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Synthesis of Cd-free quantum dots exhibiting band edge fluorescence

Research Project

Project/Area Number 18H03863
Research Category

Grant-in-Aid for Scientific Research (A)

Allocation TypeSingle-year Grants
Section一般
Review Section Medium-sized Section 28:Nano/micro science and related fields
Research InstitutionOsaka University

Principal Investigator

Kuwabata Susumu  大阪大学, 工学研究科, 教授 (40186565)

Project Period (FY) 2018-04-01 – 2021-03-31
Project Status Completed (Fiscal Year 2020)
Budget Amount *help
¥41,600,000 (Direct Cost: ¥32,000,000、Indirect Cost: ¥9,600,000)
Fiscal Year 2020: ¥8,970,000 (Direct Cost: ¥6,900,000、Indirect Cost: ¥2,070,000)
Fiscal Year 2019: ¥8,840,000 (Direct Cost: ¥6,800,000、Indirect Cost: ¥2,040,000)
Fiscal Year 2018: ¥23,790,000 (Direct Cost: ¥18,300,000、Indirect Cost: ¥5,490,000)
Keywords量子ドット / 半導体ナノ粒子 / フォトルミネッセンス / 量子サイズ効果 / コア・シェル構造 / カドミウムフリー / 蛍光材料
Outline of Final Research Achievements

Semiconductor nanoparticles (quantum dots) having a size of 10 nm or less exhibit emission characteristics and quantum size effects that bulk semiconductors do not have. So far, however, all high-performance quantum dots have been cadmium compounds. We have succeeded in synthesizing cadmium-free quantum dots by replacing the cadmium element with multiple low-toxic elements. However, its characteristics are not sufficient because it emits photoluminescence from defect sites that is spectrally broad. In this research, by constructing a core-shell structure in which the surface of a quantum dot is coated with another type of semiconductor, it is dramatically transformed into a quantum dot that exhibits sharp band-edge emission. Furthermore, the quantum dots are improved in practicality by developing new core-shell technologies.

Academic Significance and Societal Importance of the Research Achievements

サイズが10 nm以下の半導体粒子は量子ドットと呼ばれており、蛍光を発し、その色は粒子のサイズで変化し、かつ有機蛍光分子よりも耐久性が優れているので、新しい発光素子として興味が持たれている。しかし、これまでに開発されてきた高特性な量子ドットは全てカドミウム化合物であった。我々は、2007年に蛍光を発するカドミウムを含まない量子ドットを開発したが、その蛍光は欠陥サイトから発せられるため、カドミウム化合物量子ドットより劣っていた。しかし、本研究によってバンド端から蛍光を発する、カドミウム化合物と同等の高特性な量子ドットの作製に成功し、量子ドットの本格的応用の可能性を開いた。

Report

(4 results)
  • 2020 Annual Research Report   Final Research Report ( PDF )
  • 2019 Annual Research Report
  • 2018 Annual Research Report
  • Research Products

    (40 results)

All 2021 2020 2019 2018

All Journal Article (8 results) (of which Int'l Joint Research: 3 results,  Peer Reviewed: 8 results,  Open Access: 4 results) Presentation (26 results) (of which Int'l Joint Research: 12 results,  Invited: 7 results) Book (1 results) Patent(Industrial Property Rights) (5 results)

  • [Journal Article] Variations in Photoluminescence Intensity of a Quantum Dot Assembly Investigated by Its Adsorption on Cubic Metal-Organic Frameworks2021

    • Author(s)
      Kumagai Kohei、Uematsu Taro、Torimoto Tsukasa、Kuwabata Susumu
    • Journal Title

      The Journal of Physical Chemistry C

      Volume: 125 Issue: 15 Pages: 8285-8293

    • DOI

      10.1021/acs.jpcc.1c00232

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Photoluminescence Enhancement by Light Harvesting of Metal-Organic Frameworks Surrounding Semiconductor Quantum Dots2020

    • Author(s)
      Kumagai Kohei、Uematsu Taro、Torimoto Tsukasa、Kuwabata Susumu
    • Journal Title

      Chemistry of Materials

      Volume: 33 Issue: 5 Pages: 1607-1617

    • DOI

      10.1021/acs.chemmater.0c03367

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Efficient quantum-dot light-emitting diodes using ZnS/AgInS2 solid-solution quantum dots in combination with organic charge-transport materials2020

    • Author(s)
      Motomura Genichi、Ogura Kei、Kameyama Tatsuya、Torimoto Tsukasa、Uematsu Taro、Kuwabata Susumu、Tsuzuki Toshimitsu
    • Journal Title

      Applied Physics Letters

      Volume: 116 Issue: 9 Pages: 093302-093302

    • DOI

      10.1063/1.5143618

    • Related Report
      2020 Annual Research Report 2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Tailored Photoluminescence Properties of Ag(In,Ga)Se2 Quantum Dots for Near-Infrared In Vivo Imaging2020

    • Author(s)
      Tatsuya Kameyama, Hiroki Yamauchi, Takahisa Yamamoto, Toshiki Mizumaki, Hiroshi Yukawa, Masahiro Yamamoto, Shigeru Ikeda, Taro Uematsu, Yoshinobu Baba, Susumu Kuwabata, Tsukasa Torimoto
    • Journal Title

      ACS Applied Nano Materials

      Volume: 3 Issue: 4 Pages: 3275-3287

    • DOI

      10.1021/acsanm.9b02608

    • Related Report
      2020 Annual Research Report 2019 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Direct surface modification of semiconductor quantum dots with metal-organic frameworks2019

    • Author(s)
      Kumagai Kohei、Uematsu Taro、Torimoto Tsukasa、Kuwabata Susumu
    • Journal Title

      CrystEngComm

      Volume: 21 Issue: 37 Pages: 5568-5577

    • DOI

      10.1039/c9ce00769e

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Core Nanoparticle Engineering for Narrower and More Intense Band-Edge Emission from AgInS2/GaSx Core/Shell Quantum Dots2019

    • Author(s)
      Hoisang Watcharaporn、Uematsu Taro、Yamamoto Takahisa、Torimoto Tsukasa、Kuwabata Susumu
    • Journal Title

      Nanomaterials

      Volume: 9 Issue: 12 Pages: 1763-1763

    • DOI

      10.3390/nano9121763

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Wavelength-Tunable Band-Edge Photoluminescence of Nonstoichiometric Ag-In-S Nanoparticles via Ga3+ Doping2018

    • Author(s)
      Tatsuya Kameyama, Marino Kishi, Chie Miyamae, Dharmendar Kumar Sharma, Shuzo Hirata, Takahisa Yamamoto, Taro Uematsu, Martin Vacha, Susumu Kuwabata, and Tsukasa Torimoto
    • Journal Title

      ACS Applied Mater. Interfaces

      Volume: 10 Issue: 49 Pages: 42844-42855

    • DOI

      10.1021/acsami.8b15222

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Narrow band-edge photoluminescence from AgInS2 semiconductor nanoparticles by the formation of amorphous III-VI semiconductor shells2018

    • Author(s)
      Taro Uematsu, Kazutaka Wajima, Dharmendar Kumar Sharma, Shuzo Hirata, Takahisa Yamamoto, Tatsuya Kameyama, Martin Vacha, Tsukasa Torimoto, and Susumu Kuwabata
    • Journal Title

      NPG Asia Mater.

      Volume: 10 Issue: 8 Pages: 713-726

    • DOI

      10.1038/s41427-018-0067-9

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Open Access
  • [Presentation] 量子ドット~高機能化・高性能化のための表面デザイン~2021

    • Author(s)
      桑畑 進、上松 太郎
    • Organizer
      電気化学会第88回大会
    • Related Report
      2020 Annual Research Report
    • Invited
  • [Presentation] 光捕集効果を示すMOFからのエネルギー移動による量子ドットの発光増強2021

    • Author(s)
      上松 太郎, 熊谷 康平, 鳥本 司, 桑畑 進
    • Organizer
      電気化学会第88回大会
    • Related Report
      2020 Annual Research Report
  • [Presentation] 発光性半導体ナノ粒子(量子ドット)を用いたEL素子の作製:発光効率向上を目的とした素子構造の検討2021

    • Author(s)
      泉 竜之介、三田 寛人、上松 太郎、鳥本 司、桑畑 進
    • Organizer
      電気化学会第88回大会
    • Related Report
      2020 Annual Research Report
  • [Presentation] Preparation of multicolor carbon dots for photoelectrochemical studies2021

    • Author(s)
      テパキッドゥアリクン マナンヤー、上松 太郎、桑畑 進
    • Organizer
      電気化学会第88回大会
    • Related Report
      2020 Annual Research Report
  • [Presentation] カドミウムフリー量子ドットの機能向上2020

    • Author(s)
      上松 太郎
    • Organizer
      ニューセラミックス懇話会第241回研究会
    • Related Report
      2020 Annual Research Report
    • Invited
  • [Presentation] Band-Edge Emission from AgInS2/Ga2S3 Core/Shell Quantum Dots and Enhancement of Their Quantum Yield2020

    • Author(s)
      Susumu Kuwabata
    • Organizer
      PRiME 2020
    • Related Report
      2020 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Embedding Quantum Dots with High Quantum Yield in Inorganic Matrix By Sol-Gel Method2020

    • Author(s)
      Daiki Nishimura, Taro Uematsu, Tsukasa Torimoto, and Susumu Kuwabata
    • Organizer
      PRiME 2020
    • Related Report
      2020 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Narrow-Band Photoluminescence from Cadmium-Free I-III-VI Ternary Semiconductor Quantum Dots By Surface Modification2020

    • Author(s)
      T. Uematsu, K. Wajima, W. Hoisang, D. K. Sharma, S. Hirata, T. Yamamoto, T. Kameyama, M. Vacha, T. Torimoto, and S. Kuwabata
    • Organizer
      PRiME 2020
    • Related Report
      2020 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Fabrication and Evaluation of Electroluminescence Devices Using Quantum Dots As Light Emitting Materials2020

    • Author(s)
      R. Izumi, T. Uematsu, T. Torimoto, and S. Kuwabata
    • Organizer
      PRiME 2020
    • Related Report
      2020 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Synthesis of color-tunable Ag(InxGa1-x)S2/GaSy core/shell quantum dots2020

    • Author(s)
      Watcharaporn Hoisang, Taro Uematsu, Tsukasa Torimoto, and Susumu Kuwabata
    • Organizer
      電気化学会第87 回大会
    • Related Report
      2019 Annual Research Report
  • [Presentation] ゾル・ゲル法による量子ドット蛍光体を分散させた固体マトリクスの調製2020

    • Author(s)
      西村大輝、上松太郎、鳥本 司、桑畑 進
    • Organizer
      電気化学会第87 回大会
    • Related Report
      2019 Annual Research Report
  • [Presentation] コア/シェル量子ドットの電子構造が光励起電子移動に及ぼす影響2020

    • Author(s)
      上松太郎,笹倉卓也,鳥本 司,桑畑 進
    • Organizer
      電気化学会第87 回大会
    • Related Report
      2019 Annual Research Report
  • [Presentation] Improving Photoluminescence Properties of Cadmium-free Quantum Dots by the Optimization of Nanostructure2020

    • Author(s)
      Taro Uematsu
    • Organizer
      日本化学会 第100春季年会 アジア国際シンポジウム
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Synthesis of Organic Ligand Free Quantum Dots in Solid State2019

    • Author(s)
      Daiki Nishimura, Taro Uematsu, Tsukasa Torimoto, and Susumu Kuwabata
    • Organizer
      Taiwan Japan Bilateral Workshop 2019
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 硫化ガリウムシェルを有するCu-Ag-In-S量子ドットの合成と赤色発光2019

    • Author(s)
      神畑知輝、上松太郎、鳥本 司、桑畑 進
    • Organizer
      2019年電気化学秋季大会
    • Related Report
      2019 Annual Research Report
  • [Presentation] 金属有機構造体(MOFs)で包埋した量子ドットの合成と発光特性2019

    • Author(s)
      神野賢人、熊谷康平、上松太郎、鳥本 司、桑畑 進
    • Organizer
      2019年電気化学秋季大会
    • Related Report
      2019 Annual Research Report
  • [Presentation] Metal-organic frameworks as novel stabilizers for semiconductor quantum dots2019

    • Author(s)
      Kohei Kumagai, Taro Uematsu, Tsukasa Torimoto, and Susumu Kuwabata
    • Organizer
      The 1st Australia-Belgium-Japan joint symposium on excitonics and cellular communication
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Studies on exciton confinement effect of core/shell quantum dot fluorophores by photoinduced electron transfer2019

    • Author(s)
      笹倉卓也,上松太郎,鳥本司,桑畑進
    • Organizer
      電気化学会 関西支部・東海支部合同シンポジウム
    • Related Report
      2019 Annual Research Report
  • [Presentation] Photoluminescence Intensity and Quality Enhancement for AgInS2/GaSx Core/shell Quantum Dots by Improving Core Synthesis Method2019

    • Author(s)
      Taro Uematsu,Watcharaporn Hoisang,Tsukasa Torimoto,Susumu Kuwabata
    • Organizer
      Taiwan Japan Bilateral Workshop 2019
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] カドミウムフリー量子ドットからの バンド端発光と光学特性向上2019

    • Author(s)
      上松 太郎
    • Organizer
      高分子討論会2019
    • Related Report
      2019 Annual Research Report
    • Invited
  • [Presentation] Improvement of optical properties for cadmium-free quantum dot fluorophores2019

    • Author(s)
      Taro Uematsu
    • Organizer
      The 65th Annual Meeting of PSJ
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Improvement of Photoluminescence Property of Band-edge Emission from AgInS2/Ga2S3 Core/shell Quantum Dots2018

    • Author(s)
      Susumu Kuwabata
    • Organizer
      IDW' 18
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Developments of novel semiconductor nanoparticles stabilized with metal-organic frameworks (MOFs)2018

    • Author(s)
      Kohei Kumagai, Taro Uematsu, and Susumu Kuwabata
    • Organizer
      22nd Topical Meeting of the International Society of Electrochemistry
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Narrow Band-edge Emission from AgInS2/GaSx Core/shell Quantum Dots: Improvement of Quantum Yield2018

    • Author(s)
      Taro Uematsu, Kazutaka Wajima, Dharmendar Kumar Sharma, Shuzo Hirata, Takahisa Yamamoto, Tatsuya Kameyama, Martin Vacha, Tsukasa Torimoto, and Susumu Kuwabata
    • Organizer
      Japan-Taiwan Bilateral Workshop on Nano-Science
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] AgInS2/GaSx コア/シェル量子ドットコロイドからのバンド端発光と光学特性の向上2018

    • Author(s)
      上松 太郎,輪島 知卓,SHARMA Dharmendar Kumar,平田 修造,山本 剛久,亀山 達矢,VACHA Martin,鳥本 司,小谷松 大祐,桑畑 進
    • Organizer
      2018年応用物理学会秋季講演会
    • Related Report
      2018 Annual Research Report
  • [Presentation] 光電子移動を利用したコア/シェル型量子ドット蛍光体の励起子閉じ込め効果に関する評価2018

    • Author(s)
      笹倉卓也、上松太郎、鳥本 司、桑畑 進
    • Organizer
      第66回応用物理学会春季学術講演会
    • Related Report
      2018 Annual Research Report
  • [Book] 「次世代ディスプレイへの応用に向けた材料、プロセス技術の開発動向」2020

    • Author(s)
      上松 太郎、桑畑 進
    • Publisher
      技術情報協会誌
    • ISBN
      9784861047794
    • Related Report
      2019 Annual Research Report
  • [Patent(Industrial Property Rights)] 半導体ナノ粒子の製造方法及び発光デバイス2021

    • Inventor(s)
      桑畑進、上松太郎、鳥本司、亀山達矢、久保朋也
    • Industrial Property Rights Holder
      桑畑進、上松太郎、鳥本司、亀山達矢、久保朋也
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      2021-036602
    • Filing Date
      2021
    • Related Report
      2020 Annual Research Report
  • [Patent(Industrial Property Rights)] 量子ドット発光素子、量子ドット発光素子の製造方法、及び表示装置2021

    • Inventor(s)
      本村玄一、都築俊満、岩崎有希子、桑畑進、上松太郎
    • Industrial Property Rights Holder
      本村玄一、都築俊満、岩崎有希子、桑畑進、上松太郎
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      2021-032002
    • Filing Date
      2021
    • Related Report
      2020 Annual Research Report
  • [Patent(Industrial Property Rights)] 発光材料及びその製造方法2020

    • Inventor(s)
      桑畑 進、上松太郎、鳥本 司、亀山達矢、小谷松大祐
    • Industrial Property Rights Holder
      桑畑 進、上松太郎、鳥本 司、亀山達矢、小谷松大祐
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      2020-040093
    • Filing Date
      2020
    • Related Report
      2019 Annual Research Report
  • [Patent(Industrial Property Rights)] 半導体ナノ粒子の製造方法2020

    • Inventor(s)
      桑畑 進、上松太郎、鳥本 司、亀山達矢、小谷松大祐
    • Industrial Property Rights Holder
      桑畑 進、上松太郎、鳥本 司、亀山達矢、小谷松大祐
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      2020-040094
    • Filing Date
      2020
    • Related Report
      2019 Annual Research Report
  • [Patent(Industrial Property Rights)] 半導体ナノ粒子の製造方法2018

    • Inventor(s)
      桑畑 進、上松 太郎、小谷松 大祐、鳥本 司、亀山 達矢
    • Industrial Property Rights Holder
      桑畑 進、上松 太郎、小谷松 大祐、鳥本 司、亀山 達矢
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      2019-021769
    • Filing Date
      2018
    • Related Report
      2018 Annual Research Report

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Published: 2018-04-23   Modified: 2022-01-27  

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