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Experimental investigation on H-atom diffusion within ice mantles

Research Project

Project/Area Number 18K03717
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Review Section Basic Section 17010:Space and planetary sciences-related
Research InstitutionHokkaido University

Principal Investigator

Tsuge Masashi  北海道大学, 低温科学研究所, 特任助教 (60454211)

Project Period (FY) 2018-04-01 – 2021-03-31
Project Status Completed (Fiscal Year 2020)
Budget Amount *help
¥4,290,000 (Direct Cost: ¥3,300,000、Indirect Cost: ¥990,000)
Fiscal Year 2020: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2019: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2018: ¥1,820,000 (Direct Cost: ¥1,400,000、Indirect Cost: ¥420,000)
Keywords水素原子拡散 / 分子進化 / 氷星間塵 / 星間分子雲 / 星間塵
Outline of Final Research Achievements

In the chemical evolution processes occurring within low temperature molecular clouds, it has been demonstrated that chemical reactions on icy grain surface play significant roles. However, chemical processes within ice mantle, which do not require photons and cosmic rays, have not been investigated. In this work, we aimed at revealing whether hydrogen atoms can penetrate into ice mantles or not.
We found that hydrogen atoms penetrate into amorphous solid water and react with embedded atoms or molecules. The most important finding of this work is that hydrogen reactions occur above 20 K, where efficiency of surface hydrogen reactions is extremely low.

Academic Significance and Societal Importance of the Research Achievements

標準的な分子進化モデルにおいては、氷表面と氷内部が異なる相として取り扱われており、水素原子による反応は極低温(<20 K)の表面でのみ起きるとされてきた。しかしながら、本研究で見出した全く新しい反応プロセス「氷内部への水素原子侵入・拡散・反応」は、比較的高い温度(~70 K)でも有効であるとともに、氷表面に吸着する原子種が氷内部における分子生成に影響を与えることを示す。新しい反応プロセスは「光や宇宙線を必要としない氷内部の分子進化プロセス」と言い換えることができ、既存の極低温分子雲における分子進化モデルに大きな変更を要請するという学術的意義を持つ。

Report

(4 results)
  • 2020 Annual Research Report   Final Research Report ( PDF )
  • 2019 Research-status Report
  • 2018 Research-status Report
  • Research Products

    (17 results)

All 2021 2020 2019 2018

All Journal Article (15 results) (of which Int'l Joint Research: 9 results,  Peer Reviewed: 15 results,  Open Access: 1 results) Presentation (1 results) (of which Int'l Joint Research: 1 results) Book (1 results)

  • [Journal Article] Behavior of Hydroxyl Radicals on Water Ice at Low Temperatures2021

    • Author(s)
      Tsuge Masashi、Watanabe Naoki
    • Journal Title

      Accounts of Chemical Research

      Volume: 54 Issue: 3 Pages: 471-480

    • DOI

      10.1021/acs.accounts.0c00634

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Rapid Ortho-to-para Nuclear Spin Conversion of H2 on a Silicate Dust Surface2021

    • Author(s)
      Tsuge M., Namiyoshi T., Furuya K., Yamazaki T., Kouchi A., Watanabe N.
    • Journal Title

      The Astrophysical Journal

      Volume: 908 Issue: 2 Pages: 234-234

    • DOI

      10.3847/1538-4357/abd9c0

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Infrared Spectra of Monohydrogenated Aniline, ortho- and para-HC6H5NH2, Generated in Solid para-Hydrogen2020

    • Author(s)
      Tsuge Masashi、Chen Yu-Hsuan、Lee Yuan-Pern
    • Journal Title

      The Journal of Physical Chemistry A

      Volume: 124 Issue: 37 Pages: 7500-7510

    • DOI

      10.1021/acs.jpca.0c06079

    • NAID

      120007147238

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Infrared spectroscopy of H+(CO)2 in the gas phase and in para-hydrogen matrices2020

    • Author(s)
      Leicht Daniel、Rittgers Brandon M.、Douberly Gary E.、Wagner J. Philipp、McDonald David C.、Mauney Daniel T.、Tsuge Masashi、Lee Yuan-Pern、Duncan Michael A.
    • Journal Title

      The Journal of Chemical Physics

      Volume: 153 Issue: 8 Pages: 084305-084305

    • DOI

      10.1063/5.0019731

    • NAID

      120007140369

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] UV-ray irradiation never causes amorphization of crystalline CO2: A transmission electron microscopy study2020

    • Author(s)
      Tsuge M., Nguyen T., Oba Y., Hama T., Kouchi A., Watanabe N.
    • Journal Title

      Chemical Physics Letters

      Volume: 760 Pages: 137999-137999

    • DOI

      10.1016/j.cplett.2020.137999

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Diffusive hydrogenation reactions of CO embedded in amorphous solid water at elevated temperatures ~70K2020

    • Author(s)
      Tsuge M., Hidaka H., Kouchi A., Watanabe N.
    • Journal Title

      The Astrophysical Journal

      Volume: 900 Issue: 2 Pages: 187-187

    • DOI

      10.3847/1538-4357/abab9b

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Experimental Approach to Physicochemical Hydrogen Processes on Cosmic Ice Dust2020

    • Author(s)
      Watanabe Naoki、Tsuge Masashi
    • Journal Title

      Journal of the Physical Society of Japan

      Volume: 89 Issue: 5 Pages: 051015-051015

    • DOI

      10.7566/jpsj.89.051015

    • Related Report
      2019 Research-status Report
    • Peer Reviewed
  • [Journal Article] Infrared Spectra of Isomers of Protonated Aniline in Solid para-Hydrogen2020

    • Author(s)
      Tsuge Masashi、Chen Yu-Hsuan、Lee Yuan-Pern
    • Journal Title

      The Journal of Physical Chemistry A

      Volume: 124 Issue: 11 Pages: 2253-2263

    • DOI

      10.1021/acs.jpca.0c00241

    • NAID

      120006980027

    • Related Report
      2019 Research-status Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Thermal decomposition of the HXeCl・・・H2O complex in solid xenon: Experimental characterization of the two-body decomposition channel2020

    • Author(s)
      Tsuge Masashi、Rasanen Markku、Khriachtchev Leonid
    • Journal Title

      Chemical Physics Letters

      Volume: 739 Pages: 136987-136987

    • DOI

      10.1016/j.cplett.2019.136987

    • Related Report
      2019 Research-status Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Infrared spectrum of hydrogenated corannulene rim-HC20H10 isolated in solid para-hydrogen2019

    • Author(s)
      Sundararajan Pavithraa、Tsuge Masashi、Baba Masaaki、Sakurai Hidehiro、Lee Yuan-Pern
    • Journal Title

      The Journal of Chemical Physics

      Volume: 151 Issue: 4 Pages: 044304-044304

    • DOI

      10.1063/1.5111169

    • NAID

      120006709314

    • Related Report
      2019 Research-status Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Interactions of Atomic and Molecular Hydrogen with a Diamond-like Carbon Surface: H2 Formation and Desorption2019

    • Author(s)
      Tsuge Masashi、Hama Tetsuya、Kimura Yuki、Kouchi Akira、Watanabe Naoki
    • Journal Title

      The Astrophysical Journal

      Volume: 878 Issue: 1 Pages: 23-23

    • DOI

      10.3847/1538-4357/ab1e4e

    • NAID

      120006849862

    • Related Report
      2019 Research-status Report
    • Peer Reviewed
  • [Journal Article] Electronic and vibrational structure in the S0 and S1 states of corannulene2019

    • Author(s)
      Kanaoka Ayumi、Tohyama Hiromi、Kunishige Sachi、Katori Toshiharu、Nishiyama Akiko、Misono Masatoshi、Nakayama Naofumi、Sakurai Hidehiro、Tsuge Masashi、Baba Masaaki
    • Journal Title

      The Journal of Chemical Physics

      Volume: 151 Issue: 23 Pages: 234305-234305

    • DOI

      10.1063/1.5129852

    • Related Report
      2019 Research-status Report
    • Peer Reviewed
  • [Journal Article] Infrared spectra of 3-hydroxy-(1H)-pyridinium cation and 3-hydroxy-(1H)-pyridinyl radical isolated in solid para-hydrogen2018

    • Author(s)
      Tsuge Masashi、Lai Chia-Peng、Lee Yuan-Pern
    • Journal Title

      The Journal of Chemical Physics

      Volume: 149 Issue: 1 Pages: 014306-014306

    • DOI

      10.1063/1.5038363

    • NAID

      120006501201

    • Related Report
      2018 Research-status Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Infrared Spectrum of Protonated Corannulene H+C20H10 in Solid para-Hydrogen and its Potential Contribution to Interstellar Unidentified Infrared Bands2018

    • Author(s)
      Sundararajan Pavithraa、Tsuge Masashi、Baba Masaaki、Lee Yuan-Pern
    • Journal Title

      ACS Earth and Space Chemistry

      Volume: 2 Issue: 10 Pages: 1001-1010

    • DOI

      10.1021/acsearthspacechem.8b00089

    • Related Report
      2018 Research-status Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Activation of Molecular Hydrogen by Arylcarbenes2018

    • Author(s)
      Mendez‐Vega Enrique、Maehara Mika、Raut Akshay Hemant、Mieres‐Perez Joel、Tsuge Masashi、Lee Yuan‐Pern、Sander Wolfram
    • Journal Title

      Chemistry A European Journal

      Volume: 24 Issue: 70 Pages: 18801-18808

    • DOI

      10.1002/chem.201804657

    • Related Report
      2018 Research-status Report
    • Peer Reviewed / Int'l Joint Research
  • [Presentation] H2 formation on a low-temperature diamondlike carbon surface2019

    • Author(s)
      Tsuge Masashi、Hama Tetsuya、Kimura Yuki、Kouchi Akira、Watanabe Naoki
    • Organizer
      35th Symposium on Chemical Kinetics and Dynamics
    • Related Report
      2019 Research-status Report
    • Int'l Joint Research
  • [Book] Chapter 5 "Spectroscopy of molecules confined in solid para-hydrogen" in book "Molecular and Laser Spectroscopy".2020

    • Author(s)
      Tsuge Masashi、Lee Yuan-Pern
    • Publisher
      Elsevier Science Publishing Co Inc
    • ISBN
      0128188707
    • Related Report
      2019 Research-status Report

URL: 

Published: 2018-04-23   Modified: 2022-01-27  

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