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The environmental alteration of perfluoroalkyl substances by photodegradation

Research Project

Project/Area Number 18H03394
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Review Section Basic Section 64010:Environmental load and risk assessment-related
Research InstitutionNational Institute of Advanced Industrial Science and Technology

Principal Investigator

Taniyasu Sachi  国立研究開発法人産業技術総合研究所, エネルギー・環境領域, 主任研究員 (00443200)

Project Period (FY) 2018-04-01 – 2021-03-31
Project Status Completed (Fiscal Year 2020)
Budget Amount *help
¥15,600,000 (Direct Cost: ¥12,000,000、Indirect Cost: ¥3,600,000)
Fiscal Year 2020: ¥4,680,000 (Direct Cost: ¥3,600,000、Indirect Cost: ¥1,080,000)
Fiscal Year 2019: ¥4,810,000 (Direct Cost: ¥3,700,000、Indirect Cost: ¥1,110,000)
Fiscal Year 2018: ¥6,110,000 (Direct Cost: ¥4,700,000、Indirect Cost: ¥1,410,000)
Keywordsペルフルオロアルキル化合物 / 残留性有機汚染物質 / 光分解反応
Outline of Final Research Achievements

Perfluorooctanesulfonate (PFOS) and related perfluoroalkyl substances (PFAS) have been revealed as ubiquitous contaminants in the open environment. The most important nature of PFOS and perfluorooctanoic acid (PFOA) was “persistence” in the environment. Although several hypotheses regarding biological/ environmental breakdown (secondary formation) from precursors such as FTOHs (fluorotelomer alcohols) to PFOS and PFOA have been suggested, the evidence of photodegradation of perfluorosulfonic acids (PFSAs) and perflurocalboxylic acids (PFCAs) themselves in the environment is not available to date. To elucidate photodegradation of PFAS that received intensive solar radiation, aqueous solutions of individual PFAS were exposure to solar radiation under three times of artificial UV irradiation (high irradiance experiments) and under natural environmental conditions (filed experiment).

Academic Significance and Societal Importance of the Research Achievements

これまで知見が大きく不足していたPFASの全球レベルの環境動態・残留性を理解するための重要パラメータである自然環境中光分解反応の解析を試みた。その結果、難分解性として知られるPFOAも光により分解し、また、飛行時間型質量分析計を用いたノンターゲット分析技術により、実環境下においても、PFOAや8:2FTOHから分解物として2H-PFCAやuPFCAが生成することを明らかにした。一方、ノンターゲット分析では多数の未知の分解産物が検出されたが、推定/同定できた化合物はごく一部であったため、今後、環境中での動態を明らかにするためには、未知の質量数を推定/同定する技術の進歩が期待される。

Report

(4 results)
  • 2020 Annual Research Report   Final Research Report ( PDF )
  • 2019 Annual Research Report
  • 2018 Annual Research Report
  • Research Products

    (24 results)

All 2021 2020 2019 2018 Other

All Int'l Joint Research (7 results) Journal Article (9 results) (of which Int'l Joint Research: 9 results,  Peer Reviewed: 9 results,  Open Access: 1 results) Presentation (8 results) (of which Int'l Joint Research: 5 results,  Invited: 2 results)

  • [Int'l Joint Research] Nanjing University/City University of Hong Kong/Xiamen University(中国)

    • Related Report
      2020 Annual Research Report
  • [Int'l Joint Research] ISTAR(インド)

    • Related Report
      2020 Annual Research Report
  • [Int'l Joint Research] SLU(スウェーデン)

    • Related Report
      2020 Annual Research Report
  • [Int'l Joint Research] Wadsworth CenterI(米国)

    • Related Report
      2019 Annual Research Report
  • [Int'l Joint Research] 南京大学/厦門大学/香港城市大学(中国)

    • Related Report
      2019 Annual Research Report
  • [Int'l Joint Research] Orebro University(スウェーデン)

    • Related Report
      2019 Annual Research Report
  • [Int'l Joint Research] ISTAR(インド)

    • Related Report
      2019 Annual Research Report
  • [Journal Article] What's in the water? - Target and suspect screening of contaminants of emerging concern in raw water and drinking water from Europe and Asia2021

    • Author(s)
      Troeger Rikard、Ren Hanwei、Yin Daqiang、Postigo Cristina、Nguyen Phuoc-Dan、Baduel Christine、Golovko Oksana、Been Frederic、Joerss Hanna、Boleda Maria Rosa、Polesello Stefano、Roncoroni Marco、Taniyasu Sachi、Menger Frank、Ahrens Lutz、Lai Foon Yin、Wiberg Karin
    • Journal Title

      Water Research

      Volume: 272 Pages: 117099-117099

    • DOI

      10.1016/j.watres.2021.117099

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Per- and polyfluoroalkyl substances in surface water, gas and particle in open ocean and coastal environment2021

    • Author(s)
      Yamazaki Eriko、Taniyasu Sachi、Wang Xinhong、Yamashita Nobuyoshi
    • Journal Title

      Chemosphere

      Volume: 272 Pages: 129869-129869

    • DOI

      10.1016/j.chemosphere.2021.129869

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Simultaneous analysis of neutral and ionizable per- and polyfluoroalkyl substances in air2021

    • Author(s)
      Wu Rongben、Lin Huiju、Yamazaki Eriko、Taniyasu Sachi、Soerengaard Mattias、Ahrens Lutz、Lam Paul K.S.、Eun Heesoo、Yamashita Nobuyoshi
    • Journal Title

      Chemosphere

      Volume: 280 Pages: 130607-130607

    • DOI

      10.1016/j.chemosphere.2021.130607

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Nationwide distribution and potential risk of bisphenol analogues in Indian waters2020

    • Author(s)
      Lalwani Dipa、Ruan Yuefei、Taniyasu Sachi、Yamazaki Eriko、Kumar Nirmal J.I.、Lam Paul K.S.、Wang Xinhong、Yamashita Nobuyoshi
    • Journal Title

      Ecotoxicology and Environmental Safety

      Volume: 200 Pages: 110718-110718

    • DOI

      10.1016/j.ecoenv.2020.110718

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Per- and Polyfluoroalkyl Substances in the Air Particles of Asia: Levels, Seasonality, and Size-Dependent Distribution2020

    • Author(s)
      Lin Huiju、Taniyasu Sachi、Yamazaki Eriko、Wei Si、Wang Xinhong、Gai Nan、Kim Jin Hyo、Eun Heesoo、Lam Paul K. S.、Yamashita Nobuyoshi
    • Journal Title

      Environmental Science & Technology

      Volume: 54 Issue: 22 Pages: 14182-14191

    • DOI

      10.1021/acs.est.0c03387

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Nontarget Discovery of Per- and Polyfluoroalkyl Substances in Atmospheric Particulate Matter and Gaseous Phase Using Cryogenic Air Sampler2020

    • Author(s)
      Yu Nanyang、Wen Haozhe、Wang Xuebing、Yamazaki Eriko、Taniyasu Sachi、Yamashita Nobuyoshi、Yu Hongxia、Wei Si
    • Journal Title

      Environmental Science & Technology

      Volume: 54 Issue: 6 Pages: 3103-3113

    • DOI

      10.1021/acs.est.9b05457

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Vertical distribution of perfluoroalkyl substances in water columns around the Japan Sea an the Mediterranean Sea2019

    • Author(s)
      Eriko Yamazaki, Sachi Taniyasu, Yuefei Ruan, Qi Wang, Gert Petrick, Toste Tanhua, Toshitaka Gamo, Xinhong Wang, Paul K.S. Lam, Nobuyoshi Yamashita
    • Journal Title

      Chemosphere

      Volume: 231 Pages: 487-494

    • DOI

      10.1016/j.chemosphere.2019.05.132

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Accumulation of perfluoroalkyl substances in lysimeter-grown rice in Japan using tap water and simulated contaminated water2019

    • Author(s)
      Yamazaki Eriko、Taniyasu Sachi、Noborio Kosuke、Eun Heesoo、Thaker Pooja、Kumar Nirmal J.I.、Wang Xinhong、Yamashita Nobuyoshi
    • Journal Title

      Chemosphere

      Volume: 231 Pages: 502-509

    • DOI

      10.1016/j.chemosphere.2019.05.022

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Interlaboratory trial for validation of ISO 21675 for per- and polyfluoroalkyl substances (PFAS) in water2018

    • Author(s)
      Sachi Taniyasu, Eric J. Reiner, Nicole Riddell, Eriko Yamazaki, Nobuyoshi Yamashita
    • Journal Title

      ORGANOHALOGEN COMPOUNDS

      Volume: 80 Pages: 1036-1038

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Presentation] The environmental alteration of perfluoroalkyl substances by photodegradation2019

    • Author(s)
      Taniyasu Sachi, Yamashita Nobuyoshi, Yamazaki Eriko, Kannan Kurunthachalam
    • Organizer
      39th International Symposium on Halogenated Persistent Organic Pollutants (Dioxin 2019)
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Distribution of perfluorocarboxylic acids associated with atmospheric particulate matter from Asian countries2019

    • Author(s)
      MAKHIJA Lalwani Dipa, Yamazaki Eriko, Lin Huiju, Ruan, Yuefei, Taniyasu Sachi, Kumar Nimarl, Gai Nan, Yang Yong, Lam K.S. Lam Yamashita Nobuyoshi
    • Organizer
      39th International Symposium on Halogenated Persistent Organic Pollutants (Dioxin 2019)
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Application of cryogenic air sampler to monitor per- and polyfluoroalkyl substances in the atmosphere2019

    • Author(s)
      Lin Huiju, Yamazaki Eriko, MAKHIJA Lalwani Dipa, Ruan, Yuefei, Taniyasu Sachi, Yamashita Nobuyoshi, Lam K.S. Paul
    • Organizer
      39th International Symposium on Halogenated Persistent Organic Pollutants (Dioxin 2019)
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Potential input of PFAS into the Japan Sea2019

    • Author(s)
      Yamazaki Eriko, Taniyasu Sachi, Ruan Yuefei, Wang Qi, Petrick GErt, Tanhua Toste, Gamo Toshitaka, Wang Xinhong, Lam K.S. Lam, Yamashita Nobuyoshi
    • Organizer
      39th International Symposium on Halogenated Persistent Organic Pollutants (Dioxin 2019)
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] The international standardization for determination of poly and per-fluorinated alkyl substances (PFASs) in water samples2018

    • Author(s)
      Sachi Taniyasu, Nobuyoshi Yamashita
    • Organizer
      the 4th International conference on Environmental Pollution and Health (ICEPH)
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 水試料中のペルフルオロアルキル化合物測定方法の標準化2018

    • Author(s)
      谷保 佐知
    • Organizer
      第27回環境化学討論会
    • Related Report
      2018 Annual Research Report
    • Invited
  • [Presentation] 水試料中ペルフルオロアルキル化合物一斉分析の課題と国際標準規格化2018

    • Author(s)
      谷保 佐知
    • Organizer
      平成30年度 産総研 エネルギー・環境シンポジウム「水環境の評価、修復およびそれを支える計測技術」
    • Related Report
      2018 Annual Research Report
  • [Presentation] Interlaboratory trial for validation of ISO 21675 for per- and polyfluoroalkyl substances (PFAS) in water2018

    • Author(s)
      Sachi Taniyasu, Eric J. Reiner, Nicole Riddell, Eriko Yamazaki, Nobuyoshi Yamashita
    • Organizer
      the 38th International Symposium on Halogenated Persistent Organic Pollutants (POPs)
    • Related Report
      2018 Annual Research Report

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Published: 2018-04-23   Modified: 2022-01-27  

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