥810,000)
Fiscal Year 2019: ¥3,640,000 (Direct Cost: ¥2,800,000、Indirect Cost: ¥840,000)
Fiscal Year 2018: ¥10,530,000 (Direct Cost: ¥8,100,000、Indirect Cost: ¥2,430,000)
Keywordsポリオキソメタレート / Preyssler / リンタングステート / 分子性酸化物 / 機能性材料 / Preyssler型 / 触媒 / 染色剤
Outline of Final Research Achievements

The purpose of this research is to find new Preyssler-type phosphotungstates ([P5W30O110M8n+)](15-n)-, M:encapsulated cations) by changing encapsulated cations and framework metals, and their applications as catalysis materials, conductive materials, and negative staining reagents.
I obtained following results. 1) I found a new solid state heating method to move encapsulated cations and outer counter cations, and found several new compounds. 2) I found new simple and high yield synthesis method of the Preyssler-type compounds. 3) I found that the new compounds are applicable to cataysis materials, proton-conducting materials, and memory materials. 4) I found new polymer materials which can support phosphotungstic acids.

Academic Significance and Societal Importance of the Research Achievements

リンとタングステンという元素を含む新しい酸化物分子の合成方法を見出しました。得られた新しい化合物は様々な分析手法で確認しました。また、得られた新しい化合物が、触媒材料、プロトン伝導材料およびメモリー材料として優れた性質を示すことも見出しました。これらの成果は、これまでに知られていなかった新しい材料を発見するのみならず、社会の役に立つ材料の開発に役立ちます。

Report

(4 results)
  • 2020 Annual Research Report   Final Research Report ( PDF )
  • 2019 Annual Research Report
  • 2018 Annual Research Report
  • Research Products

    (21 results)

All 2021 2020 2019 2018 Other

All Int'l Joint Research (5 results) Journal Article (8 results) (of which Int'l Joint Research: 3 results,  Peer Reviewed: 8 results,  Open Access: 1 results) Presentation (4 results) (of which Int'l Joint Research: 2 results,  Invited: 1 results) Remarks (3 results) Patent(Industrial Property Rights) (1 results)

  • [Int'l Joint Research] Newcastle University(英国)

    • Related Report
      2020 Annual Research Report
  • [Int'l Joint Research] Newcastle University(英国)

    • Related Report
      2019 Annual Research Report
  • [Int'l Joint Research] Universitat Rovira i Virgili(スペイン)

    • Related Report
      2019 Annual Research Report
  • [Int'l Joint Research] University of Dehli(インド)

    • Related Report
      2019 Annual Research Report
  • [Int'l Joint Research] Universitat Rovira i Virgili(スペイン)

    • Related Report
      2018 Annual Research Report
  • [Journal Article] Ultrahigh Proton Conduction via Extended Hydrogen-Bonding Network in a Preyssler-Type Polyoxometalate-Based Framework Functionalized with Lanthanide Ion2021

    • Author(s)
      T. Iwano, K. Shitamatsu, N. Ogiwara, M. Okuno, Y. Kikukawa, S. Ikemoto, S. Shirai, S. Muratsugu, P. Waddell, R. J. Errington, M. Sadakane, S. Uchida
    • Journal Title

      ACS Appl. Mater. Interfaces

      Volume: 13 Issue: 16 Pages: 19138-19147

    • DOI

      10.1021/acsami.1c01752

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Structural Characterization of Cerium‐encapsulated Preyssler‐type Phosphotungstate: Additional Evidence of Ce(III) in the Cavity2021

    • Author(s)
      Shitamatsu Kota、Kojima Tatsuhiro、Waddell Paul G.、Sugiarto、Ooyama Haruka Egawa、Errington R. John、Sadakane Masahiro
    • Journal Title

      Zeitschrift fuer anorganische und allgemeine Chemie

      Volume: 647 Issue: 11 Pages: 1239-1244

    • DOI

      10.1002/zaac.202100075

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Poly (Triethylene Glycol Methyl Ether Methacrylate) Hydrogel as Carriers of Phosphotungstic Acid for Acid Catalytic Reaction in Water2021

    • Author(s)
      Zhu JunJie、Gotoh Takehiko、Nakai Satoshi、Tsunoji Nao、Sadakane Masahiro
    • Journal Title

      Materials Advances

      Volume: - Issue: 11 Pages: 3556-3559

    • DOI

      10.1039/d1ma00278c

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Solid‐State Ion Migration in the Preyssler‐Type Phosphotungstate for the Preparation of the Dipotassium Cation‐Encapsulated Derivative2020

    • Author(s)
      Wihadi Muh. Nur Khoiru、Sadakane Masahiro
    • Journal Title

      Zeitschrift fuer anorganische und allgemeine Chemie

      Volume: 646 Issue: 15 Pages: 1297-1302

    • DOI

      10.1002/zaac.202000217

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis of Preyssler-Type Phosphotungstate with Sodium Cation in the Central Cavity through Migration of the Ion2020

    • Author(s)
      Wihadi Muh. Nur Khoiru、Hayashi Akio、Ozeki Tomoji、Ichihashi Katsuya、Ota Hiromi、Fujibayashi Masaru、Nishihara Sadafumi、Inoue Katsuya、Tsunoji Nao、Sano Tsuneji、Sadakane Masahiro
    • Journal Title

      Bulletin of the Chemical Society of Japan

      Volume: 93 Issue: 3 Pages: 461-466

    • DOI

      10.1246/bcsj.20190326

    • NAID

      130007808664

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Immobilization of Preyssler type heteropoly acids on siliceous mesoporous supports and their catalytic activities in the dehydration of ethanol2019

    • Author(s)
      Mahuya Bandyopadhyay, Divya Jadav, Nao Tsunoji, Tsuneji Sano, Masahiro Sadakane
    • Journal Title

      Reaction Kinetics, Mechanisms and Catalysis

      Volume: 128 Issue: 1 Pages: 139-147

    • DOI

      10.1007/s11144-019-01646-1

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Self-Assembled Tetrameric Lanthanide-Containing Germanotungstate [(Ln2GeW10O38)4(W3O8)(OH)4(H2O)2]26-: Syntheses, Crystal Structure, Photoluminescence and Electrochemical Properties2019

    • Author(s)
      Imran Khan, Reetam Kaushik, Ranjay K. Tiwari, Israel Mbomekalle, Pedro de Oliveira, Takashi Matono, Haruka Egawa, Ooyama, Masahiro Sadakane, Firasat Hussain
    • Journal Title

      ChemistrySelect

      Volume: 4 Issue: 43 Pages: 12668-12675

    • DOI

      10.1002/slct.201903379

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] A Sandwich Complex of Bismuth Cation and Mono-Lacunary α-Keggin-Type Phosphotungstate: Preparation and Structural Characterisation2018

    • Author(s)
      Wihadi Muh Nur Khoiru、Hayashi Akio、Ichihashi Katsuya、Ota Hiromi、Nishihara Sadafumi、Inoue Katsuya、Tsunoji Nao、Sano Tsuneji、Sadakane Masahiro
    • Journal Title

      European Journal of Inorganic Chemistry

      Volume: 2019 Issue: 3-4 Pages: 357-362

    • DOI

      10.1002/ejic.201800541

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Presentation] Synthesis and Application of new Preyssler-type Phosphotungstates2020

    • Author(s)
      Masahiro Sadakane
    • Organizer
      INPOMS Seminar
    • Related Report
      2020 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] ユーロピウムが骨格外に結合したPreyssler型リンタングステートの合成と構造解析2020

    • Author(s)
      下松恒太, Waddel Paul, Errington John, 津野地直, 佐野庸治, 定金正洋
    • Organizer
      日本化学会春年会第100回春季年会
    • Related Report
      2019 Annual Research Report
  • [Presentation] 希土類金属を1つ内包したPreyssler型リンタングステートのカリウム塩の熱挙動の検討2019

    • Author(s)
      下松恒太, 定金正洋, 津野地直, 佐野庸治
    • Organizer
      錯体討論会第69回討論会
    • Related Report
      2019 Annual Research Report
  • [Presentation] Self-Assembly of Bismuth(3+) and Mono-Lacunary alpha-Keggin-type Phosphotungstate: Preparation and Structural Characterization of Sandwich complex2018

    • Author(s)
      Muh. Nur Khoiru Wihadi, Akio Hayashi, Katsuya Ichihashi, Hiromi Ota, Sadafumi Nishihara, Katsuya Inoue, Nao Tsunoji, Tsuneji Sano, Masahiro Sadakane
    • Organizer
      43rd International Conference on Coordination Chemistry
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Remarks] 広島大学【研究成果】

    • URL

      https://www.hiroshima-u.ac.jp/news/63983

    • Related Report
      2020 Annual Research Report
  • [Remarks] 広島大学大学院先進理工系科学研究科、最近の研究

    • URL

      https://adse.hiroshima-u.ac.jp/?p=2186

    • Related Report
      2020 Annual Research Report
  • [Remarks] EurekAlert! News Release

    • URL

      https://www.eurekalert.org/pub_releases/2021-04/hu-bst042021.php

    • Related Report
      2020 Annual Research Report
  • [Patent(Industrial Property Rights)] 分子性金属酸化物クラスター、電子デバイス、揮発性メモリ、揮発性メモリ又は不揮発性メモリ用単分子誘電体層、および記憶装置2019

    • Inventor(s)
      西原禎文、藤林将、井上克也、定金正洋
    • Industrial Property Rights Holder
      西原禎文、藤林将、井上克也、定金正洋
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      2019-159643
    • Filing Date
      2019
    • Related Report
      2019 Annual Research Report

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Published: 2018-04-23   Modified: 2022-01-27  

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