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Study of multifunctional materials utilizing the spin state of cobalt

Research Project

Project/Area Number 18K04758
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Review Section Basic Section 26040:Structural materials and functional materials-related
Research InstitutionIbaraki National College of Technology

Principal Investigator

Sato Keisuke  茨城工業高等専門学校, 国際創造工学科, 准教授 (10418212)

Co-Investigator(Kenkyū-buntansha) 原 嘉昭  茨城工業高等専門学校, 国際創造工学科, 教授 (30331979)
松尾 晶  東京大学, 物性研究所, 技術専門職員 (70379311)
Project Period (FY) 2018-04-01 – 2021-03-31
Project Status Completed (Fiscal Year 2020)
Budget Amount *help
¥4,420,000 (Direct Cost: ¥3,400,000、Indirect Cost: ¥1,020,000)
Fiscal Year 2020: ¥650,000 (Direct Cost: ¥500,000、Indirect Cost: ¥150,000)
Fiscal Year 2019: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2018: ¥2,210,000 (Direct Cost: ¥1,700,000、Indirect Cost: ¥510,000)
Keywords磁気形状記憶効果 / コバルト酸化物 / スピン状態 / 磁歪 / コバルト / 透明絶縁体 / コバルトイオン / マルチファンクション材料
Outline of Final Research Achievements

We have for the first time identified an oxide that exhibits magnetic shape memory effect even at room temperature. The sample (La1-xSrxCoO (x=0.2)) elongated rapidly when a magnetic field was applied, and the elongation was maintained even when the field was removed. X-ray diffraction experiments showed that the fraction of crystalline domains changed, confirming that the magnetic field induced twinning deformation.
We have investigated the valence and spin states of Co in In2O3 doped with Co (In2-xCoxO3). We found that Co existed in a divalent high-spin state in the amount of Co doped was small (x <0.04). The amount of Co doping increased, Co existed in the low or intermediate spin state of trivalent.

Academic Significance and Societal Importance of the Research Achievements

従来,磁気形状記憶効果はほぼ金属合金の報告であったが,本研究により,室温でも酸化物において磁気形状記憶効果を確認することが出来た.絶縁体から金属まで導電性を制御できる酸化物において非接触アクチュエーターの可能性が示された.
希薄磁性酸化物中のコバルトは,従来,2価としてしか存在しないと考えられていたが,本研究により,3価としても存在することが確認された.3価のコバルトは,環境によってスピン状態が容易に変わるため,多彩な特性を示す可能性がある.

Report

(4 results)
  • 2020 Annual Research Report   Final Research Report ( PDF )
  • 2019 Research-status Report
  • 2018 Research-status Report
  • Research Products

    (12 results)

All 2021 2020 2019 2018

All Journal Article (3 results) (of which Peer Reviewed: 3 results,  Open Access: 1 results) Presentation (9 results)

  • [Journal Article] Room temperature magnetic shape-memory effect in strontium-doped lanthanum cobaltite single crystals2020

    • Author(s)
      A. Yokosuka, H. Kumagai, M. Fukuda, K. Ando, Y. Hara, and K. Sato
    • Journal Title

      AIP Advances

      Volume: 10 Issue: 9

    • DOI

      10.1063/5.0021751

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Two Spin-State Crystallizations in LaCoO32020

    • Author(s)
      Ikeda, Akihiko Matsuda, Yasuhiro H. Sato, Keisuke
    • Journal Title

      Phys. Rev. Lett.

      Volume: 125 Issue: 17

    • DOI

      10.1103/physrevlett.125.177202

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Site occupancy, valence state, and spin state of Co ions in Co-doped In2O3 diluted magnetic semiconductor2019

    • Author(s)
      H.Kumagai, Y.Hara, K.Sato
    • Journal Title

      Journal of Magnetism and Magnetic Materials

      Volume: 489 Pages: 1653581-8

    • DOI

      10.1016/j.jmmm.2019.165358

    • Related Report
      2019 Research-status Report
    • Peer Reviewed
  • [Presentation] 微少量のコバルトを含む絶縁体(LaAlO3)の結晶作製と磁化特性2021

    • Author(s)
      高梨仁希, 原嘉昭, 佐藤桂輔
    • Organizer
      日本物理学会
    • Related Report
      2020 Annual Research Report
  • [Presentation] Excitonic phases in LaCoO3: A magnetostriction study up to 600 T2021

    • Author(s)
      池田暁彦, 松田康弘, 佐藤桂輔B, 石井裕人, 中村大輔, 澤部博信, 嶽山正二郎, 那須譲治C,東大物性研, 茨城高専B, 横浜国立C
    • Organizer
      日本物理学会
    • Related Report
      2020 Annual Research Report
  • [Presentation] Two spin state crystallizations in LaCoO3 at ultrahigh magnetic field2020

    • Author(s)
      池田暁彦, 松田康弘, 佐藤桂輔A, 津田浩B,東大物性研, 茨城高専A, 産総研B
    • Organizer
      日本物理学会
    • Related Report
      2020 Annual Research Report
  • [Presentation] (La,Sr)CoO3の磁歪の温度依存性2020

    • Author(s)
      横須賀歩, 熊谷ひかる, 福田真嬉, 原嘉昭, 佐藤桂輔
    • Organizer
      日本物理学会
    • Related Report
      2019 Research-status Report
  • [Presentation] 磁化・磁歪計測によるLaCoO3の磁場誘起スピン状態秩序とB-T相図2019

    • Author(s)
      池田暁彦, 松田康弘, 佐藤桂輔
    • Organizer
      日本物理学会
    • Related Report
      2019 Research-status Report
  • [Presentation] 微少なコバルトをドープしたTiO2の単結晶育成および磁気特性2019

    • Author(s)
      熊谷ひかる, 小針采子, 高木愛海, 佐藤桂輔, 原嘉昭
    • Organizer
      日本物理学会
    • Related Report
      2018 Research-status Report
  • [Presentation] 微少量のコバルトを含むIn2O3の磁気特性2018

    • Author(s)
      熊谷ひかる, 佐藤桂輔, 原嘉昭
    • Organizer
      日本物理学会
    • Related Report
      2018 Research-status Report
  • [Presentation] Magnetostriction study of field-induced spin-state transitions of LaCoO32018

    • Author(s)
      池田暁彦, 中村大輔, 松田康弘, 嶽山正二郎, 佐藤桂輔
    • Organizer
      日本物理学会
    • Related Report
      2018 Research-status Report
  • [Presentation] 微少なコバルトをドープした(In, La)2O3の磁気特性2018

    • Author(s)
      熊谷ひかる, 佐藤桂輔, 原嘉昭, 福田真嬉, 横須賀歩
    • Organizer
      日本物理学会
    • Related Report
      2018 Research-status Report

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Published: 2018-04-23   Modified: 2022-01-27  

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