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Increasing efficiency of carbon dioxide recycling reaction using integrated reaction system by membrane reactor

Research Project

Project/Area Number 18H03419
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Review Section Basic Section 64050:Sound material-cycle social systems-related
Research InstitutionGifu University

Principal Investigator

Uemiya Shigeyuki  岐阜大学, 工学部, 教授 (60221800)

Co-Investigator(Kenkyū-buntansha) 宮本 学  岐阜大学, 工学部, 准教授 (60538180)
Project Period (FY) 2018-04-01 – 2021-03-31
Project Status Completed (Fiscal Year 2021)
Budget Amount *help
¥17,550,000 (Direct Cost: ¥13,500,000、Indirect Cost: ¥4,050,000)
Fiscal Year 2020: ¥2,860,000 (Direct Cost: ¥2,200,000、Indirect Cost: ¥660,000)
Fiscal Year 2019: ¥5,200,000 (Direct Cost: ¥4,000,000、Indirect Cost: ¥1,200,000)
Fiscal Year 2018: ¥9,490,000 (Direct Cost: ¥7,300,000、Indirect Cost: ¥2,190,000)
Keywordsメンブレンリアクター / プロセス強化 / 二酸化炭素 / アンモニア / 水素 / メタン化 / 反応シミュレーション / カーボンサイクル / 複合化 / 化学反応シミュレーション / 資源化 / 触媒活性
Outline of Final Research Achievements

The application of a membrane reactor capable of effective mass transfer and heat transfer to the combined reaction process of converting ammonia derived from renewable energy into hydrogen and reacting it with CO2 to produce methane was investiagted. As catalysts suitable for reaction conditions in the membrane reactor, Ru/Ba/γ-Al2O3 and Ru/ZrO2 were developed for NH3 decomposition and CO2 methanation, respectively. Simulation analysis was carried out with creating a reaction model in parallel with the experiments for the membrane reactor. It was found that the development of a highly active NH3 decomposition catalyst and superior hydrogen-permeable membrane are the most important issues in aiming to improve the efficiency of cobined reaction process using a hydrogen-permeable membrane reactor.

Academic Significance and Societal Importance of the Research Achievements

地球温暖化対策としてCO2の資源化(カーボンリサイクル)には、従来にない高効率な化学プロセスが必要と言える。高効率化の一つの試みが、反応を分離・精製さらには加熱や冷却などの単位操作と組み合わせによる集積化であり、単にプロセスの簡略化のみではなく、既存の化学プロセスではなしえなかった相乗効果が期待できる。再生可能エネルギー由来のアンモニアを水素に再転換しCO2と反応させてメタンを製造する複合化反応プロセスに適した触媒を開発し、反応のシミュレーション解析により高活性なNH3分解触媒および水素透過膜の開発がシステムの効率化を目指す上で重要な課題であることを示すことができた。

Report

(4 results)
  • 2021 Final Research Report ( PDF )
  • 2020 Annual Research Report
  • 2019 Annual Research Report
  • 2018 Annual Research Report
  • Research Products

    (9 results)

All 2022 2019 2018 Other

All Presentation (7 results) (of which Int'l Joint Research: 4 results) Book (1 results) Remarks (1 results)

  • [Presentation] 膜反応器を用いたNH3分解とCO2メタン化の複合化反応システムとその1D-モデル解析2022

    • Author(s)
      後藤 遼、林 優斗、Arif Gunawan、宮本 学、近江靖則、上宮成之
    • Organizer
      化学工学会第87年会
    • Related Report
      2020 Annual Research Report
  • [Presentation] Combined reaction system of NH3 decomposition and CO2 methanation using hydrogen-permeable membrane reactor2019

    • Author(s)
      S. Uemiya
    • Organizer
      14th International Conference on Catalysis in Membrane Reactors (ICCMR14)
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Hydrogen-permeable membrane reactor applicable to combined reaction system of NH3 decomposition and CO2 methanation2019

    • Author(s)
      S. Uemiya, A. Hamajima, M. Miyamoto, Y. Oumi
    • Organizer
      18th Asia Pacific Confederation of Chemical Engineering Congress (APCChE2019)
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Effect of Membrane Permeability on the Performance of Dry Reforming of Methane Using Hydrogen Permeable Membrane Reactor2019

    • Author(s)
      M. Candra, A. Hamajima, S. Kato, Y. Oumi, M. Miyamoto, S. Uemiya
    • Organizer
      18th Asia Pacific Confederation of Chemical Engineering Congress (APCChE2019)
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] アンモニア分解とCO2メタン化の膜反応器型 複合反応システムのための触媒の検討2018

    • Author(s)
      濱島 亮、宮本 学、近江靖則、上宮成之
    • Organizer
      化学工学会第50回秋季大会
    • Related Report
      2018 Annual Research Report
  • [Presentation] 水素分離型メンブレンリアクターを用いたメタンドライリフォーミングによる合成ガス製造2018

    • Author(s)
      上宮成之、濱島 亮、高柳良基、加藤聡一朗 、近江靖則、宮本 学
    • Organizer
      石油学会第48回石油・石油化学討論会講演
    • Related Report
      2018 Annual Research Report
  • [Presentation] Effect of Catalytic Activity on the Performance of Dry Reforming of Methane Using Hydrogen-permeable Membrane Reactor2018

    • Author(s)
      Shigeyuki Uemiya, Akira Hamajima, Yoshiki Takayanagi, Soichiro Kato, Manabu Miyamoto, Yasunori Oumi
    • Organizer
      6th International Workshop on Process Intensification
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Book] 水素の製造、輸送・貯蔵技術と材料開発 事例集:第5章第5節 パラジウム系水素分離膜の高性能化技術2019

    • Author(s)
      上宮成之、共同執筆
    • Publisher
      技術情報協会
    • ISBN
      9784861047459
    • Related Report
      2018 Annual Research Report
  • [Remarks] 触媒・分離工学 上宮・宮本研究室

    • URL

      https://www1.gifu-u.ac.jp/~chemeng/index.html

    • Related Report
      2019 Annual Research Report 2018 Annual Research Report

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Published: 2018-04-23   Modified: 2023-01-30  

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