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Behavior of MeHg production in a Hg(II) ion spiked paddy field soil during multi-year rice cultivation and the mechanism of MeHg accumulation in rice grain

Research Project

Project/Area Number 18H03392
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Review Section Basic Section 64010:Environmental load and risk assessment-related
Research InstitutionKagoshima University

Principal Investigator

KODAMATANI Hitoshi  鹿児島大学, 理工学域理学系, 准教授 (30434468)

Co-Investigator(Kenkyū-buntansha) 一谷 勝之  鹿児島大学, 農水産獣医学域農学系, 准教授 (10305162)
山本 正浩  国立研究開発法人海洋研究開発機構, 超先鋭研究開発部門(超先鋭研究プログラム), 研究員 (60435849)
武内 章記  国立研究開発法人国立環境研究所, 環境計測研究センター, 主任研究員 (10469744)
神崎 亮  鹿児島大学, 理工学域理学系, 准教授 (50363320)
冨安 卓滋  鹿児島大学, 理工学域理学系, 教授 (60217552)
Project Period (FY) 2018-04-01 – 2021-03-31
Project Status Completed (Fiscal Year 2020)
Budget Amount *help
¥17,810,000 (Direct Cost: ¥13,700,000、Indirect Cost: ¥4,110,000)
Fiscal Year 2020: ¥3,510,000 (Direct Cost: ¥2,700,000、Indirect Cost: ¥810,000)
Fiscal Year 2019: ¥3,900,000 (Direct Cost: ¥3,000,000、Indirect Cost: ¥900,000)
Fiscal Year 2018: ¥10,400,000 (Direct Cost: ¥8,000,000、Indirect Cost: ¥2,400,000)
Keywordsコメ / 水銀汚染 / メチル水銀 / 土壌 / 水田 / 無機水銀 / 汚染 / 土壌汚染 / 水銀 / 稲 / 化学形態
Outline of Final Research Achievements

To investigate the accumulation of methylmercury in rice grains, the uptake behavior of mercury by rice plant was examined through hydroponic experiments, which involved addition of mercury to the culture solution. In addition, the formation of methylmercury from mercury ion in waterlogged soil and the uptake of the formed methylmercury by rice plant were investigated. The results of hydroponic experiments showed that mercury ion and methylmercury, added to the culture solution, accumulated in the roots, and only methylmercury was transferred to the ears during ear growth. The concentration of methylmercury in the waterlogged soil fluctuated greatly during the rice cultivation period, with and without rice plants. Of note, methylmercury concentration increased with decreasing soil redox potential; however, with further decrease in soil redox potential, methylmercury concentration decreased.

Academic Significance and Societal Importance of the Research Achievements

本研究は,水銀汚染を受けた水田土壌でのメチル水銀生成と,コメのメチル水銀汚染について検討を進めたものである.水耕栽培実験により,根から吸収されたメチル水銀の状況がコメの水銀濃度に与える影響を確認した.また土壌でのメチル水銀生成は,稲の成長とは関係なく育成期間の間に大きく変動し,また土壌の水銀形態がメチル水銀生成に与える影響が大きいことを確認した.人体への影響は今後の課題となるが,コメは世界人口半分の主食であり,そのコメのメチル水銀汚染がどのように起こるのか詳細に調べた本研究成果の社会的意義は大きいと言える.

Report

(4 results)
  • 2020 Annual Research Report   Final Research Report ( PDF )
  • 2019 Annual Research Report
  • 2018 Annual Research Report
  • Research Products

    (18 results)

All 2021 2020 2019 2018

All Journal Article (8 results) (of which Peer Reviewed: 7 results,  Open Access: 1 results) Presentation (10 results) (of which Int'l Joint Research: 1 results,  Invited: 1 results)

  • [Journal Article] A novel luminol chemiluminescence induced by photoexcited ketones: A selective determination method for acetone in wastewater2021

    • Author(s)
      Hitoshi Kodamatani, Daisuke Yoshimine, Takahiro Fujioka, Ryo Kanzaki, Takashi Tomiyasu
    • Journal Title

      Talanta Open

      Volume: 3 Pages: 100035-100035

    • DOI

      10.1016/j.talo.2021.100035

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Inhibitory effect of alkyl groups on N-nitrosamine formation from secondary and tertiary alkylamines with monochloramine2021

    • Author(s)
      Hitoshi Kodamatani, Taketo Tanisue, Takahiro Fujioka, Ryo Kanzaki, Takashi Tomiyasu
    • Journal Title

      Environmental Technology & Innovation

      Volume: 26 Pages: 101520-101520

    • DOI

      10.1016/j.eti.2021.101520

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Contamination, Decomposition, and Formation of <i>N</i>-Nitrosodimethylamine in Water Samples at the ng/L Level of Determination2020

    • Author(s)
      Hitoshi Kodamatani, Kenta Sugihara, Taketo Tanisue, Ryo Kanzaki, Takashi Tomiyasu
    • Journal Title

      Analytical Sciences

      Volume: 36 Issue: 11 Pages: 1393-1399

    • DOI

      10.2116/analsci.20P162

    • NAID

      130007937681

    • ISSN
      0910-6340, 1348-2246
    • Year and Date
      2020-11-10
    • Related Report
      2020 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Detailed investigation of methylmercury accumulation in rice grain from Hg2+-spiked non-contaminated paddy field soils2020

    • Author(s)
      Kodamatani Hitoshi、Daiba Yuri、Morisaki Shintarou、Ichitani Katsuyuki、Kanzaki Ryo、Tomiyasu Takashi
    • Journal Title

      Chemosphere

      Volume: 247 Pages: 125827-125827

    • DOI

      10.1016/j.chemosphere.2020.125827

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Proton Thermodynamics in a Protic Ionic Liquid, Ethylammonium Nitrate2019

    • Author(s)
      Kanzaki Ryo、Kodamatani Hitoshi、Tomiyasu Takashi
    • Journal Title

      Chemistry A European Journal

      Volume: 25 Issue: 59 Pages: 13500-13503

    • DOI

      10.1002/chem.201903485

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] 化学発光検出法を利用した有機水銀分析法の開発2019

    • Author(s)
      児玉谷 仁,冨安 卓滋
    • Journal Title

      ケミカル エンジニアリング

      Volume: 64 Pages: 63-70

    • NAID

      40021770767

    • Related Report
      2018 Annual Research Report
  • [Journal Article] Behavior of mercury from the fumarolic activity of Mt. Myoko, Japan: production of methylmercury and ethylmercury in forest soil2018

    • Author(s)
      Hitoshi Kodamatani, Souta Katsuma, Azusa Shigetomi, Toshimune Hokazono, Ryusuke Imura, Ryo Kanzaki, Takashi Tomiyasu
    • Journal Title

      Environmental Earth Sciences

      Volume: 77 Issue: 13 Pages: 478-478

    • DOI

      10.1007/s12665-018-7616-y

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Validation of pH Standards and Estimation of the Activity Coefficients of Hydrogen and Chloride Ions in an Ionic Liquid, Ethylammonium Nitrate2018

    • Author(s)
      Ryo Kanzaki, Hikaru Daiba, Hitoshi Kodamatani, Takashi Tomiyasu
    • Journal Title

      The Journal of Physical Chemistry B

      Volume: 122 Issue: 46 Pages: 10593-10599

    • DOI

      10.1021/acs.jpcb.8b08870

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Presentation] 大気中N-ニトロソアミン類の測定法開発2020

    • Author(s)
      杉原健太,児玉谷仁,神﨑亮,冨安卓滋
    • Organizer
      第80回分析化学討論会
    • Related Report
      2020 Annual Research Report
  • [Presentation] 水俣市及びその周辺土壌中における水銀濃度分布2020

    • Author(s)
      下鶴優美,児玉谷仁,神﨑亮,冨安卓滋
    • Organizer
      第80回分析化学討論会
    • Related Report
      2020 Annual Research Report
  • [Presentation] 水俣市化学工場周辺土壌中の総水銀及び有機水銀分布2020

    • Author(s)
      下鶴優美,児玉谷仁,神﨑亮,冨安卓滋
    • Organizer
      2020年度日本地球化学会67年会
    • Related Report
      2020 Annual Research Report
  • [Presentation] 水晶振動子を利用した液相中の水銀の還元気化測定法の検討2020

    • Author(s)
      野田和俊,児玉谷仁,冨安卓滋,丸本 幸治,愛澤 秀信
    • Organizer
      ケミカルセンサ研究会
    • Related Report
      2020 Annual Research Report
  • [Presentation] BEHAVIOR OF MEHG PRODUCTION IN A HG(II) ION SPIKED PADDY FIELD SOIL DURING MULTI-YEAR RICE CULTIVATION AND THE MECHANISM OF MEHG ACCUMULATION IN RICE GRAIN2019

    • Author(s)
      Hitoshi Kodamatani, Shintaro Hamasuna, Kana Honda, Takahisa Yokota, Katsuyuki Ichitani, Ryo Kanzaki, Takashi Tomiyasu
    • Organizer
      14th International Conference on Mercury as a Global Pollutant
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 222 nm光源による光化学反応を用いた硝酸・亜硝酸イオンの高感度分析法開発2019

    • Author(s)
      久保翔太郎、児玉谷仁、神崎亮、冨安卓滋
    • Organizer
      第79回分析化学討論会
    • Related Report
      2019 Annual Research Report
  • [Presentation] 化学発光反応を利用したメチル水銀分析法の開発と環境試料への応用2018

    • Author(s)
      児玉谷 仁
    • Organizer
      第103回プラズマ分光分析研究会
    • Related Report
      2018 Annual Research Report
    • Invited
  • [Presentation] 222 nm光源による硝酸・亜硝酸イオンの光化学反応2018

    • Author(s)
      久保 翔太郎,児玉谷 仁,神崎 亮,冨安 卓滋
    • Organizer
      日本分析化学会第67年会
    • Related Report
      2018 Annual Research Report
  • [Presentation] 光化学反応とルミノール化学発光を利用した硝酸・亜硝酸の高感度分析法の開発2018

    • Author(s)
      久保 翔太郎,児玉谷 仁,神崎 亮,冨安 卓滋
    • Organizer
      第78回分析化学討論会
    • Related Report
      2018 Annual Research Report
  • [Presentation] 水素化物発生原子吸光光度法による生体試料中Seの定量2018

    • Author(s)
      野添 千裕,児玉谷 仁,神崎 亮,冨安 卓滋
    • Organizer
      第78回分析化学討論会
    • Related Report
      2018 Annual Research Report

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Published: 2018-04-23   Modified: 2022-01-27  

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