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polar-nonpolar interface structure of lyotropic liquid crystal cubic phase

Research Project

Project/Area Number 18K03557
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Review Section Basic Section 13040:Biophysics, chemical physics and soft matter physics-related
Research InstitutionShizuoka University

Principal Investigator

Oka Toshihiko  静岡大学, 電子工学研究所, 准教授 (60344389)

Project Period (FY) 2018-04-01 – 2021-03-31
Project Status Completed (Fiscal Year 2020)
Budget Amount *help
¥4,420,000 (Direct Cost: ¥3,400,000、Indirect Cost: ¥1,020,000)
Fiscal Year 2020: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2019: ¥1,820,000 (Direct Cost: ¥1,400,000、Indirect Cost: ¥420,000)
Fiscal Year 2018: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Keywordsリオトロピック液晶 / 共連続キュービック相 / 三重周期極小曲面 / 構造形成 / 両親媒性分子 / X線単結晶構造解析 / キュービック相 / 単結晶領域作成 / 小角X線単結晶構造解析 / X線単結晶構造解析 / 極性-非極性界面の構造
Outline of Final Research Achievements

Amphiphilic molecules such as lipids and surfactants become lyotropic liquid crystals in the presence of water and form various phase structures by phase separation on the nanometer scale. Among them, the bicontinuous cubic phase has a periodic structure like a triply periodic minimal surface. The polar-nonpolar interface structure has been considered to be similar to a constant mean curvature surface. However, X-ray structure analysis using a single crystal region revealed that the interface is parallel to the triply periodic minimal surface in both type 1 and type 2 bicontinuous cubic phases. This was considered to be due to the advantage of increasing the structural entropy of the molecular chain rather than the loss of interfacial free energy.

Academic Significance and Societal Importance of the Research Achievements

リオトロピック液晶共連続キュービック相の極性-非極性界面構造は、20年以上にわたり平均曲率一定曲面に近いと考えられてきた。これは界面を直接観測する手法が存在しなかったためである。本研究により共連続キュービック相のX線単結晶構造解析の手法が確立し、界面構造まで調べることができるようになった。これにより界面は三重周期極小曲面に平行であることが明らかとなった。今後は分解能を上げてさらに詳細な構造が明らかになることや、モデルやシミュレーションなどと比較することにより構造形成原理が明らかになることが期待される。

Report

(4 results)
  • 2020 Annual Research Report   Final Research Report ( PDF )
  • 2019 Research-status Report
  • 2018 Research-status Report
  • Research Products

    (13 results)

All 2020 2019 2018 Other

All Int'l Joint Research (3 results) Journal Article (2 results) (of which Int'l Joint Research: 2 results,  Peer Reviewed: 2 results,  Open Access: 2 results) Presentation (8 results) (of which Int'l Joint Research: 2 results)

  • [Int'l Joint Research] Australian National University/Sydney University(オーストラリア)

    • Related Report
      2020 Annual Research Report
  • [Int'l Joint Research] Australian National University/University of Sydney(オーストラリア)

    • Related Report
      2019 Research-status Report
  • [Int'l Joint Research] Australian National University(オーストラリア)

    • Related Report
      2018 Research-status Report
  • [Journal Article] Polar-Nonpolar Interfaces of Normal Bicontinuous Cubic Phases in Nonionic Surfactant/Water Systems Are Parallel to the Gyroid Surface2020

    • Author(s)
      Toshihiko Oka, Noboru Ohta, and Stephen T. Hyde
    • Journal Title

      Langmuir

      Volume: 36 Issue: 30 Pages: 8687-8694

    • DOI

      10.1021/acs.langmuir.0c00597

    • NAID

      120007098574

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Polar-Nonpolar Interfaces of Inverse Bicontinuous Cubic Phases in Phytantriol/Water System are Parallel to Triply Periodic Minimal Surfaces2018

    • Author(s)
      Toshihiko Oka , Noboru Ohta, and Stephen Hyde
    • Journal Title

      Langmuir

      Volume: 34 Issue: 50 Pages: 15462-15469

    • DOI

      10.1021/acs.langmuir.8b03320

    • NAID

      120006772595

    • Related Report
      2018 Research-status Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Presentation] POLAR-NONPOLAR INTERFACE OF BICONTINUOUS CUBIC PHASE IN NONIONIC SURFACTANT/WATER SYSTEMS2020

    • Author(s)
      T. Oka, N. Ohta, S. Hyde
    • Organizer
      Australia Japan Colloids Symposium2020
    • Related Report
      2020 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 非イオン界面活性剤/水系における共連続キュービック相の界面構造2020

    • Author(s)
      岡俊彦、太田昇、Stephen Hyde
    • Organizer
      第71回コロイドおよび界面化学討論会
    • Related Report
      2020 Annual Research Report
  • [Presentation] 非イオン界面活性剤/水系における共連続キュービック相の界面構造2019

    • Author(s)
      岡俊彦, 太田昇, Stephen Hyde
    • Organizer
      日本物理学会2019年秋季大会(物性)
    • Related Report
      2019 Research-status Report
  • [Presentation] Polar-Nopolar Interfaces of Inverse Bicontinuous Cubic Phases in Lyotropic Liquid Crystal2019

    • Author(s)
      岡俊彦, 太田昇, Stephen Hyde
    • Organizer
      Okinawa Colloids 2019
    • Related Report
      2019 Research-status Report
    • Int'l Joint Research
  • [Presentation] 非イオン界面活性剤/水系における共連続キュービック相の界面構造2019

    • Author(s)
      岡俊彦, 太田昇, Stephen Hyde
    • Organizer
      第 9 回ソフトマター研究会
    • Related Report
      2019 Research-status Report
  • [Presentation] リオトロピック液晶共連続逆キュービック相の極性-非極性界面構造2019

    • Author(s)
      岡俊彦
    • Organizer
      日本物理学会 第74回年次大会
    • Related Report
      2018 Research-status Report
  • [Presentation] リオトロピック液晶共連続逆キュービック相の小角X線結晶構造解析2018

    • Author(s)
      岡俊彦
    • Organizer
      PF研究会「多様な物質・生命科学研究に広がる小角散乱 多(他)分野の小角散乱を学ぼう!」
    • Related Report
      2018 Research-status Report
  • [Presentation] リオトロピック液晶共連続逆キュービック相の小角 X 線単結晶構造解析2018

    • Author(s)
      岡俊彦
    • Organizer
      第8回ソフトマター研究会
    • Related Report
      2018 Research-status Report

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Published: 2018-04-23   Modified: 2022-01-27  

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