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Fabrication of visible light responsive photocatalytic antibacterial titanium surgical implement through anodization in non-aqueous electrolyte

Research Project

Project/Area Number 18K04720
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Review Section Basic Section 26030:Composite materials and interfaces-related
Research InstitutionKitami Institute of Technology

Principal Investigator

Ohtsu Naofumi  北見工業大学, 工学部, 教授 (10400409)

Project Period (FY) 2018-04-01 – 2022-03-31
Project Status Completed (Fiscal Year 2021)
Budget Amount *help
¥4,420,000 (Direct Cost: ¥3,400,000、Indirect Cost: ¥1,020,000)
Fiscal Year 2020: ¥1,820,000 (Direct Cost: ¥1,400,000、Indirect Cost: ¥420,000)
Fiscal Year 2019: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000)
Fiscal Year 2018: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
Keywordsチタン材料 / 表面処理 / 抗菌被膜 / 可視応答性光触媒 / 陽極酸化処理 / 難剥離性 / 光触媒抗菌性 / 陽極酸化 / 非水溶媒 / 硝酸塩電解浴 / 硝酸塩電界浴 / 非水溶媒陽極酸化 / NドープTiO2被膜 / 抗菌性能 / 被膜耐久性 / 抗菌性チタン / 光触媒 / 可視応答性
Outline of Final Research Achievements

In this study, aiming to fabricate antibacterial titanium surgical instruments, titanium material was anodized using a nitrate electrolyte based on a non-aqueous solvent to form a visible-light responsive photocatalytic N-doped TiO2 layer. For this purpose, the interfacial reaction occurring between the material surface and electrolyte was analyzed in detail, followed by choosing an adequate electrolyte to form a highly-adhesive layer based on the above analysis, and then, we determined an appropriate nitrate concentration in the electrolyte in the view from high-performance photocatalytic layer. As a result, we found out that the 1.0 M nitrate electrolyte based on glycerol solvent is the adequate electrolyte among the testing electrolyte, and the fabricated TiO2 layer showed high performance antibacterial activity that exceeds a conventional TiO2 coating.

Academic Significance and Societal Importance of the Research Achievements

チタン材料は、高強度および高耐食性を有する材料であり、ヒトの体に触れて繰り返し用いられる医療用手術器具や各種民生品の素材としてその需要が急激に高まっている。本研究は、こういったチタン製品の表面に、高耐久性の抗菌被膜を簡単に形成できる技術の開発に成功したものである。細菌感染症だけでなく、ウイルスの接触感染のリスク低減に大きく寄与できる研究成果であり、国民の安全・安心な生活に大きく寄与する成果である。

Report

(5 results)
  • 2021 Annual Research Report   Final Research Report ( PDF )
  • 2020 Research-status Report
  • 2019 Research-status Report
  • 2018 Research-status Report
  • Research Products

    (25 results)

All 2021 2020 2019 2018 Other

All Journal Article (5 results) (of which Peer Reviewed: 4 results) Presentation (17 results) (of which Int'l Joint Research: 4 results) Remarks (3 results)

  • [Journal Article] Pulsed anodization of NiTi alloy to form a biofunctional Ni-free oxide layer for corrosion protection and hydrophilicity2021

    • Author(s)
      Ohtsu Naofumi、Yamasaki Kako、Taniho Hiroki、Konaka Yusuke、Tate Kasumi
    • Journal Title

      Surface and Coatings Technology

      Volume: 412 Pages: 127039-127039

    • DOI

      10.1016/j.surfcoat.2021.127039

    • Related Report
      2020 Research-status Report
    • Peer Reviewed
  • [Journal Article] Electrolyte effect in pulsed anodization of NiTi alloy to form a Ni-free oxide layer2021

    • Author(s)
      Yamasaki Kako、Taniho Hiroki、Tate Kasumi、Ohtsu Naofumi
    • Journal Title

      Surface and Coatings Technology

      Volume: 417 Pages: 127221-127221

    • DOI

      10.1016/j.surfcoat.2021.127221

    • Related Report
      2020 Research-status Report
    • Peer Reviewed
  • [Journal Article] Enhanced hardness and photocatalytic performance in anodic N-doped TiO2 layer on titanium using a non-aqueous nitrate electrolyte2020

    • Author(s)
      Yamaguchi Kaho、Konaka Yusuke、Ohtsu Naofumi
    • Journal Title

      Surface and Coatings Technology

      Volume: 386 Pages: 125424-125424

    • DOI

      10.1016/j.surfcoat.2020.125424

    • Related Report
      2019 Research-status Report
    • Peer Reviewed
  • [Journal Article] Effects of alcoholic solvents on the structure of anodized TiO2 layer grown in nitrate electrolyte2020

    • Author(s)
      Yamaguchi Kaho、Funane Yoshihiro、Ohtsu Naofumi
    • Journal Title

      Surface and Coatings Technology

      Volume: 387 Pages: 125469-125469

    • DOI

      10.1016/j.surfcoat.2020.125469

    • Related Report
      2019 Research-status Report
  • [Journal Article] Photocatalytic Performance of an Anodic TiO<sub>2</sub> Layer Fabricated in a NH<sub>4</sub>NO<sub>3</sub>/Ethylene Glycol Electrolyte with Various Crystallographic Phases2019

    • Author(s)
      Mingxue Bai, Shunya Nakazono, Kaho Yamaguchi, Naofumi Ohtsu
    • Journal Title

      MATERIALS TRANSACTIONS

      Volume: 60 Issue: 9 Pages: 1821-1827

    • DOI

      10.2320/matertrans.ME201915

    • NAID

      130007695404

    • ISSN
      1345-9678, 1347-5320
    • Year and Date
      2019-07-01
    • Related Report
      2018 Research-status Report
    • Peer Reviewed
  • [Presentation] 種硝酸塩非水溶媒陽極酸化で形成したTiO2皮膜チタン材料の抗ウイルス機能評価2021

    • Author(s)
      四辻聖,舟根啓宏,松井祐弥,大津直史
    • Organizer
      日本鉄鋼協会・日本金属学会両支部合同冬季講演大会
    • Related Report
      2021 Annual Research Report
  • [Presentation] 硝酸塩非水電解液による陽極酸化チタン皮膜の抗ウイルス機能評価2021

    • Author(s)
      四辻聖,舟根啓宏,松井祐弥,大津直史
    • Organizer
      日本金属学会2021年秋季大会
    • Related Report
      2021 Annual Research Report
  • [Presentation] 材料表面の抗ウイルス機能評価 -陽極酸化チタンの事例2021

    • Author(s)
      大津直史,四辻 聖,白川和哉
    • Organizer
      日本金属学会2022年春季大会
    • Related Report
      2021 Annual Research Report
  • [Presentation] Investigation of photocatalytic antiviral performance on an anodized titanium surface using a temperature-controlled alcoholic nitrate electrolyte2021

    • Author(s)
      Y. Yotsuji, Y. Funane, N. Ohtsu
    • Organizer
      Materials Research Meetin 2021, MRM2021
    • Related Report
      2021 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 電解液温度制御による硝酸塩/非水電解液陽極酸化チタン材料の機能向上2021

    • Author(s)
      舟根 啓宏,四辻 聖,大津直史
    • Organizer
      日本鉄鋼協会・日本金属学会両支部合同冬季講演大会
    • Related Report
      2020 Research-status Report
  • [Presentation] 温度制御非水電解液による陽極酸化チタン皮膜の性能調査2021

    • Author(s)
      舟根啓宏,四辻聖,大津直史
    • Organizer
      日本金属学会2021年春季講演大会
    • Related Report
      2020 Research-status Report
  • [Presentation] 電解液温度制御による硝酸塩/非水溶媒陽極酸化TiO2皮膜の高機能化2020

    • Author(s)
      舟根 啓宏,四辻 聖,大津直史
    • Organizer
      日本金属学会2020年秋季講演大会
    • Related Report
      2020 Research-status Report
  • [Presentation] 高温硝酸塩/エチレングリコール電解液陽極酸化を用いた光触媒抗菌チタンの高性能化2020

    • Author(s)
      舟根啓宏,山口花帆,大津直史
    • Organizer
      化学系学協会北海道支部2020年冬季研究会
    • Related Report
      2019 Research-status Report
  • [Presentation] 硝酸塩/アルコール溶媒電解液温度の陽極酸化の皮膜形成への影響2019

    • Author(s)
      舟根 啓宏,山口 花帆,大津 直史
    • Organizer
      日本鉄鋼協会・日本金属学会両支部合同サマーセッション
    • Related Report
      2019 Research-status Report
  • [Presentation] 硝酸塩/アルコール溶媒を用いたチタン陽極酸化 における溶媒種の影響2019

    • Author(s)
      山口 花帆,舟根 啓宏,大津 直史
    • Organizer
      日本鉄鋼協会・日本金属学会両支部合同サマーセッション
    • Related Report
      2019 Research-status Report
  • [Presentation] Fabrication of a photocatalytic antibacterial layer on a Ti material through anodization with nitrate/glycerol electrolyte2019

    • Author(s)
      K. Yamaguchi, Y. Konaka, N. Ohtsu
    • Organizer
      Anodizing Science Technology, AST 2019
    • Related Report
      2019 Research-status Report
    • Int'l Joint Research
  • [Presentation] Comparison of anodized layer on titanium using nitrate electrolyte in various alcohol solvents for investigating layer growth mechanism2019

    • Author(s)
      K. Yamaguchi, Y. Funane, N. Ohtsu
    • Organizer
      International Symposium for Advanced Materials Research, ISAMR 2019
    • Related Report
      2019 Research-status Report
    • Int'l Joint Research
  • [Presentation] Characteristics of anodic oxide layer on titanium substrate using nitrate electrolyte in various alcohols as solvent2019

    • Author(s)
      K. Yamaguchi, Y. Funane, Y. Konaka, N. Ohtsu
    • Organizer
      European Conference on Application of Surface and Interface Analysis, ECASIA 2019
    • Related Report
      2019 Research-status Report
    • Int'l Joint Research
  • [Presentation] グリセリン溶媒陽極酸化により作製した可視応答性NドープTiO2皮膜の抗菌機能2019

    • Author(s)
      山口花帆,古仲雄亮,大津直史
    • Organizer
      化学系学協会北海道支部2019年冬季研究発表会
    • Related Report
      2018 Research-status Report
  • [Presentation] グリセリン溶媒陽極酸化による抗菌性NドープTiO2被膜の作製2018

    • Author(s)
      山口花帆,古仲雄亮,大津直史
    • Organizer
      日本金属学会2018年秋季講演大会
    • Related Report
      2018 Research-status Report
  • [Presentation] グリセリン溶媒陽極酸化によるNドープTiO2被膜の作製とその光触媒機能評価2018

    • Author(s)
      山口花帆,古仲雄亮,山根美佐雄,大津直史
    • Organizer
      日本化学会北海道支部2018年夏季研究発表会
    • Related Report
      2018 Research-status Report
  • [Presentation] 有機溶媒陽極酸化により作製したNドープTiO2光触媒被膜の環境浄化性能2018

    • Author(s)
      山口花帆,古仲雄亮,山根美佐雄,大津直史
    • Organizer
      第34回分析化学緑陰セミナー
    • Related Report
      2018 Research-status Report
  • [Remarks] 北見工業大学 大津研究室 ホームページ

    • URL

      http://www.mtrl.kitami-it.ac.jp/~ohtsu/index.html

    • Related Report
      2021 Annual Research Report 2020 Research-status Report
  • [Remarks] 北見工業大学 大津研究室ホームページ

    • URL

      http://www.mtrl.kitami-it.ac.jp/~ohtsu/presentations.html

    • Related Report
      2019 Research-status Report
  • [Remarks] 大津研究室ホームページ

    • URL

      http://www.mtrl.kitami-it.ac.jp/~ohtsu/index.html

    • Related Report
      2018 Research-status Report

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Published: 2018-04-23   Modified: 2023-01-30  

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