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Development of multi-exciton generation system and photo-energy conversion in metal halide perovskite

Research Project

Project/Area Number 18H02069
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Review Section Basic Section 36020:Energy-related chemistry
Research InstitutionThe University of Tokyo

Principal Investigator

Kinoshita Takumi  東京大学, 大学院総合文化研究科, 講師 (60635168)

Project Period (FY) 2018-04-01 – 2022-03-31
Project Status Completed (Fiscal Year 2022)
Budget Amount *help
¥17,810,000 (Direct Cost: ¥13,700,000、Indirect Cost: ¥4,110,000)
Fiscal Year 2021: ¥1,820,000 (Direct Cost: ¥1,400,000、Indirect Cost: ¥420,000)
Fiscal Year 2020: ¥1,820,000 (Direct Cost: ¥1,400,000、Indirect Cost: ¥420,000)
Fiscal Year 2019: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
Fiscal Year 2018: ¥12,220,000 (Direct Cost: ¥9,400,000、Indirect Cost: ¥2,820,000)
Keywordsペロブスカイト / 多励起子生成 / ホットキャリア / 時間分解分光 / 光エネルギー変換 / ペロブスカイト太陽電池 / 鉛ハライドペロブスカイト / エキシトン / フォノンカップリング / 高速時間分解分光 / 結晶構造解析 / 有機金属ハライドペロブスカイト / 単結晶X線構造解析 / 金属ハライドペロブスカイト / エネルギー移動 / 光電変換 / 再生可能エネルギー / 有機金属ハライドペロブスカイ
Outline of Final Research Achievements

In this study, we found that the introduction of rare earth ions into lead halide perovskite thin film nanocrystals enables multi-exciton generation by utilizing the excess energy upon photoexcitation.
It was also found that the luminescence quantum yield of rare earths exceeds 1 by excitation at photon energies above the energy gap of perovskite.
On the other hand, the internal quantum yields of the rare earths were found to vary depending on the lattice distortion of the perovskite matrix crystal. The luminescence quantum yield was improved by reducing the lattice distortion of the crystal. In the future, it is expected to be developed into a high-efficiency solar cell with low thermal energy loss by improving the exciton energy extraction.

Academic Significance and Societal Importance of the Research Achievements

本研究では、ペロブスカイト薄膜中に希土類元素をドープすることによりドナーアクセプター材料が混合した半導体薄膜を作製し、多励起子生成系の構築に成功した。これらの成果は、太陽光のエネルギーを効率的に獲得できる技術としてデバイスのエネルギー変換効率の向上につながると期待される。さらに、本研究ではホットキャリアの余剰エネルギーの取り出しも成功した。これにより、本来は熱として失われるエネルギーを光エネルギーとして活用できるため、エネルギーロスを低減し、効率的なエネルギー利用が可能になるなど、エネルギー変換技術やエレクトロニクスの分野において、持続可能な社会の実現に向けた意義のある成果が得られた。

Report

(5 results)
  • 2022 Final Research Report ( PDF )
  • 2021 Annual Research Report
  • 2020 Annual Research Report
  • 2019 Annual Research Report
  • 2018 Annual Research Report
  • Research Products

    (20 results)

All 2023 2022 2021 2020 2019 2018

All Journal Article (10 results) (of which Int'l Joint Research: 2 results,  Peer Reviewed: 10 results,  Open Access: 5 results) Presentation (10 results) (of which Int'l Joint Research: 4 results,  Invited: 6 results)

  • [Journal Article] Crystal structure of bis[octakis(dimethyl sulfoxide-κO)ytterbium(III)] pentabromidoplumbate(II) tribromide dimethyl sulfoxide monosolvate: a ytterbium-doped lead halide perovskite precursor2023

    • Author(s)
      Kinoshita Takumi、Fukumoto Kanna、Segawa Hiroshi
    • Journal Title

      Acta Crystallographica Section E Crystallographic Communications

      Volume: 79 Issue: 4 Pages: 402-405

    • DOI

      10.1107/s2056989023002852

    • Related Report
      2021 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Spectral Splitting Solar Cells Constructed with InGaP/GaAs Two-Junction Subcells and Infrared PbS Quantum Dot/ZnO Nanowire Subcells2022

    • Author(s)
      Wang Haibin、Nakao Shoichiro、Miyashita Naoya、Oteki Yusuke、Giteau Maxime、Okada Yoshitaka、Takamoto Tatsuya、Saito Hidenori、Magaino Shinichi、Takagi Katsuhiko、Hasegawa Tetsuya、Kubo Takaya、Kinoshita Takumi、Nakazaki Jotaro、Segawa Hiroshi
    • Journal Title

      ACS Energy Letters

      Volume: 7 Issue: 8 Pages: 2477-2485

    • DOI

      10.1021/acsenergylett.2c01380

    • Related Report
      2021 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Highly Efficient Wideband Solar Energy Conversion Employing Singlet-Triplet Transitions2022

    • Author(s)
      Kinoshita Takumi
    • Journal Title

      Bulletin of the Chemical Society of Japan

      Volume: 95 Issue: 2 Pages: 341-352

    • DOI

      10.1246/bcsj.20210423

    • Related Report
      2021 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Enhancement of Near-Infrared Singlet?Triplet Absorption of Ru(II) Sensitizers for Improving Conversion Efficiency of Solar Cells2021

    • Author(s)
      Kinoshita Takumi、Otsubo Miki、Ono Takaoki、Segawa Hiroshi
    • Journal Title

      ACS Applied Energy Materials

      Volume: 4 Issue: 7 Pages: 7052-7063

    • DOI

      10.1021/acsaem.1c01113

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Perovskite/CIGS Spectral Splitting Double Junction Solar Cell with 28% Power Conversion Efficiency2020

    • Author(s)
      Nakamura Motoshi、Tada Keishi、Kinoshita Takumi、Bessho Takeru、Nishiyama Chie、Takenaka Issei、Kimoto Yoshinori、Higashino Yuta、Sugimoto Hiroki、Segawa Hiroshi
    • Journal Title

      iScience

      Volume: 23 Issue: 12 Pages: 101817-101817

    • DOI

      10.1016/j.isci.2020.101817

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] p-Doping of a Hole Transport Material via a Poly(ionic liquid) for over 20% Efficiency and Hysteresis-Free Perovskite Solar Cells2020

    • Author(s)
      Geffroy Camille、Grana Eftychia、Bessho Takeru、Almosni Samy、Tang Zeguo、Sharma Anirudh、Kinoshita Takumi、Awai Fumiyasu、Cloutet Eric、Toupance Thierry、Segawa Hiroshi、Hadziioannou Georges
    • Journal Title

      ACS Applied Energy Materials

      Volume: 3 Issue: 2 Pages: 1393-1401

    • DOI

      10.1021/acsaem.9b01819

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Solid-state Dye-sensitized Solar Cells Using (CH3NH3)2SnI6 Perovskite with Wideband Sensitizer2019

    • Author(s)
      Kinoshita Takumi、Kakeno Rentaro、Segawa Hiroshi
    • Journal Title

      Chemistry Letters

      Volume: 48 Issue: 7 Pages: 637-639

    • DOI

      10.1246/cl.190165

    • NAID

      130007674917

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Modulations of various alkali metal cations on organometal halide perovskites and their influence on photovoltaic performance2018

    • Author(s)
      Tang Zeguo、Uchida Satoshi、Bessho Takeru、Kinoshita Takumi、Wang Haibin、Awai Fumiyasu、Jono Ryota、Maitani Masato M.、Nakazaki Jotaro、Kubo Takaya、Segawa Hiroshi
    • Journal Title

      Nano Energy

      Volume: 45 Pages: 184-192

    • DOI

      10.1016/j.nanoen.2017.12.047

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Near-infrared Photoelectric Conversion by Singlet-Triplet Transition of the Iminopyridine Ru(II) Complex2018

    • Author(s)
      Kinoshita Takumi、Segawa Hiroshi
    • Journal Title

      Chemistry Letters

      Volume: 47 Issue: 10 Pages: 1311-1313

    • DOI

      10.1246/cl.180574

    • NAID

      130007496162

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Cesium lead halide perovskite quantum dot deposition on GaAs substrates by dip coating2018

    • Author(s)
      Amboy Jefril M.、Jeco Bernice Mae F. Yu、Wang Haibin、Kubo Takaya、Kinoshita Takumi、Li-Kao Zacharie Jehl、Shoji Yasushi、Ahsan Nazmul、Segawa Hiroshi、Okada Yoshitaka、Balbin Jessie Jaye R.
    • Journal Title

      2018 IEEE 7th World Conference on Photovoltaic Energy Conversion

      Volume: - Pages: 0467-0467

    • DOI

      10.1109/pvsc.2018.8548078

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Presentation] 光エネルギー変換に資する ハイブリッド材料開発2023

    • Author(s)
      木下卓巳
    • Organizer
      和歌山県工業技術センター合成技術セミナー
    • Related Report
      2021 Annual Research Report
    • Invited
  • [Presentation] Material Design of Lead Halide Perovskite towards Next Generation Solar Cells2022

    • Author(s)
      Takumi Kinoshita
    • Organizer
      The 5th International Union of Materials Research Societies International Conference of Young Researchers on Advanced Materials
    • Related Report
      2021 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 金属ハライドペロブスカイトのホットキャリアエネルギー抽出2022

    • Author(s)
      木下卓巳
    • Organizer
      2022年光化学討論会
    • Related Report
      2021 Annual Research Report
  • [Presentation] ペロブスカイトの光基礎物性と太陽電池への応用2021

    • Author(s)
      木下卓巳
    • Organizer
      京大学先端科学技術研究センターWEBセミナー
    • Related Report
      2020 Annual Research Report
    • Invited
  • [Presentation] スピン反転励起による高効率近赤外光エネルギー変換系の開拓2020

    • Author(s)
      木下 卓巳
    • Organizer
      日本化学会第100春季年会
    • Related Report
      2019 Annual Research Report
    • Invited
  • [Presentation] Multiple Exciton Generation in Doped Metal Halide Perovskites2019

    • Author(s)
      K. Fukumoto, T. Kinoshita, H. Segawa
    • Organizer
      The 8th LIA NextPV International Workshop
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Solution processed multijunction perovskite solar cells with wideband photosensitizers2018

    • Author(s)
      Takumi Kinoshita
    • Organizer
      2018 Taiwan-Japan Bilateral Symposium on Green Energy
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] スピン反転励起を利用する光エネルギー変換デバイスの固体化と高効率化2018

    • Author(s)
      木下卓巳
    • Organizer
      2018光化学討論会
    • Related Report
      2018 Annual Research Report
  • [Presentation] 金属ハライドペロブスカイトを用いた有機系多接合太陽電池の開発2018

    • Author(s)
      木下卓巳
    • Organizer
      光機能材料研究会 第70回講演会「多接合・マルチバンド太陽電池」
    • Related Report
      2018 Annual Research Report
    • Invited
  • [Presentation] Photophysical Properties of Excitons in all Inorganic-Perovskite Nanocrystals2018

    • Author(s)
      Kanna Fukumoto, Takumi Kinoshita, Hiroshi Segawa
    • Organizer
      7th LIA-NextPV Workshop 2018
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research

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Published: 2018-04-23   Modified: 2024-01-30  

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