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Development of a 3d local crystal structure analysis method using electron nano-probe and its application to relaxors

Research Project

Project/Area Number 18H03674
Research Category

Grant-in-Aid for Scientific Research (A)

Allocation TypeSingle-year Grants
Section一般
Review Section Medium-sized Section 13:Condensed matter physics and related fields
Research InstitutionTohoku University

Principal Investigator

Tsuda Kenji  東北大学, 学際科学フロンティア研究所, 教授 (00241274)

Project Period (FY) 2018-04-01 – 2021-03-31
Project Status Completed (Fiscal Year 2020)
Budget Amount *help
¥44,850,000 (Direct Cost: ¥34,500,000、Indirect Cost: ¥10,350,000)
Fiscal Year 2020: ¥4,290,000 (Direct Cost: ¥3,300,000、Indirect Cost: ¥990,000)
Fiscal Year 2019: ¥19,110,000 (Direct Cost: ¥14,700,000、Indirect Cost: ¥4,410,000)
Fiscal Year 2018: ¥21,450,000 (Direct Cost: ¥16,500,000、Indirect Cost: ¥4,950,000)
Keywords局所結晶構造解析 / 収束電子回折 / ナノ電子プローブ / 機械学習 / リラクサー
Outline of Final Research Achievements

In order to develop a 3-dimensional local structure analysis method using an electron nano-probe, a new system was developed to map energy-filtered convergent-beam electron diffraction (CBED) data with a high speed and a high angular resolution. Deep neural network was successfully applied for accelerating dynamical diffraction intensity calculations of large-angle CBED (LACBED) patterns. For obtaining structural information in depth-direction, the scattering matrix method was implemented in our dynamical diffraction simulation code MBFIT for describing distribution of local structures in the electron beam direction. This newly developed analysis method was applied to local crystal structure analysis of a ferroelectric twin boundary in CaTiO3, visualization of ferroaxial domains in NiTiO3, electrostatic potential and electron density analysis of quantum paraelectric phase of KTaO3, local structure analysis of relaxor-like nano-domains in BaTiO3 under applying electric field.

Academic Significance and Societal Importance of the Research Achievements

結晶構造は材料開発の基礎となる重要な情報であるが、近年、大きな領域の平均の結晶構造ではなく、局所的な結晶構造とその不均一性が新奇物性の起源となっている例が増加している。このような試料の解析には、ナノメーター (=10億分の1 m)に絞った電子線(ナノ電子プローブ)を使う方法が威力を発揮する。本研究ではナノ電子プローブを用いて局所結晶構造とその3次元分布を定量的に調べる新たな方法を開発し、種々の物質の局所結晶構造解析に適用して、ナノ電子プローブによる局所結晶構造解析法の適用範囲を大きく拡げた。

Report

(4 results)
  • 2020 Annual Research Report   Final Research Report ( PDF )
  • 2019 Annual Research Report
  • 2018 Annual Research Report
  • Research Products

    (42 results)

All 2021 2020 2019 2018

All Journal Article (7 results) (of which Peer Reviewed: 7 results,  Open Access: 1 results) Presentation (35 results) (of which Int'l Joint Research: 8 results,  Invited: 8 results)

  • [Journal Article] Evaluation of TEM specimen quality prepared by focused ion beam using symmetry breaking index of convergent-beam electron diffraction2021

    • Author(s)
      Morikawa Daisuke、Ageishi Masaki、Sato Kaori、Tsuda Kenji、Terauchi Masami
    • Journal Title

      Microscopy

      Volume: - Issue: 4 Pages: 394-397

    • DOI

      10.1093/jmicro/dfab002

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Local crystal symmetry and structure at CaTiO3 twin boundaries2021

    • Author(s)
      Morikawa D.、Tsuda K.
    • Journal Title

      Applied Physics Letters

      Volume: 118 Issue: 9 Pages: 092901-092901

    • DOI

      10.1063/5.0043851

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Improvement of precision in refinements of structure factors using CBED patterns taken at Bragg excited conditions2021

    • Author(s)
      Bikas Aryal, Daisuke Morikawa, Kenji Tsuda and Masami Terauchi
    • Journal Title

      Acta Crystallographica, section A

      Volume: -

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Structural-transition-driven antiferromagnetic to spin-glass transition in Cd-Mg-Tb 1/1 approximants2020

    • Author(s)
      Labib Farid、Okuyama Daisuke、Fujita Nobuhisa、Yamada Tsunetomo、Ohhashi Satoshi、Morikawa Daisuke、Tsuda Kenji、Sato Taku J、Tsai An-Pang
    • Journal Title

      Journal of Physics: Condensed Matter

      Volume: 32 Issue: 48 Pages: 485801-485801

    • DOI

      10.1088/1361-648x/aba921

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Evaluation of accuracy in the determination of crystal structure factors using large-angle convergent-beam electron diffraction patterns2020

    • Author(s)
      Morikawa Daisuke、Tsuda Kenji
    • Journal Title

      Microscopy

      Volume: 70 Issue: 2 Pages: 178-185

    • DOI

      10.1093/jmicro/dfaa041

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Visualization of ferroaxial domains in an order-disorder type ferroaxial crystal2020

    • Author(s)
      Hayashida T.、Uemura Y.、Kimura K.、Matsuoka S.、Morikawa D.、Hirose S.、Tsuda K.、Hasegawa T.、Kimura T.
    • Journal Title

      Nature Communications

      Volume: 11 Issue: 1 Pages: 1-8

    • DOI

      10.1038/s41467-020-18408-6

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Electron diffraction study of crystal structures of (Sr1-xBax)2Nb2O72019

    • Author(s)
      Bikas Aryal, Daisuke Morikawa, Kenji Tsuda, Shinya Tsukada, Yukikuni Akishige and Masami Terauchi
    • Journal Title

      Physical Review Materials

      Volume: 3 Issue: 4 Pages: 044405-044405

    • DOI

      10.1103/physrevmaterials.3.044405

    • NAID

      130007647744

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Presentation] 収束電子回折法による試料深さ方向の構造解析の試み2021

    • Author(s)
      津田健治、森川大輔
    • Organizer
      日本物理学会 第76回年次大会
    • Related Report
      2020 Annual Research Report
  • [Presentation] 収束電子回折法によるBaTiO3ナノドメインの電場印可その場観察2021

    • Author(s)
      森川大輔、津田健治
    • Organizer
      日本物理学会 第76回年次大会
    • Related Report
      2020 Annual Research Report
  • [Presentation] Structure optimization of NdBaMn2O6 by combination of CBED and DFT calculations2021

    • Author(s)
      M. S. Islam, D. Morikawa, K. Tsuda, S. Yamada and M. Terauchi
    • Organizer
      日本物理学会 第76回年次大会
    • Related Report
      2020 Annual Research Report
  • [Presentation] Improvement of accuracy and precision in refinement of crystal structure factors using zone-axis incidence and tilted CBED patterns2021

    • Author(s)
      B. Aryal, D. Morikawa, K. Tsuda and M. Terauchi
    • Organizer
      American Physical Society (APS) March Meeting 2021
    • Related Report
      2020 Annual Research Report
  • [Presentation] 収束電子回折法による局所結晶構造解析2021

    • Author(s)
      津田健治
    • Organizer
      日本表面真空学会 マイクロビームアナリシス技術部会 マイクロビームアナリシス研修セミナー
    • Related Report
      2020 Annual Research Report
    • Invited
  • [Presentation] ビームロッキングEDS法による(Ba,Ca)TiO3のCaドーパント位置の解析2021

    • Author(s)
      安住成, 津田健治, 森川大輔,寺内正己, 大塚真弘, 武藤俊介, 符徳勝, 伊藤満
    • Organizer
      第38回強誘電体会議(FMA38)
    • Related Report
      2020 Annual Research Report
  • [Presentation] ビームロッキングEDS法によるCaドープBaTiO3のCa位置の解析2021

    • Author(s)
      安住成, 津田健治, 森川大輔,寺内正己, 大塚真弘, 武藤俊介, 符徳勝, 伊藤満
    • Organizer
      日本顕微鏡学会第77回学術講演会
    • Related Report
      2020 Annual Research Report
  • [Presentation] STEM-CBED法によるBaTiO3分極ナノドメインの電場印可その場観察2021

    • Author(s)
      森川 大輔, 津田 健治
    • Organizer
      日本顕微鏡学会第77回学術講演会
    • Related Report
      2020 Annual Research Report
  • [Presentation] 収束電子回折法を用いた試料ダメージ層の定量評価 III2021

    • Author(s)
      上石正樹、森川大輔、佐藤香織、津田健治、寺内正己
    • Organizer
      日本顕微鏡学会第77回学術講演会
    • Related Report
      2020 Annual Research Report
  • [Presentation] STEM-CBED法によるPMNリラクサーの局所構造解析2020

    • Author(s)
      津田健治,森川大輔、符徳勝、伊藤満
    • Organizer
      日本顕微鏡学会 第76回学術講演会
    • Related Report
      2020 Annual Research Report
  • [Presentation] CaTiO3ドメイン境界での中心対称性の破れの観察2020

    • Author(s)
      森川大輔、津田健治
    • Organizer
      日本顕微鏡学会 第76回学術講演会
    • Related Report
      2020 Annual Research Report
  • [Presentation] 収束電子回折法を用いた試料ダメージ層の定量評価 II2020

    • Author(s)
      上石正樹、森川大輔、佐藤香織、津田健治、寺内正己
    • Organizer
      日本顕微鏡学会 第76回学術講演会
    • Related Report
      2020 Annual Research Report
  • [Presentation] STEM-CBED法によるPMNリラクサーの局所構造解析2020

    • Author(s)
      津田健治,森川大輔、符徳勝、伊藤満
    • Organizer
      第37回強誘電体会議
    • Related Report
      2020 Annual Research Report
  • [Presentation] Improvement in the precision of refinement of the crystal structure factors using convergent-beam electron diffraction2020

    • Author(s)
      B. Aryal, D. Morikawa, K. Tsuda and M. Terauchi
    • Organizer
      日本物理学会 2020年秋季大会
    • Related Report
      2020 Annual Research Report
  • [Presentation] STEM-CBED法によるCaTiO3の界面誘起分極構造の観察2020

    • Author(s)
      森川大輔,津田健治
    • Organizer
      日本物理学会 2020年秋季大会
    • Related Report
      2020 Annual Research Report
  • [Presentation] LACBED図形の動力学シミュレーションへの機械学習の応用2020

    • Author(s)
      津田健治、森川大輔、越川亜美, 大関真之
    • Organizer
      日本物理学会 2020年秋季大会
    • Related Report
      2020 Annual Research Report
  • [Presentation] A Study on Occupation Sites in M6C Carbide in High Chromium Cast Iron Using Statistical Beam-Rocking TEM-EDS Analysis2020

    • Author(s)
      S. Nusen, A. Wiengmoon, D. Morikawa, N. Azumi, T. Chairuangsri, K. Tsuda and M. Terauchi
    • Organizer
      6th Forum of Center for Advanced Materials Research and International Collaboration (CAMRIC-FORUM6)
    • Related Report
      2020 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 収束電子回折による静電ポテンシャル分布解析への機械学習の応用2020

    • Author(s)
      津田健治
    • Organizer
      応用物理学会・薄膜表面科学分科会「情報データ科学に基づく結晶材料・界面・プロセス工学の新展開 -実験との連携運用術」
    • Related Report
      2020 Annual Research Report
  • [Presentation] Nanometer-scale local crystal structure analysis using convergent-beam electron diffraction2020

    • Author(s)
      Kenji Tsuda
    • Organizer
      The 4th Symposium for The Core Research Cluster for Materials Science and the 3rd Symposium on International Joint Graduate Program in Materials Science
    • Related Report
      2020 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Materials Analysis by using Electron Microscopes operated in IMRAM2020

    • Author(s)
      M.Terauchi, H.Jinnai, Y.K.Sato, D.Morikawa, K.Tsuda, and Z.Akase
    • Organizer
      2020 ONLINE JOINT SYMPOSIUM "Engineer a Better Tomorrow" TOHOKU UNIVERSITY and NATIONAL TAIPEI UNIVERSITY OF TECHNOLOGY
    • Related Report
      2020 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Local crystal structure analysis using STEM-CBED method2019

    • Author(s)
      Kenji Tsuda
    • Organizer
      The 36th International Conference of Microscopy Society of Thailand
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] ピクセル型高速STEM検出器を用いたSTEM-CBED法による強誘電ドメイン壁の局所構造解析2019

    • Author(s)
      津田健治, 佐川隆亮,橋口裕樹,近藤行人
    • Organizer
      第36回強誘電体応用会議(FMA36)
    • Related Report
      2019 Annual Research Report
  • [Presentation] ピクセル型STEM検出器を用いたSTEM-CBED法による強誘電体の局所構造解析2019

    • Author(s)
      津田健治, 佐川隆亮,橋口裕樹,近藤行人
    • Organizer
      日本顕微鏡学会第75回学術講演会
    • Related Report
      2019 Annual Research Report
  • [Presentation] 大角度ロッキングCBED図形を用いた軌道整列状態の静電ポテンシャル分布解析2019

    • Author(s)
      森川大輔,津田 健治
    • Organizer
      日本顕微鏡学会第75回学術講演会
    • Related Report
      2019 Annual Research Report
  • [Presentation] 収束電子回折法を用いた試料ダメージ層の定量評価2019

    • Author(s)
      上石正樹,森川大輔,佐藤 香織,津田 健治,寺内正己
    • Organizer
      日本顕微鏡学会第75回学術講演会
    • Related Report
      2019 Annual Research Report
  • [Presentation] Local structural study of ferroelectric domain boundaries using STEM-CBED with a fast pixelated STEM detector2019

    • Author(s)
      Kenji Tsuda, Ryusuke Sagawa, Hiroki Hashiguchi and Yukihito Kondo
    • Organizer
      Microscopy and Microanalysis 2019, Portland, OR, USA
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] ピクセル型高速STEM検出器を用いたSTEM-CBED法による局所構造解析2019

    • Author(s)
      津田健治、佐川隆亮、橋口裕樹、近藤行人
    • Organizer
      日本顕微鏡学会 第35回分析電子顕微鏡討論会
    • Related Report
      2019 Annual Research Report
    • Invited
  • [Presentation] ピクセル型高速STEM検出器を用いたSTEM-CBED法による強誘電ドメイン壁の局所構造解析 II2019

    • Author(s)
      津田健治、佐川隆亮、橋口裕樹、近藤行人
    • Organizer
      日本物理学会2019年秋季大会
    • Related Report
      2019 Annual Research Report
  • [Presentation] 大角度ロッキングCBED図形を用いた結晶構造因子決定精度の検証2019

    • Author(s)
      森川大輔,津田 健治
    • Organizer
      日本物理学会2019年秋季大会
    • Related Report
      2019 Annual Research Report
  • [Presentation] 大角度ロッキングCBED図形を用いた軌道整列相の解析と精度評価2019

    • Author(s)
      森川大輔,津田 健治
    • Organizer
      日本結晶学会令和元年度年会
    • Related Report
      2019 Annual Research Report
  • [Presentation] STEM-CBED法によるペロブスカイト型強誘電体の局所構造解析2019

    • Author(s)
      津田健治
    • Organizer
      東北大学金属材料研究所 共同利用・共同研究ワークショップ「強誘電体関連物質の機能発現に関する構造科学の新展開」
    • Related Report
      2019 Annual Research Report
    • Invited
  • [Presentation] ピクセル型高速STEM検出器を用いたSTEM-CBED法による強誘電ドメイン壁の局所構造解析2019

    • Author(s)
      津田健治, 佐川隆亮,橋口裕樹,近藤行人
    • Organizer
      日本物理学会 2019年第74回年次大会
    • Related Report
      2018 Annual Research Report
  • [Presentation] STEM-CBED study on the temperature dependence of the local structures of tetragonal BaTiO32018

    • Author(s)
      Kenji Tsuda
    • Organizer
      2018 ISAF-FMA-AMF-AMEC-PFM Joint Conference at Hiroshima (IFAAP Hiroshima2018)
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Nano-scale local structural study of ferroelectrics using STEM-CBED with a fast pixeletated STEM detector2018

    • Author(s)
      Kenji Tsuda
    • Organizer
      Workshop on STEM with Advanced Detectors
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Nano-scale local structural study of BaTiO3 using STEM-CBED with a fast pixelated STEM detector2018

    • Author(s)
      Kenji Tsuda, Michiyoshi Tanaka, Ryusuke Sagawa, Hiroki Hashiguchi and Yukihito Kondo
    • Organizer
      The 19th International Microscopy Congress 2018 (IMC19)
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research

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Published: 2018-04-23   Modified: 2022-01-27  

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