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Development of emergent electronic properties originated from geometric structures of crystals and local correlation effects

Research Project

Project/Area Number 18K03542
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Review Section Basic Section 13030:Magnetism, superconductivity and strongly correlated systems-related
Research InstitutionKyushu Institute of Technology

Principal Investigator

Watanabe Shinji  九州工業大学, 大学院工学研究院, 准教授 (40334346)

Project Period (FY) 2018-04-01 – 2021-03-31
Project Status Completed (Fiscal Year 2020)
Budget Amount *help
¥4,420,000 (Direct Cost: ¥3,400,000、Indirect Cost: ¥1,020,000)
Fiscal Year 2020: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2019: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000)
Fiscal Year 2018: ¥2,470,000 (Direct Cost: ¥1,900,000、Indirect Cost: ¥570,000)
Keywordsグリュナイゼン係数 / 比熱 / 熱膨張係数 / 臨界体積効果 / 磁気体積効果 / 価数量子臨界現象 / 準結晶 / 近似結晶 / 超音波応答 / 弾性定数 / 臨界価数ゆらぎ / SmS / 絶縁体-半金属相転移 / black-golden転移 / エキシトン / グリュナイゼンパラメーター / 量子臨界現象 / 磁気量子臨界点 / SCR理論 / 量子臨界準結晶 / 電子相関
Outline of Final Research Achievements

The theoretical framework to calculate the specific heat, the thermal-expansion coefficient, and the Gruneisen parameter due to critical valence fluctuations diverging at the quantum critical point of the valence transition is constructed. By applying this method to the quasicrystal Yb15Al34Au51, the measured temperature dependences of the specific heat, the thermal-expansion coefficient, and the Gruneisen parameter are shown to be well explained. Non-divergent Gruneisen parameter in the quantum-critical quasicrystal Yb15Al34Au51 is shown to be ascribed to the robust criticality against pressure in this material. In the odd-parity crystalline-electric-field arising from the lack of the local inversion symmetry at the Yb site in β-YbAlB4, fluctuations of the odd-parity multipole are shown to be enhanced divergently by the inter-orbital Coulomb repulsion. The theory of the magneto-volume effect is formulated.

Academic Significance and Societal Importance of the Research Achievements

量子臨界点ではグリュナイゼン係数は絶対零度で必ず発散するとこれまで信じられてきたが、圧力に対してrobustな量子臨界性を示す物質では、一般にグリュナイゼン係数は絶対零度で発散しないことを理論的に示した。これは既存概念を覆す新しい概念であり、その学術的意義は大きい。圧力に対してrobustな量子臨界性を示す準結晶Yb15Al34Au51と、特定の圧力でのみそれと共通の量子臨界性を示す近似結晶Yb14Al35Au51でグリュナイゼン係数の振る舞いに違いが出ることを明らかにした本研究の成果は、電子間の局所相互作用によって結晶の幾何学的構造特有の量子現象が生じることを示した学術的意義がある。

Report

(4 results)
  • 2020 Annual Research Report   Final Research Report ( PDF )
  • 2019 Research-status Report
  • 2018 Research-status Report
  • Research Products

    (30 results)

All 2021 2020 2019 2018 Other

All Int'l Joint Research (3 results) Journal Article (14 results) (of which Int'l Joint Research: 1 results,  Peer Reviewed: 14 results,  Open Access: 1 results) Presentation (9 results) (of which Int'l Joint Research: 5 results,  Invited: 4 results) Remarks (4 results)

  • [Int'l Joint Research] University of Geneva(スイス)

    • Related Report
      2018 Research-status Report
  • [Int'l Joint Research] Institute of Natural Sciences(中国)

    • Related Report
      2018 Research-status Report
  • [Int'l Joint Research] CEA-INAC/UJF-Grenoble(フランス)

    • Related Report
      2018 Research-status Report
  • [Journal Article] Interplay of Valence and Semimetal-to-Insulator Transitions in SmS2021

    • Author(s)
      Watanabe Shinji
    • Journal Title

      Journal of the Physical Society of Japan

      Volume: 90 Issue: 2 Pages: 023706-023706

    • DOI

      10.7566/jpsj.90.023706

    • NAID

      40022482254

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Crystalline Electronic Field in Rare-Earth Based Quasicrystal and Approximant: Analysis of Quantum Critical Au?Al?Yb Quasicrystal and Approximant2021

    • Author(s)
      Watanabe Shinji、Kawamoto Mina
    • Journal Title

      Journal of the Physical Society of Japan

      Volume: 90 Issue: 6 Pages: 063701-063701

    • DOI

      10.7566/jpsj.90.063701

    • NAID

      40022591312

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Ultrasound Response in Quantum Critical β-YbAlB4 and α-YbAl0.986Fe0.014B42020

    • Author(s)
      Watanabe Shinji
    • Journal Title

      Journal of the Physical Society of Japan

      Volume: 89 Issue: 7 Pages: 073702-073702

    • DOI

      10.7566/jpsj.89.073702

    • NAID

      120007041717

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed
  • [Journal Article] 誌上セミナー 量子臨界現象の新展開 (その2) 量子臨界磁気体積効果2020

    • Author(s)
      渡辺真仁, 三宅和正
    • Journal Title

      固体物理

      Volume: 55 Pages: 697-713

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Non-divergent Gruneisen Parameter in Quantum Critical Quasicrystal Yb_15Al_34Au_51: Reflection of Robustness of Quantum Criticality under Pressure2020

    • Author(s)
      S. Watanabe, K. Miyake
    • Journal Title

      Solid State Commun.

      Volume: 306 Pages: 113774-113774

    • DOI

      10.1016/j.ssc.2019.113774

    • Related Report
      2019 Research-status Report
    • Peer Reviewed
  • [Journal Article] 量子臨界現象の新展開 (その1) スピンゆらぎのSCR理論2020

    • Author(s)
      渡辺真仁, 三宅和正
    • Journal Title

      固体物理

      Volume: 55 Pages: 55-68

    • Related Report
      2019 Research-status Report
    • Peer Reviewed
  • [Journal Article] Charge Transfer Effect under Odd-Parity Crystalline Electric Field2020

    • Author(s)
      S. Watanabe, K. Miyake
    • Journal Title

      JPS Conf. Proc.

      Volume: 29

    • DOI

      10.7566/jpscp.29.014001

    • NAID

      120006822477

    • Related Report
      2019 Research-status Report
    • Peer Reviewed
  • [Journal Article] Theory for Non-Fermi Liquid Temperature Dependence in Resistivity of CexLa_1-xCu_5.62Au_0.38 (x = 0.02-0.10) on the Local Quantum Valence Criticality of Ce Impurities2020

    • Author(s)
      K. Miyake, S. Watanabe
    • Journal Title

      JPS Conf. Proc.

      Volume: 30

    • DOI

      10.7566/jpscp.30.011027

    • Related Report
      2019 Research-status Report
    • Peer Reviewed
  • [Journal Article] Quantum Valence Criticality in Heavy Fermions on Periodic and Aperiodic Crystals2020

    • Author(s)
      Watanabe Shinji、Miyake Kazumasa
    • Journal Title

      JPS Conf. Proc.

      Volume: 30

    • DOI

      10.7566/jpscp.30.011023

    • NAID

      120006822476

    • Related Report
      2019 Research-status Report
    • Peer Reviewed
  • [Journal Article] Charge Transfer Effect under Odd-Parity Crystalline Electric Field: Divergence of Magnetic Toroidal Fluctuation in \beta-YbAlB_42019

    • Author(s)
      S. Watanabe, K. Miyake
    • Journal Title

      J. Phys. Soc. Jpn.

      Volume: 88 Issue: 3 Pages: 033701-033701

    • DOI

      10.7566/jpsj.88.033701

    • Related Report
      2019 Research-status Report 2018 Research-status Report
    • Peer Reviewed
  • [Journal Article] Gruneisen Parameter and Thermal Expansion near Magnetic Quantum Critical Points in Itinerant Electron Systems2019

    • Author(s)
      S. Watanabe, K. Miyake
    • Journal Title

      Phys. Rev. B

      Volume: 99 Issue: 3

    • DOI

      10.1103/physrevb.99.035108

    • Related Report
      2018 Research-status Report
    • Peer Reviewed
  • [Journal Article] The Dominant Role of Critical Valence Fluctuations on High Tc Superconductivity in Heavy Fermions2018

    • Author(s)
      G. W. Scheerer, Z. Ren, S. Watanabe, G. Lapertot, D. Aoki, D. Jaccard, K. Miyake
    • Journal Title

      npj Quantum Materials

      Volume: 3 Issue: 1

    • DOI

      10.1038/s41535-018-0111-6

    • NAID

      120006578934

    • Related Report
      2018 Research-status Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] On anomalous temperature dependence of relaxation rate measured by \muSR in \alpha-YbAl_{0.986}Fe_{0.014}B_42018

    • Author(s)
      K. Miyake, S. Watanabe
    • Journal Title

      Phys. Rev. B

      Volume: 98 Issue: 7

    • DOI

      10.1103/physrevb.98.075125

    • Related Report
      2018 Research-status Report
    • Peer Reviewed
  • [Journal Article] Effects of crystalline electronic field and onsite interorbital interaction in Yb-based quasicrystal and approximant crystal2018

    • Author(s)
      S. Watanabe and K. Miyake
    • Journal Title

      Journal of Physics: Condensed Matter

      Volume: 30 Issue: 18 Pages: 184001-184001

    • DOI

      10.1088/1361-648x/aab817

    • NAID

      120006604496

    • Related Report
      2018 Research-status Report
    • Peer Reviewed
  • [Presentation] 量子臨界物質 b-YbAlB4における超音波応答2021

    • Author(s)
      渡辺真仁
    • Organizer
      日本物理学会
    • Related Report
      2020 Annual Research Report
  • [Presentation] 奇パリティ結晶場における電荷移動効果: b-YbAlB4における磁気トロイダルゆらぎの発散2019

    • Author(s)
      渡辺真仁
    • Organizer
      日本物理学会
    • Related Report
      2019 Research-status Report
  • [Presentation] Quantum Valence Criticality in Heavy Fermions on Periodic and Aperiodic Crystals2019

    • Author(s)
      S. Watanabe
    • Organizer
      International Conference on Strongly Correlated Electron Systems (SCES2019)
    • Related Report
      2019 Research-status Report
    • Int'l Joint Research / Invited
  • [Presentation] Charge Transfer Effect under Odd-Parity Crystalline Electric Field: Divergence of Magnetic Toroidal Fluctuation in β-YbAlB42019

    • Author(s)
      S. Watanabe
    • Organizer
      International Workshop on Multipole Physics and Related Phenomena (J-Physics 2019)
    • Related Report
      2019 Research-status Report
    • Int'l Joint Research
  • [Presentation] Non-Divergent Gruneisen Parameter in Quantum-Valence-Critical Quasicrystal2019

    • Author(s)
      S. Watanabe
    • Organizer
      Interdisciplinary Symposium for Quasicrystals and Strongly Correlated Electron System (QSC2019)
    • Related Report
      2019 Research-status Report
    • Int'l Joint Research / Invited
  • [Presentation] Gruneisen Parameter in Quantum Critical Metals on Periodic and Aperiodic Crystals2018

    • Author(s)
      Shinji Watanabe
    • Organizer
      International Workshop on "Emergent Phenomena in Strongly Correlated Quantum Matter"
    • Related Report
      2018 Research-status Report
    • Int'l Joint Research / Invited
  • [Presentation] Gruneisen Parameter in Quantum Critical Yb-Based Quasicrystal2018

    • Author(s)
      Shinji Watanabe
    • Organizer
      The 18th International Conference on High Pressure in Semiconductor Physics (HPSP-18) & The Workshop on High pressure Study on Superconducting (WHS)
    • Related Report
      2018 Research-status Report
    • Int'l Joint Research / Invited
  • [Presentation] 準結晶Yb15 (Al1-xGax)34 (Au1-yCuy)51のYb価数の格子定数依存性2018

    • Author(s)
      渡辺真仁
    • Organizer
      日本物理学会秋季大会
    • Related Report
      2018 Research-status Report
  • [Presentation] 量子臨界準結晶Yb15Al34Au51の比熱、熱膨張係数とグリュナイゼンパラメータ2018

    • Author(s)
      渡辺真仁
    • Organizer
      日本物理学会秋季大会
    • Related Report
      2018 Research-status Report
  • [Remarks] 固体物性理論研究室

    • URL

      https://www.mns.kyutech.ac.jp/~swata/

    • Related Report
      2020 Annual Research Report
  • [Remarks] 研究内容の紹介

    • URL

      https://www.mns.kyutech.ac.jp/~swata/topics.html

    • Related Report
      2019 Research-status Report
  • [Remarks] 九州工業大学の研究者 渡辺真仁

    • URL

      https://research02.jimu.kyutech.ac.jp/html/100000341_ja.html

    • Related Report
      2018 Research-status Report
  • [Remarks] 九州工業大学 基礎科学研究系 渡辺研究室

    • URL

      https://www.mns.kyutech.ac.jp/~swata/index.html

    • Related Report
      2018 Research-status Report

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Published: 2018-04-23   Modified: 2022-01-27  

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