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Development of novel SiO2-based membranes and their application to catalytic membrane reactors for process intensification

Research Project

Project/Area Number 18H03855
Research Category

Grant-in-Aid for Scientific Research (A)

Allocation TypeSingle-year Grants
Section一般
Review Section Medium-sized Section 27:Chemical engineering and related fields
Research InstitutionHiroshima University

Principal Investigator

Tsuru Toshinori  広島大学, 先進理工系科学研究科(工), 教授 (20201642)

Co-Investigator(Kenkyū-buntansha) 福原 長寿  静岡大学, 工学部, 教授 (30199260)
野村 幹弘  芝浦工業大学, 工学部, 教授 (50308194)
伊藤 賢志  国立研究開発法人産業技術総合研究所, 計量標準総合センター, 研究グループ長 (90371020)
Project Period (FY) 2018-04-01 – 2022-03-31
Project Status Completed (Fiscal Year 2021)
Budget Amount *help
¥44,200,000 (Direct Cost: ¥34,000,000、Indirect Cost: ¥10,200,000)
Fiscal Year 2021: ¥7,670,000 (Direct Cost: ¥5,900,000、Indirect Cost: ¥1,770,000)
Fiscal Year 2020: ¥8,060,000 (Direct Cost: ¥6,200,000、Indirect Cost: ¥1,860,000)
Fiscal Year 2019: ¥13,130,000 (Direct Cost: ¥10,100,000、Indirect Cost: ¥3,030,000)
Fiscal Year 2018: ¥15,340,000 (Direct Cost: ¥11,800,000、Indirect Cost: ¥3,540,000)
Keywords膜反応器 / シリカ / 触媒 / 反応 / 膜分離 / 脱水素反応 / 水素化反応 / エステル交換反応 / シリカ膜 / 膜反応
Outline of Final Research Achievements

Based on the membrane technology of porous silica membranes, this research aims to (1) develop and improve the separation functionality: improvement of the selectivity and permeability of the porous silica separation layer by using various membrane materials and preparation processing, (2) develop the membrane reaction functionality: development of a membrane reactor combining a reaction catalyst and separation membrane and its application to membrane reactions (dehydrogenation and dehydration reactions, and transesterification reactions), and (3) evaluate the membrane reactor systems: evaluation of the system of membrane reaction such as optimum operating conditions. This research will clarify the process intensification by membrane reactors experimentally and theoretically.

Academic Significance and Societal Importance of the Research Achievements

本研究では,水素製造のみならずオレフィンなど有用物質製造,エステル交換反応,さらにはCO2有効利用システムなどの多様な反応系において,膜反応器の検討を行った。また,膜反応シミュレーションにおいても,各種反応システムのモデル解析を行い,分離と反応の組合せた膜反応器の有用性およびプロセス強化が可能であることを明らかにすることができた。

Report

(4 results)
  • 2021 Final Research Report ( PDF )
  • 2020 Annual Research Report
  • 2019 Annual Research Report
  • 2018 Annual Research Report
  • Research Products

    (70 results)

All 2021 2020 2019 2018 Other

All Int'l Joint Research (3 results) Journal Article (33 results) (of which Int'l Joint Research: 6 results,  Peer Reviewed: 33 results,  Open Access: 8 results) Presentation (27 results) (of which Int'l Joint Research: 19 results,  Invited: 19 results) Book (5 results) Remarks (2 results)

  • [Int'l Joint Research] Chung Yuan Christian University(台湾)

    • Related Report
      2019 Annual Research Report
  • [Int'l Joint Research] 忠南国立大学(韓国)

    • Related Report
      2018 Annual Research Report
  • [Int'l Joint Research] 中原大学(台湾)

    • Related Report
      2018 Annual Research Report
  • [Journal Article] Reaction of methanol to olefin using a membrane contactor on a silica substrate2021

    • Author(s)
      Tanizume Shusei、Maehara Sota、Ishii Katsunori、Onoki Takamasa、Okuno Takuya、Tawarayama Hiromasa、Ishikawa Shinji、Nomura Mikihiro
    • Journal Title

      Separation and Purification Technology

      Volume: 254 Pages: 117647-117647

    • DOI

      10.1016/j.seppur.2020.117647

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed
  • [Journal Article] A novel catalytic reaction system capturing solid carbon from greenhouse gas, combined with dry reforming of methane2021

    • Author(s)
      Fukuhara Choji、Matsui Yoshito、Tanebayashi Masaki、Watanabe Ryo
    • Journal Title

      Chemical Engineering Journal Advances

      Volume: 5 Pages: 100057-100057

    • DOI

      10.1016/j.ceja.2020.100057

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Metal-induced microporous aminosilica creates a highly permeable gas-separation membrane2021

    • Author(s)
      Anggarini Ufafa、Yu Liang、Nagasawa Hiroki、Kanezashi Masakoto、Tsuru Toshinori
    • Journal Title

      Materials Chemistry Frontiers

      Volume: 5 Issue: 7 Pages: 3029-3042

    • DOI

      10.1039/d1qm00009h

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed
  • [Journal Article] High Performance of a Structured Ni-Based Catalyst for Autothermal Dry Reforming of Methane2020

    • Author(s)
      Dwiratna Bralin、Hirao Kazuaki、Watanabe Ryo、Fukuhara Choji
    • Journal Title

      JOURNAL OF CHEMICAL ENGINEERING OF JAPAN

      Volume: 53 Issue: 7 Pages: 304-312

    • DOI

      10.1252/jcej.20we062

    • NAID

      130007878374

    • ISSN
      0021-9592, 1881-1299
    • Year and Date
      2020-07-20
    • Related Report
      2020 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Performance characteristics of auto-methanation using Ru/CeO2 catalyst, autonomously proceeding at room temperature2020

    • Author(s)
      Hirata Nozomu、Watanabe Ryo、Fukuhara Choji
    • Journal Title

      Fuel

      Volume: 282 Pages: 118619-118619

    • DOI

      10.1016/j.fuel.2020.118619

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Catalytic performance of Ni catalysts supported on CeO2 with different morphologies for low-temperature CO2 methanation2020

    • Author(s)
      Jomjaree Thapanee、Sintuya Paweennut、Srifa Atthapon、Koo-amornpattana Wanida、Kiatphuengporn Sirapassorn、Assabumrungrat Suttichai、Sudoh Masao、Watanabe Ryo、Fukuhara Choji、Ratchahat Sakhon
    • Journal Title

      Catalysis Today

      Volume: - Pages: 010-010

    • DOI

      10.1016/j.cattod.2020.08.010

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Microstructure evolution and enhanced permeation of SiC membranes derived from allylhydridopolycarbosilane2020

    • Author(s)
      Wang Qing、Yokoji Makoto、Nagasawa Hiroki、Yu Liang、Kanezashi Masakoto、Tsuru Toshinori
    • Journal Title

      Journal of Membrane Science

      Volume: 612 Pages: 118392-118392

    • DOI

      10.1016/j.memsci.2020.118392

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Tuning the microstructure of polycarbosilane-derived SiC(O) separation membranes via thermal-oxidative cross-linking2020

    • Author(s)
      Wang Qing、Yu Liang、Nagasawa Hiroki、Kanezashi Masakoto、Tsuru Toshinori
    • Journal Title

      Separation and Purification Technology

      Volume: 248 Pages: 117067-117067

    • DOI

      10.1016/j.seppur.2020.117067

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed
  • [Journal Article] High‐performance molecular‐separation ceramic membranes derived from oxidative cross‐linked polytitanocarbosilane2020

    • Author(s)
      Wang Qing、Yu Liang、Nagasawa Hiroki、Kanezashi Masakoto、Tsuru Toshinori
    • Journal Title

      Journal of the American Ceramic Society

      Volume: 103 Issue: 8 Pages: 4473-4488

    • DOI

      10.1111/jace.17108

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed
  • [Journal Article] SiC mesoporous membranes for sulfuric acid decomposition at high temperatures in the iodine-sulfur process2020

    • Author(s)
      Yu Xin、Wang Qing、Nagasawa Hiroki、Kanezashi Masakoto、Tsuru Toshinori
    • Journal Title

      RSC Advances

      Volume: 10 Issue: 68 Pages: 41883-41890

    • DOI

      10.1039/d0ra06919a

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Theoretical study of oxygen adsorption energy on supported metal cluster using d-band center theory and HSAB concept2020

    • Author(s)
      Miura Kazuya、Watanabe Ryo、Fukuhara Choji
    • Journal Title

      Surface Science

      Volume: 696 Pages: 121601-121601

    • DOI

      10.1016/j.susc.2020.121601

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Deactivation factor of CuCl2-KCl/Al2O3 catalyst for ethylene oxychlorination in a commercial-scale plant2020

    • Author(s)
      Ohashi Tomokazu、Someya Sae、Mori Yoshihiko、Asakawa Tetsuo、Hanaya Makoto、Oguri Motohiro、Watanabe Ryo、Fukuhara Choji
    • Journal Title

      Applied Catalysis A: General

      Volume: 589 Pages: 117205-117205

    • DOI

      10.1016/j.apcata.2019.117205

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Development of Silica Membranes to Improve Dehydration Reactions2019

    • Author(s)
      Katsunori Ishii, Ai Shibata, Toshichika Takeuchi, Junko Yoshiura, Takumi Urabe, Yosuke Kameda, Mikihiro Nomura
    • Journal Title

      Journal of the Japan Petroleum Institute

      Volume: 62 Issue: 5 Pages: 211-219

    • DOI

      10.1627/jpi.62.211

    • NAID

      130007700279

    • ISSN
      1346-8804, 1349-273X
    • Year and Date
      2019-09-01
    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Vapor-permeation dehydration of isopropanol using a flexible and thin organosilica membrane with high permeance2019

    • Author(s)
      Gong Genghao、Mamoru Murata、Nagasawa Hiroki、Kanezashi Masakoto、Hu Yunxia、Tsuru Toshinori
    • Journal Title

      Journal of Membrane Science

      Volume: 588 Pages: 117226-117226

    • DOI

      10.1016/j.memsci.2019.117226

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Infrared-spectroscopic porosimetry: Development and application for characterization of hundred-nanometer-thick porous thin films2019

    • Author(s)
      Nagasawa Hiroki、Eguchi Kosuke、Kanezashi Masakoto、Tsuru Toshinori
    • Journal Title

      Thin Solid Films

      Volume: 685 Pages: 299-305

    • DOI

      10.1016/j.tsf.2019.06.038

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Organosilica-Based Membranes in Gas and Liquid-Phase Separation2019

    • Author(s)
      Ren Xiuxiu、Tsuru Toshinori
    • Journal Title

      Membranes

      Volume: 9 Issue: 9 Pages: 107-107

    • DOI

      10.3390/membranes9090107

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Formation of active species for propane dehydrogenation with hydrogen sulfide co-feeding over transition metal catalyst2019

    • Author(s)
      Watanabe Ryo、Hirata Nozomu、Miura Kazuya、Yoda Yuta、Fushimi Yuya、Fukuhara Choji
    • Journal Title

      Applied Catalysis A: General

      Volume: 587 Pages: 117238-117238

    • DOI

      10.1016/j.apcata.2019.117238

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Auto-methanation Performance of Structured Ni-type Catalyst for CO2 Transformation2019

    • Author(s)
      Fukuhara Choji、Ratchahat Sakhon、Kamiyama Asuka、Sudoh Masao、Watanabe Ryo
    • Journal Title

      Chemistry Letters

      Volume: 48 Issue: 5 Pages: 441-444

    • DOI

      10.1246/cl.190025

    • NAID

      130007642542

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Removal of As(iii) and As(v) from water using green, silica-based ceramic hollow fibre membranes via direct contact membrane distillation2019

    • Author(s)
      Hubadillah Siti Khadijah、Dzarfan Othman Mohd Hafiz、Sheikh Abdul Kadir Siti Hamimah、Jamalludin Mohd Riduan、Harun Zawati、Abd Aziz Mohd Haiqal、Rahman Mukhlis A.、Jaafar Juhana、Nomura Mikihiro、Honda Sawao、Iwamoto Yuji、Fansuri Hamzah
    • Journal Title

      RSC Advances

      Volume: 9 Issue: 6 Pages: 3367-3376

    • DOI

      10.1039/c8ra08143c

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Auto-methanation of Carbon Dioxide: A Novel Route for Transforming CO2 over Ni-based Catalyst2019

    • Author(s)
      Fukuhara Choji、Ratchahat Sakhon、Suzuki Yuji、Sudoh Masao、Watanabe Ryo
    • Journal Title

      Chemistry Letters

      Volume: 48 Issue: 3 Pages: 196-199

    • DOI

      10.1246/cl.180894

    • NAID

      130007607581

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] 物質・熱移動の促進による触媒反応場のプロセス強化(PI)2019

    • Author(s)
      福原長寿
    • Journal Title

      触媒

      Volume: 61 Pages: 9-15

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Hydrothermal stability and permeation properties of TiO2-ZrO2 (5/5) nanofiltration membranes at high temperatures2019

    • Author(s)
      Anisah Sofiatun、Kanezashi Masakoto、Nagasawa Hiroki、Tsuru Toshinori
    • Journal Title

      Separation and Purification Technology

      Volume: 212 Pages: 1001-1012

    • DOI

      10.1016/j.seppur.2018.12.006

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Atmospheric-Pressure Plasma-Enhanced Chemical Vapor Deposition of Hybrid Silica Membranes2018

    • Author(s)
      Nagasawa Hiroki、Yamamoto Yuta、Kanezashi Masakoto、Tsuru Toshinori
    • Journal Title

      JOURNAL OF CHEMICAL ENGINEERING OF JAPAN

      Volume: 51 Issue: 9 Pages: 732-739

    • DOI

      10.1252/jcej.17we195

    • NAID

      130007485228

    • ISSN
      0021-9592, 1881-1299
    • Year and Date
      2018-09-20
    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Improved thermal and oxidation stability of bis(triethoxysilyl)ethane (BTESE)-derived membranes, and their gas-permeation properties2018

    • Author(s)
      Yu Xin、Nagasawa Hiroki、Kanezashi Masakoto、Tsuru Toshinori
    • Journal Title

      Journal of Materials Chemistry A

      Volume: 6 Issue: 46 Pages: 23378-23387

    • DOI

      10.1039/c8ta07572g

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Fluorine Doping of Microporous Organosilica Membranes for Pore Size Control and Enhanced Hydrophobic Properties2018

    • Author(s)
      Kanezashi Masakoto、Murata Masaaki、Nagasawa Hiroki、Tsuru Toshinori
    • Journal Title

      ACS Omega

      Volume: 3 Issue: 8 Pages: 8612-8620

    • DOI

      10.1021/acsomega.8b01370

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Preparation, characterization, and evaluation of TiO2-ZrO2 nanofiltration membranes fired at different temperatures2018

    • Author(s)
      Anisah Sofiatun、Puthai Waravut、Kanezashi Masakoto、Nagasawa Hiroki、Tsuru Toshinori
    • Journal Title

      Journal of Membrane Science

      Volume: 564 Pages: 691-699

    • DOI

      10.1016/j.memsci.2018.07.072

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Role of Amine Type in CO2 Separation Performance within Amine Functionalized Silica/Organosilica Membranes: A Review2018

    • Author(s)
      Yu Liang、Kanezashi Masakoto、Nagasawa Hiroki、Tsuru Toshinori
    • Journal Title

      Applied Sciences

      Volume: 8 Issue: 7 Pages: 1032-1032

    • DOI

      10.3390/app8071032

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Tailoring a Thermally Stable Amorphous SiOC Structure for the Separation of Large Molecules: The Effect of Calcination Temperature on SiOC Structures and Gas Permeation Properties2018

    • Author(s)
      Inde Hiroki、Kanezashi Masakoto、Nagasawa Hiroki、Nakaya Toshimi、Tsuru Toshinori
    • Journal Title

      ACS Omega

      Volume: 3 Issue: 6 Pages: 6369-6377

    • DOI

      10.1021/acsomega.8b00632

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Pervaporation dehydration of aqueous solutions of various types of molecules via organosilica membranes: Effect of membrane pore sizes and molecular sizes2018

    • Author(s)
      Moriyama Norihiro、Nagasawa Hiroki、Kanezashi Masakoto、Tsuru Toshinori
    • Journal Title

      Separation and Purification Technology

      Volume: 207 Pages: 108-115

    • DOI

      10.1016/j.seppur.2018.06.021

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Subnanopore structural change of time-elapsed silica PECVD films elucidated by slow positron annihilation and ellipsometric porosimetry2018

    • Author(s)
      Yoshimoto Shigeru、Ito Kenji、Hosomi Hiroyuki、Takeda Masaaki、Tsuru Toshinori
    • Journal Title

      JJAP Conference Proceedings

      Volume: 7 Pages: 1125051-1125055

    • DOI

      10.7567/jjapcp.7.011205

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Bis(triethoxysilyl)ethane (BTESE)-derived silica membranes: pore formation mechanism and gas permeation properties2018

    • Author(s)
      Moriyama Norihiro、Nagasawa Hiroki、Kanezashi Masakoto、Ito Kenji、Tsuru Toshinori
    • Journal Title

      Journal of Sol-Gel Science and Technology

      Volume: 86 Issue: 1 Pages: 63-72

    • DOI

      10.1007/s10971-018-4618-x

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Enhanced CO2 separation performance for tertiary amine-silica membranes via thermally induced local liberation of CH3Cl2018

    • Author(s)
      Yu Liang、Kanezashi Masakoto、Nagasawa Hiroki、Moriyama Norihiro、Tsuru Toshinori、Ito Kenji
    • Journal Title

      AIChE Journal

      Volume: 64 Issue: 5 Pages: 1528-1539

    • DOI

      10.1002/aic.16040

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Fluorine-induced microporous silica membranes: Dramatic improvement in hydrothermal stability and pore size controllability for highly permeable propylene/propane separation2018

    • Author(s)
      Kanezashi Masakoto、Matsutani Takuya、Nagasawa Hiroki、Tsuru Toshinori
    • Journal Title

      Journal of Membrane Science

      Volume: 549 Pages: 111-119

    • DOI

      10.1016/j.memsci.2017.11.072

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Presentation] Silicon-Based Membranes with Molecular-Net-Sieving Properties: Application to gas and liquid phase separation2021

    • Author(s)
      Toshinori Tsuru
    • Organizer
      2020 Dalian University of Technology-Overseas Partner Universities Series Online Exchange Conference
    • Related Report
      2020 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Essential properties of ceramic substrates for zeolite membranes - standardization for industrialization-2020

    • Author(s)
      Mikihiro Nomura
    • Organizer
      Korean Membrane Society 30th Anniversary Meeting
    • Related Report
      2020 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 触媒反応工学と常温作動のメタン化技術が拓くCO2資源化プロセスの強化(PI)2020

    • Author(s)
      福原長寿
    • Organizer
      化学工学会第51回秋季大会
    • Related Report
      2020 Annual Research Report
    • Invited
  • [Presentation] Innovative Chemical Reaction System Contributing to Issue of CO2 Reduction and Utilization2020

    • Author(s)
      Choji Fukuhara
    • Organizer
      日本化学会化学系学協会東北大会
    • Related Report
      2020 Annual Research Report
    • Invited
  • [Presentation] オルガノシリカ膜による有機溶媒混合物の逆浸透分離2020

    • Author(s)
      都留稔了
    • Organizer
      日本膜学会年会
    • Related Report
      2020 Annual Research Report
    • Invited
  • [Presentation] Organosilica and SiC-based membranes: Development and application to selective removal of water vapor from steam/gas mixtures at moderate-to-high temperatures2020

    • Author(s)
      Toshinori Tsuru
    • Organizer
      The 16th International Conference on Inorganic Membranes (ICIM 16)
    • Related Report
      2020 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Organosilica-based ceramic membranes for organic solvent reverse osmosis (OSRO): Experimental verification and theoretical prediction2020

    • Author(s)
      Toshinori Tsuru
    • Organizer
      International Congress on Membranes & Membrane Processes 2020 (ICOM2020)
    • Related Report
      2020 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Silica-Based Membranes with Molecular-Net-Sieving Properties: Application to gas and liquid phase separation for Sustainable Development Goals (SDGs)2019

    • Author(s)
      Toshinori Tsuru
    • Organizer
      The 26th Regional Symposium on Chemical Engineering (RSCE 2019),
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Development of Silica-based membranes and Applications to Catalytic Membrane Reactors,2019

    • Author(s)
      Toshinori Tsuru
    • Organizer
      The 14th International Conference on Catalysis in Membrane Reactors (ICCMR14)
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 様々な水源に対応できるRobust膜の開発と環境・エネルギーへの展開2019

    • Author(s)
      都留稔了
    • Organizer
      高知大学研究拠点プロジェクト「革新的な水・バイオマス循環システムの構築」
    • Related Report
      2019 Annual Research Report
    • Invited
  • [Presentation] Auto-methanation of carbon dioxide with oxidation: a novel routefor CO2 transformation over supported metal catalyst2019

    • Author(s)
      Choji Fukuhara, Sakhon Ratchahat, Masao Sudoh, Ryo Watanabe
    • Organizer
      The 18th Asian Pacific Confederation of Chemical Engineering Congress
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Auto-methanation of carbon dioxide: a novel route for CO2 transformation over Ni-based catalyst2019

    • Author(s)
      Choji Fukuhara, Sakhon Ratchahat, Asuka Kamiyama, Masao Sudoh, Ryo Watanabe
    • Organizer
      The 8th Asia-Pacific Congress on Catalysis
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Auto-methanation over structured Ni-type catalyst for process intensification of carbon dioxide transformation2019

    • Author(s)
      Choji Fukuhara, Ryo Watanabe, Sakhon Ratchahat, Asuka Kamiyama, Masao Sudoh
    • Organizer
      6th european conference on environmental applications of advanced oxidation processes
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Auto-methanation of carbon dioxide over Ni-based catalyst: a novel route for CO2 transformation with oxidation2019

    • Author(s)
      Choji Fukuhara, Sakhon Ratchahat, Yuji Suzuki, Masao Sudoh, Ryo Watanabe
    • Organizer
      6th european conference on environmental applications of advanced oxidation processes
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Na-22 based low-energy AMOC measurements for chemical analysis of the free-volume holes in hydrocarbon-silica hybrid thin films2019

    • Author(s)
      Kenji Ito
    • Organizer
      15th International Workshop on Slow Positron Beam Techniques and Applications (SLOPOS-15)
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Gas permeation through silica membranes prepared by using a counter diffusion chemical vapor deposition2019

    • Author(s)
      Mikihiro Nomura
    • Organizer
      9th International Symposium on Inorganic Membranes
    • Related Report
      2019 Annual Research Report
    • Invited
  • [Presentation] Deposition mechanism of the silica hybrid membranes prepared by counter diffusion CVD method2019

    • Author(s)
      Katsunori Ishii, Mikihiro Nomura
    • Organizer
      12th Conference of Aseanian Membrane Society
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Development of hydrogen permselective membranes for propylene production2019

    • Author(s)
      Katsunori Ishii, Mikihiro Nomura
    • Organizer
      5th International Symposium on Innovative Materials for Processes in Energy Systems
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] A powerful CO2 methanation reactor with Ni/CeO2 structured catalyst: estimation of mass and heat transfer profiles2018

    • Author(s)
      Choji Fukuhara, Ryo Watanabe, Sakhon Ratchahat, Masao Sudoh
    • Organizer
      23rd International Conference on Chemical Reactiors (Ghent, Belgium)
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Advantage of structured catalyst system for CO2 methanation under extremely high flow rate (Florence, Italy)2018

    • Author(s)
      Sakhon Ratchahat,Masao Sudoh,Yuji Suzuki,Ryo
    • Organizer
      The 25th International Symposium on Chemical Reaction Engineering
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Design of the hydrogen permselective membranes prepared by using a counter diffusion CVD method2018

    • Author(s)
      Mikihiro Nomura, Ayumi Ikeda, Katsunori Ishii, Manami Yoshida, Yosuke Kameda, Junko Yoshiura
    • Organizer
      11th Conference of Aseanian Membrane Society
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Improvement of gas separation properties through MFI membranes2018

    • Author(s)
      Mikihiro Nomura
    • Organizer
      The workshop at Nanjing Tech University
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Silica-Based Membranes with Molecular-Net-Sieving Properties: Development and Applications2018

    • Author(s)
      T. Tsuru
    • Organizer
      International Symposium on Advanced Membranes & Sustainable Technologies
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 多孔性セラミック膜の開発と各種分離プロセスへの応用2018

    • Author(s)
      都留稔了
    • Organizer
      中国四国地区化学工学懇話会特別講演
    • Related Report
      2018 Annual Research Report
    • Invited
  • [Presentation] Membrane Technology for Sustainable Development Goals: Application to water and energy2018

    • Author(s)
      T. Tsuru
    • Organizer
      MIRAI workshop
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] シリカ系多孔質分離膜の高度化と触媒膜反応器への応用2018

    • Author(s)
      都留稔了
    • Organizer
      化学工学会秋季大会
    • Related Report
      2018 Annual Research Report
    • Invited
  • [Presentation] ゾルゲル法による触媒膜の開発と触媒膜型反応への応用2018

    • Author(s)
      都留稔了
    • Organizer
      第3回東日本キャタリシスセミナー
    • Related Report
      2018 Annual Research Report
    • Invited
  • [Book] 脱石油に向けたCO2資源化技術2020

    • Author(s)
      福原長寿(執筆者計76名)
    • Total Pages
      375
    • Publisher
      シーエムシー出版
    • ISBN
      9784781315102
    • Related Report
      2020 Annual Research Report
  • [Book] 分離プロセスの最適化とスケールアップの進め方2019

    • Author(s)
      都留稔了,松田弘幸,日秋俊彦ほか執筆者計76名
    • Total Pages
      600
    • Publisher
      エヌ・ティー・エス
    • ISBN
      9784861047664
    • Related Report
      2019 Annual Research Report
  • [Book] PCP/MOFおよび各種多孔質材料の作り方,使い方,評価解析2019

    • Author(s)
      都留稔了,草壁克己,宮原 稔,田中大輔ほか執筆者計98名
    • Total Pages
      639
    • Publisher
      (株)技術情報協会
    • Related Report
      2019 Annual Research Report
  • [Book] ゾル-ゲル法によるシリカ系膜の水素透過特性(二酸化炭素・水素分離膜の開発と応用)2018

    • Author(s)
      金指正言,長澤寛規,都留稔了(監修:中尾真一・喜多英敏)
    • Total Pages
      11
    • Publisher
      CMC 出版
    • Related Report
      2018 Annual Research Report
  • [Book] Advanced Materials for Membrane Fabrication and Modification2018

    • Author(s)
      Stephen Gray, Toshinori Tsuru, Yoram Cohen, Woei Jye Lau
    • Total Pages
      600
    • Publisher
      CRC book
    • ISBN
      9781138739055
    • Related Report
      2018 Annual Research Report
  • [Remarks] 広島大学 大学院 工学研究科 分離工学研究室

    • URL

      https://home.hiroshima-u.ac.jp/membrane/

    • Related Report
      2018 Annual Research Report
  • [Remarks] 芝浦工業大学 分離システム工学研究室

    • URL

      https://t-web.shibaura-it.ac.jp/search/detail.php?f_hashvalue=0c4d88eef353b47f275dc5b465009ec7

    • Related Report
      2018 Annual Research Report

URL: 

Published: 2018-04-23   Modified: 2023-01-30  

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