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Construction of new mechanism for dual-ion storage batteries concerted by lithium and multivalent ions

Research Project

Project/Area Number 18H05249
Research Category

Grant-in-Aid for Scientific Research (S)

Allocation TypeSingle-year Grants
Review Section Broad Section D
Research InstitutionTohoku University

Principal Investigator

ICHITSUBO Tetsu  東北大学, 金属材料研究所, 教授 (40324826)

Co-Investigator(Kenkyū-buntansha) 岡本 範彦  東北大学, 金属材料研究所, 准教授 (60505692)
河口 智也  東北大学, 金属材料研究所, 助教 (00768103)
谷村 洋  東北大学, 金属材料研究所, 助教 (70804087)
八木 俊介  東京大学, 生産技術研究所, 准教授 (60452273)
Project Period (FY) 2018-06-11 – 2023-03-31
Project Status Completed (Fiscal Year 2022)
Budget Amount *help
¥198,640,000 (Direct Cost: ¥152,800,000、Indirect Cost: ¥45,840,000)
Fiscal Year 2022: ¥13,780,000 (Direct Cost: ¥10,600,000、Indirect Cost: ¥3,180,000)
Fiscal Year 2021: ¥16,640,000 (Direct Cost: ¥12,800,000、Indirect Cost: ¥3,840,000)
Fiscal Year 2020: ¥22,360,000 (Direct Cost: ¥17,200,000、Indirect Cost: ¥5,160,000)
Fiscal Year 2019: ¥46,020,000 (Direct Cost: ¥35,400,000、Indirect Cost: ¥10,620,000)
Fiscal Year 2018: ¥99,840,000 (Direct Cost: ¥76,800,000、Indirect Cost: ¥23,040,000)
Keywordsデュアルキャリア / 多価イオン / 蓄電池 / デントライト / デンドライト / 多価カチオン伝導 / 協奏効果 / デンドライトフリー / 合金負極蓄電池
Outline of Final Research Achievements

While the physicochemical mechanisms of storage batteries using monovalent ions such as lithium and sodium are well understood, the basic science of storage battery systems using multivalent ions such as magnesium as carriers remains largely unexplored. In this study, we proposed the concept of a dual-ion battery system using both monovalent and multivalent ions, and clarified the concerted effects of promoting the diffusion of multivalent ions in the cathode material and controlling the deposition of monovalent alkaline elements in the metal anode.

Academic Significance and Societal Importance of the Research Achievements

持続的なエネルギーシステムを実現するため,新規蓄電池技術の開発は不可欠である.本研究は,一価イオンと多価イオンの協奏的効果に着眼し,反応機構の解明から電極材料設計指針の確立,デバイスの構築まで,デュアルイオン蓄電池系に関わる学理基盤を築いた.本研究で得られた知見は,デュアルイオン蓄電池だけでなく,リチウムイオン蓄電池やマグネシウム蓄電池などを含む単一イオンをキャリアとする蓄電池系の材料開発にも適用でき,安全・安心かつ低コスト・高エネルギー密度を兼備した蓄電池技術の実現に貢献する.

Assessment Rating
Ex-post Assessment Comments (Rating)

A: In light of the aim of introducing the research area into the research categories, expected outcomes of research have been produced.

Assessment Rating
Interim Assessment Comments (Rating)

A: In light of the aim of introducing the research area into the research categories, the expected progress has been made in research.

Report

(11 results)
  • 2023 Ex-post Assessment (Comments) ( PDF )
  • 2022 Annual Research Report   Final Research Report ( PDF )
  • 2021 Annual Research Report
  • 2020 Abstract (Interim Assessment) ( PDF )   Annual Research Report   Interim Assessment (Comments) ( PDF )
  • 2019 Annual Research Report
  • 2018 Abstract ( PDF )   Comments on the Screening Results ( PDF )   Annual Research Report
  • Research Products

    (26 results)

All 2023 2022 2021 2020 2019 2018 Other

All Journal Article (4 results) (of which Peer Reviewed: 4 results,  Open Access: 1 results) Presentation (11 results) (of which Int'l Joint Research: 4 results,  Invited: 3 results) Book (1 results) Remarks (4 results) Patent(Industrial Property Rights) (6 results) (of which Overseas: 2 results)

  • [Journal Article] Dendrite-free alkali metal electrodeposition from contact-ion-pair state induced by mixing alkaline earth cation2022

    • Author(s)
      Li Hongyi、Murayama Masaki、Ichitsubo Tetsu
    • Journal Title

      Cell Reports Physical Science

      Volume: 3 Issue: 6 Pages: 100907-100907

    • DOI

      10.1016/j.xcrp.2022.100907

    • Related Report
      2022 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Influences of enhanced entropy in layered rocksalt oxide cathodes for lithium-ion batteries2022

    • Author(s)
      Tomoya Kawaguchi, Xiao Bian, Takuya Hatakeyama, Hongyi Li, Tetsu Ichitsubo
    • Journal Title

      ACS Applied Energy Materials

      Volume: TBD Issue: 4 Pages: 4369-4381

    • DOI

      10.1021/acsaem.1c03968

    • Related Report
      2022 Annual Research Report 2021 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Circumventing huge volume strain in alloy anodes of lithium batteries2020

    • Author(s)
      Li Hongyi、Yamaguchi Takitaro、Matsumoto Shingo、Hoshikawa Hiroaki、Kumagai Toshiaki、Okamoto Norihiko L.、Ichitsubo Tetsu
    • Journal Title

      Nature Communications

      Volume: 11 Issue: 1 Pages: 1584-1584

    • DOI

      10.1038/s41467-020-15452-0

    • Related Report
      2020 Annual Research Report 2019 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Suppressive effect of Fe cations in Mg(Mn1-xFex)2O4 positive electrodes on oxidative electrolyte decomposition for Mg rechargeable batteries2019

    • Author(s)
      Jonghyun Han, Shunsuke Yagi, Tetsu Ichitsubo
    • Journal Title

      Journal of Power Sources

      Volume: 435 Pages: 226822-226822

    • DOI

      10.1016/j.jpowsour.2019.226822

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Presentation] ハイエントロピー酸化物を用いた蓄電池正極材料2023

    • Author(s)
      河口智也,安田優哉,根本菜摘,下川航平,李弘毅,岡本範彦,市坪哲
    • Organizer
      電気化学会第90回大会
    • Related Report
      2022 Annual Research Report
  • [Presentation] 難電析多価カチオン添加によるアルカリ金属負極のデンドライト成長抑制2022

    • Author(s)
      李 弘毅,村山 将来,市坪哲
    • Organizer
      電気化学会秋季大会
    • Related Report
      2022 Annual Research Report
  • [Presentation] 「リチウム合金化に伴う体積歪形成の回避」2021

    • Author(s)
      李弘毅,山口滝太郎,松本慎吾,星川浩介,熊谷俊昭,岡本範彦,市坪哲,
    • Organizer
      2021電気化学秋季大会
    • Related Report
      2021 Annual Research Report
  • [Presentation] 「リチウム蓄電池用集電体一体型アルミ箔負極の開発」2021

    • Author(s)
      西村匠平,李弘毅,山口滝太郎,松本慎吾,星川浩介,熊谷俊昭,岡本範彦,市坪哲
    • Organizer
      2021電気化学秋季大会
    • Related Report
      2021 Annual Research Report
  • [Presentation] 汎用金属で高性能電池を創る!―マグネシウムイオンを利用した蓄電デバイス研究―2019

    • Author(s)
      市坪 哲,下川 航平, 李 弘毅,岡本 範彦
    • Organizer
      第9回 CSJ化学フェスタ2019(日本化学会)
    • Related Report
      2019 Annual Research Report
    • Invited
  • [Presentation] 協奏的相互作用による多価カチオン固体内拡散の促進現象2019

    • Author(s)
      李弘毅,岡本範彦,熊谷悠,大場史康,市坪哲
    • Organizer
      第45回 固体イオニクス討論会
    • Related Report
      2019 Annual Research Report
  • [Presentation] 協調的相互作用による多価カチオン固体内拡散の促進現象2019

    • Author(s)
      李弘毅,岡本範彦,熊谷悠,大場史康,市坪哲
    • Organizer
      日本金属学会 2019年秋期大会(第165回)
    • Related Report
      2019 Annual Research Report
  • [Presentation] Facilitating Intercalation of Multivalent Cation Utilizing Concerted Interactionin Dual-Ion Battery Systems2019

    • Author(s)
      Hongyi Li
    • Organizer
      The 2nd Symposium for World Leading Research Centers
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Concerted Motion of Li-Mg Dual Ions in Intercalation Cathode Materials2018

    • Author(s)
      Li Hongyi
    • Organizer
      69th Annual Meeting of the International Society of Electrochemistry
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Dual-ion rechargeable battery systems utilizing concerted interactions2018

    • Author(s)
      Li Hongyi
    • Organizer
      Japan-France Battery Seminar
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Facilitating solid-phase diffusion of multivalent ions utilizing concerted interactions in dual-ion battery systems2018

    • Author(s)
      Hongyi Li
    • Organizer
      Summit of Materials Science 2018
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Book] Magnesium Batteries: Research and Applications, Chapter 112019

    • Author(s)
      Hongyi Li, Tetsu Ichitsubo, Eiichiro Matsubara
    • Total Pages
      34
    • Publisher
      The Royal Society of Chemistry
    • ISBN
      9781788014342
    • Related Report
      2019 Annual Research Report
  • [Remarks] 構造制御機能材料学研究部門のHP

    • URL

      http://ilab.imr.tohoku.ac.jp/

    • Related Report
      2019 Annual Research Report
  • [Remarks] リチウム合金化に伴う巨大体積歪の回避に成功

    • URL

      http://ilab.imr.tohoku.ac.jp/?p=905

    • Related Report
      2019 Annual Research Report
  • [Remarks] 協奏的動きがもたらす多価イオン拡散の促進現象を発見

    • URL

      http://ilab.imr.tohoku.ac.jp/?p=335

    • Related Report
      2019 Annual Research Report
  • [Remarks] 協奏的動きがもたらす多価イオン拡散の促進現象を発見

    • URL

      http://www.imr.tohoku.ac.jp/ja/news/results/detail---id-1035.html

    • Related Report
      2018 Annual Research Report
  • [Patent(Industrial Property Rights)] 正極活物質、マグネシウム蓄電池の製造方法2023

    • Inventor(s)
      市坪哲、河口智也、安田優哉
    • Industrial Property Rights Holder
      市坪哲、河口智也、安田優哉
    • Industrial Property Rights Type
      特許
    • Filing Date
      2023
    • Related Report
      2022 Annual Research Report
  • [Patent(Industrial Property Rights)] リチウム金属二次電池用電解液およびリチウム金属二次電池2022

    • Inventor(s)
      市坪哲、李弘毅、清水大地
    • Industrial Property Rights Holder
      市坪哲、李弘毅、清水大地
    • Industrial Property Rights Type
      特許
    • Filing Date
      2022
    • Related Report
      2022 Annual Research Report
    • Overseas
  • [Patent(Industrial Property Rights)] 「アルカリ金属二次電池用電解液およびアルカリ金属二次電池」2021

    • Inventor(s)
      市坪哲、李弘毅、村山将来
    • Industrial Property Rights Holder
      市坪哲、李弘毅、村山将来
    • Industrial Property Rights Type
      特許
    • Filing Date
      2021
    • Related Report
      2021 Annual Research Report
    • Overseas
  • [Patent(Industrial Property Rights)] リチウム二次電池用負極及びリチウム二次電池」2021

    • Inventor(s)
      松本慎吾、山口滝太郎、市坪哲、李弘毅、西村匠平
    • Industrial Property Rights Holder
      松本慎吾、山口滝太郎、市坪哲、李弘毅、西村匠平
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      2021-200898
    • Filing Date
      2021
    • Related Report
      2021 Annual Research Report
  • [Patent(Industrial Property Rights)] 集電体一体型二次電池用負極及びリチウム二次電池2019

    • Inventor(s)
      松本慎吾, 山口滝太郎, 星河浩介, 市坪哲, 李弘毅
    • Industrial Property Rights Holder
      松本慎吾, 山口滝太郎, 星河浩介, 市坪哲, 李弘毅
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      2019-229603
    • Filing Date
      2019
    • Related Report
      2019 Annual Research Report
  • [Patent(Industrial Property Rights)] リチウム二次電池及びバッテリーシステム2019

    • Inventor(s)
      山口滝太郎, 松本慎吾, 星河浩介, 市坪哲, 李弘毅
    • Industrial Property Rights Holder
      山口滝太郎, 松本慎吾, 星河浩介, 市坪哲, 李弘毅
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      2019-229604
    • Filing Date
      2019
    • Related Report
      2019 Annual Research Report

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Published: 2018-06-12   Modified: 2024-03-28  

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