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Is an in-situ gas environment TEM truly showing the reaction between materials and gases?

Research Project

Project/Area Number 18K04824
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Review Section Basic Section 27020:Chemical reaction and process system engineering-related
Research InstitutionNagoya University

Principal Investigator

Tokunaga Tomoharu  名古屋大学, 工学研究科, 助教 (90467332)

Project Period (FY) 2018-04-01 – 2021-03-31
Project Status Completed (Fiscal Year 2020)
Budget Amount *help
¥4,420,000 (Direct Cost: ¥3,400,000、Indirect Cost: ¥1,020,000)
Fiscal Year 2020: ¥650,000 (Direct Cost: ¥500,000、Indirect Cost: ¥150,000)
Fiscal Year 2019: ¥780,000 (Direct Cost: ¥600,000、Indirect Cost: ¥180,000)
Fiscal Year 2018: ¥2,990,000 (Direct Cost: ¥2,300,000、Indirect Cost: ¥690,000)
Keywordsガス環境TEM / イオン化 / 窒素 / 原子状窒素 / プラズマ環境 / 電子線照射 / イオン / 窒化
Outline of Final Research Achievements

It was found that ions and electrons associated with the ionization of gas molecule were generated in the nitrogen gas atmosphere during electron beam (EB) irradiation, and the generated ions were found to be N2+ ions. This result indicates that not only gas but also ions are present in the gas environment during EB irradiation. When Cr2O3 was kept in this atmosphere, it was found to be nitrided. Researchers should consider the effect of ions when observing specimens in a gas atmosphere during EB irradiation.

Academic Significance and Societal Importance of the Research Achievements

ガスと材料の反応を観察することが可能と考えられてきたガス環境その場観察手法は,ガスと材料の反応だけではなく,電子線照射に伴って発生するイオンとの反応が含まれる可能性が考えられた.ガス環境その場観察から得られた研究成果を再検証する必要があると共に,発生するイオンを除去した環境を形成する必要があると考えられた.

Report

(4 results)
  • 2020 Annual Research Report   Final Research Report ( PDF )
  • 2019 Research-status Report
  • 2018 Research-status Report
  • Research Products

    (8 results)

All 2020 2019 2018

All Journal Article (1 results) (of which Peer Reviewed: 1 results) Presentation (6 results) (of which Int'l Joint Research: 1 results) Book (1 results)

  • [Journal Article] Removal of carbon contamination in ETEM by introducing Ar during electron beam irradiation2018

    • Author(s)
      TOKUNAGA T.、SAITO K.、KUNO K.、HIGUCHI K.、YAMAMOTO Y.、YAMAMOTO T.
    • Journal Title

      Journal of Microscopy

      Volume: 273 Issue: 1 Pages: 46-52

    • DOI

      10.1111/jmi.12759

    • Related Report
      2018 Research-status Report
    • Peer Reviewed
  • [Presentation] ガス環境TEM 内に形成されるイオン環境の解析と窒素イオンによる金属の窒化反応2020

    • Author(s)
      徳永智春, 樋口公孝, 山本悠太, 河上 匠, 山本剛久
    • Organizer
      日本顕微鏡学会 第76回学術講演会
    • Related Report
      2020 Annual Research Report
  • [Presentation] ガス環境TEM内に発生するイオンと活性元素発生の可能性2020

    • Author(s)
      徳永智春, 河上 匠, 樋口公孝, 山本悠太, 山本剛久
    • Organizer
      日本県境学会 第63回シンポジウム
    • Related Report
      2020 Annual Research Report
  • [Presentation] ガス環境TEM観察中に発生するイオン環境の調査2020

    • Author(s)
      徳永 智春,河上 匠,大川原 彩恵,樋口 公孝,山本 悠太,山本 剛久
    • Organizer
      応用物理学会
    • Related Report
      2019 Research-status Report
  • [Presentation] Estimation of Ion Atmosphere Generated inside ETEM during Electron Beam Irradiation2019

    • Author(s)
      Tomoharu Tokunaga, Takumi Kawakami, Kimitaka Higuchi, Yuta Yamamoto, Takahisa Yamamoto
    • Organizer
      AMTC6
    • Related Report
      2019 Research-status Report
    • Int'l Joint Research
  • [Presentation] 窒素雰囲気への電子線照射時に形成されるイオン環境の解析2019

    • Author(s)
      河上 匠,樋口公孝,山本悠太,徳永智春,山本剛久
    • Organizer
      顕微鏡学会
    • Related Report
      2019 Research-status Report
  • [Presentation] 電子線照射中におけるTEM内Ar雰囲気に発生するイオン環境2018

    • Author(s)
      徳永智春,川上匠,久野孝平,樋口公孝,山本悠太,山本剛久
    • Organizer
      第79回応用物理学会秋季学術講演会
    • Related Report
      2018 Research-status Report
  • [Book] 金属ナノ粒子の合成/構造制御とペースト化及び最新応用展開2020

    • Author(s)
      米澤 徹 他
    • Total Pages
      354
    • Publisher
      R&D支援センター
    • Related Report
      2020 Annual Research Report

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Published: 2018-04-23   Modified: 2022-01-27  

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