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Creation of New-Generation Nanocarbons Using Plasma CVD

Research Project

Project/Area Number 18K03598
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Review Section Basic Section 14030:Applied plasma science-related
Research InstitutionTohoku University

Principal Investigator

Hatakeyama Rikizo  東北大学, 未来科学技術共同研究センター, 名誉教授 (00108474)

Co-Investigator(Kenkyū-buntansha) 權 垠相  東北大学, 理学研究科, 准教授 (10360538)
美齊津 文典  東北大学, 理学研究科, 教授 (20219611)
Project Period (FY) 2018-04-01 – 2021-03-31
Project Status Completed (Fiscal Year 2020)
Budget Amount *help
¥4,290,000 (Direct Cost: ¥3,300,000、Indirect Cost: ¥990,000)
Fiscal Year 2020: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2019: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2018: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
Keywordsクローン・プラズマCVD / ナノカーボンハイブリッド / カーボンナノチューブ / グラフェン / 原子内包フラーレン / 原子内包フラーレンン
Outline of Final Research Achievements

The perfectly structure-controlled growth of single-walled carbon nanotubes (SWNTs) has been a long-standing challenge in the field concerned, where the concept of cloning without using metal catalysts is expected to be a key method for its realization. Here the experiment using shortly-segmented SWNTs as a molecular seed for the first time clarifies that plasma-enhanced chemical vapour deposition (PECVD) is much more effective compared with thermal chemical vapour deposition (TCVD) in the cloning growth. Then according to another experiment using carbon nanorings (CNRs), which can be viewed as sidewall segments of SWNTs without caps, the growth into SWNTs turns out to occur only in the case of PECVD.
Furthermore, it is found that a hybrid material consisting of cloned SWNTs and graphene, which yields a fundamental unit of spatial disposition in the three-dimensional integration, can be created by controlling PECVD-parameters.

Academic Significance and Societal Importance of the Research Achievements

0次元から3次元に亘るナノスケールの各種炭素同素体(ナノカーボン)は各々に優れた諸特性を有するが、これらの混成シナジー特性を活用すべく階層システムの構築が期待されている。ここで第一に重要となるのが、その発見当初からの永続的課題である1次元のSWNTの精密構造制御成長法の確立であるので、原型小分子として短片化SWNT及びCNRを用いてTCVDとPECVD法による比較研究を先ず行った。その結果、SWNTのクローン成長へのPECVDの圧倒的優位性を発見し、さらに発展的に1次元SWNT/2次元グラフェンのハイブリッド形成による3次元集積化の実現性を見出したことは、学術的・産業応用上大きな意義がある。

Report

(4 results)
  • 2020 Annual Research Report   Final Research Report ( PDF )
  • 2019 Research-status Report
  • 2018 Research-status Report
  • Research Products

    (38 results)

All 2021 2020 2019 2018

All Journal Article (20 results) (of which Int'l Joint Research: 5 results,  Peer Reviewed: 20 results,  Open Access: 5 results) Presentation (18 results) (of which Int'l Joint Research: 9 results,  Invited: 8 results)

  • [Journal Article] Synthesis of Stoichiometric SrTiO3 and Its Carrier Doping from Air-Stable Bimetallic Complexes2021

    • Author(s)
      Oyeka Ebube E.、Oka Daichi、Kwon Eunsang、Fukumura Tomoteru
    • Journal Title

      Inorganic Chemistry

      Volume: 60 Issue: 3 Pages: 1277-1283

    • DOI

      10.1021/acs.inorgchem.0c03457

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Structure Assignment and Separation of Isomers of Palladium Oxide Cluster Anions Studied by Ion Mobility Mass Spectrometry2020

    • Author(s)
      M. Abdul Latif, Toshiaki Nagata, Motoyoshi Nakano, Keijiro Ohshimo, Fuminori Misaizu
    • Journal Title

      The Journal of Physical Chemistry C

      Volume: - Issue: 17 Pages: 9604-9610

    • DOI

      10.1021/acs.jpcc.0c01847

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Sequential Growth of Iridium Cluster Anions Based on Simple Cubic Packing2020

    • Author(s)
      K. Koyasu, R. Tomihara, T. Nagata, J. W. J. Wu, M. Nakano, K. Ohshimo, F. Misaizu and T. Tsukuda
    • Journal Title

      Phys. Chem. Chem. Phys.

      Volume: 22 Issue: 32 Pages: 17842-17846

    • DOI

      10.1039/d0cp03122d

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Conformation of K+(Crown Ether) Complexes Revealed by Ion Mobility-Mass Spectrometry and Ultraviolet Spectroscopy2020

    • Author(s)
      Tainaka Sota、Ujihira Tomoyuki、Kubo Mayuko、Kida Motoki、Shimoyama Daisuke、Muramatsu Satoru、Abe Manabu、Haino Takeharu、Ebata Takayuki、Misaizu Fuminori、Ohshimo Keijiro、Inokuchi Yoshiya
    • Journal Title

      The Journal of Physical Chemistry A

      Volume: 124 Issue: 48 Pages: 9980-9990

    • DOI

      10.1021/acs.jpca.0c09068

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Surface Analyses of Amorphous Aluminum Oxides with AlO6 Clusters2020

    • Author(s)
      M. Fukuhara, T. Kuroda, F. Hasegawa, T. Hashida, H. Yagyu, K. Konno, M.Nishijima, E. Kwon
    • Journal Title

      MRS Commun.

      Volume: 10 Issue: 4 Pages: 674-679

    • DOI

      10.1557/mrc.2020.82

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Self-Assembly of Photoresponsive Azo-Containing Phospholipids with A Polar Group As The Tail2020

    • Author(s)
      S. Ma, S. Kurihara, Y. Tomimori, S. Kim, E. Kwon, A. Muramatsud, K. Kanie
    • Journal Title

      RSC Adv.

      Volume: 10 Issue: 54 Pages: 32984-32991

    • DOI

      10.1039/d0ra06803a

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Time-of-Flight Mass Spectrometric Diagnostics for Ionized and Neutral Species in High Power Pulsed Magnetron Sputtering of Titanium2020

    • Author(s)
      K. Tsukamoto, T. Tamura, H. Matsusaki, M. Tona, H. Yamamoto, Y. Nakagomi, H. Nishida, Y. Hirai, N. Nishimiya, M. Sanekata, K. Ohshimo, K. Koyasu, F. Misaizu
    • Journal Title

      Jpn. J. Appl. Phys.

      Volume: 59 Issue: SH Pages: SHHB05-SHHB05

    • DOI

      10.35848/1347-4065/ab71de

    • Related Report
      2019 Research-status Report
    • Peer Reviewed
  • [Journal Article] Geometrical Structures of Gas Phase Cerium Oxide Cluster Cations Studied by Ion Mobility Mass Spectrometry2019

    • Author(s)
      T. Nagata, J. W. J. Wu, M. Nakano, K. Ohshimo, F. Misaizu
    • Journal Title

      J. Phys. Chem. C

      Volume: 123 Issue: 27 Pages: 16641-16650

    • DOI

      10.1021/acs.jpcc.9b01378

    • Related Report
      2019 Research-status Report
    • Peer Reviewed
  • [Journal Article] Structures of Stable Oxide Cluster Ions of First-Row Late Transition Metals: An Ion Mobility-Mass Spectrometric Study2019

    • Author(s)
      F. Misaizu, M. A. Latif, J. W. J. Wu, R. Moriyama, M. Nakano, K. Koyasu, K. Ohshimo
    • Journal Title

      AIP Conf. Proc.

      Volume: 2186 Pages: 030017-030017

    • DOI

      10.1063/1.5137928

    • Related Report
      2019 Research-status Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Structural Evolution of Iridium Oxide Cluster Anions IrnOm- (n = 5-8) with Sequential Oxidation: Binding Mode of O Atoms and Ir Framework2019

    • Author(s)
      R. Tomihara, K. Koyasu, T. Nagata, J. W. J. Wu, M. Nakano, K. Ohshimo, F. Misaizu, T. Tsukuda
    • Journal Title

      J. Phys. Chem. C

      Volume: 123 Issue: 24 Pages: 15301-15306

    • DOI

      10.1021/acs.jpcc.9b02935

    • Related Report
      2019 Research-status Report
    • Peer Reviewed
  • [Journal Article] Thermodynamic Properties and Molecular Dynamics of [Li + @C 60 ](PF 6 -) Associated with Structural Phase Transitions2019

    • Author(s)
      H. Suzuki, M. Ishida, C. Otani, K. Kawachi, Y. Kasama, K. Eunsang, Y. Miyazaki, M. Nakano
    • Journal Title

      Phys. Chem. Chem. Phys.

      Volume: 21 Issue: 29 Pages: 16147-16153

    • DOI

      10.1039/c9cp02849h

    • Related Report
      2019 Research-status Report
    • Peer Reviewed
  • [Journal Article] Formation of Five-Membered Carbocycles from d-Glucose: A Concise Synthesis of 4-Hydroxy-2-(hydroxymethyl)cyclopentenone2019

    • Author(s)
      Y. Koseki, T. Watanabe, T. Kamishima, E. Kwon, H. Kasai
    • Journal Title

      Bull. Chem. Soc. Jpn.

      Volume: 92 Issue: 8 Pages: 1324-1328

    • DOI

      10.1246/bcsj.20190063

    • NAID

      130007689998

    • Related Report
      2019 Research-status Report
    • Peer Reviewed
  • [Journal Article] Visible Photodissociation of the CO2 Dimer Cation: Fast and Slow Dissociation Dynamics in the Excited State2019

    • Author(s)
      Y. Nakashima, K. Okutsu, K. Fujimoto, Y. Ito, M. Kanno, M. Nakano, K. Ohshimo, H. Kono, F. Misaizu
    • Journal Title

      Phys. Chem. Chem. Phys.

      Volume: 21 Issue: 6 Pages: 3083-3091

    • DOI

      10.1039/c8cp07068g

    • Related Report
      2018 Research-status Report
    • Peer Reviewed / Open Access
  • [Journal Article] Dielectric Relaxation of Powdered Molecular Gyrotops Having a Thiophene Dioxide-diyl as a Dipolar Rotor2018

    • Author(s)
      M. Tsurunaga, Y. Inagaki, H. Momma, E. Kwon, K. Yamaguchi, K. Yoza, W. Setaka
    • Journal Title

      Org. Lett.

      Volume: 20 Issue: 21 Pages: 6934-6937

    • DOI

      10.1021/acs.orglett.8b03087

    • Related Report
      2019 Research-status Report 2018 Research-status Report
    • Peer Reviewed
  • [Journal Article] Extensive first-principles molecular dynamics study on Li encapsulation into C60 and its experimental confirmation2018

    • Author(s)
      Ohno K.、Manjanath A.、Kawazoe Y.、Hatakeyama R.、Misaizu F.、Kwon E.、Fukumura H.、Ogasawara H.、Yamada Y.、Zhang C.、Sumi N.、Kamigaki T.、Kawachi K.、Yokoo K.、Ono S.、Kasama Y.
    • Journal Title

      Nanoscale

      Volume: 10 Issue: 4 Pages: 1825-1836

    • DOI

      10.1039/c7nr07237f

    • Related Report
      2018 Research-status Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Stable Compositions and Structures of Copper Oxide Cluster Cations CunOm+ (n = 2-8) Studied by Ion Mobility Mass Spectrometry2018

    • Author(s)
      M. A. Latif, J. W. J. Wu, R. Moriyama, M. Nakano, K. Ohshimo, F. Misaizu
    • Journal Title

      ACS Omega

      Volume: 3 Issue: 12 Pages: 18705-18713

    • DOI

      10.1021/acsomega.8b02466

    • Related Report
      2018 Research-status Report
    • Peer Reviewed / Open Access
  • [Journal Article] Ion Imaging of MgI+ Photofragment in Ultraviolet Photodissociation Mass-selected Mg+ICH3 Complex2018

    • Author(s)
      K. Okutsu, K. Yamazaki, M. Nakano, K. Ohshimo, F. Misaizu
    • Journal Title

      J. Phys. Chem. A

      Volume: 122 Issue: 22 Pages: 4948-4953

    • DOI

      10.1021/acs.jpca.8b01944

    • Related Report
      2018 Research-status Report
    • Peer Reviewed
  • [Journal Article] Small Carbon Nano-Onions: An Ion Mobility Mass Spectrometric Study2018

    • Author(s)
      Moriyama Ryoichi、Wu Jenna W. J.、Nakano Motoyoshi、Ohshimo Keijiro、Misaizu Fuminori
    • Journal Title

      The Journal of Physical Chemistry C

      Volume: 122 Issue: 9 Pages: 5195-5200

    • DOI

      10.1021/acs.jpcc.8b00597

    • Related Report
      2018 Research-status Report
    • Peer Reviewed
  • [Journal Article] Electronic structure of Li + @C 60 : Photoelectron spectroscopy of the Li + @C 60 [PF 6 ? ] salt and STM of the single Li + @C 60 molecules on Cu(111)2018

    • Author(s)
      Yamada Yoichi、Kuklin Artem V.、Sato Sho、Esaka Fumitaka、Sumi Naoto、Zhang Chunyang、Sasaki Masahiro、Kwon Eunsung、Kasama Yukihiko、Avramov Pavel V.、Sakai Seiji
    • Journal Title

      Carbon

      Volume: 133 Pages: 23-30

    • DOI

      10.1016/j.carbon.2018.02.106

    • Related Report
      2018 Research-status Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Amorphous Aluminum-Oxide Supercapacitors2018

    • Author(s)
      M. Fukuhara, T. Kuroda, F. Hasegawa, T. Hashida, E. Kwon, K. Konno
    • Journal Title

      Europhys. Lett.

      Volume: 123

    • Related Report
      2018 Research-status Report
    • Peer Reviewed / Open Access
  • [Presentation] リフレクトロン型飛行時間質量分析計を用いたDeep Oscillation Magnetron Sputtering(DOMS)のイオン組成分析2021

    • Author(s)
      中込 雄基, 西田 寛, 西宮 信夫, 實方 真臣, 山本 宏晃, 平田 直之, 戸名 正英, 塚本 恵三,冨宅 喜代一, 大下 慶次郎, 美齊津 文典
    • Organizer
      第68回応用物理学会春季学術講演会
    • Related Report
      2020 Annual Research Report
  • [Presentation] 高出力パルスマグネトロンスパッタリングにおけるリフレクトロン型飛行時間質量分析計を用いたプラズマ診断法の開発2020

    • Author(s)
      實方 真臣, 中込 雄基, 平山 睦大, 渡部 達也, 西田 寛, 西宮 信夫, 戸名 正英, 平田 直之, 山本 宏晃, 塚本 恵三, 大下 慶次郎, 美齊津 文典
    • Organizer
      第68回質量分析総合討論会2020
    • Related Report
      2020 Annual Research Report
  • [Presentation] イオン移動度質量分析法による酸化イットリウムクラスター正イオンの幾何構造および化学反応の研究2020

    • Author(s)
      三竿 洋太朗, 中野 元善, 永田 利明, 美齊津 文典
    • Organizer
      分子科学会オンライン討論会
    • Related Report
      2020 Annual Research Report
  • [Presentation] Crystal Structure and Application of Lithium-Cation Endohedral [C60] Fullerene2020

    • Author(s)
      E. Kwon, T. Matsukawa, A. Hoshikawa, T. Ishigaki, R. Hatakeyama, K. Kawachi, Y. Kasama
    • Organizer
      Asian Consortium on Computational Materials Science (ACCMS) 2020
    • Related Report
      2019 Research-status Report
    • Int'l Joint Research / Invited
  • [Presentation] リフレクトロン型飛行時間質量分析計を用いた変調パルス電力マグネトロンスパッ タリングの成分分析法の開発2020

    • Author(s)
      中込 雄基,平山 睦大,渡部 達也,兼行 亮輔,西宮 信夫,實方 真臣,山本 宏晃,戸名 正英,塚本 恵三,大下 慶次郎,美齊津 文典
    • Organizer
      第67回応物春季学術講演会
    • Related Report
      2019 Research-status Report
  • [Presentation] 銅および銀クラスター正イオンへの酸素分子吸着反応の研究2020

    • Author(s)
      伊藤 亮佑,門口 真之,平田 直之,山本 宏晃,戸名 正英,塚本 恵三,大下 慶次郎,美齊津 文典
    • Organizer
      日本化学会第100春季年会
    • Related Report
      2019 Research-status Report
  • [Presentation] Structure and Applications of Lithium-Cation Endohedral [C60] Fullerene.2019

    • Author(s)
      E. Kwon, T. Matsukawa, A. Hoshikawa, T. Ishigaki, R. Hatakeyama, K. Kawachi, Y. Kasama
    • Organizer
      Collaborative Conference on Materials Research (CCMR) 2019
    • Related Report
      2019 Research-status Report
    • Int'l Joint Research / Invited
  • [Presentation] Crystal Structure and Energy Storage Characteristics of Lithium-Cation Endohedral [C60] Fullerene2019

    • Author(s)
      E. Kwon, T. Matsukawa, A. Hoshikawa, T. Ishigaki, R. Hatakeyama, K. Kawachi, Y. Kasama
    • Organizer
      International Congress on Pure & Applied Chemistry (ICPAC) Yangon 2019
    • Related Report
      2019 Research-status Report
    • Int'l Joint Research / Invited
  • [Presentation] エレクトロスプレーイオン化質量分析を用いたLi+イオン内包フラーレン(Li+@C60) の酸化反応機構の研究2019

    • Author(s)
      大下 慶次郎,長谷川 皓平,上野 裕,美齊津 文典
    • Organizer
      第13回分子科学討論会
    • Related Report
      2019 Research-status Report
  • [Presentation] ナノアーキテクチャア視座プラズマ材料科学の基礎2018

    • Author(s)
      畠山力三
    • Organizer
      (独)日本学術振興会プラズマ材料科学第153委員会 プラズマ材料科学基礎講座(第13回)
    • Related Report
      2018 Research-status Report
    • Invited
  • [Presentation] An Implantable Photovoltaic Device using Single-Walled Carbon Nanotubes and Performance Evaluation in vivo2018

    • Author(s)
      O. Murakami, K. Minemura, T. Hirata, R. Hatakeyama, M. Kyoso
    • Organizer
      40th Annual International Conference of the IEEE Engineering in Medicine and Biology Society
    • Related Report
      2018 Research-status Report
    • Int'l Joint Research
  • [Presentation] 次世代車載エネルギーデバイス用ナノカーボンハイブリッドの創製2018

    • Author(s)
      畠山力三
    • Organizer
      先進ロジスティクス交通システム研究プロジェクト報告会(第1回、東北大学未来科学技術共同研究センター)
    • Related Report
      2018 Research-status Report
  • [Presentation] 構成原子数200-800の領域における炭素ナノオニオン(二層フラーレン)の観測2018

    • Author(s)
      中野元善, 森山遼一, Jenna W. J. Wu, 大下慶次郎, 美齊津文典
    • Organizer
      第7回イオン移動度研究会
    • Related Report
      2018 Research-status Report
    • Invited
  • [Presentation] Geometrical Structures and Reactions of Cerium Oxide Cluster Cations Studied by Ion Mobility Mass Spectrometry2018

    • Author(s)
      T. Nagata, J. W. J. Wu, M. Nakano, K. Ohshimo, F. Misaizu
    • Organizer
      International Bunsen Discussion Meeting on Gas-Phase Model Systems for Catalysis - GPMC2018 (Hot Topic Presentation)
    • Related Report
      2018 Research-status Report
    • Int'l Joint Research
  • [Presentation] Bilayer Fullerenes Studied by Ion Mobility Mass Spectrometry2018

    • Author(s)
      M. Nakano, R. Moriyama, J. W. J. Wu, K. Ohshimo, F. Misaizu
    • Organizer
      19th International Symposium on Small Particles and Inorganic Clusters (Hot Topic Presentation)
    • Related Report
      2018 Research-status Report
    • Int'l Joint Research
  • [Presentation] Structure and Energy Storage Properties of Lithium-Cation Endohedral [C60] Fullerene2018

    • Author(s)
      E. Kwon, T. Matsukawa, A. Hoshikawa, T. Ishigaki, T. Kamigaki, K. Kawachi, Y. Kasama
    • Organizer
      Collaborative Conference on Materials Research (CCMR) 2018
    • Related Report
      2018 Research-status Report
    • Int'l Joint Research / Invited
  • [Presentation] Research Program of Atom Endohedral Fullerenes in Tohoku University Japan: Introduction and Research Activities2018

    • Author(s)
      E. Kwon, F. Misaizu, T. Kaneko, Y. Iwabuchi, Y. Kasama, K. Kawachi, T. Kamigaki
    • Organizer
      19th International Symposium on Small Particles and Inorganic Clusters (ISSPIC-XIX)
    • Related Report
      2018 Research-status Report
    • Int'l Joint Research / Invited
  • [Presentation] Structure and Properties of Lithium-Cation Endohedral [C60] Metallofullerene2018

    • Author(s)
      E. Kwon, T. Matsukawa, A. Hoshikawa, T. Ishigaki, T. Kamigaki, K. Kawachi, Y. Kasama
    • Organizer
      International Congress on Pure & Applied Chemistry Langkawi (ICPAC Langkawi) 2018
    • Related Report
      2018 Research-status Report
    • Int'l Joint Research / Invited

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Published: 2018-04-23   Modified: 2022-01-27  

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