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Atomic structures of dislocations and the related functionality in functional crystalline materials

Research Project

Project/Area Number 18H03840
Research Category

Grant-in-Aid for Scientific Research (A)

Allocation TypeSingle-year Grants
Section一般
Review Section Medium-sized Section 26:Materials engineering and related fields
Research InstitutionNagoya University

Principal Investigator

NAKAMURA ATSUTOMO  名古屋大学, 工学研究科, 准教授 (20419675)

Co-Investigator(Kenkyū-buntansha) 栃木 栄太  東京大学, 大学院工学系研究科(工学部), 助教 (50709483)
Project Period (FY) 2018-04-01 – 2021-03-31
Project Status Completed (Fiscal Year 2020)
Budget Amount *help
¥45,110,000 (Direct Cost: ¥34,700,000、Indirect Cost: ¥10,410,000)
Fiscal Year 2020: ¥10,270,000 (Direct Cost: ¥7,900,000、Indirect Cost: ¥2,370,000)
Fiscal Year 2019: ¥10,920,000 (Direct Cost: ¥8,400,000、Indirect Cost: ¥2,520,000)
Fiscal Year 2018: ¥23,920,000 (Direct Cost: ¥18,400,000、Indirect Cost: ¥5,520,000)
Keywords転位 / 機能性材料 / 電子物性 / 格子欠陥 / 双結晶 / 電気伝導 / 原子・電子構造
Outline of Final Research Achievements

Dislocations are line defects in crystalline materials and often bring unusual properties due to the singular atomic arrangements and change the functional properties of the materials. In this study, the atomic and electronic structures of dislocations were analyzed by electron microscopy, and the effects of dislocations on functional properties and mechanical properties of materials were evaluated by bicrystal technique and plastic deformation tests. As a result, it was confirmed that a large anisotropy was exhibited in the electrical conductivity at the low grain boundaries in functional materials. From electrical conduction measurements, it was reconfirmed that the handling of the electrical contact areas is important for accurate measurements.

Academic Significance and Societal Importance of the Research Achievements

転位は材料の機械的性質のみならず電気的・光学的など材料の機能的性質に影響することが知られている。しかし、系統的な実験がなく、影響度合いは不明なままである。本研究では、転位構造に依存した機能的性質を系統的に測定を行った。測定に当たっては測定器との接触部を作る必要があるが、そうした接触部が転位の性質をご認識させていることが新たに分かった。また、転位電子構造の理解には、点欠陥によるものと転位コア特有の配列によるものの両方を区別する必要があることが分かった。

Report

(4 results)
  • 2020 Annual Research Report   Final Research Report ( PDF )
  • 2019 Annual Research Report
  • 2018 Annual Research Report
  • Research Products

    (25 results)

All 2021 2020 2019 2018 Other

All Int'l Joint Research (2 results) Journal Article (11 results) (of which Int'l Joint Research: 6 results,  Peer Reviewed: 11 results,  Open Access: 3 results) Presentation (12 results) (of which Int'l Joint Research: 5 results,  Invited: 6 results)

  • [Int'l Joint Research] ダルムシュタット工科大学(ドイツ)

    • Related Report
      2020 Annual Research Report
  • [Int'l Joint Research] ケースウェスターンリザーブ大学(米国)

    • Related Report
      2020 Annual Research Report
  • [Journal Article] Dislocation-based crack initiation and propagation in single-crystal SrTiO32021

    • Author(s)
      Xufei Fang, Kuan Ding, Christian Minnert, Atsutomo Nakamura, Karsten Durst
    • Journal Title

      Journal of Materials Science

      Volume: 56 Issue: 9 Pages: 5479-5492

    • DOI

      10.1007/s10853-020-05587-2

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Influence of dislocations on thermal conductivity of strontium titanate2020

    • Author(s)
      Melanie Johanning, Lukas Porz, Jinfeng Dong, Atsutomo Nakamura, Jing-Feng Li, Jurgen Rodel
    • Journal Title

      Applied Physics Letters

      Volume: 117 Issue: 2 Pages: 21902-21902

    • DOI

      10.1063/5.0010234

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Room-temperature creep deformation of cubic ZnS crystals under controlled light conditions2020

    • Author(s)
      Oshima Yu、Nakamura Atsutomo、Lagerlof K.Peter D.、Yokoi Tatsuya、Matsunaga Katsuyuki
    • Journal Title

      Acta Materialia

      Volume: 195 Pages: 690-697

    • DOI

      10.1016/j.actamat.2020.06.016

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Carrier-trapping induced reconstruction of partial-dislocation cores responsible for light-illumination controlled plasticity in an inorganic semiconductor2020

    • Author(s)
      Matsunaga Katsuyuki、Hoshino Sena、Ukita Masaya、Oshima Yu、Yokoi Tatsuya、Nakamura Atsutomo
    • Journal Title

      Acta Materialia

      Volume: 195 Pages: 645-653

    • DOI

      10.1016/j.actamat.2020.06.010

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Bridging the Gap between Bulk Compression and Indentation Test on Room-Temperature Plasticity in Oxides: Case Study on SrTiO32020

    • Author(s)
      Xufei Fang, Lukas Porz, Kuan Ding, Atsutomo Nakamura
    • Journal Title

      Crystals

      Volume: 10 Issue: 10 Pages: 933-933

    • DOI

      10.3390/cryst10100933

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Nanoscale to microscale reversal in room-temperature plasticity in SrTiO3 by tuning defect concentration2020

    • Author(s)
      Xufei Fang, Kuan Ding, Stephan Janocha, Christian Minnert, Wolfgang Rheinheimer, Till Fromling, Karsten Durst, Atsutomo Nakamura, Jurgen Rodel
    • Journal Title

      Scripta Materialia

      Volume: 188 Pages: 228-232

    • DOI

      10.1016/j.scriptamat.2020.07.033

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Photo-indentation: A new route to understanding dislocation behavior in light2020

    • Author(s)
      Atsutomo Nakamura, Xufei Fang, Ayaka Matsubara, Eita Tochigi, Yu Oshima, Tatsushi Saito, Tatsuya Yokoi, Yuichi Ikuhara, Katsuyuki Matsunaga
    • Journal Title

      Nano Letters

      Volume: 21 Issue: 5 Pages: 1962-1967

    • DOI

      10.1021/acs.nanolett.0c04337

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Electronic and Atomic Structures of Dislocations in an Inorganic Semiconductor Showing Unexpected Large Plasticity at Room Temperature2019

    • Author(s)
      K. Matsunaga, Y. Oshima, A. Nakamura
    • Journal Title

      AMTC Letters

      Volume: 6 Pages: 188-189

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Room-Temperature Deformation Behavior of Cubic Zinc Sulfide Single Crystals under Controlled Light Conditions2019

    • Author(s)
      Y. Oshima, A. Nakamura, T. Yokoi, K. Matsunaga
    • Journal Title

      AMTC Letters

      Volume: 6 Pages: 154-155

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Dissociation reaction of the 1/3<-1101> edge dislocation in alpha-Al2O32018

    • Author(s)
      Eita Tochigi, Teruyasu Mizoguchi, Eiji Okunishi, Atsutomo Nakamura, Naoya Shibata, Yuichi Ikuhara
    • Journal Title

      Journal of Materials Science

      Volume: 53 Issue: 11 Pages: 8049-8058

    • DOI

      10.1007/s10853-018-2133-7

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Electronic and Atomic Structures of Edge and Screw Dislocations in Rock Salt Structured Ionic Crystals2018

    • Author(s)
      Masaya Ukita, Atsutomo Nakamura, Tatsuya Yokoi, Katsuyuki Matsunaga
    • Journal Title

      Philosophical Magazine

      Volume: 98 Issue: 24 Pages: 2189-2204

    • DOI

      10.1080/14786435.2018.1478146

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Presentation] 機能性セラミックス粒界の原子構造解析と機能特性2020

    • Author(s)
      中村篤智
    • Organizer
      日本セラミックス協会 第33回秋 季シンポジウム
    • Related Report
      2020 Annual Research Report
    • Invited
  • [Presentation] Electronic and Atomic Structures of Dislocations in an Inorganic Semiconductor Showing Unexpected Large Plasticity at Room Temperature2019

    • Author(s)
      K. Matsunaga, Y. Oshima, A. Nakamura,
    • Organizer
      The 6th International Symposium on Advanced Microscopy and Theoretical Calculations (AMTC6)
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Structures and electrical conduction properties of boundary dislocations at lowangle grain boundaries in SrTiO32019

    • Author(s)
      A. Nakamura, K. Matsunaga
    • Organizer
      Intergranular and Interphase Boundaries in Materials (IIB2019)
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Room-temperature plastic deformation behavior of ZnS crystals under controlled light conditions2019

    • Author(s)
      A. Nakamura, Y. Oshima, K. Matsunaga
    • Organizer
      The MRS-Japan主催 Materials Research Meeting 2019 (MRM 2019)
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 化合物半導体粒界の物性解析に向けた原子間ポテンシャルの構築2019

    • Author(s)
      横井達矢, 野田祐輔, 中村篤智, 松永克志
    • Organizer
      日本金属学会 2019年秋期(第165回)講演大会
    • Related Report
      2019 Annual Research Report
  • [Presentation] MgOの(100)/[001]小傾角粒界における転位偏析構造2019

    • Author(s)
      春原光希, 中村篤智, 栃木栄太, 幾原雄一, 横井達矢, 松永克志
    • Organizer
      日本金属学会 2019年秋期(第165回)講演大会
    • Related Report
      2019 Annual Research Report
  • [Presentation] 無機結晶における転位コアの構造と機能2019

    • Author(s)
      中村篤智
    • Organizer
      日本金属学会2019年春期(第164回)講演大会
    • Related Report
      2018 Annual Research Report
    • Invited
  • [Presentation] Dislocation structures and electrical conduction properties of low angle grain boundaries in strontium titanate2018

    • Author(s)
      A. Nakamura
    • Organizer
      THERMEC’2018
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Atomic Structure and Electrical Conduction Property of Dislocations in Strontium Titanate2018

    • Author(s)
      A. Nakamura, Y. Furushima, E. Tochigi, Y. Ikuhara, T. Yokoi, K. Matsunaga
    • Organizer
      ICSMA18
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 機能性材料における結晶転位の構造と機能2018

    • Author(s)
      中村篤智
    • Organizer
      日本材料学会主催 第67期第1回マルチスケール材料力学部門委員会
    • Related Report
      2018 Annual Research Report
    • Invited
  • [Presentation] チタン酸ストロンチウムにおける転位のコア構造と電気伝導性2018

    • Author(s)
      中村篤智, 古嶋佑帆, 野路健人, 栃木栄太, 幾原雄一, 横井達矢, 松永克志
    • Organizer
      日本材料学会主催 第4回材料WEEK
    • Related Report
      2018 Annual Research Report
  • [Presentation] 最近の転位機能特性の発見と機能発現メカニズム解明における課題2018

    • Author(s)
      中村篤智
    • Organizer
      日本金属学会 第1回 材料機能特性のアーキテクチャー研究会
    • Related Report
      2018 Annual Research Report

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Published: 2018-04-23   Modified: 2022-01-27  

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