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New mechanism of degrading crystallinity

Research Project

Project/Area Number 18K03782
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Review Section Basic Section 17040:Solid earth sciences-related
Research InstitutionYamaguchi University

Principal Investigator

Nagashima Mariko  山口大学, 大学院創成科学研究科, 教授 (80580274)

Project Period (FY) 2018-04-01 – 2022-03-31
Project Status Completed (Fiscal Year 2021)
Budget Amount *help
¥4,290,000 (Direct Cost: ¥3,300,000、Indirect Cost: ¥990,000)
Fiscal Year 2021: ¥780,000 (Direct Cost: ¥600,000、Indirect Cost: ¥180,000)
Fiscal Year 2020: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2019: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2018: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000)
Keywords結晶質 / 非晶質 / メタミクト / ラマン分光 / クリノゾイサイト / 偏光ラマン / 結晶性 / 原子配列 / 岩石・鉱物・鉱床学
Outline of Final Research Achievements

Severe structural damage which is not attributed to self-radiation due to radioactive elements was observed in natural Cr+V-bearing clinozoisite. To investigate this phenomenon polarized Raman spectroscopy was applied in this study. This phenomenon is understood as "the fragmentation of the crystalline matter preserving the original atomic arrangement into crystalline nano regions with the non-crystalline boundary". The cause of this phenomenon is that the orientational disorder of the OH group is strongly promoted when the M3 octahedron is partially occupied by V(+Cr), and as a result, the linkages between the structural units are disturbed, leading to the periodicity fault and size reduction of coherent structural domains.

Academic Significance and Societal Importance of the Research Achievements

天然鉱物では含まれる放射性元素の壊変に起因する非晶質化がよく知られており,結晶質固体物質における結晶性の変化は物質の特性を大きく左右する重要な現象である。私は2011年に天然鉱物から放射性元素に起因しない未知の結晶性低下現象を見出したが,当時はそのメカニズムは未解明であった。しかし本研究により,現象の実態を正確に把握することに成功し,さらにその原因や発生メカニズムを提唱するに至った。今後,さらなる検証を要するが,本現象は結晶質物質に普遍的に起こり得るため,本研究成果は天然・合成問わず結晶質物質を扱う分野全体に波及すると考えられる。

Report

(5 results)
  • 2021 Annual Research Report   Final Research Report ( PDF )
  • 2020 Research-status Report
  • 2019 Research-status Report
  • 2018 Research-status Report
  • Research Products

    (30 results)

All 2022 2021 2020 2019 2018 Other

All Int'l Joint Research (8 results) Journal Article (15 results) (of which Int'l Joint Research: 6 results,  Peer Reviewed: 15 results,  Open Access: 10 results) Presentation (7 results) (of which Int'l Joint Research: 1 results,  Invited: 1 results)

  • [Int'l Joint Research] ハンブルク大学(ドイツ)

    • Related Report
      2021 Annual Research Report
  • [Int'l Joint Research] ベルン大学(スイス)

    • Related Report
      2021 Annual Research Report
  • [Int'l Joint Research] University of Bern(スイス)

    • Related Report
      2020 Research-status Report
  • [Int'l Joint Research] University of Hamburg(ドイツ)

    • Related Report
      2020 Research-status Report
  • [Int'l Joint Research] University of Bern(スイス)

    • Related Report
      2019 Research-status Report
  • [Int'l Joint Research] University of Hamburg(ドイツ)

    • Related Report
      2019 Research-status Report
  • [Int'l Joint Research] University of Bern(スイス)

    • Related Report
      2018 Research-status Report
  • [Int'l Joint Research] University of Hamburg(ドイツ)

    • Related Report
      2018 Research-status Report
  • [Journal Article] The Role of Scandium Substitution in Babingtonite Group Minerals2022

    • Author(s)
      Nagashima M., Nishio-Hamane, D., Matsumoto, T., Fukuda, C.
    • Journal Title

      Minerals

      Volume: 12 Issue: 3 Pages: 333-333

    • DOI

      10.3390/min12030333

    • Related Report
      2021 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Dalyite (K<sub>2</sub>ZrSi<sub>6</sub>O<sub>15</sub>) and Zektzerite (LiNaZrSi<sub>6</sub>O<sub>15</sub>) in Aegirine-bearing Albitite from Iwagi Islet, SW Japan2021

    • Author(s)
      Imaoka, T., Akita, S., Nagashima, M.
    • Journal Title

      Journal of Geography (Chigaku Zasshi)

      Volume: 130 Issue: 3 Pages: 369-378

    • DOI

      10.5026/jgeography.130.369

    • NAID

      130008066577

    • ISSN
      0022-135X, 1884-0884
    • Year and Date
      2021-06-25
    • Related Report
      2021 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] On the nature of Pb species in Pb-exchanged zeolite stellerite (STI): A combined experimental and theoretical study2021

    • Author(s)
      Roos, D.P., Scheinost, A.C., Churakov, S.V., Nagashima, M., Cametti,G.
    • Journal Title

      Microporous and Mesoporous Materials

      Volume: 327 Pages: 111444-111444

    • DOI

      10.1016/j.micromeso.2021.111444

    • Related Report
      2021 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Ferriprehnite, Ca<sub>2</sub>Fe<sup>3+</sup>(AlSi<sub>3</sub>)O<sub>10</sub>(OH)<sub>2</sub>, an Fe<sup>3+</sup> analogue of prehnite, from Kouragahana, Shimane Peninsula, Japan2021

    • Author(s)
      Nagashima, M.,Nishio-Hamane, D., Ito, S., Tanaka, T.
    • Journal Title

      Journal of Mineralogical and Petrological Sciences

      Volume: 116 Issue: 3 Pages: 129-139

    • DOI

      10.2465/jmps.210127

    • NAID

      130008065778

    • ISSN
      1345-6296, 1349-3825
    • Related Report
      2021 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Ore and skarn mineralogy of the Eboshi deposit of the Naganobori copper mine, Yamaguchi, Japan2021

    • Author(s)
      NAGASHIMA Mariko、MORISHITA Yukina、IMOTO Yuji、IMAOKA Teruyoshi
    • Journal Title

      Journal of Mineralogical and Petrological Sciences

      Volume: 116 Issue: 1 Pages: 26-44

    • DOI

      10.2465/jmps.200818

    • NAID

      130007995434

    • ISSN
      1345-6296, 1349-3825
    • Related Report
      2020 Research-status Report
    • Peer Reviewed / Open Access
  • [Journal Article] The structural state of Finnish Cr- and V-bearing clinozoisite: insights from Raman spectroscopy2021

    • Author(s)
      Nagashima Mariko、Armbruster Thomas、Nishio-Hamane Daisuke、Mihailova Boriana
    • Journal Title

      Physics and Chemistry of Minerals

      Volume: 48 Issue: 1

    • DOI

      10.1007/s00269-020-01129-z

    • Related Report
      2020 Research-status Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Chemical and lithium isotope characteristics of murakamiite and Li–rich pectolite from Iwagi Islet, Southwest Japan2021

    • Author(s)
      IMAOKA Teruyoshi、KIMURA Jun-Ichi、CHANG Qing、ISHIKAWA Tsuyoshi、NAGASHIMA Mariko、TAKESHITA Natsuki
    • Journal Title

      Journal of Mineralogical and Petrological Sciences

      Volume: 116 Issue: 1 Pages: 9-25

    • DOI

      10.2465/jmps.200721

    • NAID

      130007995424

    • ISSN
      1345-6296, 1349-3825
    • Related Report
      2020 Research-status Report
    • Peer Reviewed / Open Access
  • [Journal Article] Crystal chemistry of Sr–rich piemontite from manganese ore deposit of the Tone mine, Nishisonogi Peninsula, Nagasaki, southwest Japan2020

    • Author(s)
      NAGASHIMA Mariko、SANO Yuko、KOCHI Takako、AKASAKA Masahide、SANO-FURUKAWA Asami
    • Journal Title

      Journal of Mineralogical and Petrological Sciences

      Volume: 115 Issue: 5 Pages: 391-406

    • DOI

      10.2465/jmps.191122

    • NAID

      130007935423

    • ISSN
      1345-6296, 1349-3825
    • Related Report
      2020 Research-status Report
    • Peer Reviewed / Open Access
  • [Journal Article] Multi-methodical study of the Ti, Fe2+ and Fe3+ distribution in chevkinite-subgroup minerals: X-ray diffraction, neutron diffraction, 57Fe Moessbauer spectroscopy and electron-microprobe analyses2020

    • Author(s)
      Nagashima Mariko、Armbruster Thomas、Akasaka Masahide、Sano-Furukawa Asami、Nishio-Hamane Daisuke、Malsy Anna、Imaoka Teruyoshi、Nakashima Kazuo
    • Journal Title

      Physics and Chemistry of Minerals

      Volume: 47 Issue: 6

    • DOI

      10.1007/s00269-020-01096-5

    • Related Report
      2020 Research-status Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Aluminosugilite, KNa2Al2Li3Si12O30, an Al-analogue of sugilite, from the Cerchiara mine, Liguria, Italy.2020

    • Author(s)
      Nagashima, M., Fukuda, C., Matsumoto, T., Imaoka, T., Odicino, G., and Armellino, G.
    • Journal Title

      European Journal of Mineralogy

      Volume: 32 Issue: 1 Pages: 57-66

    • DOI

      10.5194/ejm-32-57-2020

    • Related Report
      2019 Research-status Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Crystal chemistry and Raman spectroscopy of momoiite from Japan2019

    • Author(s)
      ENDO Shunsuke、NAGASHIMA Mariko、ENAMI Masaki
    • Journal Title

      Journal of Mineralogical and Petrological Sciences

      Volume: 114 Issue: 4 Pages: 161-169

    • DOI

      10.2465/jmps.190219

    • NAID

      130007719449

    • ISSN
      1345-6296, 1349-3825
    • Related Report
      2019 Research-status Report
    • Peer Reviewed / Open Access
  • [Journal Article] Distribution of Cr3+ between octahedral and tetrahedral sites in synthetic blue and green (CaMgSi2O6)95(CaCrAlSiO6)5-diopsides.2019

    • Author(s)
      Akasaka, M., Takasu, Y., Handa, M., Nagashima, M., Hamada, M., and Ejima, T
    • Journal Title

      Mineralogical Magazine

      Volume: 83 Issue: 4 Pages: 497-505

    • DOI

      10.1180/mgm.2019.1

    • Related Report
      2019 Research-status Report
    • Peer Reviewed
  • [Journal Article] Synthesis and crystal chemistry of mukhinite, V-analogue of clinozoisite on the join Ca2Al3Si3O12(OH)?Ca2Al2VSi3O12(OH)2018

    • Author(s)
      Nagashima Mariko、Nishio-Hamane Daisuke、Nakano Nobuhiko、Kawasaki Toshisuke
    • Journal Title

      Physics and Chemistry of Minerals

      Volume: 46 Issue: 1 Pages: 63-76

    • DOI

      10.1007/s00269-018-0988-4

    • Related Report
      2019 Research-status Report 2018 Research-status Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Crystal chemistry of poppiite, V–analogue of pumpellyite, from the Komatsu mine, Saitama Prefecture, Japan2018

    • Author(s)
      NAGASHIMA Mariko、MATSUMOTO Takashi、YAMADA Takashi、TAKIZAWA Minoru、MOMMA Koichi
    • Journal Title

      Journal of Mineralogical and Petrological Sciences

      Volume: 113 Issue: 5 Pages: 251-262

    • DOI

      10.2465/jmps.180613

    • NAID

      130007506107

    • ISSN
      1345-6296, 1349-3825
    • Related Report
      2018 Research-status Report
    • Peer Reviewed / Open Access
  • [Journal Article] Relationship between cation substitution and hydrogen-bond system in hydrous pyroxenoids with three-periodic single-chain of SiO4 tetrahedra: pectolite, murakamiite, marshallsussmanite, serandite and tanohataite.2018

    • Author(s)
      Nagashima, M., Imaoka, T., Fukuda, C. and Pettke, T.
    • Journal Title

      European Journal of Mineralogy

      Volume: in press Issue: 3 Pages: 451-463

    • DOI

      10.1127/ejm/2018/0030-2744

    • Related Report
      2018 Research-status Report
    • Peer Reviewed / Int'l Joint Research
  • [Presentation] 山口県長門市津黄安山岩に産する沸石類の産状2021

    • Author(s)
      永嶌真理子, 西岡美結
    • Organizer
      日本鉱物科学会
    • Related Report
      2021 Annual Research Report
  • [Presentation] 山口県美祢市長登銅山梅ヶ窪坑に産する鉱石鉱物とスカルン鉱物の鉱物学的特徴2021

    • Author(s)
      窪津優花, 永嶌真理子
    • Organizer
      日本鉱物科学会
    • Related Report
      2021 Annual Research Report
  • [Presentation] 島根半島古浦が鼻の熱水変質玄武岩中に産する二次鉱物とその生成プロセスについて2021

    • Author(s)
      伊藤修一, 永嶌真理子
    • Organizer
      日本鉱物科学会
    • Related Report
      2021 Annual Research Report
  • [Presentation] 山口県山口市一の坂銀山産鉱石の鉱物学的特徴2021

    • Author(s)
      岡谷実冶子, 永嶌真理子
    • Organizer
      日本鉱物科学会
    • Related Report
      2021 Annual Research Report
  • [Presentation] 山口県美祢市長登銅山烏帽子坑に産するコバルト鉱石2019

    • Author(s)
      永嶌真理子・井本裕二・森下幸菜
    • Organizer
      日本鉱物科学会2019年年会
    • Related Report
      2019 Research-status Report
  • [Presentation] Crystal chemistry of synthetic mukhinite, V-analogue of clinozoisite, on the join Ca2Al3Si3O12(OH)-Ca2Al2VSi3O12(OH)2019

    • Author(s)
      Nagashima, M. , Nishio-Hamane, D., Nakano, N., and Kawasaki, T.
    • Organizer
      日本地球惑星科学連合 2019年大会
    • Related Report
      2019 Research-status Report
  • [Presentation] Crystal chemistry of hydrous pyroxenoids with three-periodic single-chain of SiO4 tetrahedra.2018

    • Author(s)
      Nagashima, M., Imaoka, T., Fukuda, C., and Pettke, T.
    • Organizer
      IMA2018 Melbourne, Australia
    • Related Report
      2018 Research-status Report
    • Int'l Joint Research / Invited

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Published: 2018-04-23   Modified: 2023-01-30  

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